JP4443403B2 - チーグラー触媒の存在下でのポリ−１−オレフィンの製造方法 - Google Patents
チーグラー触媒の存在下でのポリ−１−オレフィンの製造方法 Download PDFInfo
- Publication number
- JP4443403B2 JP4443403B2 JP2004508135A JP2004508135A JP4443403B2 JP 4443403 B2 JP4443403 B2 JP 4443403B2 JP 2004508135 A JP2004508135 A JP 2004508135A JP 2004508135 A JP2004508135 A JP 2004508135A JP 4443403 B2 JP4443403 B2 JP 4443403B2
- Authority
- JP
- Japan
- Prior art keywords
- magnesium alkoxide
- temperature
- polymerization
- component
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 29
- 239000011777 magnesium Substances 0.000 claims description 97
- -1 Magnesium alkoxide Chemical class 0.000 claims description 59
- 229910052749 magnesium Inorganic materials 0.000 claims description 57
- 239000000725 suspension Substances 0.000 claims description 34
- 239000006185 dispersion Substances 0.000 claims description 30
- 229930195733 hydrocarbon Natural products 0.000 claims description 27
- 150000002430 hydrocarbons Chemical class 0.000 claims description 27
- 238000006116 polymerization reaction Methods 0.000 claims description 23
- 239000004215 Carbon black (E152) Substances 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 18
- 239000000460 chlorine Substances 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- 239000002283 diesel fuel Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 238000010008 shearing Methods 0.000 claims description 13
- 239000010936 titanium Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 9
- 150000003623 transition metal compounds Chemical class 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 229910052723 transition metal Inorganic materials 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- 150000002902 organometallic compounds Chemical class 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 150000003464 sulfur compounds Chemical class 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 239000002612 dispersion medium Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000002609 medium Substances 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 230000035484 reaction time Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 description 15
- 239000007787 solid Substances 0.000 description 10
- 238000009835 boiling Methods 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 239000011261 inert gas Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- ONIKNECPXCLUHT-UHFFFAOYSA-N 2-chlorobenzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1Cl ONIKNECPXCLUHT-UHFFFAOYSA-N 0.000 description 1
- VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 206010011416 Croup infectious Diseases 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910007926 ZrCl Inorganic materials 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10223798A DE10223798A1 (de) | 2002-05-29 | 2002-05-29 | Verfahren zum Herstellen eines Poly-1-olefins in Gegenwart eines Ziegler Katalysators |
| US38968302P | 2002-06-17 | 2002-06-17 | |
| PCT/EP2003/005345 WO2003099882A1 (en) | 2002-05-29 | 2003-05-22 | Method for producing a poly-1olefin in the presence of a ziegler catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005527675A JP2005527675A (ja) | 2005-09-15 |
| JP2005527675A5 JP2005527675A5 (enExample) | 2006-05-11 |
| JP4443403B2 true JP4443403B2 (ja) | 2010-03-31 |
Family
ID=29585320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004508135A Expired - Lifetime JP4443403B2 (ja) | 2002-05-29 | 2003-05-22 | チーグラー触媒の存在下でのポリ−１−オレフィンの製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7402637B2 (enExample) |
| EP (1) | EP1507805B1 (enExample) |
| JP (1) | JP4443403B2 (enExample) |
| CN (1) | CN100503660C (enExample) |
| WO (1) | WO2003099882A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004037229A1 (de) | 2004-07-29 | 2006-02-16 | Basell Polyolefine Gmbh | Verfahren zum Herstellen eines Poly-1-olefins in Gegenwart eines Ziegler Katalysators |
| DE102005007186A1 (de) * | 2005-02-16 | 2006-08-31 | Basell Polyolefine Gmbh | Verfahren zum Herstellen von 1-Olefin(co)polymeren |
| DE102005056775A1 (de) * | 2005-11-28 | 2007-05-31 | Basell Polyolefine Gmbh | Verfahren für den Katalysatorwechsel in einem Gasphasenwirbelschichtreaktor |
| BR112012009515A2 (pt) | 2009-10-22 | 2017-02-21 | Basell Polyolefine Gmbh | "componentes catalíticos para a polimerização de olefinas e catalisadores obtidos a partir dos mesmos" |
| US8940654B2 (en) | 2010-06-18 | 2015-01-27 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| EP3416990B1 (en) * | 2016-02-15 | 2020-06-17 | Basell Polyolefine GmbH | Preactivated catalyst component for the polymerization of olefins |
| CN109627363A (zh) * | 2017-10-09 | 2019-04-16 | 中国石化扬子石油化工有限公司 | 一种一锅法制备小粒径聚烯烃催化剂的方法 |
| CN112725054B (zh) * | 2019-10-28 | 2023-10-20 | 南京中科康润新材料科技有限公司 | 一种低碳烯烃经聚合直接合成高性能高粘度基础油的工艺方法 |
| EP4155324A3 (en) * | 2021-09-22 | 2023-05-03 | Sumitomo Chemical Company, Limited | Method for producing solid catalyst component for olefin polymerization, method for producing catalyst for olefin polymerization, and method for producing olefin polymer |
| WO2025235588A1 (en) | 2024-05-10 | 2025-11-13 | Equistar Chimicals, Lp | High-performance ziegler catalyst for loop-slurry process |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3644318A (en) | 1968-08-21 | 1972-02-22 | Hoechst Ag | Process for the polymerization of olefins |
| DE3538099A1 (de) | 1985-10-26 | 1987-04-30 | Ruhrchemie Ag | Verfahren zur homo- und mischpolymerisation von olefinen |
| FR2623812B1 (fr) | 1987-11-30 | 1992-02-21 | Bp Chimie Sa | Catalyseur de polymerisation d'olefines de type ziegler natta et procede de preparation a partir de dialcoxyde de magnesium |
| US5648309A (en) | 1990-06-01 | 1997-07-15 | Hoechst Aktiengesellschaft | Process for the preparation of a poly-1-olefin |
| DE4017661A1 (de) * | 1990-06-01 | 1991-12-05 | Hoechst Ag | Verfahren zur herstellung eines poly-1-olefins |
| DE10003872A1 (de) * | 1999-11-26 | 2001-08-16 | Basell Polyolefine Gmbh | Verfahren zum Herstellen eines Poly-l-olefins in Gegenwart eines Ziegler Katalysators |
-
2003
- 2003-05-22 WO PCT/EP2003/005345 patent/WO2003099882A1/en not_active Ceased
- 2003-05-22 EP EP03737968.2A patent/EP1507805B1/en not_active Expired - Lifetime
- 2003-05-22 JP JP2004508135A patent/JP4443403B2/ja not_active Expired - Lifetime
- 2003-05-22 US US10/514,095 patent/US7402637B2/en not_active Expired - Lifetime
- 2003-05-22 CN CNB038123347A patent/CN100503660C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20050239978A1 (en) | 2005-10-27 |
| WO2003099882A1 (en) | 2003-12-04 |
| EP1507805B1 (en) | 2014-01-08 |
| JP2005527675A (ja) | 2005-09-15 |
| CN100503660C (zh) | 2009-06-24 |
| US7402637B2 (en) | 2008-07-22 |
| CN1656131A (zh) | 2005-08-17 |
| EP1507805A1 (en) | 2005-02-23 |
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