JP3914286B2 - ポリプロピレンインフレートフィルム - Google Patents
ポリプロピレンインフレートフィルム Download PDFInfo
- Publication number
- JP3914286B2 JP3914286B2 JP19430396A JP19430396A JP3914286B2 JP 3914286 B2 JP3914286 B2 JP 3914286B2 JP 19430396 A JP19430396 A JP 19430396A JP 19430396 A JP19430396 A JP 19430396A JP 3914286 B2 JP3914286 B2 JP 3914286B2
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- propylene
- olefin
- ethylene
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 22
- -1 Polypropylene Polymers 0.000 title claims description 24
- 239000004743 Polypropylene Substances 0.000 title 1
- 238000009826 distribution Methods 0.000 claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 239000002861 polymer material Substances 0.000 claims abstract description 17
- 229920000098 polyolefin Polymers 0.000 claims abstract description 15
- 239000000155 melt Substances 0.000 claims abstract description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000008096 xylene Substances 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims description 36
- 229920001384 propylene homopolymer Polymers 0.000 claims description 23
- 239000004711 α-olefin Substances 0.000 claims description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
- 239000005977 Ethylene Substances 0.000 claims description 21
- 229920000642 polymer Polymers 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 4
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 4
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 229920005684 linear copolymer Polymers 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 17
- 239000003054 catalyst Substances 0.000 description 16
- 239000011777 magnesium Substances 0.000 description 11
- 229910052749 magnesium Inorganic materials 0.000 description 11
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 239000011949 solid catalyst Substances 0.000 description 8
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 150000003609 titanium compounds Chemical class 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 238000002083 X-ray spectrum Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229920001038 ethylene copolymer Polymers 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 239000002198 insoluble material Substances 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- LOLKAJARZKDJTD-UHFFFAOYSA-N 4-Ethoxy-4-oxobutanoic acid Chemical compound CCOC(=O)CCC(O)=O LOLKAJARZKDJTD-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000012748 slip agent Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000005910 alkyl carbonate group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000000181 anti-adherent effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- UXXXZMDJQLPQPH-UHFFFAOYSA-N bis(2-methylpropyl) carbonate Chemical compound CC(C)COC(=O)OCC(C)C UXXXZMDJQLPQPH-UHFFFAOYSA-N 0.000 description 1
- SWBJZPDGKVYSLT-UHFFFAOYSA-N bis(2-methylpropyl) propanedioate Chemical compound CC(C)COC(=O)CC(=O)OCC(C)C SWBJZPDGKVYSLT-UHFFFAOYSA-N 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Wrappers (AREA)
- Polarising Elements (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/505,925 US5641848A (en) | 1995-07-24 | 1995-07-24 | Polypropylene blown film |
| US08/505925 | 1995-07-24 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH09104064A JPH09104064A (ja) | 1997-04-22 |
| JPH09104064A5 JPH09104064A5 (OSRAM) | 2004-07-29 |
| JP3914286B2 true JP3914286B2 (ja) | 2007-05-16 |
Family
ID=24012453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19430396A Expired - Fee Related JP3914286B2 (ja) | 1995-07-24 | 1996-07-24 | ポリプロピレンインフレートフィルム |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5641848A (OSRAM) |
| EP (1) | EP0757069B1 (OSRAM) |
| JP (1) | JP3914286B2 (OSRAM) |
| KR (1) | KR970006331A (OSRAM) |
| CN (1) | CN1065815C (OSRAM) |
| AT (1) | ATE224926T1 (OSRAM) |
| AU (1) | AU707222B2 (OSRAM) |
| BR (1) | BR9603157A (OSRAM) |
| CA (1) | CA2181877A1 (OSRAM) |
| DE (1) | DE69623885T2 (OSRAM) |
| MX (1) | MX9602938A (OSRAM) |
| NO (1) | NO963061L (OSRAM) |
| TW (1) | TW347405B (OSRAM) |
| ZA (1) | ZA966247B (OSRAM) |
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| US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
| US6107404A (en) * | 1998-12-28 | 2000-08-22 | Ford Motor Company | Paintable, surface-damage resistant reactor grade thermoplastic olefin (TPO) |
