JP4675439B2 - 化学気相堆積チャンバ内でプラズマ前処理を用いた窒化タングステンの堆積 - Google Patents
化学気相堆積チャンバ内でプラズマ前処理を用いた窒化タングステンの堆積 Download PDFInfo
- Publication number
- JP4675439B2 JP4675439B2 JP50576499A JP50576499A JP4675439B2 JP 4675439 B2 JP4675439 B2 JP 4675439B2 JP 50576499 A JP50576499 A JP 50576499A JP 50576499 A JP50576499 A JP 50576499A JP 4675439 B2 JP4675439 B2 JP 4675439B2
- Authority
- JP
- Japan
- Prior art keywords
- tungsten nitride
- wafer
- deposition
- plasma
- tungsten
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/40—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
- H10P14/42—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials using a gas or vapour
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/01—Manufacture or treatment
- H10W20/031—Manufacture or treatment of conductive parts of the interconnections
- H10W20/032—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
- H10W20/033—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers in openings in dielectrics
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0227—Pretreatment of the material to be coated by cleaning or etching
- C23C16/0245—Pretreatment of the material to be coated by cleaning or etching by etching with a plasma
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/08—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metal halides
- C23C16/14—Deposition of only one other metal element
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/0223—Manufacture or treatment of FETs having insulated gates [IGFET] having source and drain regions or source and drain extensions self-aligned to sides of the gate
- H10D30/0225—Manufacture or treatment of FETs having insulated gates [IGFET] having source and drain regions or source and drain extensions self-aligned to sides of the gate using an initial gate mask complementary to the prospective gate location, e.g. using dummy source and drain electrodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/013—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator
- H10D64/01302—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon
- H10D64/01304—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H10D64/01306—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon
- H10D64/01308—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon the conductor further comprising a non-elemental silicon additional conductive layer, e.g. a metal silicide layer formed by the reaction of silicon with an implanted metal
- H10D64/01312—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon the conductor further comprising a non-elemental silicon additional conductive layer, e.g. a metal silicide layer formed by the reaction of silicon with an implanted metal the additional layer comprising a metal or metal silicide formed by deposition, i.e. without a silicidation reaction, e.g. sputter deposition
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/661—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation
- H10D64/662—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation the conductor further comprising additional layers, e.g. multiple silicon layers having different crystal structures
- H10D64/664—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation the conductor further comprising additional layers, e.g. multiple silicon layers having different crystal structures the additional layers comprising a barrier layer between the layer of silicon and an upper metal or metal silicide layer
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/40—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
- H10P14/42—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials using a gas or vapour
- H10P14/43—Chemical deposition, e.g. chemical vapour deposition [CVD]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Vapour Deposition (AREA)
- Electrodes Of Semiconductors (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/884,811 US6309713B1 (en) | 1997-06-30 | 1997-06-30 | Deposition of tungsten nitride by plasma enhanced chemical vapor deposition |
| US08/884,811 | 1997-06-30 | ||
| US09/067,429 | 1998-04-27 | ||
| US09/067,429 US6872429B1 (en) | 1997-06-30 | 1998-04-27 | Deposition of tungsten nitride using plasma pretreatment in a chemical vapor deposition chamber |
