JP4530616B2 - ポリチオフェン類を用いたデバイス - Google Patents
ポリチオフェン類を用いたデバイス Download PDFInfo
- Publication number
- JP4530616B2 JP4530616B2 JP2003006210A JP2003006210A JP4530616B2 JP 4530616 B2 JP4530616 B2 JP 4530616B2 JP 2003006210 A JP2003006210 A JP 2003006210A JP 2003006210 A JP2003006210 A JP 2003006210A JP 4530616 B2 JP4530616 B2 JP 4530616B2
- Authority
- JP
- Japan
- Prior art keywords
- thin film
- polythiophenes
- polythiophene
- film transistor
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/464—Lateral top-gate IGFETs comprising only a single gate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/466—Lateral bottom-gate IGFETs comprising only a single gate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/151—Copolymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Thin Film Transistor (AREA)
- Electroluminescent Light Sources (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/042,356 US6621099B2 (en) | 2002-01-11 | 2002-01-11 | Polythiophenes and devices thereof |
| US10/042,356 | 2002-01-11 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003264327A JP2003264327A (ja) | 2003-09-19 |
| JP2003264327A5 JP2003264327A5 (enExample) | 2006-02-23 |
| JP4530616B2 true JP4530616B2 (ja) | 2010-08-25 |
Family
ID=21921442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003006210A Expired - Lifetime JP4530616B2 (ja) | 2002-01-11 | 2003-01-14 | ポリチオフェン類を用いたデバイス |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US6621099B2 (enExample) |
| EP (1) | EP1329474B1 (enExample) |
| JP (1) | JP4530616B2 (enExample) |
| DE (1) | DE60308738T2 (enExample) |
Families Citing this family (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1289342B1 (en) * | 2001-09-04 | 2006-11-22 | Sony Deutschland GmbH | Aligned emissive polymer blends, film and device based thereon |
| US6949762B2 (en) * | 2002-01-11 | 2005-09-27 | Xerox Corporation | Polythiophenes and devices thereof |
| US6770904B2 (en) * | 2002-01-11 | 2004-08-03 | Xerox Corporation | Polythiophenes and electronic devices generated therefrom |
| EP1498456A4 (en) * | 2002-04-22 | 2009-06-10 | Konica Corp | ORGANIC SEMICONDUCTOR COMPOSITION, ORGANIC SEMICONDUCTOR ELEMENT AND MANUFACTURING METHOD THEREFOR |
| US6821811B2 (en) * | 2002-08-02 | 2004-11-23 | Semiconductor Energy Laboratory Co., Ltd. | Organic thin film transistor and method of manufacturing the same, and semiconductor device having the organic thin film transistor |
| US6803262B2 (en) * | 2002-10-17 | 2004-10-12 | Xerox Corporation | Process using self-organizable polymer |
| US6890868B2 (en) * | 2002-10-17 | 2005-05-10 | Xerox Corporation | Process for depositing gelable composition that includes dissolving gelable composition in liquid with agitating to disrupt gelling |
| US7220985B2 (en) * | 2002-12-09 | 2007-05-22 | Spansion, Llc | Self aligned memory element and wordline |
| GB0229191D0 (en) * | 2002-12-14 | 2003-01-22 | Plastic Logic Ltd | Embossing of polymer devices |
| EP1434281A3 (en) * | 2002-12-26 | 2007-10-24 | Konica Minolta Holdings, Inc. | Manufacturing method of thin-film transistor, thin-film transistor sheet, and electric circuit |
