JP4921529B2 - 銅転炉ダストの処理方法 - Google Patents
銅転炉ダストの処理方法 Download PDFInfo
- Publication number
- JP4921529B2 JP4921529B2 JP2009176410A JP2009176410A JP4921529B2 JP 4921529 B2 JP4921529 B2 JP 4921529B2 JP 2009176410 A JP2009176410 A JP 2009176410A JP 2009176410 A JP2009176410 A JP 2009176410A JP 4921529 B2 JP4921529 B2 JP 4921529B2
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- JP
- Japan
- Prior art keywords
- treatment
- copper
- solution
- sulfuric acid
- converter dust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 73
- 229910052802 copper Inorganic materials 0.000 title claims description 73
- 239000010949 copper Substances 0.000 title claims description 73
- 238000000034 method Methods 0.000 title claims description 33
- 239000000428 dust Substances 0.000 title claims description 31
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 68
- 229910052785 arsenic Inorganic materials 0.000 claims description 34
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 33
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 32
- 229910052725 zinc Inorganic materials 0.000 claims description 32
- 239000011701 zinc Substances 0.000 claims description 32
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 28
- 229910052793 cadmium Inorganic materials 0.000 claims description 26
- 238000006386 neutralization reaction Methods 0.000 claims description 23
- 238000002386 leaching Methods 0.000 claims description 17
- 238000005987 sulfurization reaction Methods 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 6
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 35
- 238000005486 sulfidation Methods 0.000 description 21
- 238000003723 Smelting Methods 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000012545 processing Methods 0.000 description 8
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 6
- -1 arsenic ions Chemical class 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229910052797 bismuth Inorganic materials 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 2
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 2
- 229940007718 zinc hydroxide Drugs 0.000 description 2
- ZDFBXXSHBTVQMB-UHFFFAOYSA-N 2-ethylhexoxy(2-ethylhexyl)phosphinic acid Chemical compound CCCCC(CC)COP(O)(=O)CC(CC)CCCC ZDFBXXSHBTVQMB-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
- Physical Water Treatments (AREA)
- Removal Of Specific Substances (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009176410A JP4921529B2 (ja) | 2009-07-29 | 2009-07-29 | 銅転炉ダストの処理方法 |
CL2010000811A CL2010000811A1 (es) | 2009-07-29 | 2010-07-29 | Metodo para el procesamiento de polvo de convertidor de cobre que comprende un proceso de lixiviacion para remover plomo y otros metales insolubles a partir del polvo de convertidor de cobre, sulfidizacion recuperando el cobre y el arsenico, y neutralizacion de solucion resultante recuperando el cinc y el cadmio. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009176410A JP4921529B2 (ja) | 2009-07-29 | 2009-07-29 | 銅転炉ダストの処理方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011026687A JP2011026687A (ja) | 2011-02-10 |