| US6166139A (en) * | 1998-12-28 | 2000-12-26 | Visteon Global Technologies, Inc. | Paintable, surface-damage resistant compounded grade thermoplastic olefin (TPO) |
| CA2377008C (en) | 1999-06-24 | 2008-11-25 | The Dow Chemical Company | Polyolefin composition with improved impact properties |
| US6593005B2 (en) | 2000-01-24 | 2003-07-15 | Dow Global Technologies Inc. | Composition and films thereof |
| ES2254419T3 (es) * | 2000-05-04 | 2006-06-16 | Dow Global Technologies Inc. | Fundido molecular y metodos para producir y usar el fundido molecular. |
| EP1297067B1 (en) * | 2000-05-26 | 2005-05-11 | Dow Global Technologies Inc. | Polyethylene rich/polypropylene blends and their uses |
| EP1390416B1 (en) | 2000-12-22 | 2004-12-29 | Dow Global Technologies, Inc. | Propylene copolymer foams |
| WO2004003874A2 (en) | 2002-06-26 | 2004-01-08 | Avery Dennison Corporation | Oriented films comprising polypropylene / olefin elastomer blends |
| AU2003277288A1 (en) * | 2002-10-07 | 2004-05-04 | Dow Global Technologies Inc. | Highly crystalline polypropylene with low xylene solubles |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| BR0315341B1 (pt) | 2002-10-15 | 2014-02-18 | Adesivos compreendendo poliolefina. | |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| CN1863830B (zh) | 2003-10-07 | 2011-04-20 | 陶氏环球技术公司 | 用于空气骤冷吹塑薄膜的聚丙烯组合物 |
| ITMI20032009A1 (it) * | 2003-10-16 | 2005-04-17 | Moplefan Spa | Pellicola piana trasparente e colorata per l'applicazione nella etichettatura a stampaggio |
| US20060008666A1 (en) * | 2004-07-06 | 2006-01-12 | Miller Mark B | Heat shrinkable film using a blend of polypropylene impact copolymer, syndiotactic polypropylene and/or polypropylene random copolymer |
| US7217767B2 (en) * | 2004-07-06 | 2007-05-15 | Fina Technology, Inc. | Blends of polypropylene impact copolymer with other polymers |
| US20060147663A1 (en) * | 2004-12-30 | 2006-07-06 | Fina Technology, Inc. | Co-extruded film structures of polypropylene impact copolymer with other polymers |
| US7816466B2 (en) | 2005-02-03 | 2010-10-19 | Basell Poliolefine Italia S.R.L. | Propylene polymer composition for injection molding |
| DE602006007572D1 (de) | 2005-05-12 | 2009-08-13 | Basell Poliolefine Srl | Propylen-ethylen-copolymere und herstellungsverfahren dafür |
| AU2006265203A1 (en) * | 2005-07-01 | 2007-01-11 | Basell Poliolefine Italia S.R.L. | Propylene polymers having broad molecular weight distribution |
| BRPI0616556A2 (pt) * | 2005-08-08 | 2011-06-21 | Basell Poliolefine Srl | processo para a nucleação de resinas de polipropileno |
| TWI386310B (zh) * | 2005-10-07 | 2013-02-21 | Dow Global Technologies Llc | 多層彈性膜結構物 |
| US7915342B2 (en) * | 2005-11-28 | 2011-03-29 | Fina Techology, Inc. | Breathable films |
| EP2049333B1 (en) | 2006-06-14 | 2012-12-05 | Avery Dennison Corporation | Conformable and die-cuttable machine direction oriented labelstocks and labels, and process for preparing |
| AU2007261011B2 (en) | 2006-06-20 | 2012-04-05 | Avery Dennison Corporation | Multilayered polymeric film for hot melt adhesive labeling and label stock and label thereof |
| ATE487593T1 (de) * | 2006-08-31 | 2010-11-15 | Treofan Germany Gmbh & Co Kg | Biaxial orientierte elektroisolierfolie |
| WO2008079733A1 (en) * | 2006-12-15 | 2008-07-03 | Fina Technology, Inc. | Polypropylene blown film |
| BRPI0719502B1 (pt) * | 2006-12-21 | 2019-01-02 | Dow Global Technologies Inc | película e artigo |
| US8440319B2 (en) * | 2007-05-10 | 2013-05-14 | Fina Technology, Inc. | Heat resistant polypropylene film |
| US8487033B2 (en) | 2007-05-16 | 2013-07-16 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions, methods for making the same, and articles made therefrom |
| US8507628B2 (en) * | 2007-10-02 | 2013-08-13 | Fina Technology, Inc. | Propylene based polymers for injection stretch blow molding |
| US20100249354A1 (en) * | 2009-03-26 | 2010-09-30 | Fina Technology, Inc. | Injection stretch blow molded articles and syndiotactic polymers for use therein |
| US9090000B2 (en) * | 2009-03-26 | 2015-07-28 | Fina Technology, Inc. | Injection stretch blow molded articles and random copolymers for use therein |
| WO2013004804A1 (en) * | 2011-07-07 | 2013-01-10 | Basell Poliolefine Italia S.R.L. | Polypropylene composition |