| US7973313B2 (en) | 2003-02-24 | 2011-07-05 | Semiconductor Energy Laboratory Co., Ltd. | Thin film integrated circuit device, IC label, container comprising the thin film integrated circuit, manufacturing method of the thin film integrated circuit device, manufacturing method of the container, and management method of product having the container |
| US6897284B2 (en) * | 2003-03-19 | 2005-05-24 | Xerox Corporation | Polythiophenes and devices thereof |
| US6855951B2 (en) * | 2003-03-19 | 2005-02-15 | Xerox Corporation | Fluorinated polythiophenes and devices thereof |
| DE10337346A1 (de) | 2003-08-12 | 2005-03-31 | Covion Organic Semiconductors Gmbh | Konjugierte Polymere enthaltend Dihydrophenanthren-Einheiten und deren Verwendung |
| CN100492697C (zh) * | 2003-08-22 | 2009-05-27 | 松下电器产业株式会社 | 纵型有机fet及其制造方法 |
| US7169883B2 (en) * | 2003-08-22 | 2007-01-30 | Xerox Corporation | Polymers |
| US20080217604A1 (en) * | 2003-08-29 | 2008-09-11 | Matsushita Electric Industrial Co., Ltd. | Organic Semiconductor Film, Electron Device Using the Same and Manufacturing Method Therefor |
| US6852586B1 (en) * | 2003-10-01 | 2005-02-08 | Advanced Micro Devices, Inc. | Self assembly of conducting polymer for formation of polymer memory cell |
| KR101007787B1 (ko) * | 2003-12-08 | 2011-01-14 | 삼성전자주식회사 | 퀴녹살린환을 주쇄에 포함하는 유기박막 트랜지스터용유기반도체 고분자 |
| US7768405B2 (en) * | 2003-12-12 | 2010-08-03 | Semiconductor Energy Laboratory Co., Ltd | Semiconductor device and manufacturing method thereof |
| KR101137797B1 (ko) * | 2003-12-15 | 2012-04-20 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 박막 집적회로장치의 제조방법, 비접촉형 박막집적회로장치 및 그 제조 방법, 비접촉형 박막 집적회로장치를 가지는 아이디 태그 및 동전 |
| WO2005070992A2 (en) * | 2004-01-27 | 2005-08-04 | Canon Kabushiki Kaisha | Conjugated thiophene compound, conprising perfluorinated and alkylated sidechains, conductive organic thin film containing the compound, and field-effect type organic transistor employing the thin film |
| US7531832B2 (en) * | 2004-02-16 | 2009-05-12 | Japan Science And Technology Agency | Light-emitting transistor |
| US7057205B2 (en) * | 2004-03-17 | 2006-06-06 | Lucent Technologies Inc. | P-type OFET with fluorinated channels |
| TWI228833B (en) * | 2004-05-04 | 2005-03-01 | Ind Tech Res Inst | Method for enhancing the electrical characteristics of organic electronic devices |
| DE102004020298A1 (de) * | 2004-04-26 | 2005-11-10 | Covion Organic Semiconductors Gmbh | Elektrolumineszierende Polymere und deren Verwendung |
| GB0410921D0 (en) * | 2004-05-14 | 2004-06-16 | Plastic Logic Ltd | Self-aligned active layer island |
| CN102702486A (zh) | 2004-05-18 | 2012-10-03 | 默克专利股份有限公司 | 单体、低聚和聚噻吩并[3,2-b]噻吩 |
| KR20070033992A (ko) * | 2004-06-09 | 2007-03-27 | 메르크 파텐트 게엠베하 | 중합성 티에노[3,2-b]티오펜 |
| US7294850B2 (en) * | 2004-06-10 | 2007-11-13 | Xerox Corporation | Device with small molecular thiophene compound having divalent linkage |
| US7312469B2 (en) * | 2004-06-10 | 2007-12-25 | Xerox Corporation | Device with small molecular thiophene compound |
| US7102017B2 (en) * | 2004-06-10 | 2006-09-05 | Xerox Corporation | Processes to prepare small molecular thiophene compounds |
| KR101069519B1 (ko) | 2004-07-08 | 2011-09-30 | 삼성전자주식회사 | 올리고티오펜과 n-형 방향족 화합물을 주쇄에 교호로 포함하는 유기 반도체 고분자 |
