JP4728164B2 - 多彩模様塗膜形成方法、多彩模様塗装物品及び多彩模様塗装物品の補修塗装方法 - Google Patents
多彩模様塗膜形成方法、多彩模様塗装物品及び多彩模様塗装物品の補修塗装方法 Download PDFInfo
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- JP4728164B2 JP4728164B2 JP2006125933A JP2006125933A JP4728164B2 JP 4728164 B2 JP4728164 B2 JP 4728164B2 JP 2006125933 A JP2006125933 A JP 2006125933A JP 2006125933 A JP2006125933 A JP 2006125933A JP 4728164 B2 JP4728164 B2 JP 4728164B2
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- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- HOWFTCIROIVKLW-UHFFFAOYSA-L strontium;dinitrite Chemical compound [Sr+2].[O-]N=O.[O-]N=O HOWFTCIROIVKLW-UHFFFAOYSA-L 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical class OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 239000001016 thiazine dye Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical class S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical class C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229920001567 vinyl ester resin Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- 238000011041 water permeability test Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- XSMMCTCMFDWXIX-UHFFFAOYSA-N zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 description 1
- 235000019352 zinc silicate Nutrition 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Description
1. 金属基材表面又は金属基材上の旧塗装面に、防錆顔料を含有する下塗り塗料(I)を塗装し、該塗面上に、水性多彩模様塗料(II)を塗装する多彩模様塗膜形成方法であって、該水性多彩模様塗料(II)が、着色塗料粒子(A)及び塗膜形成成分(B)を、着色塗料粒子(A)/塗膜形成成分(B)の固形分質量比で、1/99〜60/40の範囲内で含み、反応性官能基(x)を含有する水性樹脂(a)及び着色剤(b)を含んでなる着色塗料粒子(A)並びに反応性官能基(x)と反応し得る反応性官能基(y)を含有する塗膜形成成分(B)を含んでなるものであることを特徴とする多彩模様塗膜形成方法、
2. 金属基材表面又は金属基材上の旧塗装面に、防錆顔料を含有する下塗り塗料(I)を塗装し、該下塗り塗面上に中塗り塗料を塗装し、該中塗り塗面上に、水性多彩模様塗料(II)を塗装する多彩模様塗膜形成方法であって、該水性多彩模様塗料(II)が、着色塗料粒子(A)及び塗膜形成成分(B)を、着色塗料粒子(A)/塗膜形成成分(B)の固形分質量比で、1/99〜60/40の範囲内で含み、反応性官能基(x)を含有する水性樹脂(a)及び着色剤(b)を含んでなる着色塗料粒子(A)並びに反応性官能基(x)と反応し得る反応性官能基(y)を含有する塗膜形成成分(B)を含んでなるものであることを特徴とする多彩模様塗膜形成方法、
3. 下塗り塗料(I)により形成される下塗塗膜と水性多彩模様塗料(II)により形成される多彩模様塗膜との明度差ΔL*が、−20〜+20の範囲内であることを特徴とする1項に記載の多彩模様塗膜形成方法、
