JP4758650B2 - 1−ブテンポリマーの製造方法 - Google Patents

1−ブテンポリマーの製造方法 Download PDF

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Publication number
JP4758650B2
JP4758650B2 JP2004556103A JP2004556103A JP4758650B2 JP 4758650 B2 JP4758650 B2 JP 4758650B2 JP 2004556103 A JP2004556103 A JP 2004556103A JP 2004556103 A JP2004556103 A JP 2004556103A JP 4758650 B2 JP4758650 B2 JP 4758650B2
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formula
group
compound
alkyl
butene
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JP2006509059A (ja
JP2006509059A5 (enExample
Inventor
レスコニ,ルイジ
イングルジオ,アントニオ カスチオ
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バーゼル・ポリオレフィン・ゲーエムベーハー
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/08Butenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
JP2004556103A 2002-12-04 2003-11-03 1−ブテンポリマーの製造方法 Expired - Lifetime JP4758650B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP02080120 2002-12-04
EP02080120.5 2002-12-04
US43180302P 2002-12-09 2002-12-09
US60/431,803 2002-12-09
PCT/EP2003/012236 WO2004050724A1 (en) 2002-12-04 2003-11-03 Process for preparing 1-butene polymers

Publications (3)

Publication Number Publication Date
JP2006509059A JP2006509059A (ja) 2006-03-16
JP2006509059A5 JP2006509059A5 (enExample) 2006-12-14
JP4758650B2 true JP4758650B2 (ja) 2011-08-31

Family

ID=44597271

Family Applications (1)

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JP2004556103A Expired - Lifetime JP4758650B2 (ja) 2002-12-04 2003-11-03 1−ブテンポリマーの製造方法

Country Status (7)

Country Link
EP (1) EP1567565B1 (enExample)
JP (1) JP4758650B2 (enExample)
KR (1) KR101059401B1 (enExample)
AT (1) ATE383379T1 (enExample)
AU (1) AU2003276242A1 (enExample)
DE (1) DE60318616T2 (enExample)
WO (1) WO2004050724A1 (enExample)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4571798B2 (ja) 2001-06-12 2010-10-27 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンの重合方法
WO2004033510A2 (en) 2002-10-10 2004-04-22 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60329523D1 (de) 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
DE10358082A1 (de) * 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
WO2006010139A2 (en) * 2004-07-08 2006-01-26 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system and process for use thereof
KR101293405B1 (ko) * 2005-03-18 2013-08-05 바젤 폴리올레핀 게엠베하 메탈로센 화합물
US7803887B2 (en) 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
US7728086B2 (en) 2005-03-23 2010-06-01 Basell Polyolefine Gmbh Process for the polymerization of olefins
EP1861435B1 (en) * 2005-03-23 2016-01-13 Basell Polyolefine GmbH Process for the polymerization of olefins
US7964679B2 (en) 2005-05-03 2011-06-21 Basell Poliolefine Italia S.R.L. Process for the polymerization of alpha olefins
WO2006120177A2 (en) 2005-05-11 2006-11-16 Basell Poliolefine Itatia S.R.L. Polymerization process for preparing polyolefin blends
JP2009530341A (ja) 2006-03-17 2009-08-27 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物類
JP2009533382A (ja) 2006-04-12 2009-09-17 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
JP2010500418A (ja) * 2006-04-21 2010-01-07 バーゼル・ポリオレフィン・ゲーエムベーハー エチレンプロピレンコポリマーの製造方法
US8742042B2 (en) * 2006-04-21 2014-06-03 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
ES2565438T3 (es) * 2010-07-01 2016-04-04 Borealis Ag Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores
EP2402353B1 (en) * 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
JP5966321B2 (ja) * 2010-11-19 2016-08-10 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
WO2012134721A2 (en) * 2011-03-25 2012-10-04 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
JP5880000B2 (ja) * 2011-12-14 2016-03-08 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
EP2902419B1 (en) 2012-09-25 2020-08-19 Mitsui Chemicals, Inc. Method for producing olefin polymer, and olefin polymer
EP2722345B1 (en) 2012-10-18 2018-12-05 Borealis AG Catalyst for the polymerisation of olefins
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
ES2622627T3 (es) 2012-10-18 2017-07-06 Borealis Ag Procedimiento de polimerización
JP6264808B2 (ja) * 2013-09-26 2018-01-24 日本ポリプロ株式会社 メタロセン化合物及びそれを使用する重合触媒によるオレフィン重合体の製造方法
WO2016039416A1 (ja) 2014-09-11 2016-03-17 三井化学株式会社 1-ブテン由来の構成単位を含むオレフィン(共)重合体の製造方法
JP6921563B2 (ja) * 2017-03-07 2021-08-18 出光興産株式会社 遷移金属化合物及びオレフィン系重合体の製造方法
EP4316834A4 (en) 2021-03-31 2025-03-26 Mitsui Chemicals, Inc. ETHYLENE-A-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION AND FILM
US20240191068A1 (en) 2021-03-31 2024-06-13 Mitsui Chemicals, Inc. Ethylene resin composition and shaped article
EP4316833A4 (en) 2021-03-31 2025-03-26 Mitsui Chemicals, Inc. ETHYLENE-α-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, FILM AND LAMINATE

