JP5551333B2 - 透明性基材用装飾材、装飾方法及び装飾品 - Google Patents
透明性基材用装飾材、装飾方法及び装飾品 Download PDFInfo
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- JP5551333B2 JP5551333B2 JP2007329689A JP2007329689A JP5551333B2 JP 5551333 B2 JP5551333 B2 JP 5551333B2 JP 2007329689 A JP2007329689 A JP 2007329689A JP 2007329689 A JP2007329689 A JP 2007329689A JP 5551333 B2 JP5551333 B2 JP 5551333B2
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- 150000004696 coordination complex Chemical class 0.000 description 1
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- ZWLIYXJBOIDXLL-UHFFFAOYSA-N decanedihydrazide Chemical compound NNC(=O)CCCCCCCCC(=O)NN ZWLIYXJBOIDXLL-UHFFFAOYSA-N 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- XDSGMUJLZDSCPA-UHFFFAOYSA-N diazanium;phenoxybenzene;sulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 XDSGMUJLZDSCPA-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- SWRGUMCEJHQWEE-UHFFFAOYSA-N ethanedihydrazide Chemical compound NNC(=O)C(=O)NN SWRGUMCEJHQWEE-UHFFFAOYSA-N 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910001849 group 12 element Inorganic materials 0.000 description 1
- 229910021476 group 6 element Inorganic materials 0.000 description 1
- 229910021474 group 7 element Inorganic materials 0.000 description 1
- 229910021472 group 8 element Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Chemical class N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- VAKIVKMUBMZANL-UHFFFAOYSA-N iron phosphide Chemical compound P.[Fe].[Fe].[Fe] VAKIVKMUBMZANL-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- GWVMLCQWXVFZCN-UHFFFAOYSA-N isoindoline Chemical compound C1=CC=C2CNCC2=C1 GWVMLCQWXVFZCN-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 1
- CRVVHBFLWWQMPT-UHFFFAOYSA-N naphthalene-1-sulfonic acid;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 CRVVHBFLWWQMPT-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- LGYJSPMYALQHBL-UHFFFAOYSA-N pentanedihydrazide Chemical compound NNC(=O)CCCC(=O)NN LGYJSPMYALQHBL-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- PJQYNUFEEZFYIS-UHFFFAOYSA-N perylene maroon Chemical compound C=12C3=CC=C(C(N(C)C4=O)=O)C2=C4C=CC=1C1=CC=C2C(=O)N(C)C(=O)C4=CC=C3C1=C42 PJQYNUFEEZFYIS-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- FURYAADUZGZUGQ-UHFFFAOYSA-N phenoxybenzene;sulfuric acid Chemical compound OS(O)(=O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 FURYAADUZGZUGQ-UHFFFAOYSA-N 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000001008 quinone-imine dye Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- ZIWRUEGECALFST-UHFFFAOYSA-M sodium 4-(4-dodecoxysulfonylphenoxy)benzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCOS(=O)(=O)c1ccc(Oc2ccc(cc2)S([O-])(=O)=O)cc1 ZIWRUEGECALFST-UHFFFAOYSA-M 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- FNWBQFMGIFLWII-UHFFFAOYSA-N strontium aluminate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Sr+2].[Sr+2] FNWBQFMGIFLWII-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 239000001016 thiazine dye Substances 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical class S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Chemical class 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Description
すなわち本発明は
1.
透明性基材用の装飾材であって、該装飾材が、塗料組成物を粒状化してなる塗料粒子成分が分散媒体中に分散されてなるものであり、該塗料粒子成分がその成分の一部として光輝性顔料及び樹脂を含む光輝性塗料組成物が水溶性多糖類及び金属化合物に由来する多糖類金属塩ゲル中に内包してなる光輝性塗料粒子成分を含むものであって、該光輝性塗料粒子成分に含まれる光輝性顔料が、大きさが3〜400μmの範囲内であり、該光輝性塗料粒子成分中における光輝性顔料の含有量が、該光輝性塗料粒子成分に含まれる樹脂100質量部を基準として1〜50質量部の範囲内にあり、金属化合物が、金属水酸化物、金属酸化物及び金属炭酸塩より選ばれる金属化合物と有機酸金属塩を併用したものであることを特徴とする透明性基材用装飾材、
2.
光輝性塗料粒子成分が、大きさが20〜20,000μmの範囲内である1項に記載の透明性基材用装飾材、
3.
