JP4458843B2 - 改良重合法 - Google Patents

改良重合法 Download PDF

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Publication number
JP4458843B2
JP4458843B2 JP2003515572A JP2003515572A JP4458843B2 JP 4458843 B2 JP4458843 B2 JP 4458843B2 JP 2003515572 A JP2003515572 A JP 2003515572A JP 2003515572 A JP2003515572 A JP 2003515572A JP 4458843 B2 JP4458843 B2 JP 4458843B2
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JP
Japan
Prior art keywords
monomer
styrene
acrylonitrile
diene
added
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Expired - Fee Related
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JP2003515572A
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English (en)
Japanese (ja)
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JP2004536915A5 (enExample
JP2004536915A (ja
Inventor
ヴィラサガー，シュリパシー
ローリー，バーン
フェラーリス，デーン・エム
コルボーン，ロバート・イー
フェン，ケ
リトルジョン，マシュー・ハル
タウンゼンド，デビッド・フランシス
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SABIC Global Technologies BV
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SABIC Global Technologies BV
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Biological Depolymerization Polymers (AREA)
JP2003515572A 2001-07-24 2002-07-24 改良重合法 Expired - Fee Related JP4458843B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US30744501P 2001-07-24 2001-07-24
US10/200,877 US6784253B2 (en) 2001-07-24 2002-07-23 Enhanced polymerization process
PCT/US2002/023674 WO2003010214A1 (en) 2001-07-24 2002-07-24 Enhanced polymerization process

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2008267855A Division JP5378749B2 (ja) 2001-07-24 2008-10-16 改良重合法

Publications (3)

Publication Number Publication Date
JP2004536915A JP2004536915A (ja) 2004-12-09
JP2004536915A5 JP2004536915A5 (enExample) 2006-01-05
JP4458843B2 true JP4458843B2 (ja) 2010-04-28

Family

ID=26896191

Family Applications (2)

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JP2003515572A Expired - Fee Related JP4458843B2 (ja) 2001-07-24 2002-07-24 改良重合法
JP2008267855A Expired - Fee Related JP5378749B2 (ja) 2001-07-24 2008-10-16 改良重合法

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Application Number Title Priority Date Filing Date
JP2008267855A Expired - Fee Related JP5378749B2 (ja) 2001-07-24 2008-10-16 改良重合法

Country Status (7)

Country Link
US (1) US6784253B2 (enExample)
EP (1) EP1414873B1 (enExample)
JP (2) JP4458843B2 (enExample)
CN (1) CN100471883C (enExample)
AT (1) ATE416202T1 (enExample)
DE (1) DE60230152D1 (enExample)
WO (1) WO2003010214A1 (enExample)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1313506C (zh) * 2004-08-04 2007-05-02 中国石油天然气集团公司 一种附聚后聚丁二烯胶乳与苯乙烯和丙烯腈的聚合方法
US8084550B2 (en) * 2005-05-23 2011-12-27 Sabic Innovative Plastics Ip B.V. Low gloss thermoplastic composition
US20070173619A1 (en) * 2005-05-23 2007-07-26 Yu Claire Q Low gloss thermoplastic articles
KR101126016B1 (ko) * 2005-10-04 2012-03-19 주식회사 엘지화학 잔류 단량체 함량이 낮은 그라프트 고무 라텍스의 제조방법
KR101098683B1 (ko) 2006-12-22 2011-12-23 주식회사 엘지화학 중합전환율이 높은 아크릴로 니트릴-부타디엔-스티렌계공중합 라텍스 분말의 제조방법
US9732178B1 (en) 2008-07-24 2017-08-15 Bridgestone Corporation Block copolymers including high vinyl segments
EP2308906A1 (en) 2009-10-07 2011-04-13 Styron Europe GmbH Impact-modified monovinylidene aromatic polymer having low rubber crosslinking
CN102199253B (zh) * 2010-03-26 2013-02-13 中国石油天然气股份有限公司 一种abs树脂的双峰乳液接枝制备方法
DE102010031338A1 (de) * 2010-07-14 2012-01-19 Wacker Chemie Ag Teilkontinuierliches Verfahren zur Emulsionspolymerisation
KR101385907B1 (ko) * 2011-04-12 2014-04-15 주식회사 엘지화학 중합 생산성이 개선된 폴리부타디엔 라텍스 제조방법
US9193874B2 (en) 2012-07-16 2015-11-24 Empire Technology Development Llc Self-renewing hydrophilic organic coatings
US9023962B2 (en) * 2012-08-20 2015-05-05 Honeywell International Inc. Synthesis of high molecular weight poly(2,3,3,3-tetrafluoropropene)
EP2920255B1 (en) * 2012-11-19 2019-03-13 Hewlett-Packard Development Company, L.P. Compositions for three-dimensional (3d) printing
US9321867B2 (en) * 2012-12-21 2016-04-26 Honeywell International Inc. Synthesis of 2,3,3,3-tetrafluoropropene/vinylidene fluoride copolymers
US8906995B2 (en) 2013-03-15 2014-12-09 Sabic Global Technologies B.V. Polymer compositions, method of manufacture, and articles formed therefrom
US9493670B2 (en) 2013-04-18 2016-11-15 Empire Technology Development Llc Coatings that provide hydrophilic surface
CA2923011A1 (en) 2013-10-14 2015-04-23 Halliburton Energy Services, Inc. Treatment fluids containing polysaccharides with friction reducing grafts thereon
CN104693636B (zh) * 2013-12-06 2017-07-14 中国石油天然气股份有限公司 一种具有提高abs接枝共聚物转化率的聚合方法
WO2015165810A1 (de) * 2014-04-30 2015-11-05 Styrolution Group Gmbh Thermoplastische formmassen mit optimiertem restmonomeranteil
CN105601769A (zh) * 2016-03-03 2016-05-25 天津大沽化工股份有限公司 一种改善abs树脂基色的接枝胶乳凝聚方法
KR102699824B1 (ko) 2017-10-13 2024-08-27 사빅 글로벌 테크놀러지스 비.브이. 탄성중합체 응집체 조성물을 생산하기 위한 공정
EP3694635B1 (en) 2017-10-13 2022-12-28 SABIC Global Technologies B.V. A process for production of elastomer agglomerate composition, elastomer agglomerate composition and its use
JP7009284B2 (ja) * 2018-03-30 2022-01-25 株式会社カネカ グラフト共重合体の製造方法、及び塩化ビニル系樹脂組成物の製造方法
CN109796550B (zh) * 2019-01-08 2021-09-03 同济大学 一种低分子量液体橡胶的制备方法
EP3680266B1 (en) * 2019-01-09 2025-08-27 Trinseo Europe GmbH Influence of vinylidene substituted aromatic monomers on nitrile migration
CN114085338B (zh) * 2020-08-24 2024-01-30 中国石油天然气股份有限公司 聚合物胶乳凝聚粒子及其制备方法
WO2022074101A1 (en) 2020-10-08 2022-04-14 Ineos Styrolution Group Gmbh Preparation of diene polymer latex of high gel content and controlled cross linking
US20250051489A1 (en) * 2021-12-27 2025-02-13 Sabic Global Technologies B.V. Process of manufacturing graft polymer compositions
EP4554989A1 (de) 2022-07-15 2025-05-21 INEOS Styrolution Group GmbH Verfahren zur herstellung von asa- oder abs-pfropfcopolymeren mit verminderter verfärbung