4. 中塗り塗料により形成される中塗り塗膜と、水性多彩模様模様塗料(II)により形成される多彩模様塗膜との明度差ΔL*が、−20〜+20の範囲内であることを特徴とする2項に記載の多彩模様塗膜形成方法、
5. 着色塗料粒子(A)が、水性樹脂(a)、着色剤(b)及び水溶性多糖類を含む水性塗料組成物を、水溶性多糖類と水不溶性もしくは難溶性の塩を形成し得る一価又は多価の金属イオンを含有する水性媒体と接触させることにより得られるものである1項ないし4項のいずれか1項に記載の多彩模様塗膜形成方法、
6. 金属イオンの供給源となる金属化合物が、金属水酸化物、金属酸化物、金属炭酸塩よりなる群から選ばれる少なくとも1種である5項に記載の多彩模様塗膜形成方法、
7. 1項ないし6項のいずれか1項に記載の方法により得られる多彩模様塗装物品、
8. 7項に記載の多彩模様塗装物品に、下塗り塗膜又は中塗り塗膜との明度差ΔL*が−20〜+20の範囲内である多彩模様塗膜を形成する多彩模様塗料を塗装することを特徴とする多彩模様塗装物品の補修塗装方法、
に関する。
上記水性下塗り塗料(I)又は必要に応じて設けられる中塗り塗料の塗面上に塗装される水性多彩模様塗料(II)は、着色塗料粒子(A)及び塗膜形成成分(B)を含む塗料である。かかる構成により水性多彩模様塗料(II)により形成される多彩模様塗膜の透水量を低減させ、防水性を向上させることができ、上記下塗塗料(I)により形成される塗膜及び必要に応じて設けられる中塗り塗膜と共に、金属基材表面の防食性を向上させる効果がある。
Ti=Va/Vb
ここでVaは、回転数が6回転/分にて測定した塗料粘度(mPa・sec)であり、Vbは、同じく回転数が60回転/分にて測定した塗料粘度(mPa・sec)である。
製造例1
1リットルのステンレス容器に下記成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより、下塗り塗料用の顔料ペーストを得た。
モノエチレングリコール 5部
「スラオフ72N」(注1) 2部
「ノプコサントK」(注2) 6部
「SNデフォーマー380」(注3) 4部
「チタンJR−605」(注4) 192部
フタロシアニンブルー 3部
酸化鉄 3部
「K−WHITE 140W」(注5) 55部
次いで、該顔料ペースト360部に、「ウォーターゾルS118」(注6)500部、「SNデフォーマー380」5部および「アデカノールUH−438」(注7)4部、亜硝酸ナトリウムを3部配合し、攪拌混合して、赤灰色の下塗り塗料(I−1)を得た。下塗り塗料(I−1)の塗膜のL*値を明細書記載の方法で測定したところ72であった。
(注1)「スラオフ72N」:商品名、武田薬品工業(株)製、防腐剤、
(注2)「ノプコサント K」 :商品名、サンノプコ社製、顔料分散剤、
(注3)「SNデフォーマー380」:商品名、サンノプコ社製、消泡剤、
(注4)「JR−605」:商品名、テイカ社製、チタン白、
(注5)「K−WHITE 140W」:商品名、テイカ社製、リン酸塩系防錆顔料、
(注6)「ウォーターゾルS118」:商品名、大日本インキ化学工業(株)製、不揮発分60%のエポキシエステルエマルション、
(注7)「アデカノールUH438」:商品名、旭電化社製、ポリエーテルウレタン変性物、粘性調整剤、
製造例2
顔料ペースト組成を下記とする以外は上記製造例1と同様にして赤灰色の下塗り塗料(I−2)を得た。下塗り塗料(I−2)の塗膜のL*値を明細書記載の方法で測定したところ72であった。
顔料ペースト組成
上水 100部
モノエチレングリコール 5部
「スラオフ72N」(注1) 2部
「ノプコサントK」(注2) 6部
「SNデフォーマー380」(注3) 4部
「チタンJR−605」(注4) 192部
フタロシアニンブルー 3部
酸化鉄 3部。
製造例3
2リットルの4つ口フラスコに脱イオン水312部、「Newcol 707SF」(注8)2.3部を加え、窒素置換後、80℃に保ち、下記組成のプレエマルションを滴下する直前に0.7部の過硫酸アンモニウムを加え、該プレエマルションを3時間にわたって滴下した。
脱イオン水 338部
アクリル酸 6部
スチレン 97部
メチルメタクリレート 260部
2−エチルヘキシルアクリレート 100部
n−ブチルアクリレート 182部
「Newcol 707SF」(注8) 62部
過硫酸アンモニウム 1.2部
