JP4758650B2 - １−ブテンポリマーの製造方法 - Google Patents

１−ブテンポリマーの製造方法 Download PDF

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Publication number
JP4758650B2
JP4758650B2 JP2004556103A JP2004556103A JP4758650B2 JP 4758650 B2 JP4758650 B2 JP 4758650B2 JP 2004556103 A JP2004556103 A JP 2004556103A JP 2004556103 A JP2004556103 A JP 2004556103A JP 4758650 B2 JP4758650 B2 JP 4758650B2
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Japan
Prior art keywords
formula
group
compound
alkyl
butene
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Expired - Lifetime
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JP2004556103A
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Japanese (ja)
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JP2006509059A5 (enExample
JP2006509059A (ja
Inventor
レスコニ，ルイジ
イングルジオ，アントニオ カスチオ
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バーゼル・ポリオレフィン・ゲーエムベーハー
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
JP2004556103A 2002-12-04 2003-11-03 １−ブテンポリマーの製造方法 Expired - Lifetime JP4758650B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP02080120 2002-12-04
EP02080120.5 2002-12-04
US43180302P 2002-12-09 2002-12-09
US60/431,803 2002-12-09
PCT/EP2003/012236 WO2004050724A1 (en) 2002-12-04 2003-11-03 Process for preparing 1-butene polymers

Publications (3)

Publication Number Publication Date
JP2006509059A JP2006509059A (ja) 2006-03-16
JP2006509059A5 JP2006509059A5 (enExample) 2006-12-14
JP4758650B2 true JP4758650B2 (ja) 2011-08-31

Family

ID=44597271

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004556103A Expired - Lifetime JP4758650B2 (ja) 2002-12-04 2003-11-03 １−ブテンポリマーの製造方法

Country Status (7)

Country Link
EP (1) EP1567565B1 (enExample)
JP (1) JP4758650B2 (enExample)
KR (1) KR101059401B1 (enExample)
AT (1) ATE383379T1 (enExample)
AU (1) AU2003276242A1 (enExample)
DE (1) DE60318616T2 (enExample)
WO (1) WO2004050724A1 (enExample)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002100908A1 (en) 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
EP1549688A2 (en) 2002-10-10 2005-07-06 Basell Polyolefine GmbH Process for the copolymerization of ethylene
DE60329523D1 (de) 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE10358082A1 (de) * 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
KR20070039930A (ko) * 2004-07-08 2007-04-13 엑손모빌 케미칼 패턴츠 인코포레이티드 초임계 조건에서 중합체의 제조방법
EP1858934B1 (en) 2005-03-18 2013-04-24 Basell Polyolefine GmbH Metallocene compounds
PL1858907T3 (pl) 2005-03-18 2009-04-30 Basell Polyolefine Gmbh Metalocenowe związki
CN101146836B (zh) 2005-03-23 2011-06-08 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
WO2006100258A1 (en) 2005-03-23 2006-09-28 Basell Polyolefine Gmbh Process for the polymerization of olefins
WO2006117285A1 (en) 2005-05-03 2006-11-09 Basell Polyolefine Gmbh Process for the polymerization of alpha olefins
EP1879959B1 (en) 2005-05-11 2011-07-06 Basell Poliolefine Italia S.r.l. Polymerization process for preparing polyolefin blends
ATE526337T1 (de) 2006-03-17 2011-10-15 Basell Polyolefine Gmbh Metallocenverbindungen
JP2009533382A (ja) 2006-04-12 2009-09-17 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
US8785575B2 (en) * 2006-04-21 2014-07-22 Basell Polyolefine Gmbh Process for the preparation of ethylene propylene copolymers
JP5295098B2 (ja) * 2006-04-21 2013-09-18 バーゼル・ポリオレフィン・ゲーエムベーハー エチレンコポリマーの製造方法
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
EP2402354B1 (en) * 2010-07-01 2016-03-02 Borealis AG Process for olefin polymerisation using group 4 metallocene as catalysts
JP5966321B2 (ja) * 2010-11-19 2016-08-10 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
JP5826913B2 (ja) * 2011-03-25 2015-12-02 エクソンモービル ケミカル パテンツ インコーポレイテッド ビニル末端高級オレフィンポリマー及びその製造方法
JP5880000B2 (ja) * 2011-12-14 2016-03-08 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
KR101640356B1 (ko) 2012-09-25 2016-07-15 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체의 제조 방법 및 올레핀 중합체
ES2711081T3 (es) 2012-10-18 2019-04-30 Borealis Ag Catalizador para la polimerización de olefinas
EP2722344B1 (en) 2012-10-18 2017-03-22 Borealis AG Polymerisation process
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
JP6264808B2 (ja) * 2013-09-26 2018-01-24 日本ポリプロ株式会社 メタロセン化合物及びそれを使用する重合触媒によるオレフィン重合体の製造方法
SG11201701851XA (en) 2014-09-11 2017-04-27 Mitsui Chemicals Inc Production method of olefin (co)polymer containing constituent unit derived from 1-butene
JP6921563B2 (ja) * 2017-03-07 2021-08-18 出光興産株式会社 遷移金属化合物及びオレフィン系重合体の製造方法
EP4316834A4 (en) 2021-03-31 2025-03-26 Mitsui Chemicals, Inc. ETHYLENE-A-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION AND FILM
US20240191068A1 (en) 2021-03-31 2024-06-13 Mitsui Chemicals, Inc. Ethylene resin composition and shaped article
JP7681097B2 (ja) 2021-03-31 2025-05-21 三井化学株式会社 エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、フィルムおよび積層体