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2430562A (en) 1944-02-23 1947-11-11 Goodrich Co B F Polymerization of butadiene-1,3 hydrocarbons
US4003871A (en) 1975-01-08 1977-01-18 Celanese Corporation High solids styrene-butadiene emulsions
US3991136A (en) 1975-04-02 1976-11-09 Monsanto Company Method of producing ABS polyblends having a low residual monomer content
GB1594863A (en) 1978-03-03 1981-08-05 Int Synthetic Rubber Emulsion polymerisation process
US4145494A (en) 1978-05-10 1979-03-20 The General Tire & Rubber Company Aqueous free radical emulsion polymerization
US4272425A (en) 1979-10-26 1981-06-09 The B. F. Goodrich Company Treating dispersions of acrylonitrile polymers
DE3327190A1 (de) 1983-07-28 1985-02-07 Basf Ag, 6700 Ludwigshafen Verfahren zur behandlung von (co)polymerisatdispersionen
IT1190360B (it) 1985-05-24 1988-02-16 Enichem Polimeri Processo per la preparazione di polibutadiene aggraffato con stirolo ed acrilonitrile avente bassissimo contenuto finale di monomeri residui non reagiti
JP2555294B2 (ja) * 1989-06-30 1996-11-20 日本合成ゴム株式会社 紙塗被組成物
US5414045A (en) * 1993-12-10 1995-05-09 General Electric Company Grafting, phase-inversion and cross-linking controlled multi-stage bulk process for making ABS graft copolymers
US6384129B1 (en) 1995-08-30 2002-05-07 General Electric Company Semi-batch emulsion process for making diene rubber latex, rubber latex made thereby, and graft copolymer made therefrom
JPH1017602A (ja) * 1996-07-05 1998-01-20 Oji Paper Co Ltd 共重合体ラテックスの製造方法および印刷用塗被紙
JP3502791B2 (ja) * 1999-06-29 2004-03-02 日本エイアンドエル株式会社 オフセット印刷用紙被覆用共重合体ラテックスおよび該ラテックスを含有するオフセット印刷用紙被覆用組成物

Also Published As

Publication number Publication date
WO2003010214A1 (en) 2003-02-06
EP1414873A1 (en) 2004-05-06
US20040059079A1 (en) 2004-03-25
US6784253B2 (en) 2004-08-31
DE60230152D1 (de) 2009-01-15
CN1556818A (zh) 2004-12-22
ATE416202T1 (de) 2008-12-15
JP2004536915A (ja) 2004-12-09
CN100471883C (zh) 2009-03-25
JP2009007590A (ja) 2009-01-15
JP5378749B2 (ja) 2013-12-25
EP1414873B1 (en) 2008-12-03

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