滴下終了後30分より、30分間0.7部の過硫酸アンモニウムを7部の脱イオン水に溶かした触媒水溶液を滴下し、さらに2時間80℃に保持し、その後40〜60℃に降温した後、アンモニア水でpHを調整し、エマルション(e1)を得た。エマルションは、固形分52%、平均粒子径180nm、pH8.2であった。
(注8) 「ニューコール707SF」:商品名、日本乳化剤社製、ポリオキシエチレン鎖を有するアニオン性界面活性剤、不揮発分30%。
製造例4
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、赤灰色の中塗り塗料を得た。かかる中塗り塗膜のL*値は、明細書記載の方法で測定したところ70であった。
52%エマルション(e1) 200部
「TEXANOL」(注9) 20部
「SNデフォーマーA63」(注10) 2部
「ノプコサントK」(注2) 3部
「チタンJR−605」(注4) 90部
炭酸カルシウム(注11) 170部
フタロシアニンブルー 3部
酸化鉄 3部
2.5%ヒドロキシエチルセルロース 25部
(注9)「TEXANOL」:商品名、イーストマンケミカル社製、2,2,4−トリメチルペンタンジオールモノイソブチレート、
(注10)「SNデホーマーA63」:商品名、消泡剤、サンノプコ社製
(注11)炭酸カルシウム:比重2.7。
製造例5
容量2リットルの4つ口フラスコに、脱イオン水285部及び「ニューコール707SF」(注8)1部を加え、窒素置換後、85℃に保った。その中に、下記組成の成分をエマルション化してなるプレエマルションの3%分と、過硫酸アンモニウム3部を脱イオン水120部に溶解させた開始剤水溶液123部のうちの41部とをそれぞれ添加し、添加20分後から、残りのプレエマルションと残りの開始剤水溶液とを4時間かけてフラスコに滴下した。
脱イオン水 368部
スチレン 150部
メチルメタクリレート 413部
n−ブチルアクリレート 240部
2−エチルヘキシルアクリレート 150部
ダイアセトンアクリルアミド 20部
1,6−ヘキサンジオールジアクリレート 5部
2−ヒドロキシエチルアクリレート 20部
アクリル酸 2部
「ニューコール707SF」(注8) 66部
滴下終了後、これをさらに2時間85℃に保持した後、40〜60℃に降温した。次いで、アンモニア水でpHを調整し、固形分が55%のエマルション(e2)を得た。エマルション(e2)の平均粒子径は170nm、pHは8.3であった。
製造例6
1リットルのステレンス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、固形分50%の水性クリヤー塗料(C1)を得た。
55%エマルション(e2) 750部
「TEXANOL」(注9) 50部
水 279部
「タルク SS」(注12) 250部
「SNデフォーマー380」(注3) 10部
「アデカノールUH−438」(注7) 6部。
(注12)「タルク SS」:商品名、日本タルク社製、タルク。
製造例7
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより、白顔料ペーストを得た。
水 45部
「スラオフ72N」(注1) 3部
「DISPER BYK−190」(注13) 6部
「SNデフォーマー380」(注3) 3部
「チタンJR−605」(注4) 100部。
(注13)「DISPER BYK−190」:商品名、BYKケミー社製、分散剤。
製造例8
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより、青顔料ペーストを得た。
水 65部
モノエチレングリコール 5部
「スラオフ72N」(注1) 1部
「DISPER BYK−190」(注13) 6部
「SNデフォーマー380」(注3) 2部
フタロシアニンブルー 25部。
製造例9
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより、赤錆顔料ペーストを得た。
水 65部
モノエチレングリコール 5部
「スラオフ72N」(注1) 1部
「DISPER BYK−190」(注13) 6部
「SNデフォーマー380」(注3) 2部
酸化鉄 30部。
製造例10
1リットルのステンレス容器に下記の成分を仕込み、ディスパーで30分間均一になるまで攪拌することにより、黒顔料ペーストを得た。
水 65部
モノエチレングリコール 5部
「スラオフ72N」(注1) 1部
「DISPER BYK−190」(注13) 6部
「SNデフォーマー380」(注3) 2部
