JP4890256B2 - 人工毛髪用繊維及びその製造方法 - Google Patents
人工毛髪用繊維及びその製造方法 Download PDFInfo
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- JP4890256B2 JP4890256B2 JP2006539210A JP2006539210A JP4890256B2 JP 4890256 B2 JP4890256 B2 JP 4890256B2 JP 2006539210 A JP2006539210 A JP 2006539210A JP 2006539210 A JP2006539210 A JP 2006539210A JP 4890256 B2 JP4890256 B2 JP 4890256B2
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- vinyl chloride
- fiber
- mass
- vinyl
- artificial hair
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- 239000000835 fiber Substances 0.000 title claims description 54
- 210000004209 hair Anatomy 0.000 title claims description 48
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 53
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 36
- 229920005989 resin Polymers 0.000 claims description 35
- 239000011347 resin Substances 0.000 claims description 35
- 229920006312 vinyl chloride fiber Polymers 0.000 claims description 34
- 229920006163 vinyl copolymer Polymers 0.000 claims description 31
- 239000011342 resin composition Substances 0.000 claims description 29
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 17
- 238000002074 melt spinning Methods 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000000034 method Methods 0.000 description 15
- 229920006026 co-polymeric resin Polymers 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 229920001519 homopolymer Polymers 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- -1 compatibilizers Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000012760 heat stabilizer Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- BSVVEHIYIQCYHQ-UHFFFAOYSA-N butyl prop-2-enoate;chloroethene Chemical compound ClC=C.CCCCOC(=O)C=C BSVVEHIYIQCYHQ-UHFFFAOYSA-N 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- BMZQPXKCLRADET-UHFFFAOYSA-N chloroethene;2-ethylhexyl prop-2-enoate Chemical compound ClC=C.CCCCC(CC)COC(=O)C=C BMZQPXKCLRADET-UHFFFAOYSA-N 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- BCBHWVAFKCCWBG-UHFFFAOYSA-N chloroethene;ethenyl propanoate Chemical compound ClC=C.CCC(=O)OC=C BCBHWVAFKCCWBG-UHFFFAOYSA-N 0.000 description 1
- GRFFKYTUNTWAGG-UHFFFAOYSA-N chloroethene;prop-2-enenitrile Chemical compound ClC=C.C=CC#N GRFFKYTUNTWAGG-UHFFFAOYSA-N 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000006084 composite stabilizer Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/48—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
(a)塩化ビニル系樹脂(大洋塩ビ株式会社製、TH−1000)100質量部、ビニル系共重合体を構成するモノマーの割合がスチレン80質量%及びアクリロニトリル20質量%であるビニル系共重合体(電気化学工業株式会社製、AS−3)20質量部、ハイドロタルサイト熱安定剤及びCa−Zn金属石鹸安定剤にポリエチレンワックス及び特殊脂肪酸エステルの滑剤をパック化して得た複合安定剤・滑剤(日産化学工業株式会社製、CP−410A)8質量部、並びに、亜リン酸エステル熱安定剤(旭電化工業株式会社製、アデカスタブ1500)1質量部を配合してなる樹脂組成物をヘンシェルミキサで混合する工程、(b)前記混合した樹脂組成物をノズル断面積0.06mm2、孔数120、及び、金型温度180℃の紡糸金型から押出し量10kg/時間で溶融紡糸して150デニールの繊維とする工程、(c)前記溶融紡糸した繊維を100℃の空気雰囲気下で300%に延伸して50デニールの繊維とする工程、そして、(d)前記延伸した繊維に120℃の空気雰囲気下で繊維全長が処理前の75%の長さに収縮するまで熱弛緩処理を施す工程を順次経て、67デニールの塩化ビニル系繊維を得た。
実施例1の(a)工程の樹脂組成物におけるビニル系共重合体を構成するモノマーの割合をスチレン20質量%、アクリロニトリル5質量%、及び、メチルメタクリレート75質量%とした以外は、実施例1と同様にして塩化ビニル系繊維を得た。
実施例1の(a)工程の樹脂組成物におけるビニル系共重合体を構成するモノマーの割合をスチレン70質量%、及び、アクリロニトリル30質量%とした以外は、実施例1と同様にして塩化ビニル系繊維を得た。
実施例1の(a)工程の樹脂組成物におけるビニル系共重合体を構成するモノマーの割合をスチレン10質量%、及び、メチルメタクリレート90質量%とした以外は、実施例1と同様にして塩化ビニル系繊維を得た。
実施例1の(a)工程の樹脂組成物におけるビニル系共重合体の配合量を3質量部とした以外は、実施例1と同様にして塩化ビニル系繊維を得た。
実施例1の(a)工程の樹脂組成物におけるビニル系共重合体の配合量を60質量部とした以外は、実施例1と同様にして塩化ビニル系繊維を得た。
○:角度比が0.85以上で、カールが均一にかかり合格であるもの
×:角度比が0.85未満で、カールが不均一にかかり不合格であるもの
で評価した。
○:糸切れ頻度において、1時間当たり、0回で生産性の点でより効果が上がったもの
△:2回以下でロングラン製造対象製品として問題がないもの
×:3回以上でロングラン製造対象製品として成り立たないもの
