JP3578992B2 - 複合陽極材料およびその製法 - Google Patents
複合陽極材料およびその製法 Download PDFInfo
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- JP3578992B2 JP3578992B2 JP2000565576A JP2000565576A JP3578992B2 JP 3578992 B2 JP3578992 B2 JP 3578992B2 JP 2000565576 A JP2000565576 A JP 2000565576A JP 2000565576 A JP2000565576 A JP 2000565576A JP 3578992 B2 JP3578992 B2 JP 3578992B2
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- Prior art keywords
- particles
- nickel
- nickel hydroxide
- anode
- conductive
- Prior art date
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- Expired - Fee Related
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- 239000002131 composite material Substances 0.000 title claims description 49
- 239000010405 anode material Substances 0.000 title description 67
- 238000004519 manufacturing process Methods 0.000 title description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 173
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims description 133
- 239000002245 particle Substances 0.000 claims description 123
- 239000000463 material Substances 0.000 claims description 92
- 229910052759 nickel Inorganic materials 0.000 claims description 85
- 239000004020 conductor Substances 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 13
- 230000008021 deposition Effects 0.000 claims description 5
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 3
- 239000010406 cathode material Substances 0.000 claims 13
- 239000007774 positive electrode material Substances 0.000 claims 10
- 239000007769 metal material Substances 0.000 claims 7
- 238000005551 mechanical alloying Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 64
- 229910021645 metal ion Inorganic materials 0.000 description 32
- 239000011149 active material Substances 0.000 description 29
- 238000010899 nucleation Methods 0.000 description 24
- 230000006911 nucleation Effects 0.000 description 24
- 239000003607 modifier Substances 0.000 description 20
- 230000001965 increasing effect Effects 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000011701 zinc Substances 0.000 description 18
- 239000003518 caustics Substances 0.000 description 17
- 238000002156 mixing Methods 0.000 description 16
- 229910052725 zinc Inorganic materials 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- 238000001556 precipitation Methods 0.000 description 14
- 238000012546 transfer Methods 0.000 description 14
- 238000007792 addition Methods 0.000 description 13
- 229910017052 cobalt Inorganic materials 0.000 description 13
- 239000010941 cobalt Substances 0.000 description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 13
- 239000000835 fiber Substances 0.000 description 13
- 229910018095 Ni-MH Inorganic materials 0.000 description 12
- 229910018477 Ni—MH Inorganic materials 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000006260 foam Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 229910052788 barium Inorganic materials 0.000 description 10
- 229910052802 copper Inorganic materials 0.000 description 10
- 239000010949 copper Substances 0.000 description 10
- 230000006872 improvement Effects 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 239000000725 suspension Substances 0.000 description 10
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 9
- 239000000908 ammonium hydroxide Substances 0.000 description 9
- 239000006183 anode active material Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 229910052748 manganese Inorganic materials 0.000 description 9
- 239000011572 manganese Substances 0.000 description 9
- 229910052712 strontium Inorganic materials 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 229910052804 chromium Inorganic materials 0.000 description 8
- 229910052742 iron Inorganic materials 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- -1 nickel metal hydride Chemical class 0.000 description 8
- 230000002829 reductive effect Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 230000008961 swelling Effects 0.000 description 8
- 229910005813 NiMH Inorganic materials 0.000 description 7
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 229910052738 indium Inorganic materials 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 239000013081 microcrystal Substances 0.000 description 7
- 229910052727 yttrium Inorganic materials 0.000 description 7
- 229910052793 cadmium Inorganic materials 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000006104 solid solution Substances 0.000 description 6
