JP4732443B2 - 硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類 - Google Patents

硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類 Download PDF

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JP4732443B2
JP4732443B2 JP2007509477A JP2007509477A JP4732443B2 JP 4732443 B2 JP4732443 B2 JP 4732443B2 JP 2007509477 A JP2007509477 A JP 2007509477A JP 2007509477 A JP2007509477 A JP 2007509477A JP 4732443 B2 JP4732443 B2 JP 4732443B2
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chromium
catalyst
sulfate
support
catalyst composition
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JP2007533821A (ja
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マクダニエル、マックス、ピー．
コリンズ、キャシー、エス．
ベンハム、エリザベス、エー．
デスロリエ、ポール、ジェイ．
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シェブロン フィリップス ケミカル カンパニー エルピー
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Priority claimed from US10/829,850 external-priority patent/US7214642B2/en
Priority claimed from US10/829,844 external-priority patent/US7112643B2/en
Application filed by シェブロン フィリップス ケミカル カンパニー エルピー filed Critical シェブロン フィリップス ケミカル カンパニー エルピー
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2007509477A 2004-04-22 2005-03-24 硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類 Expired - Fee Related JP4732443B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10/829,850 2004-04-22
US10/829,850 US7214642B2 (en) 2004-04-22 2004-04-22 Methods of preparing active chromium/alumina catalysts via treatment with sulfate
US10/829,844 US7112643B2 (en) 2004-04-22 2004-04-22 Polymers having low levels of long chain branching and methods of making the same
US10/829,844 2004-04-22
PCT/US2005/009668 WO2005107943A1 (en) 2004-04-22 2005-03-24 Methods of preparing active chromium/alumina catalysts via treatment with sulfate and polymers produced using the chromium/alumina catalysts

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JP2010232648A Division JP2011006714A (ja) 2004-04-22 2010-10-15 硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類

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JP2007533821A JP2007533821A (ja) 2007-11-22
JP4732443B2 true JP4732443B2 (ja) 2011-07-27

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JP2007509477A Expired - Fee Related JP4732443B2 (ja) 2004-04-22 2005-03-24 硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類
JP2010232648A Withdrawn JP2011006714A (ja) 2004-04-22 2010-10-15 硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類
JP2014178637A Expired - Fee Related JP5894237B2 (ja) 2004-04-22 2014-09-03 硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類

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JP2014178637A Expired - Fee Related JP5894237B2 (ja) 2004-04-22 2014-09-03 硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類

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EP (2) EP1748842A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (3) JP4732443B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (2) KR101121598B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU2005240523A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (2) BR122015030148B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (2) CA2564483C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IN (1) IN2012DN02743A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
RU (1) RU2006141236A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
SG (1) SG136947A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO2005107943A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7897539B2 (en) 2007-05-16 2011-03-01 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US7638456B2 (en) * 2007-12-18 2009-12-29 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US7910669B2 (en) 2009-03-17 2011-03-22 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
KR101483247B1 (ko) 2013-04-23 2015-01-16 주식회사 엘지화학 폴리올레핀 중합용 촉매의 제조 방법 및 폴리올레핀 제조방법
US10246528B2 (en) 2014-01-09 2019-04-02 Chevron Phillips Chemical Company Lp Chromium (III) catalyst systems with activator-supports
US10005861B2 (en) 2016-06-09 2018-06-26 Chevron Phillips Chemical Company Lp Methods for increasing polymer production rates with halogenated hydrocarbon compounds
CN116063598A (zh) 2018-09-17 2023-05-05 切弗朗菲利浦化学公司 改性负载型铬催化剂和由其生产的基于乙烯的聚合物
US11780786B2 (en) 2020-09-14 2023-10-10 Chevron Phillips Chemical Company Lp Transition metal-catalyzed production of alcohol and carbonyl compounds from hydrocarbons
US12134591B2 (en) 2022-10-31 2024-11-05 Chevron Phillips Chemical Company Lp Methanol production from methane utilizing a supported chromium catalyst