| PCT/US1998/013305 WO1999000830A1 (en) | 1997-06-30 | 1998-06-26 | Improved deposition of tungsten nitride using plasma pretreatment in a chemical vapor deposition chamber |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002507327A JP2002507327A (ja) | 2002-03-05 |
| JP2002507327A5 JP2002507327A5 (https=) | 2005-12-22 |
| JP4675439B2 true JP4675439B2 (ja) | 2011-04-20 |
Family
ID=26747858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50576499A Expired - Lifetime JP4675439B2 (ja) | 1997-06-30 | 1998-06-26 | 化学気相堆積チャンバ内でプラズマ前処理を用いた窒化タングステンの堆積 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6872429B1 (https=) |
| EP (1) | EP0996973A1 (https=) |
| JP (1) | JP4675439B2 (https=) |
| KR (1) | KR20010014314A (https=) |
| TW (1) | TW432529B (https=) |
| WO (1) | WO1999000830A1 (https=) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6150257A (en) * | 1998-08-28 | 2000-11-21 | Micron Technology, Inc. | Plasma treatment of an interconnect surface during formation of an interlayer dielectric |
| US6355571B1 (en) * | 1998-11-17 | 2002-03-12 | Applied Materials, Inc. | Method and apparatus for reducing copper oxidation and contamination in a semiconductor device |
| US6391785B1 (en) * | 1999-08-24 | 2002-05-21 | Interuniversitair Microelektronica Centrum (Imec) | Method for bottomless deposition of barrier layers in integrated circuit metallization schemes |
| KR101035221B1 (ko) * | 2002-12-27 | 2011-05-18 | 가부시키가이샤 알박 | 질화 텅스텐막의 형성 방법 |
| US7311946B2 (en) | 2003-05-02 | 2007-12-25 | Air Products And Chemicals, Inc. | Methods for depositing metal films on diffusion barrier layers by CVD or ALD processes |
| JP2006156716A (ja) * | 2004-11-30 | 2006-06-15 | Renesas Technology Corp | 半導体装置およびその製造方法 |
| JP4738178B2 (ja) * | 2005-06-17 | 2011-08-03 | 富士通セミコンダクター株式会社 | 半導体装置の製造方法 |
| JP4608530B2 (ja) * | 2007-09-07 | 2011-01-12 | 株式会社アルバック | バリア膜製造方法 |
| JP2010010624A (ja) * | 2008-06-30 | 2010-01-14 | Ulvac Japan Ltd | 半導体装置の製造装置及び半導体装置の製造方法 |
| JP5925476B2 (ja) * | 2011-12-09 | 2016-05-25 | 株式会社アルバック | タングステン化合物膜の形成方法 |
| US9275865B2 (en) | 2012-10-31 | 2016-03-01 | Applied Materials, Inc. | Plasma treatment of film for impurity removal |
| US10622214B2 (en) * | 2017-05-25 | 2020-04-14 | Applied Materials, Inc. | Tungsten defluorination by high pressure treatment |
| KR102569956B1 (ko) * | 2017-07-25 | 2023-08-22 | 어플라이드 머티어리얼스, 인코포레이티드 | 개선된 박막 캡슐화 |
| US10276411B2 (en) | 2017-08-18 | 2019-04-30 | Applied Materials, Inc. | High pressure and high temperature anneal chamber |
| CN111936664A (zh) | 2018-03-19 | 2020-11-13 | 应用材料公司 | 在航空航天部件上沉积涂层的方法 |
| US11015252B2 (en) | 2018-04-27 | 2021-05-25 | Applied Materials, Inc. | Protection of components from corrosion |
| US11009339B2 (en) | 2018-08-23 | 2021-05-18 | Applied Materials, Inc. | Measurement of thickness of thermal barrier coatings using 3D imaging and surface subtraction methods for objects with complex geometries |
| US10636705B1 (en) | 2018-11-29 | 2020-04-28 | Applied Materials, Inc. | High pressure annealing of metal gate structures |
| EP3959356A4 (en) | 2019-04-26 | 2023-01-18 | Applied Materials, Inc. | METHOD OF PROTECTING AEROSPACE COMPONENTS AGAINST CORROSION AND OXIDATION |
| US11794382B2 (en) | 2019-05-16 | 2023-10-24 | Applied Materials, Inc. | Methods for depositing anti-coking protective coatings on aerospace components |
| US11697879B2 (en) | 2019-06-14 | 2023-07-11 | Applied Materials, Inc. | Methods for depositing sacrificial coatings on aerospace components |
| US11466364B2 (en) | 2019-09-06 | 2022-10-11 | Applied Materials, Inc. | Methods for forming protective coatings containing crystallized aluminum oxide |
| US11519066B2 (en) | 2020-05-21 | 2022-12-06 | Applied Materials, Inc. | Nitride protective coatings on aerospace components and methods for making the same |
| CN115734826A (zh) | 2020-07-03 | 2023-03-03 | 应用材料公司 | 用于翻新航空部件的方法 |
| US11976002B2 (en) | 2021-01-05 | 2024-05-07 | Applied Materials, Inc. | Methods for encapsulating silver mirrors on optical structures |
| CN112938910B (zh) * | 2021-04-16 | 2022-09-20 | 中国检验检疫科学研究院 | 一种薄片状氮化钨纳米材料的合成方法及应用 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2571542B1 (fr) * | 1984-10-09 | 1987-01-23 | Labo Electronique Physique | Procede de realisation d'un dispositif semiconducteur incluant l'action de plasma |
| EP0261846B1 (en) * | 1986-09-17 | 1992-12-02 | Fujitsu Limited | Method of forming a metallization film containing copper on the surface of a semiconductor device |