| US9676532B2 (en) | 2012-08-15 | 2017-06-13 | Avery Dennison Corporation | Packaging reclosure label for high alcohol content products |
| WO2014070384A1 (en) | 2012-10-31 | 2014-05-08 | Exxonmobil Chemical Patents Inc. | Articles comprising broad molecular weight distribution polypropylene resins |
| US9453093B2 (en) | 2012-10-31 | 2016-09-27 | Exxonmobil Chemical Patents Inc. | Broad molecular weight distribution polypropylene resins |
| US9902822B2 (en) | 2012-10-31 | 2018-02-27 | Exxonmobil Chemical Patents Inc. | Articles comprising broad molecular weight distribution polypropylene resins |
| US9458311B2 (en) | 2013-08-27 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Ethylene based polymers and articles made therefrom |
| WO2015030942A2 (en) * | 2013-08-27 | 2015-03-05 | Exxonmobil Chemical Patents Inc. | Ethylene-based polymers and articles made therefrom |
| BR112016028445B1 (pt) | 2014-06-02 | 2022-05-31 | Avery Dennison Corporation | Filme orientado com resistência à abrasão, clareza e conformabilidade, conjunto de rótulo compreendendo o filme e método para produzir um artigo rotulado |
| KR101598715B1 (ko) * | 2014-11-12 | 2016-02-29 | 한화토탈 주식회사 | 폴리프로필렌 수지 조성물 및 이것으로 제조된 필름 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4185148A (en) * | 1976-05-17 | 1980-01-22 | Mitsubishi Rayon Company Limited | Process for producing the polypropylene film for electrical appliances |
| PH16274A (en) * | 1978-12-13 | 1983-08-26 | Sumitomo Chemical Co | Molded products of polypropylene |
| JPS61181848A (ja) * | 1985-02-06 | 1986-08-14 | Mitsubishi Chem Ind Ltd | 二軸延伸フイルム用ポリプロピレン樹脂組成物 |
| US4814135A (en) * | 1987-12-22 | 1989-03-21 | Union Carbide Corporation | Process for extrusion |
| US5212246A (en) * | 1990-09-28 | 1993-05-18 | Himont Incorporated | Olefin polymer films |
| IT1260497B (it) * | 1992-05-29 | 1996-04-09 | Himont Inc | Polimeri cristallini del propilene aventi migliorata processabilita' allo stato e processo per la loro preparazione |
| US5286791A (en) * | 1992-05-29 | 1994-02-15 | Himont Incorporated | Impact modified graft copolymer compositions containing broad molecular weight distribution polypropylene |
| US5318842A (en) * | 1992-12-03 | 1994-06-07 | Himont Incorporated | Biaxially oriented propylene polymer film or sheet articles |
| JP2793482B2 (ja) * | 1993-10-13 | 1998-09-03 | 昭和電工株式会社 | ポリオレフィン系樹脂組成物およびその成形体 |
| US5409992A (en) * | 1994-02-28 | 1995-04-25 | Himont Incorporated | Calenderable blends containing broad molecular weight distribution propylene polymer material |
-
1995
- 1995-07-24 US US08/505,925 patent/US5641848A/en not_active Expired - Lifetime
-
1996
- 1996-07-20 EP EP96111738A patent/EP0757069B1/en not_active Expired - Lifetime
- 1996-07-20 AT AT96111738T patent/ATE224926T1/de not_active IP Right Cessation
- 1996-07-20 DE DE69623885T patent/DE69623885T2/de not_active Expired - Lifetime
- 1996-07-22 TW TW085108899A patent/TW347405B/zh active
- 1996-07-23 MX MX9602938A patent/MX9602938A/es not_active IP Right Cessation
- 1996-07-23 NO NO963061A patent/NO963061L/no not_active Application Discontinuation
- 1996-07-23 CA CA002181877A patent/CA2181877A1/en not_active Abandoned
- 1996-07-23 AU AU60653/96A patent/AU707222B2/en not_active Ceased
- 1996-07-23 ZA ZA9606247A patent/ZA966247B/xx unknown
- 1996-07-24 KR KR1019960029911A patent/KR970006331A/ko not_active Withdrawn
- 1996-07-24 CN CN96108896A patent/CN1065815C/zh not_active Expired - Fee Related
- 1996-07-24 BR BR9603157A patent/BR9603157A/pt active Search and Examination
- 1996-07-24 JP JP19430396A patent/JP3914286B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0757069B1 (en) | 2002-09-25 |
| ATE224926T1 (de) | 2002-10-15 |
| NO963061L (no) | 1997-01-27 |
| ZA966247B (en) | 1997-02-11 |
| KR970006331A (ko) | 1997-02-19 |
| TW347405B (en) | 1998-12-11 |
| AU6065396A (en) | 1997-01-30 |
| EP0757069A1 (en) | 1997-02-05 |
| DE69623885T2 (de) | 2003-06-05 |
| CN1065815C (zh) | 2001-05-16 |
| CA2181877A1 (en) | 1997-01-25 |
| DE69623885D1 (de) | 2002-10-31 |
| JPH09104064A (ja) | 1997-04-22 |
| NO963061D0 (no) | 1996-07-23 |
| BR9603157A (pt) | 1998-05-05 |
| MX9602938A (es) | 1997-01-31 |
| US5641848A (en) | 1997-06-24 |
| CN1143564A (zh) | 1997-02-26 |
| AU707222B2 (en) | 1999-07-08 |
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