JP4682066B2 - 内照式看板用フィルム - Google Patents
内照式看板用フィルム Download PDFInfo
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- JP4682066B2 JP4682066B2 JP2006066832A JP2006066832A JP4682066B2 JP 4682066 B2 JP4682066 B2 JP 4682066B2 JP 2006066832 A JP2006066832 A JP 2006066832A JP 2006066832 A JP2006066832 A JP 2006066832A JP 4682066 B2 JP4682066 B2 JP 4682066B2
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- Prior art keywords
- film
- ethylene
- meth
- copolymer
- parts
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- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
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- JGCWKVKYRNXTMD-UHFFFAOYSA-N bicyclo[2.2.1]heptane;isocyanic acid Chemical compound N=C=O.N=C=O.C1CC2CCC1C2 JGCWKVKYRNXTMD-UHFFFAOYSA-N 0.000 description 3
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- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- XBZSBBLNHFMTEB-UHFFFAOYSA-N cyclohexane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCCC(C(O)=O)C1 XBZSBBLNHFMTEB-UHFFFAOYSA-N 0.000 description 1
- VKONPUDBRVKQLM-UHFFFAOYSA-N cyclohexane-1,4-diol Chemical compound OC1CCC(O)CC1 VKONPUDBRVKQLM-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- VKLYZBPBDRELST-UHFFFAOYSA-N ethene;methyl 2-methylprop-2-enoate Chemical compound C=C.COC(=O)C(C)=C VKLYZBPBDRELST-UHFFFAOYSA-N 0.000 description 1
- HGVPOWOAHALJHA-UHFFFAOYSA-N ethene;methyl prop-2-enoate Chemical compound C=C.COC(=O)C=C HGVPOWOAHALJHA-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 1
- 239000005043 ethylene-methyl acrylate Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- BWSZXUOMATYHHI-UHFFFAOYSA-N tert-butyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(C)(C)C BWSZXUOMATYHHI-UHFFFAOYSA-N 0.000 description 1
- 239000012970 tertiary amine catalyst Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
Description
店名のような意匠を施すには内照式看板用フィルムに印刷やマーキングフィルムを積層等して行われる。
内照式看板用フィルムには、耐候性、防汚性、マーキングフィルムとの接着力、耐水性、耐摩耗性、柔軟性及び抗張力等の力学的性質が必要とされている。このため、通常、軟質ポリ塩化ビニル系樹脂フィルムが用いられてきた。しかし、軟質ポリ塩化ビニル系樹脂フィルムを用いた場合、軟質ポリ塩化ビニル系樹脂に含有される可塑剤等が、経時的に表層へ滲み出すことにより、表面の粘着性が増して大気中の汚れが付着したり、耐候性または柔軟性等が低下したりするという問題点があった。
本発明に用いられるシ−ト状繊維としては特に限定されず、例えば、ビニロン繊維、ナイロン繊維、ポリエステル繊維、ポリアミド繊維等の合成繊維又は木綿、麻等の天然繊維を単独又は混合した編織物;ガラス繊維、炭素繊維、アラミド繊維等が挙げられる。なかでも、機械強度および難燃性能が必要とされる用途においては、ガラス繊維が好適に用いられる。
まず、保護層用の表面処理剤を以下のようにして作製した。なお、以下の表面処理剤の配合と性状を、表1にまとめて示した。
(表面処理剤1)
攪拌機、温度計、冷却器及び窒素ガス導入管を備えた反応容器に分子量1000のポリカーボネートジオール(日本ポリウレタン工業(株)製 商品名:ニッポラン981) 320.3部、イソホロンジイソシアネート(住友バイエルウレタン(株)製 商品名:ディスモジュールI)75.1部、トルエン500部を仕込み、窒素雰囲気下80℃、6時間以上反応させた。イソシアネート(NCO)濃度が理論量に到達した時点で2−ヒドロキシエチルメタアクリレート4.6部、トルエン100部を仕込み、ウレタンプレポリマーの両末端のNCOが消滅するまでさらに80℃、6時間反応させ、樹脂固形分濃度40%、粘度4000mPa・s(25℃)、重量平均分子量34000の高分子直鎖状ウレタンプレポリマー溶液を得た。