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3624063A (en) 1969-07-10 1971-11-30 Phillips Petroleum Co Ethylene polymerization using catalyst of controlled particle size
US3976632A (en) 1974-12-04 1976-08-24 Phillips Petroleum Company Reactivation of organochromium olefin polymerization catalyst in presence of oxygen
CA1172236A (en) * 1980-12-31 1984-08-07 Max P. Mcdaniel Phosphated alumina or aluminum phosphate chromium catalyst
US4364842A (en) * 1980-12-31 1982-12-21 Phillips Petroleum Company Phosphate supported chromium catalyst
JPS5838319A (ja) * 1981-08-31 1983-03-05 Nissan Motor Co Ltd フアンシユラウド
JPS5849706A (ja) * 1981-09-18 1983-03-24 Asahi Chem Ind Co Ltd オレフイン重合触媒
US4803253A (en) 1982-03-30 1989-02-07 Phillips Petroleum Company Ethylene polymer produced using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4690990A (en) 1982-03-30 1987-09-01 Phillips Petroleum Company Polymerization process using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4444966A (en) * 1982-05-05 1984-04-24 Phillips Petroleum Company Polymerization using phosphated alumina or aluminum phosphate chromium catalyst
US4806513A (en) 1984-05-29 1989-02-21 Phillips Petroleum Company Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same
US4607019A (en) 1984-12-12 1986-08-19 Exxon Research & Engineering Co. Polymerization catalyst, production and use
US4619980A (en) * 1985-04-01 1986-10-28 Phillips Petroleum Company Polymerization catalyst, method of making and use therefor
US4855271A (en) 1987-06-22 1989-08-08 Phillips Petroleum Company Catalyst and polymerization of olefins
US5200379A (en) 1990-06-07 1993-04-06 Phillips Petroleum Company Olefin polymerization using supported pentadienyl derivative-transition metal complexes
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
CA2043904C (en) 1990-10-09 1997-10-07 Kent E. Mitchell Olefin polymerization
US5237025A (en) 1990-10-09 1993-08-17 Phillips Petroleum Company Process for making bimodal polyolefins using two independent particulate catalysts
DE69219668T2 (de) * 1991-03-29 1997-09-11 Chevron Usa Inc Cyclopentadienylgruppe enthaltende Alpha-Olefin-Polymerisationskatalysatoren auf Basis eines Metals der 6B-Gruppe und Verfahren zur Polymerisation von Alpha-Olefinen
US5244990A (en) 1992-01-07 1993-09-14 Phillips Petroleum Company Prepolymerized catalyst and use thereof
US5179178A (en) 1992-05-15 1993-01-12 Phillips Petroleum Company Olefin polymerization
JPH06248025A (ja) * 1992-12-28 1994-09-06 Sumitomo Chem Co Ltd エチレン−αオレフィン共重合体
JPH0797343A (ja) * 1993-05-19 1995-04-11 Koa Oil Co Ltd 低級オレフィンの低重合方法及び低重合用触媒
DE69614741T2 (de) 1995-03-29 2002-07-04 Koa Oil Co. Ltd., Tokio/Tokyo Katalysator für die Oligomerisation von Olefinen, Verfahren zur Herstellung desselben und seine Anwendung zur Oligomerisation von Olefinen
JPH08323207A (ja) * 1995-03-29 1996-12-10 Koa Oil Co Ltd オレフィンの低重合方法、その触媒及び触媒の製造方法
JP3114632B2 (ja) * 1995-10-31 2000-12-04 東ソー株式会社 エチレン系共重合体、その製造方法およびその組成物
JP3662729B2 (ja) * 1996-10-24 2005-06-22 日本ポリオレフィン株式会社 エチレン系重合体及び中空成形体
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
US5998558A (en) * 1997-12-29 1999-12-07 Union Carbide Chemicals & Plastics Technology Corporation Ethylene polymers having enhanced processing ease
ATE244268T1 (de) * 1998-03-12 2003-07-15 Bp Chem Int Ltd Äthylen-homopolymer
CA2331413C (en) * 1998-05-18 2007-04-17 Phillips Petroleum Company Catalyst composition for polymerizing monomers
WO2000078828A1 (fr) * 1999-06-17 2000-12-28 Mitsui Chemicals, Inc. (co)polymeres d'etylene et leur utilisation
US6828268B1 (en) * 1999-11-05 2004-12-07 Phillips Petroleum Company Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst
CA2338094C (en) * 2001-02-23 2009-09-15 Nova Chemicals Corporation Catalyst for olefin polymerization
JP2003105016A (ja) * 2001-07-27 2003-04-09 Japan Polyolefins Co Ltd エチレン系重合体製造用触媒、エチレン系重合体の製造方法およびエチレン−α−オレフィン共重合体
ATE355311T1 (de) * 2001-11-23 2006-03-15 Basell Polyolefine Gmbh Polyolefin-kunststoffrohre
JP2003165873A (ja) * 2001-11-29 2003-06-10 Asahi Kasei Corp ポリエチレン樹脂組成物及び成形体
EP1325925A1 (en) * 2002-01-03 2003-07-09 Repsol Quimica S.A. Chromium catalysts active in olefin polymerization
US6914113B2 (en) * 2002-07-25 2005-07-05 Fina Technology, Inc. Film clarity and rheological breadth in polyethylene resins
JP2004149761A (ja) * 2002-09-02 2004-05-27 Sumitomo Chem Co Ltd エチレン重合体

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Publication number Publication date
EP2374537A2 (en) 2011-10-12
CA2730830A1 (en) 2005-11-17
EP2374537A3 (en) 2011-11-02
CA2564483A1 (en) 2005-11-17
JP5894237B2 (ja) 2016-03-23
JP2007533821A (ja) 2007-11-22
KR20070004988A (ko) 2007-01-09
CA2564483C (en) 2011-09-13
EP1748842A1 (en) 2007-02-07
JP2011006714A (ja) 2011-01-13
RU2006141236A (ru) 2008-05-27
IN2012DN02743A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 2015-09-11
KR20120006061A (ko) 2012-01-17
JP2015013999A (ja) 2015-01-22
BR122015030148B1 (pt) 2017-01-31
BRPI0510174B1 (pt) 2016-04-26
WO2005107943A1 (en) 2005-11-17
CA2730830C (en) 2013-09-24
BRPI0510174A (pt) 2007-10-02
SG136947A1 (en) 2007-11-29
HK1132003A1 (en) 2010-02-12
KR101121598B1 (ko) 2012-03-16
AU2005240523A1 (en) 2005-11-17

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