JP3672063B2 - ボンディングワイヤ - Google Patents
ボンディングワイヤ Download PDFInfo
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- JP3672063B2 JP3672063B2 JP19951297A JP19951297A JP3672063B2 JP 3672063 B2 JP3672063 B2 JP 3672063B2 JP 19951297 A JP19951297 A JP 19951297A JP 19951297 A JP19951297 A JP 19951297A JP 3672063 B2 JP3672063 B2 JP 3672063B2
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
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Description
【発明の属する技術分野】
本発明は半導体素子上の電極と外部リードとを接続するために用いるボンディングワイヤに関する。
【0002】
【従来の技術】
IC,LSIなどの半導体素子(チップ)の電極と外部リードとを接続するため直径0.02〜0.1mmのボンディングワイヤが用いられている。このボンディングワイヤには良好な導電性、チップや外部リードとの接合性、使用雰囲気中での耐環境性が要求される。そのため、ボンディングワイヤとしてはAl,Au,Cu等の純金属もしくはその合金が用いられている。近年では低コスト化という観点から樹脂を用いた半導体パッケージが多用されてきており、そのため耐環境性に優れるAu系ワイヤが最も多く用いられている。
【0003】
最近の半導体デバイスの発展はパッケージの多ピン化をもたらし、その結果として、より細いワイヤを用いて狭いピッチで長い距離のワイヤボンディングを行う必要性が増してきた。しかしながら、従来のAu系ボンディングワイヤで線経をより細くするとワイヤ強度が弱いため、樹脂封入を始めとする半導体デバイス組み立て工程中においてワイヤの変形不良が頻発化し、半導体デバイスの組み立て収率が大幅に低下するという問題があった。
【0004】
こうした問題を解決する手段として、例えば特公昭62―22450、特公昭62―22451等で示されているように、多量のAgを添加してワイヤ強度を高めるという方法が提案されている。しかし、Agを多量に添加したワイヤは半導体素子上の電極との接合信頼性が低くなり、実際の半導体パッケージに使用することは困難である。
【0005】
【発明が解決しようとする課題】
本発明の目的は、かかる点に鑑み、Agを多量に含むAu系ワイヤの接合信頼性を向上させ、多ピン半導体デバイス用として好適な高強度ボンディングワイヤを提供することにある。
【0006】
【課題を解決するための手段】
上記の目的を達成するために、本発明のボンディングワイヤは、第一にAg を20〜40 重量%(以下単に%と記す)を含み、さらにPdを0 .1を超えて5 %以下を含み、残部がAu 及び不可避不純物からなる点に特徴があり、第二にAg を20 〜40%を含み、Pd を0 .1を超えて5 %以下を含み、さらにSr ,Ce 、Ge 、In 、Sn の1 種以上を0 .0001 〜0 .01 %含み、残部がAu 及び不可避不純物からなる点に特徴があり、第三にAg を20〜40%を含み、Pd を0 .1を超えて5 %以下を含み、さらにCu 、Pt 、Ru 、Os 、Rh 、Ir の内の1 種以上を合計で0 .1 を超えて3%以下であり、かつ、Ru又はIrの内、少なくとも一つ以上を含有する場合は、Ru又はIrの内で含有される元素の含有割合についてはそれぞれ0 .0001〜0.05 重量%の範囲の含有を除き、残部がAu 及び不可避不純物からなる点に特徴があり、第四にAg を20 〜40%を含み、Pd を0 .1 を超えて5 %以下を含み、Sr ,Ce 、Ge 、In 、Sn の1 種以上を0 .0001 〜0 .01 %含み、さらにCu 、Pt 、Ru 、Os 、Rh 、Ir の内の1 種以上を合計で0 .1 を超えて3%以下を含み、残部がAu 及び不可避不純物からなる点に特徴がある。
【0007】
【発明の実施の形態】
以下に本発明の構成について詳細に説明する。
【0008】
Ag は金に固溶することによりワイヤ強度を向上させる元素である。Ag の濃度を20 〜40 %としたのは、20 %未満では強度向上の効果が不十分であり、逆に40 %を超すと強度向上の効果が低下するだけでなく、耐食性が低下してプラスチックパッケージ中で使用するのが難しくなるからである。
【0009】
Pd は、その機構は不明であるが、Ag を多量に含むAu 系ワイヤの接合信頼性を向上させる元素である。Pd の濃度を0 .1 を超えて5 %以下としたのは、0 .1%以下では接合信頼性向上効果が不充分だからであり、逆に5 %を超えると効果が飽和するからである。
【0010】
第二および第四の発明に用いるSr,Ce 、Ge 、Sn 、In はワイヤの耐熱性やルーピング性を向上するための添加元素である。 Sr ,Ce 、Ge 、Sn 、In の1 種以上を合計量で0 .0001 〜0 .01 %としたのは、0 .0001 %未満では添加による耐熱性の向上効果が不十分であり、逆に0 .01 %を超えると接合性の低下が起こるからである。
【0011】
また、第三および第四の発明に用いるCu 、Pt 、Ru 、Os 、Rh 、Ir はワイヤ強度をさらに向上させる元素である。Cu 、Pt 、Ru 、Os 、Rh 、Ir の内の1 種以上を合計量で0 .1 を超えて3%以下としたのは、0 .1 %以下では添加効果が不十分であり、逆に3 %を超えるとワイヤの加工性や接合性が低下するからである。
【0012】
【実施例】
次に実施例を用いて本発明をさらに説明する。