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06184179A (ja) * 1991-11-30 1994-07-05 Hoechst Ag 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途
JPH07196718A (ja) * 1993-12-28 1995-08-01 Mitsui Petrochem Ind Ltd 予備重合触媒、オレフィン重合用触媒およびオレフィンの重合方法
JPH09202795A (ja) * 1995-04-24 1997-08-05 Mitsui Toatsu Chem Inc キラルな新規メタロセン化合物とその合成方法及びそれを用いたオレフィンの重合方法
JPH10298219A (ja) * 1997-04-30 1998-11-10 Mitsui Chem Inc 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分
JPH11286519A (ja) * 1998-04-02 1999-10-19 Mitsui Chem Inc オレフィンの重合方法
JP2001081124A (ja) * 1999-09-17 2001-03-27 Sumitomo Chem Co Ltd 付加重合用触媒、およびオレフィン重合体の製造方法
JP2002506074A (ja) * 1998-03-11 2002-02-26 ザ ダウ ケミカル カンパニー ジエン錯体を製造するための統合方法
JP2002220503A (ja) * 2000-11-24 2002-08-09 Idemitsu Petrochem Co Ltd ポリオレフィン系樹脂組成物とその成形体及びフィルム
JP2003516420A (ja) * 1999-12-10 2003-05-13 ダウ グローバル テクノロジーズ インコーポレーテッド 置換4族金属錯体、触媒及びオレフィン重合法

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US6479424B1 (en) * 1998-12-14 2002-11-12 Bp Corporation North America Inc. Fluxional catalysts and related ligands containing bulky substituents
JP4571798B2 (ja) * 2001-06-12 2010-10-27 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンの重合方法

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06184179A (ja) * 1991-11-30 1994-07-05 Hoechst Ag 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途
JPH07196718A (ja) * 1993-12-28 1995-08-01 Mitsui Petrochem Ind Ltd 予備重合触媒、オレフィン重合用触媒およびオレフィンの重合方法
JPH09202795A (ja) * 1995-04-24 1997-08-05 Mitsui Toatsu Chem Inc キラルな新規メタロセン化合物とその合成方法及びそれを用いたオレフィンの重合方法
JPH10298219A (ja) * 1997-04-30 1998-11-10 Mitsui Chem Inc 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分
JP2002506074A (ja) * 1998-03-11 2002-02-26 ザ ダウ ケミカル カンパニー ジエン錯体を製造するための統合方法
JPH11286519A (ja) * 1998-04-02 1999-10-19 Mitsui Chem Inc オレフィンの重合方法
JP2001081124A (ja) * 1999-09-17 2001-03-27 Sumitomo Chem Co Ltd 付加重合用触媒、およびオレフィン重合体の製造方法
JP2003516420A (ja) * 1999-12-10 2003-05-13 ダウ グローバル テクノロジーズ インコーポレーテッド 置換4族金属錯体、触媒及びオレフィン重合法
JP2002220503A (ja) * 2000-11-24 2002-08-09 Idemitsu Petrochem Co Ltd ポリオレフィン系樹脂組成物とその成形体及びフィルム

Also Published As

Publication number Publication date
DE60318616T2 (de) 2009-01-08
JP2006509059A (ja) 2006-03-16
EP1567565B1 (en) 2008-01-09
AU2003276242A1 (en) 2004-06-23
ATE383379T1 (de) 2008-01-15
WO2004050724A1 (en) 2004-06-17
KR101059401B1 (ko) 2011-08-29
DE60318616D1 (de) 2008-02-21
KR20050089028A (ko) 2005-09-07
EP1567565A1 (en) 2005-08-31

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