| US4913929A (en) * | 1987-04-21 | 1990-04-03 | The Board Of Trustees Of The Leland Stanford Junior University | Thermal/microwave remote plasma multiprocessing reactor and method of use |
| US4751101A (en) * | 1987-04-30 | 1988-06-14 | International Business Machines Corporation | Low stress tungsten films by silicon reduction of WF6 |
| JPS63317676A (ja) | 1987-06-19 | 1988-12-26 | Sharp Corp | 無粒構造金属化合物薄膜の製造方法 |
| JPS645015A (en) | 1987-06-26 | 1989-01-10 | Sharp Kk | Manufacture of integrated circuit element |
| US4847111A (en) * | 1988-06-30 | 1989-07-11 | Hughes Aircraft Company | Plasma-nitridated self-aligned tungsten system for VLSI interconnections |
| KR940000906B1 (ko) * | 1988-11-21 | 1994-02-04 | 가부시키가이샤 도시바 | 반도체장치의 제조방법 |
| US5232872A (en) | 1989-05-09 | 1993-08-03 | Fujitsu Limited | Method for manufacturing semiconductor device |
| IT1241922B (it) | 1990-03-09 | 1994-02-01 | Eniricerche Spa | Procedimento per realizzare rivestimenti di carburo di silicio |
| KR100228259B1 (ko) | 1990-10-24 | 1999-11-01 | 고지마 마따오 | 박막의 형성방법 및 반도체장치 |
| US5250467A (en) | 1991-03-29 | 1993-10-05 | Applied Materials, Inc. | Method for forming low resistance and low defect density tungsten contacts to silicon semiconductor wafer |
| KR930011538B1 (ko) * | 1991-07-16 | 1993-12-10 | 한국과학기술연구원 | 실리콘 반도체소자의 금속배선 형성용 텅스텐 질화박막 증착방법 |
| WO1994004716A1 (en) * | 1992-08-14 | 1994-03-03 | Hughes Aircraft Company | Surface preparation and deposition method for titanium nitride onto carbonaceous materials |
| JPH07142416A (ja) | 1993-06-21 | 1995-06-02 | Applied Materials Inc | 改良された界面を有する層のプラズマ化学蒸着法 |
| WO1995034092A1 (en) | 1994-06-03 | 1995-12-14 | Materials Research Corporation | A method of nitridization of titanium thin films |
| JPH0869994A (ja) * | 1994-08-30 | 1996-03-12 | Fujitsu Ltd | 半導体装置の製造方法 |
| US5576071A (en) * | 1994-11-08 | 1996-11-19 | Micron Technology, Inc. | Method of reducing carbon incorporation into films produced by chemical vapor deposition involving organic precursor compounds |
| EP0711846A1 (en) | 1994-11-14 | 1996-05-15 | Applied Materials, Inc. | Titanium nitride deposited by chemical vapor deposition |
| JP2978748B2 (ja) * | 1995-11-22 | 1999-11-15 | 日本電気株式会社 | 半導体装置の製造方法 |
| US6009827A (en) | 1995-12-06 | 2000-01-04 | Applied Materials, Inc. | Apparatus for creating strong interface between in-situ SACVD and PECVD silicon oxide films |
| US5648175A (en) * | 1996-02-14 | 1997-07-15 | Applied Materials, Inc. | Chemical vapor deposition reactor system and integrated circuit |
| US5633200A (en) * | 1996-05-24 | 1997-05-27 | Micron Technology, Inc. | Process for manufacturing a large grain tungsten nitride film and process for manufacturing a lightly nitrided titanium salicide diffusion barrier with a large grain tungsten nitride cover layer |
| TW365685B (en) * | 1996-10-31 | 1999-08-01 | Texas Instruments Inc | Low-temperature processes for depositing barrier films containing tungsten and nitrogen |
| EP0841690B1 (en) * | 1996-11-12 | 2006-03-01 | Samsung Electronics Co., Ltd. | Tungsten nitride (WNx) layer manufacturing method and metal wiring manufacturing method |
| US6162715A (en) * | 1997-06-30 | 2000-12-19 | Applied Materials, Inc. | Method of forming gate electrode connection structure by in situ chemical vapor deposition of tungsten and tungsten nitride |
| US5913145A (en) | 1997-08-28 | 1999-06-15 | Texas Instruments Incorporated | Method for fabricating thermally stable contacts with a diffusion barrier formed at high temperatures |
| US6095085A (en) * | 1998-08-20 | 2000-08-01 | Micron Technology, Inc. | Photo-assisted remote plasma apparatus and method |
-
1998
- 1998-04-27 US US09/067,429 patent/US6872429B1/en not_active Expired - Lifetime
- 1998-06-26 TW TW087110410A patent/TW432529B/zh not_active IP Right Cessation
- 1998-06-26 KR KR1019997012452A patent/KR20010014314A/ko not_active Withdrawn
- 1998-06-26 EP EP98934178A patent/EP0996973A1/en not_active Withdrawn
- 1998-06-26 WO PCT/US1998/013305 patent/WO1999000830A1/en not_active Ceased
- 1998-06-26 JP JP50576499A patent/JP4675439B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20010014314A (ko) | 2001-02-26 |
| TW432529B (en) | 2001-05-01 |
| US6872429B1 (en) | 2005-03-29 |
| JP2002507327A (ja) | 2002-03-05 |
| WO1999000830A1 (en) | 1999-01-07 |
| EP0996973A1 (en) | 2000-05-03 |
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