- 229910052718 tin Inorganic materials 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 5
- 239000007772 electrode material Substances 0.000 description 5
- NPURPEXKKDAKIH-UHFFFAOYSA-N iodoimino(oxo)methane Chemical group IN=C=O NPURPEXKKDAKIH-UHFFFAOYSA-N 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910006279 γ-NiOOH Inorganic materials 0.000 description 5
- 229910005580 NiCd Inorganic materials 0.000 description 4
- 229910052787 antimony Inorganic materials 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000002847 impedance measurement Methods 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 229910052987 metal hydride Inorganic materials 0.000 description 4
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910052779 Neodymium Inorganic materials 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- OSOVKCSKTAIGGF-UHFFFAOYSA-N [Ni].OOO Chemical compound [Ni].OOO OSOVKCSKTAIGGF-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 description 3
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- 229910052745 lead Inorganic materials 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 229910000483 nickel oxide hydroxide Inorganic materials 0.000 description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000027756 respiratory electron transport chain Effects 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- 229910000048 titanium hydride Inorganic materials 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- NBFQLHGCEMEQFN-UHFFFAOYSA-N N.[Ni] Chemical compound N.[Ni] NBFQLHGCEMEQFN-UHFFFAOYSA-N 0.000 description 2
- 229910002640 NiOOH Inorganic materials 0.000 description 2
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 150000001869 cobalt compounds Chemical class 0.000 description 2
- 239000002482 conductive additive Substances 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000003411 electrode reaction Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 230000037427 ion transport Effects 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 2
- 150000004681 metal hydrides Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 150000002815 nickel Chemical group 0.000 description 2
- 229910001453 nickel ion Inorganic materials 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
- 230000037361 pathway Effects 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 229910052706 scandium Inorganic materials 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 230000009919 sequestration Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910017759 LaH3 Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910003266 NiCo Inorganic materials 0.000 description 1
- 229910006015 NiCoCd Inorganic materials 0.000 description 1
- 229910006027 NiCoMg Inorganic materials 0.000 description 1
- 229910006083 NiCoZn Inorganic materials 0.000 description 1
- ZQQGQJKVMMDIKF-UHFFFAOYSA-N [Ni+4] Chemical compound [Ni+4] ZQQGQJKVMMDIKF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 229910021346 calcium silicide Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 229910000652 nickel hydride Inorganic materials 0.000 description 1
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000701 toxic element Toxicity 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 229910003160 β-NiOOH Inorganic materials 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/626—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/32—Nickel oxide or hydroxide electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/135,460 | 1998-08-17 | ||
| US09/135,460 US6177213B1 (en) | 1998-08-17 | 1998-08-17 | Composite positive electrode material and method for making same |
| PCT/US1999/018164 WO2000010212A1 (en) | 1998-08-17 | 1999-08-11 | Composite positive electrode material and method for making same |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004043303A Division JP5099960B2 (ja) | 1998-08-17 | 2004-02-19 | 複合陽極材料およびその製法 |
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| JP2002522894A JP2002522894A (ja) | 2002-07-23 |
| JP3578992B2 true JP3578992B2 (ja) | 2004-10-20 |
| JP2002522894A5 JP2002522894A5 (enExample) | 2005-05-19 |
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| JP2004043303A Expired - Lifetime JP5099960B2 (ja) | 1998-08-17 | 2004-02-19 | 複合陽極材料およびその製法 |
| JP2010171955A Pending JP2010282973A (ja) | 1998-08-17 | 2010-07-30 | 複合陽極材料およびその製法 |
