JP4677527B2 - プロペンからアクロレインを生じさせる不均一系触媒による気相部分酸化の長期稼働を行う方法 - Google Patents

プロペンからアクロレインを生じさせる不均一系触媒による気相部分酸化の長期稼働を行う方法 Download PDF

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JP4677527B2
JP4677527B2 JP2006537118A JP2006537118A JP4677527B2 JP 4677527 B2 JP4677527 B2 JP 4677527B2 JP 2006537118 A JP2006537118 A JP 2006537118A JP 2006537118 A JP2006537118 A JP 2006537118A JP 4677527 B2 JP4677527 B2 JP 4677527B2
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catalyst
bed
propene
temperature
gas mixture
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JP2007509867A (ja
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ディーテルレ マルティーン
ペツォルト ヨッヘン
ヨアヒム ミュラー−エンゲル クラウス
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/14—Treating with free oxygen-containing gas with control of oxygen content in oxidation gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2006537118A 2003-10-29 2004-10-15 プロペンからアクロレインを生じさせる不均一系触媒による気相部分酸化の長期稼働を行う方法 Expired - Lifetime JP4677527B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US51511403P 2003-10-29 2003-10-29
DE10350812A DE10350812A1 (de) 2003-10-29 2003-10-29 Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation von Propen zu Acrolein
PCT/EP2004/011638 WO2005047224A1 (de) 2003-10-29 2004-10-15 Verfahren zum langzeitbetrieb einer heterogen katalysierten gasphasenpartialoxidation von propen zu acrolein

Related Child Applications (1)

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JP2010250320A Division JP2011026351A (ja) 2003-10-29 2010-11-08 プロペンからアクロレインを生じさせる不均一系触媒による気相部分酸化の長期稼働を行う方法

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JP2007509867A JP2007509867A (ja) 2007-04-19
JP4677527B2 true JP4677527B2 (ja) 2011-04-27

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JP2006537118A Expired - Lifetime JP4677527B2 (ja) 2003-10-29 2004-10-15 プロペンからアクロレインを生じさせる不均一系触媒による気相部分酸化の長期稼働を行う方法
JP2010250320A Withdrawn JP2011026351A (ja) 2003-10-29 2010-11-08 プロペンからアクロレインを生じさせる不均一系触媒による気相部分酸化の長期稼働を行う方法

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EP (1) EP1682474B1 (enExample)
JP (2) JP4677527B2 (enExample)
KR (1) KR101110524B1 (enExample)
BR (1) BRPI0416073B1 (enExample)
MY (1) MY137100A (enExample)
RU (1) RU2349576C9 (enExample)
TW (1) TWI369347B (enExample)
WO (1) WO2005047224A1 (enExample)