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06184179A (ja) * 1991-11-30 1994-07-05 Hoechst Ag 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途
JPH07196718A (ja) * 1993-12-28 1995-08-01 Mitsui Petrochem Ind Ltd 予備重合触媒、オレフィン重合用触媒およびオレフィンの重合方法
JPH09202795A (ja) * 1995-04-24 1997-08-05 Mitsui Toatsu Chem Inc キラルな新規メタロセン化合物とその合成方法及びそれを用いたオレフィンの重合方法
JPH10298219A (ja) * 1997-04-30 1998-11-10 Mitsui Chem Inc 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分
JPH11286519A (ja) * 1998-04-02 1999-10-19 Mitsui Chem Inc オレフィンの重合方法
JP2001081124A (ja) * 1999-09-17 2001-03-27 Sumitomo Chem Co Ltd 付加重合用触媒、およびオレフィン重合体の製造方法
JP2002506074A (ja) * 1998-03-11 2002-02-26 ザ ダウ ケミカル カンパニー ジエン錯体を製造するための統合方法
JP2002220503A (ja) * 2000-11-24 2002-08-09 Idemitsu Petrochem Co Ltd ポリオレフィン系樹脂組成物とその成形体及びフィルム
JP2003516420A (ja) * 1999-12-10 2003-05-13 ダウ グローバル テクノロジーズ インコーポレーテッド 置換４族金属錯体、触媒及びオレフィン重合法

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US6479424B1 (en) * 1998-12-14 2002-11-12 Bp Corporation North America Inc. Fluxional catalysts and related ligands containing bulky substituents
WO2002100908A1 (en) * 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06184179A (ja) * 1991-11-30 1994-07-05 Hoechst Ag 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途
JPH07196718A (ja) * 1993-12-28 1995-08-01 Mitsui Petrochem Ind Ltd 予備重合触媒、オレフィン重合用触媒およびオレフィンの重合方法
JPH09202795A (ja) * 1995-04-24 1997-08-05 Mitsui Toatsu Chem Inc キラルな新規メタロセン化合物とその合成方法及びそれを用いたオレフィンの重合方法
JPH10298219A (ja) * 1997-04-30 1998-11-10 Mitsui Chem Inc 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分
JP2002506074A (ja) * 1998-03-11 2002-02-26 ザ ダウ ケミカル カンパニー ジエン錯体を製造するための統合方法
JPH11286519A (ja) * 1998-04-02 1999-10-19 Mitsui Chem Inc オレフィンの重合方法
JP2001081124A (ja) * 1999-09-17 2001-03-27 Sumitomo Chem Co Ltd 付加重合用触媒、およびオレフィン重合体の製造方法
JP2003516420A (ja) * 1999-12-10 2003-05-13 ダウ グローバル テクノロジーズ インコーポレーテッド 置換４族金属錯体、触媒及びオレフィン重合法
JP2002220503A (ja) * 2000-11-24 2002-08-09 Idemitsu Petrochem Co Ltd ポリオレフィン系樹脂組成物とその成形体及びフィルム

Also Published As

Publication number Publication date
WO2004050724A1 (en) 2004-06-17
DE60318616D1 (de) 2008-02-21
KR101059401B1 (ko) 2011-08-29
KR20050089028A (ko) 2005-09-07
AU2003276242A1 (en) 2004-06-23
JP2006509059A (ja) 2006-03-16
EP1567565A1 (en) 2005-08-31
EP1567565B1 (en) 2008-01-09
DE60318616T2 (de) 2009-01-08
ATE383379T1 (de) 2008-01-15

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