カーボンブラック 25部。
製造例11
容器に下記の成分を順次配合し、均一となるように攪拌混合して、着色塗料粒子用の水性塗料組成物(a−1)を得た。
白顔料ペースト 154部
55%エマルション(e2) 250部
「TEXANOL」(注9) 20部
「SNデフォーマー380」(注3) 2部
「アデカノールUH−438」(注7) 2部
2%アルギン酸ナトリウム水溶液 280部。
上記製造例11において、配合組成を下記表1に示す配合組成に変える以外は製造例11と同様にして、水性塗料組成物(a−2)〜(a−6)を製造した。
製造例17
4リットルステンレス容器に、0.15%水酸化カルシウム(注14)水溶液を1,300部仕込み、75mmの径を有する攪拌羽根を用いて回転速度2,500rpmで攪拌しながら、上記で得られた水性塗料組成物(a−1)650部を徐々に容器内に滴下し、着色塗料粒子を生成させた。次いで容器内液を同回転速度でさらに15分攪拌した後、200メッシュの金網を用いて濾別し、着色塗料粒子(A−1)を得た。得られた着色塗料粒子(A−1)は、目視による色が白色であり、固形分が20%であった。
(注14) 水酸化カルシウム:25℃の水100gに対して0.15g溶解。
4リットルステンレス容器に、水酸化カルシウム24部と脱イオン水1,200部を仕込み、75mmの径を有する攪拌羽根を用いて回転速度1500rpmで攪拌しながら、上記水性塗料組成物(a−2)600部を徐々に容器内に滴下し、着色塗料粒子を生成させた。次いで容器内液を同回転速度でさらに15分攪拌した後、200メッシュの金網にて濾別し、着色塗料粒子(A−2)を得た。得られた着色塗料粒子(A−2)は、目視による色が白色であり、固形分が20%であった。
製造例17において、水性塗料組成物(a−1)の代わりに下記表2に示す水性塗料組成物を使用する以外は上記製造例17と同様にして、着色塗料粒子(A−3)〜(A−6)を得た。
製造例23〜27
500ミリリットルのステレンス容器に、下記表3に示す成分を順次攪拌しながら仕込み、その後、均一になるまで攪拌することにより、多彩模様塗料(II‐1)〜(II−5)を得た。得られた塗料の性状値、形成塗膜のL*値及び透水量を表3にあわせて示す。
(注16) 2%ヒドロキシエチルセルロース水溶液:和光純薬社製、ヒドロキシエチルセルロースを濃度が2%となるように脱イオン水に溶解させ調製した水溶液、
(注17) 「プライマルASE−60」:商品名、ローム・アンド・ハース社製、ポリアクリル酸系粘性調整剤、酸価270mgKOH/g、有効成分28%、
(注18) 「プライマルTT−615」:商品名、ローム・アンド・ハース社製、長鎖アルキル基含有ポリアクリル酸系粘性調整剤、有効成分30%、
(*)塗膜L*値
ブリキ板に試料をスプレーで2回塗装し、塗面を水平に置いて、温度20℃、相対湿度60%の条件下、48時間乾燥した後、「CR‐300」(ミノルタ社製、色彩色差計)を使用し、塗面上を無作為に3箇所選び測定した値の平均値。
(**)塗膜透水量
JIS A 6909に規定されている透水試験B法により測定した値。
実施例1〜4及び比較例1〜2
素材としてJIS K 5410に規定する鋼板(150×70×0.8mm)をキシレンにて脱脂したものを使用した。該素材に表4に示す各水性下塗り塗料を、塗付量が100g/m2となるようにローラーで塗装し、気温20℃・相対湿度60%の条件下で1日乾燥させた後、その上に表4に示す各水性多彩模様塗料を、スプレーを用いて塗付量300g/m2となるように塗装した後、気温20℃・相対湿度60%の条件下で7日乾燥させて、各試験塗板を作成した。
素材として上記実施例1と同様の鋼板を使用し、該素材に水性下塗り塗料(I−1)を、塗付量が100g/m2となるようにローラーで塗装し、気温20℃・相対湿度60%の条件下で1日乾燥させ、その上に製造例4で得られた中塗り塗料を、ローラーを用いて塗付量100g/m2となるように塗装し、気温20℃・相対湿度60%の条件下で7日乾燥させた後、さらに水性多彩模様塗料(II−1)を、スプレーを用いて塗付量300g/m2となるように塗装した後、試験塗板を作成した。
得られた各試験塗板を下記試験に供した。結果を表4にあわせて示す。
各試験塗板の塗膜を目視で観察し、次の基準で評価した。
◎:多彩な意匠感、質感が十分あり、非常に良好、
〇:多彩な意匠感、質感があり、良好、
△:模様ムラが認められ、やや不良、
×:ワレやチヂミなどの塗膜欠陥あり。
(*2)補修性