| US7105375B2 (en) * | 2004-07-30 | 2006-09-12 | Xerox Corporation | Reverse printing |
| KR100691319B1 (ko) * | 2004-09-15 | 2007-03-12 | 엘지.필립스 엘시디 주식회사 | 유기 박막 트랜지스터 및 그의 제조 방법 |
| US7270694B2 (en) | 2004-10-05 | 2007-09-18 | Xerox Corporation | Stabilized silver nanoparticles and their use |
| CN100345888C (zh) * | 2004-11-01 | 2007-10-31 | 中国科学院化学研究所 | 一种支链共轭聚噻吩衍生物材料及其制备方法 |
| US7170093B2 (en) * | 2004-11-05 | 2007-01-30 | Xerox Corporation | Dielectric materials for electronic devices |
| KR100603397B1 (ko) * | 2004-11-18 | 2006-07-20 | 삼성에스디아이 주식회사 | 유기 박막 트랜지스터 및 이를 구비한 평판 디스플레이 장치 |
| EP1670079B1 (en) * | 2004-12-08 | 2010-12-01 | Samsung Mobile Display Co., Ltd. | Method of forming a conductive pattern of a thin film transistor |
| KR20060070716A (ko) * | 2004-12-21 | 2006-06-26 | 한국전자통신연구원 | 유기 메모리 소자 및 제조 방법 |
| JP4731942B2 (ja) * | 2005-02-16 | 2011-07-27 | 住友化学株式会社 | ポリチオフェン |
| US7619242B2 (en) * | 2005-02-25 | 2009-11-17 | Xerox Corporation | Celluloses and devices thereof |
| JP2006261486A (ja) * | 2005-03-18 | 2006-09-28 | Ricoh Co Ltd | 有機薄膜トランジスタ及びそれを用いた画像表示装置 |
| US7321021B2 (en) * | 2005-03-22 | 2008-01-22 | Xerox Corporation | Removing impurities from polythiophene |
| US8089062B2 (en) * | 2005-03-23 | 2012-01-03 | Xerox Corporation | Wax encapsulated electronic devices |
| GB2424759A (en) * | 2005-04-01 | 2006-10-04 | Seiko Epson Corp | Inkjet deposition of polythiophene semiconductor material dissolved in halogenated aromatic solvents |
| US20060231908A1 (en) * | 2005-04-13 | 2006-10-19 | Xerox Corporation | Multilayer gate dielectric |
| KR101102158B1 (ko) * | 2005-05-11 | 2012-01-02 | 삼성전자주식회사 | 신규한 유기 고분자 반도체, 이를 이용한 유기 고분자반도체 박막의 형성방법 및 이를 이용한 유기박막트랜지스터 |
| US7341893B2 (en) * | 2005-06-02 | 2008-03-11 | Hewlett-Packard Development Company, L.P. | Structure and method for thin film device |
| US7994509B2 (en) * | 2005-11-01 | 2011-08-09 | Hewlett-Packard Development Company, L.P. | Structure and method for thin film device with stranded conductor |
| US7705346B2 (en) * | 2005-06-06 | 2010-04-27 | Xerox Corporation | Barrier layer for an organic electronic device |
| US9024298B2 (en) * | 2005-07-26 | 2015-05-05 | Xerox Corporation | Encapsulation layer for electronic devices |
| CN101297415A (zh) * | 2005-08-01 | 2008-10-29 | 普莱克斯托尼克斯公司 | 导电聚合物的潜在掺杂 |
| JP4860980B2 (ja) * | 2005-10-20 | 2012-01-25 | ローム株式会社 | モータ駆動回路およびそれを用いたディスク装置 |
| US7314908B2 (en) * | 2005-11-18 | 2008-01-01 | Xerox Corporation | Polythiophene processes |
| US7425723B2 (en) * | 2005-12-21 | 2008-09-16 | Xerox Corporation | Organic thin-film transistors |
| US7632703B2 (en) * | 2005-12-22 | 2009-12-15 | Xerox Corporation | Organic thin-film transistors |
| US7345303B2 (en) * | 2005-12-22 | 2008-03-18 | Xerox Corporation | Organic thin-film transistors |
| US7784173B2 (en) * | 2005-12-27 | 2010-08-31 | Palo Alto Research Center Incorporated | Producing layered structures using printing |
| US8637138B2 (en) | 2005-12-27 | 2014-01-28 | Palo Alto Research Center Incorporated | Layered structures on thin substrates |
| US7816146B2 (en) * | 2005-12-27 | 2010-10-19 | Palo Alto Research Center Incorporated | Passive electronic devices |