JP4921529B2 true JP4921529B2 (ja) | 2012-04-25 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2009176410A Active JP4921529B2 (ja) | 2009-07-29 | 2009-07-29 | 銅転炉ダストの処理方法 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP4921529B2 (es) |
CL (1) | CL2010000811A1 (es) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104528993A (zh) * | 2014-12-18 | 2015-04-22 | 湖北师范学院 | 一种利用烟气中so2处理含砷废水的方法 |
CN105624412A (zh) * | 2016-01-18 | 2016-06-01 | 中南大学 | 一种铜烟灰冶选联合处理的方法 |
CN109266859A (zh) * | 2018-10-12 | 2019-01-25 | 湖北大江环保科技股份有限公司 | 一种高压浸出奥炉烟灰的方法 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102517449A (zh) * | 2011-12-16 | 2012-06-27 | 山东方圆有色金属技术服务有限公司 | 一种冶炼烟灰有价元素综合回收工艺 |
KR101503750B1 (ko) | 2013-10-01 | 2015-03-24 | 주식회사 동산에스엔알 | 금속아연 회수방법 |
JP6015824B2 (ja) * | 2015-07-30 | 2016-10-26 | 住友金属鉱山株式会社 | 銅製錬煙灰の処理方法 |
CN105567984B (zh) * | 2016-01-18 | 2017-07-07 | 中南大学 | 一种铜烟灰控电位选择分离的方法 |
JP6743491B2 (ja) * | 2016-05-31 | 2020-08-19 | 住友金属鉱山株式会社 | 廃酸の処理方法 |
JP7031207B2 (ja) * | 2017-10-05 | 2022-03-08 | 住友金属鉱山株式会社 | 銅製錬において発生する廃酸の処理方法 |
CN107628710A (zh) * | 2017-11-07 | 2018-01-26 | 长沙埃比林环保科技有限公司 | 一种无机凝聚法处理含铅废水的方法 |
JP7415275B2 (ja) | 2019-06-21 | 2024-01-17 | 住友金属鉱山株式会社 | カドミウム溶液の製造方法 |
CN111363928B (zh) * | 2020-04-07 | 2021-07-09 | 云南驰宏资源综合利用有限公司 | 一种高砷铅锌烟尘硫酸浸出时抑制砷化氢气体的方法 |
CN112195346A (zh) * | 2020-10-09 | 2021-01-08 | 长沙矿冶研究院有限责任公司 | 一种铜铅火法冶炼含砷烟灰转化浸出脱除砷的工艺 |
CN113088708A (zh) * | 2021-03-30 | 2021-07-09 | 中南大学 | 一种炼铜白烟尘与污酸资源化协同处理回收多金属的方法 |
CN113444886B (zh) * | 2021-07-21 | 2022-12-06 | 东北大学 | 一种铜冶炼烟尘的有价元素浸出回收方法 |
CN113549766B (zh) * | 2021-07-21 | 2022-11-04 | 东北大学 | 一种铅冶炼烟尘脱砷并回收有价金属的方法 |
CN113957251A (zh) * | 2021-09-26 | 2022-01-21 | 济源豫光有色冶金设计研究院有限公司 | 用废铅蓄电池酸无害化处理铜烟灰并回收多种金属的方法 |
KR102678814B1 (ko) * | 2022-03-21 | 2024-06-26 | 전남대학교산학협력단 | 아연, 구리 폐기물로부터 용매추출을 이용한 유가금속 회수방법 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5175616A (es) * | 1974-12-26 | 1976-06-30 | Hachinohe Smelting Co | |
JPS595655B2 (ja) * | 1980-05-27 | 1984-02-06 | 同和鉱業株式会社 | 銅の回収法 |
JPS57201577A (en) * | 1981-06-03 | 1982-12-10 | Sumitomo Metal Mining Co Ltd | Treatment of smelter smoke ash containing copper |
JPS58141346A (ja) * | 1982-02-15 | 1983-08-22 | Dowa Mining Co Ltd | 産業副産物からの金属採取法 |
JP3825537B2 (ja) * | 1997-08-01 | 2006-09-27 | 同和鉱業株式会社 | As含有排水の処理方法 |
JP4478585B2 (ja) * | 2005-01-17 | 2010-06-09 | 日鉱金属株式会社 | 飛灰からの有価物回収方法 |
JP4817005B2 (ja) * | 2005-09-29 | 2011-11-16 | Jx日鉱日石金属株式会社 | 銅転炉ダストの処理方法 |
-
2009
- 2009-07-29 JP JP2009176410A patent/JP4921529B2/ja active Active
-
2010
- 2010-07-29 CL CL2010000811A patent/CL2010000811A1/es unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104528993A (zh) * | 2014-12-18 | 2015-04-22 | 湖北师范学院 | 一种利用烟气中so2处理含砷废水的方法 |
CN105624412A (zh) * | 2016-01-18 | 2016-06-01 | 中南大学 | 一种铜烟灰冶选联合处理的方法 |
CN109266859A (zh) * | 2018-10-12 | 2019-01-25 | 湖北大江环保科技股份有限公司 | 一种高压浸出奥炉烟灰的方法 |
Also Published As
Publication number | Publication date |
---|---|
CL2010000811A1 (es) | 2011-03-11 |
JP2011026687A (ja) | 2011-02-10 |
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