JP4028057B2 - 耐熱性撥水コーティング層を有する材料 - Google Patents
耐熱性撥水コーティング層を有する材料 Download PDFInfo
- Publication number
- JP4028057B2 JP4028057B2 JP36370797A JP36370797A JP4028057B2 JP 4028057 B2 JP4028057 B2 JP 4028057B2 JP 36370797 A JP36370797 A JP 36370797A JP 36370797 A JP36370797 A JP 36370797A JP 4028057 B2 JP4028057 B2 JP 4028057B2
- Authority
- JP
- Japan
- Prior art keywords
- aqueous emulsion
- och
- hydrolyzate
- coating layer
- fluorocarbon silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011247 coating layer Substances 0.000 title claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 25
- 239000005871 repellent Substances 0.000 title claims description 22
- 239000000463 material Substances 0.000 title claims description 18
- 230000002940 repellent Effects 0.000 title description 3
- 239000000839 emulsion Substances 0.000 claims description 64
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 40
- 229910000077 silane Inorganic materials 0.000 claims description 40
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 39
- 239000004094 surface-active agent Substances 0.000 claims description 26
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 17
- 239000000758 substrate Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 26
- 239000011521 glass Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- -1 silicon alkoxide Chemical class 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000003618 dip coating Methods 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- AJWLYSOPXUSOQB-UHFFFAOYSA-N tetrakis[2-(2-methoxyethoxy)ethyl] silicate Chemical compound COCCOCCO[Si](OCCOCCOC)(OCCOCCOC)OCCOCCOC AJWLYSOPXUSOQB-UHFFFAOYSA-N 0.000 description 2
- 238000003878 thermal aging Methods 0.000 description 2
- PJBRRBQODBNARK-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethoxysilane Chemical compound COCCOCCO[SiH3] PJBRRBQODBNARK-UHFFFAOYSA-N 0.000 description 1
- FCAHAWLPBAUUPP-UHFFFAOYSA-N 2-[2-(2-methoxyethoxy)ethoxy]ethoxysilane Chemical compound COCCOCCOCCO[SiH3] FCAHAWLPBAUUPP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Landscapes
- Surface Treatment Of Glass (AREA)
- Paints Or Removers (AREA)
- Silicon Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36370797A JP4028057B2 (ja) | 1997-12-17 | 1997-12-17 | 耐熱性撥水コーティング層を有する材料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36370797A JP4028057B2 (ja) | 1997-12-17 | 1997-12-17 | 耐熱性撥水コーティング層を有する材料 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11181355A JPH11181355A (ja) | 1999-07-06 |
| JPH11181355A5 JPH11181355A5 (enExample) | 2005-07-28 |
| JP4028057B2 true JP4028057B2 (ja) | 2007-12-26 |
Family
ID=18479990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP36370797A Expired - Fee Related JP4028057B2 (ja) | 1997-12-17 | 1997-12-17 | 耐熱性撥水コーティング層を有する材料 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4028057B2 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6709504B2 (en) | 2000-05-19 | 2004-03-23 | E. I. Du Pont De Nemours And Company | Emulsion and water-repellent composition |
| KR100741256B1 (ko) * | 2000-05-19 | 2007-07-19 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 에멀젼 및 발수성 조성물 |
| JP2002121486A (ja) | 2000-10-06 | 2002-04-23 | E I Du Pont De Nemours & Co | フルオロカーボンシラン加水分解物含有水性エマルジョンおよび耐熱撥水性の被覆物 |
| JP4667935B2 (ja) * | 2005-04-07 | 2011-04-13 | 明成化学工業株式会社 | 繊維構造物の撥水加工方法および当該方法により撥水加工された繊維構造物 |
| JP6674558B2 (ja) | 2016-04-20 | 2020-04-01 | ダウ シリコーンズ コーポレーション | リチウムアルキルシリコネート組成物、塗膜、及びその作製方法 |
-
1997
- 1997-12-17 JP JP36370797A patent/JP4028057B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH11181355A (ja) | 1999-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2405277C (en) | Emulsion and water-repellent composition | |
| ES2319962T3 (es) | Emulsion y producto revestido con ella. | |
| JP5114355B2 (ja) | 撥水・撥油性コーティング物品およびその製造 | |
| CN101668822A (zh) | 赋予防水性的含水硅氧烷乳液 | |
| US20130040058A1 (en) | Formulation suitable for use as an anti-graffiti coating having improved coverage properties | |
| JPH01161057A (ja) | 水ベースシリコーン−有機重合体組成物及びそのための方法 | |
| JP2006225629A (ja) | オルガノシリコーンレジンエマルジョン組成物及び該組成物の被膜が形成された物品 | |
| JP4028057B2 (ja) | 耐熱性撥水コーティング層を有する材料 | |
| JP3228085B2 (ja) | 撥水処理剤 | |
| WO1999029636A1 (en) | Fluorocarbon silane hydrolysate-containing aqueous emulsions, and materials coated therewith | |
| JP2005179402A (ja) | フルオロカーボンシラン加水分解物含有水性エマルジョンおよび耐油防汚性・撥水撥油性の被覆物 | |
| US6709504B2 (en) | Emulsion and water-repellent composition | |
| JP2924018B2 (ja) | コーティング用組成物 | |
| JP2001329174A (ja) | フルオロカーボンシラン加水分解物含有水性エマルジョンおよび耐熱撥水性被覆物 | |
| JP2001335693A (ja) | フルオロカーボンシラン加水分解物含有水性エマルジョンおよび耐油防汚性・耐熱撥水性の被覆物 | |
| KR100511565B1 (ko) | 동결안정성을 가지는 실리콘계 수성 발수 에멀젼 | |
| JP5022584B2 (ja) | フルオロカーボンシラン含有水性エマルジョン並びに水滴転落性および撥水撥油性の被覆物 | |
| TW202017977A (zh) | 聚矽氧樹脂乳膠組成物、其製造方法、塗佈劑及被覆物品 | |
| CN101243160A (zh) | 溶致液晶和囊泡 | |
| JP4162240B2 (ja) | セラミックス表面保護膜用組成物 | |
| TW201811943A (zh) | 一種具有防滑功能的保護性塗層組合物、塗佈製品及其製備方法 | |
| JP2002313548A (ja) | 調理器および調理器用トッププレート |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20041216 Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20041216 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20041216 |
|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20041216 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20060629 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20060707 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20061010 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20061013 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20061228 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20070202 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070423 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20071005 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20071011 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101019 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111019 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111019 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20121019 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20131019 Year of fee payment: 6 |
|
| LAPS | Cancellation because of no payment of annual fees |