| US20070188483A1 (en) * | 2006-01-30 | 2007-08-16 | The Samson Group, Llc | Display apparatus for outdoor signs and related system of displays and methods of use |
| KR100772662B1 (ko) | 2006-02-01 | 2007-11-02 | 학교법인 포항공과대학교 | 전계 효과 전하 이동도를 증가시킬 수 있는 유기 박막트랜지스터 및 그 제조방법 |
| KR101314931B1 (ko) * | 2006-10-30 | 2013-10-04 | 삼성전자주식회사 | 유기 고분자 반도체, 이의 제조방법 및 이를 이용한 양극성 유기 박막 트랜지스터 |
| US7816469B2 (en) * | 2006-12-12 | 2010-10-19 | Xerox Corporation | Process for producing polymer nanodispersions |
| JP2008235780A (ja) * | 2007-03-23 | 2008-10-02 | Toshiba Corp | 薄膜トランジスタおよびその製造方法 |
| US7795614B2 (en) | 2007-04-02 | 2010-09-14 | Xerox Corporation | Device with phase-separated dielectric structure |
| US7754510B2 (en) | 2007-04-02 | 2010-07-13 | Xerox Corporation | Phase-separated dielectric structure fabrication process |
| US7652339B2 (en) * | 2007-04-06 | 2010-01-26 | Xerox Corporation | Ambipolar transistor design |
| US20090142482A1 (en) * | 2007-11-30 | 2009-06-04 | Xerox Corporation | Methods of Printing Conductive Silver Features |
| US20090148600A1 (en) * | 2007-12-05 | 2009-06-11 | Xerox Corporation | Metal Nanoparticles Stabilized With a Carboxylic Acid-Organoamine Complex |
| US20090224011A1 (en) * | 2008-03-07 | 2009-09-10 | Sperbeck Bryanlee P | Method of and an apparatus for assisting in putting on and taking off a wet suit used by water enthusiasts |
| US7821068B2 (en) | 2008-08-18 | 2010-10-26 | Xerox Corporation | Device and process involving pinhole undercut area |
| US8298314B2 (en) * | 2008-08-18 | 2012-10-30 | Xerox Corporation | Silver nanoparticles and process for producing same |
| US8419822B2 (en) * | 2008-08-18 | 2013-04-16 | Xerox Corporation | Methods for producing carboxylic acid stabilized silver nanoparticles |
| KR20100064657A (ko) * | 2008-12-05 | 2010-06-15 | 엘지디스플레이 주식회사 | 박막트랜지스터 어레이기판과 그 제조방법 |
| US8834965B2 (en) | 2009-02-12 | 2014-09-16 | Xerox Corporation | Organoamine stabilized silver nanoparticles and process for producing same |
| US7935278B2 (en) | 2009-03-05 | 2011-05-03 | Xerox Corporation | Feature forming process using acid-containing composition |
| US20100233361A1 (en) * | 2009-03-12 | 2010-09-16 | Xerox Corporation | Metal nanoparticle composition with improved adhesion |
| KR101644048B1 (ko) * | 2009-08-25 | 2016-07-29 | 삼성전자 주식회사 | 유기 반도체 고분자 및 이를 포함하는 트랜지스터 |
| WO2011093463A1 (ja) * | 2010-01-29 | 2011-08-04 | 日立化成工業株式会社 | トリメチレン構造を有する化合物、トリメチレン構造を有する単位を含む高分子化合物、及びトリメチレン構造を有する反応性化合物 |
| US8366971B2 (en) | 2010-04-02 | 2013-02-05 | Xerox Corporation | Additive for robust metal ink formulations |
| US9076975B2 (en) | 2010-04-27 | 2015-07-07 | Xerox Corporation | Dielectric composition for thin-film transistors |
| US8147908B2 (en) | 2010-06-09 | 2012-04-03 | Xerox Corporation | Increased throughput for large-scale production of low melt organoamine stabilized silver nano-particles |
| US8765025B2 (en) | 2010-06-09 | 2014-07-01 | Xerox Corporation | Silver nanoparticle composition comprising solvents with specific hansen solubility parameters |
| JP5692228B2 (ja) * | 2010-07-02 | 2015-04-01 | コニカミノルタ株式会社 | 有機光電変換素子およびそれを用いた太陽電池 |
| US8158032B2 (en) | 2010-08-20 | 2012-04-17 | Xerox Corporation | Silver nanoparticle ink composition for highly conductive features with enhanced mechanical properties |