で評価した。
Claims (4)
- (A)塩化ビニル系樹脂100質量部、並びに、(B)スチレン70〜90質量%とアクリロニトリル30〜10質量%とを重合含有するビニル系共重合体5〜50質量部、を含有する塩化ビニル系樹脂組成物で構成されていることを特徴とする人工毛髪用繊維。
- (A)塩化ビニル系樹脂100質量部、並びに、(B)スチレン10〜40質量%とメチルメタリレート90〜50質量%とアクリロニトリル0〜10質量%とを重合含有するビニル系共重合体5〜50質量部、を含有する塩化ビニル系樹脂組成物で構成されていることを特徴とする人工毛髪用繊維。
- 請求項1又は2に記載の塩化ビニル系樹脂組成物を170〜190℃の温度で溶融紡糸することを特徴とする人工毛髪用繊維の製造方法。
- 前記溶融紡糸した塩化ビニル系繊維を90〜120℃の温度に保持した空気雰囲気下で2〜4倍まで延伸した後、この延伸した塩化ビニル系繊維を110〜140℃の温度に保持した空気雰囲気下で延伸前の60〜100%の長さになるまで熱弛緩させることを特徴とする請求項3に記載の人工毛髪用繊維の製造方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP2006539210A JP4890256B2 (ja) | 2004-10-01 | 2005-09-15 | 人工毛髪用繊維及びその製造方法 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004289563 | 2004-10-01 | ||
JP2004289563 | 2004-10-01 | ||
JP2006539210A JP4890256B2 (ja) | 2004-10-01 | 2005-09-15 | 人工毛髪用繊維及びその製造方法 |
PCT/JP2005/017048 WO2006038447A1 (ja) | 2004-10-01 | 2005-09-15 | 塩化ビニル系樹脂組成物、塩化ビニル系繊維及びその製造方法、並びに、人工毛髪用繊維 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2006038447A1 JPWO2006038447A1 (ja) | 2008-07-31 |
JP4890256B2 true JP4890256B2 (ja) | 2012-03-07 |
Family
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Family Applications (1)
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JP2006539210A Active JP4890256B2 (ja) | 2004-10-01 | 2005-09-15 | 人工毛髪用繊維及びその製造方法 |
Country Status (2)
Country | Link |
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JP (1) | JP4890256B2 (ja) |
WO (1) | WO2006038447A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20210246294A1 (en) * | 2018-03-20 | 2021-08-12 | Denka Company Limited | Fiber for artificial hair and hair accessory product |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AP2015008880A0 (en) * | 2013-06-06 | 2015-11-30 | Kaneka Corp | Fiber bundle for hair and head accessory |
JP6216228B2 (ja) * | 2013-11-13 | 2017-10-18 | 旭化成株式会社 | 繊維及び不織布 |
WO2019235055A1 (ja) * | 2018-06-07 | 2019-12-12 | デンカ株式会社 | 人工毛髪用繊維及び頭髪装飾製品 |
WO2023021883A1 (ja) * | 2021-08-20 | 2023-02-23 | デンカ株式会社 | 人工毛髪用繊維、人工毛髪用繊維束及び頭髪装飾製品 |
WO2023145171A1 (ja) * | 2022-01-25 | 2023-08-03 | デンカ株式会社 | 人工毛髪用繊維及び頭髪装飾製品 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4882118A (ja) * | 1972-02-12 | 1973-11-02 | ||
JPH0673609A (ja) * | 1992-08-28 | 1994-03-15 | Asahi Chem Ind Co Ltd | 塩化ビニリデン系繊維の製造法 |
JPH06220712A (ja) * | 1993-01-22 | 1994-08-09 | Asahi Chem Ind Co Ltd | 合成樹脂繊維 |
JPH11140334A (ja) * | 1997-11-11 | 1999-05-25 | Tosoh Corp | 樹脂組成物 |
JP2001131824A (ja) * | 1999-10-28 | 2001-05-15 | Kanegafuchi Chem Ind Co Ltd | ポリ塩化ビニル系樹脂組成物よりなる繊維 |
JP2004360090A (ja) * | 2003-06-02 | 2004-12-24 | Kaneka Corp | 難燃繊維複合体 |
-
2005
- 2005-09-15 JP JP2006539210A patent/JP4890256B2/ja active Active
- 2005-09-15 WO PCT/JP2005/017048 patent/WO2006038447A1/ja active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4882118A (ja) * | 1972-02-12 | 1973-11-02 | ||
JPH0673609A (ja) * | 1992-08-28 | 1994-03-15 | Asahi Chem Ind Co Ltd | 塩化ビニリデン系繊維の製造法 |
JPH06220712A (ja) * | 1993-01-22 | 1994-08-09 | Asahi Chem Ind Co Ltd | 合成樹脂繊維 |
JPH11140334A (ja) * | 1997-11-11 | 1999-05-25 | Tosoh Corp | 樹脂組成物 |
JP2001131824A (ja) * | 1999-10-28 | 2001-05-15 | Kanegafuchi Chem Ind Co Ltd | ポリ塩化ビニル系樹脂組成物よりなる繊維 |
JP2004360090A (ja) * | 2003-06-02 | 2004-12-24 | Kaneka Corp | 難燃繊維複合体 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20210246294A1 (en) * | 2018-03-20 | 2021-08-12 | Denka Company Limited | Fiber for artificial hair and hair accessory product |
Also Published As
Publication number | Publication date |
---|---|
WO2006038447A1 (ja) | 2006-04-13 |
JPWO2006038447A1 (ja) | 2008-07-31 |
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