| JP2011201852A Expired - Lifetime JP5467086B2 (ja) | 1998-08-17 | 2011-09-15 | 複合陽極材料 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2004043303A Expired - Lifetime JP5099960B2 (ja) | 1998-08-17 | 2004-02-19 | 複合陽極材料およびその製法 |
| JP2010171955A Pending JP2010282973A (ja) | 1998-08-17 | 2010-07-30 | 複合陽極材料およびその製法 |
| JP2011201852A Expired - Lifetime JP5467086B2 (ja) | 1998-08-17 | 2011-09-15 | 複合陽極材料 |
Country Status (12)
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| EP (2) | EP1116287B1 (enExample) |
| JP (4) | JP3578992B2 (enExample) |
| KR (2) | KR20060105055A (enExample) |
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| BR (1) | BR9913060A (enExample) |
| CA (1) | CA2339211A1 (enExample) |
| MX (1) | MX216887B (enExample) |
| NO (1) | NO20010772L (enExample) |
| RU (1) | RU2208270C2 (enExample) |
| TW (1) | TW432739B (enExample) |
| WO (1) | WO2000010212A1 (enExample) |
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| WO2022145030A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Salt containing electrolytes that promote the formation of proton-conducting rechargeable batteries |
| WO2022145027A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Ionic liquid electrolytes including salt additives for use in proton-conducting rechargeable batteries |
| WO2022145029A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Group 14 element-containing metal hydride with a superlattice structure for use in hydrogen storage. |
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-
1998
- 1998-08-17 US US09/135,460 patent/US6177213B1/en not_active Expired - Lifetime
-
1999
- 1999-08-11 WO PCT/US1999/018164 patent/WO2000010212A1/en not_active Ceased
- 1999-08-11 AU AU53476/99A patent/AU759414B2/en not_active Ceased
- 1999-08-11 KR KR1020067017476A patent/KR20060105055A/ko not_active Ceased
- 1999-08-11 BR BR9913060-2A patent/BR9913060A/pt not_active Application Discontinuation
- 1999-08-11 KR KR1020017001991A patent/KR100725609B1/ko not_active Expired - Lifetime
- 1999-08-11 MX MXPA01001580 patent/MX216887B/es not_active IP Right Cessation
- 1999-08-11 CA CA002339211A patent/CA2339211A1/en not_active Abandoned
- 1999-08-11 RU RU2001107121/09A patent/RU2208270C2/ru not_active IP Right Cessation
- 1999-08-11 EP EP99939133.7A patent/EP1116287B1/en not_active Expired - Lifetime
- 1999-08-11 JP JP2000565576A patent/JP3578992B2/ja not_active Expired - Fee Related
- 1999-08-11 EP EP04024169.7A patent/EP1496555B1/en not_active Expired - Lifetime
- 1999-08-20 TW TW088114217A patent/TW432739B/zh not_active IP Right Cessation
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2000
- 2000-12-30 US US09/751,180 patent/US6348285B2/en not_active Expired - Lifetime
- 2000-12-30 US US09/751,176 patent/US6569566B2/en not_active Expired - Lifetime
- 2000-12-30 US US09/751,177 patent/US6548209B2/en not_active Expired - Lifetime
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2001
- 2001-02-15 NO NO20010772A patent/NO20010772L/no not_active Application Discontinuation
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2004
- 2004-02-19 JP JP2004043303A patent/JP5099960B2/ja not_active Expired - Lifetime
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2010
- 2010-07-30 JP JP2010171955A patent/JP2010282973A/ja active Pending
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2011
- 2011-09-15 JP JP2011201852A patent/JP5467086B2/ja not_active Expired - Lifetime
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| KR100725609B1 (ko) | 2007-06-08 |
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| US6177213B1 (en) | 2001-01-23 |
| RU2208270C2 (ru) | 2003-07-10 |
| MX216887B (es) | 2003-10-10 |
| US6569566B2 (en) | 2003-05-27 |
| CA2339211A1 (en) | 2000-02-24 |
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| JP2010282973A (ja) | 2010-12-16 |
| EP1116287A1 (en) | 2001-07-18 |
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| NO20010772D0 (no) | 2001-02-15 |
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| BR9913060A (pt) | 2001-05-08 |
| EP1496555B1 (en) | 2013-06-19 |
| KR20060105055A (ko) | 2006-10-09 |
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| EP1496555A3 (en) | 2010-03-24 |
| US20010023040A1 (en) | 2001-09-20 |
| JP5099960B2 (ja) | 2012-12-19 |
| JP5467086B2 (ja) | 2014-04-09 |
| JP2004214210A (ja) | 2004-07-29 |
| JP2012023049A (ja) | 2012-02-02 |
| WO2000010212A1 (en) | 2000-02-24 |
| US6548209B2 (en) | 2003-04-15 |
| EP1116287A4 (en) | 2003-04-02 |
| US20020146505A1 (en) | 2002-10-10 |
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