【0013】
(実施例1 〜10 )純度99 .999 %の金、99 .99 %のPd 、Ag 、Cu 、Pt、Ru 、Os 、Rh 、Ir 、及び所定の添加元素を1 %含む金母合金を用いて、表1 に示す組成の金合金を溶解鋳造した。
【0014】
【表1】
【0015】
このように作製された試料の評価として、ワイヤ強度は引張り試験により求めた。ボンディング接合性すなわちボンディングワイヤと半導体素子の電極及び外部リードとの接合性は、ステージ温度250℃で超音波熱圧着方式によりボンディングしたワイヤについて、フックを引っかけて引張り試験を実施した場合に、破断がワイヤの部分で起こった場合を良、接合部で破断した場合を不良と評価した。
【0016】
樹脂の封入抵抗によるワイヤ変形については、上記と同様な方法で5mmの間隔にワイヤボンディングした試料について、モールド機(トランスファーモールド型)によりエポキシ樹脂(住友ベークライト製、EME-6300)を金型温度180℃、射出圧100Kg/cm2の条件でモールドした時のワイヤの流れ量をX線透過装置により撮影したX線写真から求め、その値で評価した。
【0017】
ボンディング接合部分の耐環境信頼性については、上記と同様な方法でワイヤボンディングと樹脂封入した試料について、175℃の電気炉中に200時間保持した場合のワイヤ接合部の電気抵抗値を測定し、保持前に比較して電気抵抗値の変化が認められなかった場合を良、電気抵抗値の増加が起こった場合を不良と評価した。
【0018】
表2に上記評価の結果を示した。
【0019】
【表2】
【0020】
第2,4表において明らかなように、本発明によるボンディングワイヤは、市販品に比較して強度が高く、ワイヤ流れ量が小さい。また、比較材と比べるとボンディング接合部の耐環境性が良好であり、接合性にも問題の無いことがわかる。
【0021】
【発明の効果】
以上から明らかなように、本発明により、半導体デバイス組み立て時におけるワイヤの変形不良が起こりにくく、かつ接合信頼性も良好である多ピン半導体デバイス用として好適なボンディングワイヤを提供することができる。
Claims (4)
- Ag が20 〜40 重量%、Pdが0 .1を超えて5 重量%以下、残部がAu 及び不可避不純物からなることを特徴とするボンディングワイヤ。
- Ag が20 〜40 重量%、Pdが0 .1を超えて5 重量%以下、Sr、Ce、Ge、In、Sn の内の1 種以上が合計量で0 .0001〜0 .01 重量%、残部がAu 及び不可避不純物からなることを特徴とするボンディングワイヤ。
- Ag が20 〜40 重量%、Pdが0 .1を超えて5 重量%以下、Cu、Pt、Ru、Os、Rh、Ir の内の1 種以上が合計量で0 .1を超えて3 重量%以下であり、かつ、Ru又はIrの内、少なくとも一つ以上を含有する場合は、Ru又はIrの内で含有される元素の含有割合についてはそれぞれ0.0001〜0.05 重量%の範囲の含有を除き、残部がAu 及び不可避不純物からなることを特徴とするボンディングワイヤ。
- Ag が20 〜40 重量%、Pdが0 .1を超えて5 重量%以下、Sr、Ce、Ge、In、Sn の内の1 種以上が合計量で0 .0001〜0 .01 重量%、さらにCu、Pt、Ru、Os、Rh、Ir の内の1 種以上が合計量で0 .1を超えて3 重量%以下、残部がAu 及び不可避不純物からなることを特徴とするボンディングワイヤ。
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JP4596467B2 (ja) | 2005-06-14 | 2010-12-08 | 田中電子工業株式会社 | 高い接合信頼性、圧着ボールの高い真円性、高い直進性および高い耐樹脂流れ性を有するボンディングワイヤ用金合金線 |
JP4726206B2 (ja) * | 2005-06-14 | 2011-07-20 | 田中電子工業株式会社 | 高い初期接合性、高い接合信頼性、圧着ボールの高い真円性、高い直進性、高い耐樹脂流れ性および低い比抵抗を有するボンディングワイヤ用金合金線 |
JP4726205B2 (ja) | 2005-06-14 | 2011-07-20 | 田中電子工業株式会社 | 高い初期接合性、高い接合信頼性、圧着ボールの高い真円性、高い直進性および高い耐樹脂流れ性を有するボンディングワイヤ用金合金線 |
JP4793989B2 (ja) * | 2006-03-29 | 2011-10-12 | 田中電子工業株式会社 | 高い初期接合性、高い接合信頼性および圧着ボールの高い真円性を有するボンディングワイヤ用金合金線 |
CN105908002B (zh) * | 2016-04-22 | 2018-05-01 | 汕头市骏码凯撒有限公司 | 一种金合金键合丝及其制造方法 |
CN107665874A (zh) * | 2017-09-07 | 2018-02-06 | 汕头市骏码凯撒有限公司 | 一种包覆金的金合金复合键合丝及其制造方法 |
CN108091631A (zh) * | 2017-12-13 | 2018-05-29 | 汕头市骏码凯撒有限公司 | 具有金包覆层的金合金复合键合丝及其制造方法 |
CN108796269A (zh) * | 2018-06-30 | 2018-11-13 | 汕头市骏码凯撒有限公司 | 金合金键合丝及其制造方法 |
CN110117733A (zh) * | 2019-04-30 | 2019-08-13 | 汕头市骏码凯撒有限公司 | 一种金银合金键合丝及其制造方法 |
EP4245871A1 (fr) * | 2022-03-18 | 2023-09-20 | Nivarox-FAR S.A. | Alliage d'or |
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