塗料粒子成分が、その成分の一部として着色材及び樹脂を含む着色塗料組成物を粒状化してなる着色塗料粒子成分をさらに含む1項または2項に記載の透明性基材用装飾材、
4.
光輝性塗料粒子成分と着色塗料粒子成分の含有割合が光輝性塗料粒子成分/着色塗料粒子成分固形分質量比で99/1〜1/99の範囲内にある3項に記載の透明性基材用装飾材、
5.
さらに塗膜形成成分を含む1項ないし4項のいずれか1項に記載の透明性基材用装飾材、
6.
塗料粒子成分及び塗膜形成成分の配合割合が、塗料粒子成分/塗膜形成成分固形分質量比で、1/99〜70/30の範囲内にある1項ないし5項のいずれか1項に記載の透明性基材用装飾材、
7.
透明性基材に、下塗り材層を介してまたは介さずに1項ないし6項のいずれか1項の記載の装飾材による装飾層を設けることを特徴とする透明性基材の装飾方法、
8.
下塗り材層を設けるための下塗り材がヒドラジン誘導体を含む組成物である7項に記載の装飾方法、
9.
7項または8項に記載の装飾方法により得られる装飾品、
に関する。
製造例1
容量2リットルの4つ口フラスコに、脱イオン水285部及び「ニューコール707SF」(注1)1部加え、窒素置換後、85℃に保った。その中に下記の組成の成分をエマルション化してなるプレエマルションの3%分と、過硫酸アンモニウム3部を脱イオン水120部に溶解させた開始剤水溶液123部のうちの41部とそれぞれ添加し、添加20分後から、残りのプレエマルションと過硫酸アンモニウム水溶液とを4時間かけてフラスコに滴下した。
脱イオン水 368部
スチレン 150部
メチルメタクリレート 413部
n−ブチルアクリレート 240部
2−エチルヘキシルアクリレート 150部
ダイアセトンアクリルアミド 20部
2−ヒドロキシエチルアクリレート 25部
アクリル酸 2部
「ニューコール707SF」(注1) 66部
滴下後、これをさらに2時間85℃に保持した後、40〜60℃に降温した。次いで、アンモニア水でpHを調整し、固形分が55%のエマルション(a1)を得た。エマルション(a1)の平均粒子径は170nm、pHは8.3であった。
(注1) 「ニューコール707SF」:商品名、日本乳化剤社製、ポリオキシエチレン鎖を有するアニオン性界面活性剤、不揮発分30%。
製造例2
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、光輝性顔料ペースト(b1)を得た。
水 225部
「スラオフ72N」(注2) 15部
「DISPER BYK−190」(注3) 30部
「SNデフォーマー380」(注4) 15部
「パールグレイズ MM−100R」(注5) 200部
(注2)「スラオフ72N」:商品名、武田薬品工業(株)製、防腐剤、
(注3)「DISPER BYK−190」:商品名、BYKケミー社製、顔料分散剤、
(注4)「SNデフォーマー380」:商品名、サンノプコ社製、消泡剤、
(注5)「パールグレイズ MM−100R」:商品名、日本光研工業製、天然マイカ系パール顔料、大きさ1〜15μm。
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、光輝性顔料ペースト(b2)を得た。
水 225部
「スラオフ72N」(注2) 15部
「DISPER BYK−190」(注3) 30部
「SNデフォーマー380」(注4) 15部
「パールグレイズ ME−100R」(注6) 200部
(注6)「パールグレイズ ME−100R」:商品名、日本光研工業製、天然マイカ系パール顔料、大きさ10〜60μm。
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、光輝性顔料ペースト(b3)を得た。
水 225部
「スラオフ72N」(注2) 15部
「DISPER BYK−190」(注3) 30部
「SNデフォーマー380」(注4) 15部
「パールグレイズ MS−100R」(注7) 200部
(注7)「パールグレイズ MS−100R」:商品名、日本光研工業製、天然マイカ系パール顔料、大きさ20〜100μm。
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、光輝性顔料ペースト(b4)を得た。
水 225部
「スラオフ72N」(注2) 15部
「DISPER BYK−190」(注3) 30部
「SNデフォーマー380」(注4) 15部
「パールグレイズ ML−100R」(注8) 200部