| US8623447B2 (en) | 2010-12-01 | 2014-01-07 | Xerox Corporation | Method for coating dielectric composition for fabricating thin-film transistors |
| US8586134B2 (en) | 2011-05-06 | 2013-11-19 | Xerox Corporation | Method of fabricating high-resolution features |
| US20130029034A1 (en) | 2011-07-28 | 2013-01-31 | Xerox Corporation | Process for producing silver nanoparticles |
| WO2013133688A1 (en) | 2012-03-09 | 2013-09-12 | Mimos Berhad | Nanocomposite casting composition |
| US9525135B2 (en) | 2013-01-28 | 2016-12-20 | Xerox Corporation | Thixotropic composition |
| KR101532310B1 (ko) * | 2013-02-18 | 2015-06-29 | 삼성전자주식회사 | 2차원 소재 적층 플렉서블 광센서 |
| CN105304497B (zh) * | 2015-09-30 | 2021-05-14 | 京东方科技集团股份有限公司 | 一种薄膜晶体管、阵列基板及相关制作方法 |
| WO2021041456A1 (en) * | 2019-08-27 | 2021-03-04 | Phillips 66 Company | Methods and systems of organic semiconducting polymers |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2664430B1 (fr) * | 1990-07-04 | 1992-09-18 | Centre Nat Rech Scient | Transistor a effet de champ en couche mince de structure mis, dont l'isolant et le semiconducteur sont realises en materiaux organiques. |
| FR2703359B1 (fr) * | 1993-03-31 | 1995-06-23 | Cis Bio Int | Copolymère nucléotide(s)/polymère conducteur électronique ; son procédé de préparation et son utilisation . |
| US5619357A (en) | 1995-06-06 | 1997-04-08 | International Business Machines Corporation | Flat panel display containing black matrix polymer |
| US6242561B1 (en) * | 1996-03-06 | 2001-06-05 | Basf Aktiengesellschaft | Substituted polythiophenes, processes for their preparation their use |
| US5969376A (en) | 1996-08-23 | 1999-10-19 | Lucent Technologies Inc. | Organic thin film transistor having a phthalocyanine semiconductor layer |
| US6107117A (en) * | 1996-12-20 | 2000-08-22 | Lucent Technologies Inc. | Method of making an organic thin film transistor |
| US5777070A (en) | 1997-10-23 | 1998-07-07 | The Dow Chemical Company | Process for preparing conjugated polymers |
| US6447668B1 (en) * | 1998-07-09 | 2002-09-10 | Acm Research, Inc. | Methods and apparatus for end-point detection |
| NO314525B1 (no) * | 1999-04-22 | 2003-03-31 | Thin Film Electronics Asa | Fremgangsmåte ved fremstillingen av organiske halvledende innretninger i tynnfilm |
| GB0028867D0 (en) * | 2000-11-28 | 2001-01-10 | Avecia Ltd | Field effect translators,methods for the manufacture thereof and materials therefor |
| US6770904B2 (en) * | 2002-01-11 | 2004-08-03 | Xerox Corporation | Polythiophenes and electronic devices generated therefrom |
-
2002
- 2002-01-11 US US10/042,356 patent/US6621099B2/en not_active Expired - Lifetime
-
2003
- 2003-01-10 DE DE60308738T patent/DE60308738T2/de not_active Expired - Lifetime
- 2003-01-10 EP EP03000412A patent/EP1329474B1/en not_active Expired - Lifetime
- 2003-01-14 JP JP2003006210A patent/JP4530616B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20030136958A1 (en) | 2003-07-24 |
| DE60308738D1 (de) | 2006-11-16 |
| US6621099B2 (en) | 2003-09-16 |
| DE60308738T2 (de) | 2007-01-18 |
| EP1329474B1 (en) | 2006-10-04 |
| JP2003264327A (ja) | 2003-09-19 |
| EP1329474A1 (en) | 2003-07-23 |
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