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MY144024A (en) * 2003-09-22 2011-07-29 Basf Ag Preparation of annular unsupported catalysts
US7538059B2 (en) 2006-01-31 2009-05-26 Rohm And Haas Company Regeneration of mixed metal oxide catalysts
JP2009263352A (ja) * 2008-03-31 2009-11-12 Mitsubishi Chemicals Corp モリブデンを含有する触媒を備えた固定床式反応器を用いた不飽和脂肪族アルデヒド、不飽和炭化水素及び不飽和脂肪酸からなる群から選ばれる少なくとも一種の反応物を製造する製造方法
EP2261196B1 (en) 2008-04-09 2014-01-15 Nippon Shokubai Co., Ltd. Process for the production of acrolein and/or acrylic acid
DE102008041573A1 (de) 2008-08-26 2010-03-04 Basf Se Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enhaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal
DE102008040799A1 (de) 2008-07-28 2008-12-11 Basf Se Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enthaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal
BRPI0916635B1 (pt) 2008-07-28 2020-04-14 Basf Se processo para separar ácido acrílico, presente como um produto principal, e glioxal, presente como um subproduto em uma mistura gasosa
DE102008042061A1 (de) 2008-09-12 2010-03-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008042060A1 (de) 2008-09-12 2009-06-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008042064A1 (de) 2008-09-12 2010-03-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102009027401A1 (de) 2009-07-01 2010-02-18 Basf Se Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung
DE102010001228A1 (de) 2010-01-26 2011-02-17 Basf Se Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung
WO2011000808A2 (de) 2009-07-01 2011-01-06 Basf Se Verfahren der abtrennung von acrylsäure aus dem produktgasgemisch einer heterogen katalysierten partiellen gasphasenoxidation wenigstens einer c3-vorläuferverbindung
DE102009047291A1 (de) 2009-11-30 2010-09-23 Basf Se Verfahren zur Herstellung von (Meth)acrolein durch heterogen katalysierte Gasphasen-Partialoxidation
DE102010042216A1 (de) 2010-10-08 2011-06-09 Basf Se Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure
DE102010048405A1 (de) * 2010-10-15 2011-05-19 Basf Se Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein
DE102011079035A1 (de) 2011-07-12 2013-01-17 Basf Se Mo, Bi und Fe enthaltende Multimetalloxidmassen
DE102011084040A1 (de) 2011-10-05 2012-01-05 Basf Se Mo, Bi und Fe enthaltende Multimetalloxidmasse
EP2731715B1 (de) 2011-07-12 2019-12-11 Basf Se Mo, bi und fe enthaltende multimetalloxidmassen
MY182262A (en) * 2013-07-18 2021-01-18 Nippon Kayaku Kk Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
DE102015209638A1 (de) 2015-05-27 2016-07-07 Basf Se Verfahren zur Herstellung eines Bismut und Wolfram enthaltenden Multielementoxids durch Co-Präzipitation
EP3331847B1 (en) 2015-08-07 2019-10-09 Basf Se Process for production of acrylic acid
DE102018200841A1 (de) 2018-01-19 2019-07-25 Basf Se Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen
KR102893876B1 (ko) 2018-07-26 2025-12-03 바스프 에스이 액상 p 중 존재하는 아크릴산의 원치않는 라디칼 중합의 억제 방법
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
WO2021191042A1 (de) 2020-03-26 2021-09-30 Basf Se Verfahren zur hemmung der unerwünschten radikalischen polymerisation von in einer flüssigen phase p befindlicher acrylsäure
JP2025527551A (ja) 2022-08-16 2025-08-22 ベーアーエスエフ・エスエー アルケン及び／又はアルコールを気相酸化してα，β－不飽和アルデヒド及び／又はα，β－不飽和カルボン酸を形成するためのバルク触媒成形体の製造方法
WO2025172145A1 (de) 2024-02-16 2025-08-21 Basf Se Anorganische faser-haltiger multi-element-vollkatalysatorformkörper zur herstellung von ungesättigten aldehyden und ungesättigten carbonsäuren; dessen herstellungsverfahren sowie verwendung in der gasphasenoxidation
WO2025176520A1 (de) 2024-02-23 2025-08-28 Basf Se Verfahren zur herstellung eines ethylenisch ungesättigten aldehyds und/oder einer ethylenisch ungesättigten carbonsäure an einem katalysatorfestbett eines rohrbündelreaktors
TW202615389A (zh) 2024-08-05 2026-04-16 德商巴地斯顏料化工廠 分離（甲基）丙烯酸的方法
WO2026032892A1 (de) 2024-08-05 2026-02-12 Basf Se Verfahren zur herstellung von (meth)acrylsäurealkylester ausgehend von (meth)acrylsäure

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JPS63137755A (ja) * 1986-11-28 1988-06-09 Nippon Shokubai Kagaku Kogyo Co Ltd 触媒の再活性化法
US5365266A (en) * 1991-12-10 1994-11-15 Carpenter Loren C Video imaging method and apparatus for audience participation
JP2702864B2 (ja) * 1993-03-12 1998-01-26 株式会社日本触媒 触媒の再生方法
DE4431957A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein
US6346646B1 (en) 1997-11-25 2002-02-12 Mitsubishi Rayon Co., Ltd. Process for producing methacrolein and methacrylic acid
JP3562983B2 (ja) * 1997-11-25 2004-09-08 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造方法
US6384274B1 (en) 1998-09-27 2002-05-07 Rohm And Haas Company Single reactor process for preparing acrylic acid from propylene having improved capacity
US6620968B1 (en) 1999-11-23 2003-09-16 Rohm And Haas Company High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids
DE10337788A1 (de) 2003-08-14 2004-10-28 Basf Ag Verfahren zur Herstellung von (Meth)acrolein und/oder (Meth)acrylsäure

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Publication number Publication date
WO2005047224A1 (de) 2005-05-26
BRPI0416073A (pt) 2007-01-02
EP1682474B1 (de) 2015-01-14
MY137100A (en) 2008-12-31
JP2007509867A (ja) 2007-04-19
TW200535127A (en) 2005-11-01
TWI369347B (en) 2012-08-01
EP1682474A1 (de) 2006-07-26
JP2011026351A (ja) 2011-02-10
RU2349576C9 (ru) 2010-02-20
RU2349576C2 (ru) 2009-03-20
RU2006118265A (ru) 2007-12-10
KR20060100397A (ko) 2006-09-20
BRPI0416073B1 (pt) 2014-03-25
KR101110524B1 (ko) 2012-01-31

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