(注8)「パールグレイズ ML−100R」:商品名、日本光研工業製、天然マイカ系パール顔料、大きさ20〜200μm。
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、光輝性顔料ペースト(b5)を得た。
水 225部
「スラオフ72N」(注2) 15部
「DISPER BYK−190」(注3) 30部
「SNデフォーマー380」(注4) 15部
「パールグレイズ MXL−100R」(注9) 200部
(注9)「パールグレイズ MXL−100R」:商品名、日本光研工業製、天然マイカ系パール顔料、大きさ45〜500μm。
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、光輝性顔料ペースト(b6)を得た。
水 225部
「スラオフ72N」(注2) 15部
「DISPER BYK−190」(注3) 30部
「SNデフォーマー380」(注4) 15部
「パールグレイズ ME−100R」(注6) 100部
フタロシアニンブルー 90部。
製造例8
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて60分間攪拌混合することにより、緑顔料ペースト(b7)を得た。
水 400部
「スラオフ72N」(注2) 15部
「DISPER BYK−190」(注3) 48部
「SNデフォーマー380」(注4) 15部
フタロシアニングリーン 90部。
製造例9
1リットルのステンレス容器に下記の成分を仕込み、攪拌機にて60分間攪拌混合することにより、青顔料ペースト(b8)を得た。
水 400部
「スラオフ72N」(注2) 15部
「DISPER BYK−190」(注3) 48部
「SNデフォーマー380」(注4) 15部
フタロシアニンブルー 90部。
製造例10
容器に下記の成分を順次配合し、均一となるように攪拌混合して、塗料粒子用水性塗料組成物(A−1)を得た。
55%エマルション(a1) 250部
光輝性顔料ペースト(b1) 60部
10%アジピン酸ジヒドラジド水溶液 4部
「TEXANOL」(注10) 20部
「SNデフォーマー380」(注4) 2部
「アデカノールUH−438」(注11) 2部
2%アルギン酸ナトリウム水溶液 280部
(注10)「TEXANOL」:商品名、イーストマンケミカル社製、2,2,4−トリメチルペンタンジオールモノイソブチレート、造膜助剤、
(注11)「アデカノールUH−438」:商品名、アデカ社製、ポリエーテルウレタン変性物、粘性調整剤。
上記製造例10において、配合組成を下記表1に示す配合組成に変える以外は、製造例10と同様にして塗料粒子用水性塗料組成物(A−2)〜(A−10)を製造した。
製造例20
4リットルステンレス容器に、水酸化カルシウム、酢酸カルシウムをそれぞれ0.10%、0.25%になるように調整した水溶液を1,300部仕込み、75mmの径を有する攪拌羽根を用いて回転数2,500rpmで攪拌しながら、上記製造例10で得られた水性塗料組成物(A−1)650部を徐々に容器内に滴下し、塗料粒子を生成させた。次いで容器内液を同回転速度でさらに15分攪拌した後、100メッシュの金網を用いて濾別し、塗料粒子(B−1)を得た。得られた塗料粒子は、固形分が20%であり、大きさは100〜10,000μmであった。
上記製造例20において、配合組成を下記表2とする以外は製造例20と同様にして塗料粒子(B−2)〜(B−10)を製造した。
製造例30
容量2リットルの4つ口フラスコに、脱イオン水568部及び「ニューコール707SF」(注1)23部を加え、窒素置換後、85℃に保った。その中に、下記組成の成分をエマルション化してなるプレエマルションの3%分と、過硫酸アンモニウム3部を脱イオン水120部に溶解させた開始剤水溶液123部のうちの41部とをそれぞれ添加し、添加20分後から、残りのプレエマルションと残りの開始剤水溶液とを4時間かけてフラスコに滴下した。
脱イオン水 368部
スチレン 150部
メチルメタクリレート 413部
n−ブチルアクリレート 240部
2−エチルヘキシルアクリレート 150部
ダイアセトンアクリルアミド 20部
2−ヒドロキシエチルアクリレート 25部
アクリル酸 2部
「ニューコール707SF」(注1) 44部
滴下終了後、これをさらに2時間85℃に保持した後、40〜60℃に降温した。次いで、アンモニア水でpHを調整し、エマルション(a2)を得た。該エマルションは固形分が48%であり、平均粒子径は90nmであった。