攪拌機、温度計、冷却器及び窒素ガス導入管を備えた反応容器に分子量1000のポリカーボネートジオール(日本ポリウレタン工業(株)製 商品名:ニッポラン981) 324.7部、ノルボルナンジイソシアネート(三井武田ケミカル(株)製 商品名:コスモネートNBDI)70.6部、トルエン500部を仕込み、窒素雰囲気下80℃、6時間以上反応させた。イソシアネート(NCO)濃度が理論量に到達した時点で2−ヒドロキシエチルメタアクリレート4.7部、トルエン100部を仕込み、ウレタンプレポリマーの両末端のNCOが消滅するまでさらに80℃、6時間反応させ、樹脂固形分濃度40%、粘度4700mPa・s(25℃)、重量平均分子量36000の高分子直鎖状ウレタンプレポリマー溶液を得た。
攪拌機、温度計、冷却器、窒素ガス導入管、および滴下装置を備えた反応容器に、トルエン450部を仕込み、攪拌しながら110℃まで昇温した。そこにメチルメタアクリレート220.5部、n−ブチルメタアクリレート77.0部、2−ヒドロキシエチルメタアクリレート52.5部、ラジカル開始剤(商品名:ABN−E、日本ヒドラジン工業(株)製)1.0部、トルエン100部からなる混合物を4時間かけて滴下した。滴下終了後、同温度で1時間反応させた。さらにトルエン100部、ABN−E0.5部からなる混合液を1時間かけて滴下した。滴下終了後、同温度で3時間反応させ、樹脂固形分35%、粘度110mPa・s(25℃)、重量平均分子量43000のアクリル樹脂を得た。このアクリル樹脂1000部にイソシアネート硬化剤(架橋剤)としてコロネートHLS(日本ポリウレタン工業(株)製)225部を混合した。この樹脂溶液を表面処理剤3とする。
「サンプル作製」
(基材作製)
エチレン−酢酸ビニル共重合体 EVAFLEX V5274(三井−デュポンポリケミカル(株)製)100重量部および水酸化アルミニウム H−42STV(昭和電工(株)製)50重量部を160℃にて2本ロールにて混練した後、熱プレスにより300μmのフィルムを作製した。ここで得られたフィルムをガラスクロス H202(ユニチカ(株)製)の両面にラミネーター(130℃)により積層させた。
得られた基材の片面にバーコーターにより変性エチレン−酢酸ビニル共重合体系プライマー ハニセメン P−957(ハニー化成(株)製)を乾燥膜厚5μmにて塗工した後、乾燥機にて乾燥を行った。その後、表2に記載の各表面処理剤を所定厚みに塗工した後、同様に乾燥を行った。
最後に表2に記載の表面粗さを付与するために、ロール表面にシボ加工が施された2本ロールによりシボ加工を実施した。
得られた内照式看板用フィルムについて以下の評価を行った。
(表面粗さ)
作製した内照式看板用フィルムの表面形状を走査型レーザー顕微鏡(商品名:1LM21レーザーテック(株)製)にて測定した。
(表面処理剤密着性)
作製した内照式看板用フィルムを180°に折り曲げた後、粘着テープにより表面処理剤の密着性を確認した。目視により粘着テープに表面処理剤が転写されないものを○、転写されるものを×と判断した。
プラスチックス樹脂の耐候性評価(JIS A1415)に準拠し作製した内照式看板用フィルムを促進曝露2000時間実施した後の外観を目視にて確認した。また併せて退色度合いを測色機(商品名:3600CD ミノルタ(株)製)にて測定した。
(マーキングフィルム接着性)
内照式看板用フィルムの表面に25mm×300mmにカットしたマーキングフィルム(商品名:エコパレット タックペイント KT0000 積水化学工業(株)製)を2kgのロールにて300mm/分の速度で貼付した後、23℃×24時間サンプルを養生した後、常法に従い接着力を測定した。
(透光率)
JIS K 7105「プラスチックの光学的特性評価試験方法」に準拠して、内照式看板用フィルムの全光線透過率(%)を測定した。
以上の評価結果を表2及び表3に示す。
Claims (3)
- シート状繊維の両面に膜厚50μm〜1mmのエチレン−(メタ)アクリル酸アルキル共重合体、エチレン−(メタ)アクリル酸共重合体、エチレン−酢酸ビニル共重合体およびエチレン−ビニルアルコ−ル共重合体からなる群より選択される少なくとも1種類の熱可塑性樹脂からなるフィルムを積層した構成体の片面または両面に、エチレン−酢酸ビニル共重合体系プライマーを介して、膜厚1〜100μmのエチレン性不飽和二重結合基を両末端に有する高分子直鎖状ポリウレタンプレポリマーに、少なくとも1種の(メタ)アクリル酸エステルを含有するビニル系化合物を反応させてなるアクリルウレタン共重合体からなるものであって、前記高分子直鎖状ポリウレタンプレポリマーの重量平均分子量が10,000〜100,000であり、該高分子直鎖状ポリウレタンプレポリマーとビニル系化合物との重量比が60/40〜30/70からなる保護層を積層してなり、
保護層の表面にシボ加工を施し、該保護層の表面粗さが、50>Rz/Sm>5(ここで、Rzは十点平均粗さ、Smは凹凸の平均間隔を示す)で表されることを特徴とする内照式看板用フィルム。 - 保護層の膜厚が、3〜20μmであることを特徴とする請求項1記載の内照式看板用フィルム。
- 透光率が15%を超えることを特徴とする請求項1又は2記載の内照式看板用フィルム。
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JP5410051B2 (ja) * | 2008-08-20 | 2014-02-05 | 株式会社ブリヂストン | 接着剤用樹脂組成物 |
WO2009084386A1 (ja) * | 2007-12-27 | 2009-07-09 | Bridgestone Corporation | 接着性樹脂組成物 |
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JP5410058B2 (ja) * | 2007-12-27 | 2014-02-05 | 株式会社ブリヂストン | 接着剤用樹脂組成物 |
JP2010072378A (ja) * | 2008-09-19 | 2010-04-02 | Sekisui Chem Co Ltd | 看板用難燃性シート |
JP5365501B2 (ja) * | 2009-12-24 | 2013-12-11 | 平岡織染株式会社 | 不燃性内照式電飾看板 |
JP5365500B2 (ja) * | 2009-12-24 | 2013-12-11 | 平岡織染株式会社 | 不燃性内照式電飾看板 |
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