各試験塗板の下部をマスキングテープで保護した後、上部を#240の研磨紙を用いて円状に研磨した。その後、表4に示す各水性多彩模様塗料を、スプレーを用いて塗付量300g/m2となるように塗装し、気温20℃・相対湿度60%の条件下で1日乾燥させた。下部と上部を目視にて観察し、下記基準で評価した。
○:下部と上部の境界がわからない、
△:下部と上部の境界がわずかにわかる、
×:下部と上部の境界がはっきりわかる。
(*3)防食性
各試験塗板を、JIS K 5621に規定されている耐複合サイクル防食性試験に36サイクル供して、その塗膜面を下記基準で評価した。
〇:塗膜にさびが認められない、
△:塗膜に一部さびが認められる、
×:塗膜の全面にさびが認められる。
(*4)耐水性
各試験塗板を23℃の上水に7日間浸漬し、引き上げた後、目視で観察し、次の基準で評価した。
○:良好、
△:艶引け、白化、フクレが認められる、
×:著しくフクレが認められる、又は塗膜が軟化する。
Claims (8)
- 金属基材表面又は金属基材上の旧塗装面に、防錆顔料を含有する下塗り塗料(I)を塗装し、該塗面上に、水性多彩模様塗料(II)を塗装する多彩模様塗膜形成方法であって、該水性多彩模様塗料(II)が、着色塗料粒子(A)及び塗膜形成成分(B)を、着色塗料粒子(A)/塗膜形成成分(B)の固形分質量比で、1/99〜60/40の範囲内で含み、反応性官能基(x)を含有する水性樹脂(a)及び着色剤(b)を含んでなる着色塗料粒子(A)並びに反応性官能基(x)と反応し得る反応性官能基(y)を含有する塗膜形成成分(B)を含んでなるものであることを特徴とする多彩模様塗膜形成方法。
- 金属基材表面又は金属基材上の旧塗装面に、防錆顔料を含有する下塗り塗料(I)を塗装し、該下塗り塗面上に中塗り塗料を塗装し、該中塗り塗面上に、水性多彩模様塗料(II)を塗装する多彩模様塗膜形成方法であって、該水性多彩模様塗料(II)が、着色塗料粒子(A)及び塗膜形成成分(B)を、着色塗料粒子(A)/塗膜形成成分(B)の固形分質量比で、1/99〜60/40の範囲内で含み、反応性官能基(x)を含有する水性樹脂(a)及び着色剤(b)を含んでなる着色塗料粒子(A)並びに反応性官能基(x)と反応し得る反応性官能基(y)を含有する塗膜形成成分(B)を含んでなるものであることを特徴とする多彩模様塗膜形成方法。
- 下塗り塗料(I)により形成される下塗塗膜と水性多彩模様塗料(II)により形成される多彩模様塗膜との明度差ΔL*が、−20〜+20の範囲内であることを特徴とする請求項1に記載の多彩模様塗膜形成方法。
- 中塗り塗料により形成される中塗り塗膜と、水性多彩模様模様塗料(II)により形成される多彩模様塗膜との明度差ΔL*が、−20〜+20の範囲内であることを特徴とする請求項2に記載の多彩模様塗膜形成方法。
- 着色塗料粒子(A)が、水性樹脂(a)、着色剤(b)及び水溶性多糖類を含む水性塗料組成物を、水溶性多糖類と水不溶性もしくは難溶性の塩を形成し得る一価又は多価の金属イオンを含有する水性媒体と接触させることにより得られるものである請求項1ないし4のいずれか1項に記載の多彩模様塗膜形成方法。
- 金属イオンの供給源となる金属化合物が、金属水酸化物、金属酸化物、金属炭酸塩よりなる群から選ばれる少なくとも1種である請求項5に記載の多彩模様塗膜形成方法。
- 請求項1ないし6のいずれか1項に記載の方法により得られる多彩模様塗装物品。
- 請求項7に記載の多彩模様塗装物品に、下塗り塗膜又は中塗り塗膜との明度差ΔL*が−20〜+20の範囲内である多彩模様塗膜を形成する多彩模様塗料を塗装することを特徴とする多彩模様塗装物品の補修塗装方法。
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Publication number | Priority date | Publication date | Assignee | Title |
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Family Cites Families (5)
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JP3400878B2 (ja) * | 1994-10-28 | 2003-04-28 | エスケー化研株式会社 | 自然石調塗装方法及びそれに用いる自然石調塗料組成物 |
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