製造例31
2リットルのステレンス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、水性クリヤー塗料(C−1)を得た。
48%エマルション(a2) 860部
「TEXANOL」(注10) 50部
水 279部
「SNデフォーマー380」(注4) 10部
「アデカノールUH−438」(注11) 6部
下塗り用水性クリヤー塗料の製造
製造例32
2リットルのステレンス容器に下記の成分を仕込み、攪拌機にて30分間攪拌混合することにより、水性クリヤー塗料(D−1)を得た。
「ポリデュレックス G624」(注12) 860部
「TEXANOL」(注10) 50部
水 279部
「SNデフォーマー380」(注4) 10部
「アデカノールUH−438」(注11) 6部
10%アジピン酸ジヒドラジド水溶液 25部
(注12)「ポリデュレックス G624」:商品名、旭化成ケミカルズ製,シリコーン変性アクリルエマルション,不揮発成分46%
装飾材の製造及び試験塗板の作成
実施例1〜5及び比較例1〜4
500ミリリットルのステンレス容器に、下記表3に示す成分を順次攪拌しながら仕込み、その後、均一になるまで攪拌することにより、装飾材(E−1)〜(E−9)を製造した。次いで、フロートガラス板(300×300×2mm)上に、下塗り用水性クリヤー塗料(D−1)を乾燥膜厚が30μmになるようにスプレー塗装し、気温23℃、相対湿度60%の条件下で1日間乾燥させたものを被塗板とした。この上に各装飾材を乾燥膜厚が150μmになるようにスプレーで塗装し、気温23℃、相対湿度60%の条件下で7日間乾燥させて、各試験塗板を得た。
実施例1〜5及び比較例1〜4で得られた各試験塗板を下記基準にて評価試験に供した。結果を表3に併せて示す。
(*1)意匠性
各試験塗板の外観を明所(D65標準光源下)において目視で観察し、次の基準で評価した。
◎:光輝感、透明感が十分にある、
○:光輝感、透明感がある、
×A:透明感はあるが、光輝感にかける、
×B:光輝感はややあるが、透明感にかける。
(*2)耐水性
各試験塗板を23℃の上水に7日間浸漬し、引き上げた後、目視にて観察し、次の基準で評価した。
○:良好、
△:艶引け、白化、フクレのいずれか1つが認められる、
×:著しいフクレが認められる、又は塗膜が軟化する。
Claims (9)
- 透明性基材用の装飾材であって、該装飾材が、塗料組成物を粒状化してなる塗料粒子成分が分散媒体中に分散されてなるものであり、該塗料粒子成分がその成分の一部として光輝性顔料及び樹脂を含む光輝性塗料組成物が水溶性多糖類及び金属化合物に由来する多糖類金属塩ゲル中に内包してなる光輝性塗料粒子成分を含むものであって、該光輝性塗料粒子成分に含まれる光輝性顔料が、大きさが3〜400μmの範囲内であり、該光輝性塗料粒子成分中における光輝性顔料の含有量が、該光輝性塗料粒子成分に含まれる樹脂100質量部を基準として1〜50質量部の範囲内にあり、金属化合物が、金属水酸化物、金属酸化物及び金属炭酸塩より選ばれる金属化合物と有機酸金属塩を併用したものであることを特徴とする透明性基材用装飾材。
- 光輝性塗料粒子成分が、大きさが20〜20,000μmの範囲内である請求項1に記載の透明性基材用装飾材。
- 塗料粒子成分が、その成分の一部として着色材及び樹脂を含む着色塗料組成物を粒状化してなる着色塗料粒子成分をさらに含む請求項1または2に記載の透明性基材用装飾材。
- 光輝性塗料粒子成分と着色塗料粒子成分の含有割合が光輝性塗料粒子成分/着色塗料粒子成分固形分質量比で99/1〜1/99の範囲内にある請求項3に記載の透明性基材用装飾材。
- さらに塗膜形成成分を含む請求項1ないし4のいずれか1項に記載の透明性基材用装飾材。
- 塗料粒子成分及び塗膜形成成分の配合割合が、塗料粒子成分/塗膜形成成分固形分質量比で、1/99〜70/30の範囲内にある請求項1ないし5のいずれか1項に記載の透明性基材用装飾材。
- 透明性基材に、下塗り材層を介してまたは介さずに請求項1ないし6のいずれか1項の記載の装飾材による装飾層を設けることを特徴とする透明性基材の装飾方法。
- 下塗り材層を設けるための下塗り材がヒドラジン誘導体を含む組成物である請求項7に記載の装飾方法。
- 請求項7または8に記載の装飾方法により得られる装飾品。
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