JP2690199B2 - トリフルオロメタンと二酸化炭素又はヘキサフルオロエタンと二酸化炭素の共沸混合物様組成物 - Google Patents
トリフルオロメタンと二酸化炭素又はヘキサフルオロエタンと二酸化炭素の共沸混合物様組成物Info
- Publication number
- JP2690199B2 JP2690199B2 JP7504537A JP50453795A JP2690199B2 JP 2690199 B2 JP2690199 B2 JP 2690199B2 JP 7504537 A JP7504537 A JP 7504537A JP 50453795 A JP50453795 A JP 50453795A JP 2690199 B2 JP2690199 B2 JP 2690199B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon dioxide
- azeotrope
- composition
- trifluoromethane
- refrigerant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 63
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 45
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical group FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 22
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 22
- WMIYKQLTONQJES-UHFFFAOYSA-N hexafluoroethane Chemical compound FC(F)(F)C(F)(F)F WMIYKQLTONQJES-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 239000003507 refrigerant Substances 0.000 abstract description 32
- 238000001816 cooling Methods 0.000 abstract description 9
- 238000010438 heat treatment Methods 0.000 abstract description 8
- 238000009835 boiling Methods 0.000 description 19
- 238000005057 refrigeration Methods 0.000 description 11
- 238000001704 evaporation Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 230000006835 compression Effects 0.000 description 8
- 238000007906 compression Methods 0.000 description 8
- 230000008020 evaporation Effects 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000001079 digestive effect Effects 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 229920004449 Halon® Polymers 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000004378 air conditioning Methods 0.000 description 3
- 230000000779 depleting effect Effects 0.000 description 3
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- MEXUFEQDCXZEON-UHFFFAOYSA-N bromochlorodifluoromethane Chemical compound FC(F)(Cl)Br MEXUFEQDCXZEON-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- AFYPFACVUDMOHA-UHFFFAOYSA-N chlorotrifluoromethane Chemical compound FC(F)(F)Cl AFYPFACVUDMOHA-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 229940124568 digestive agent Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- YACLCMMBHTUQON-UHFFFAOYSA-N 1-chloro-1-fluoroethane Chemical class CC(F)Cl YACLCMMBHTUQON-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XWCDCDSDNJVCLO-UHFFFAOYSA-N Chlorofluoromethane Chemical compound FCCl XWCDCDSDNJVCLO-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000000926 atmospheric chemistry Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- YNKZSBSRKWVMEZ-UHFFFAOYSA-N bromo-chloro-fluoromethane Chemical class FC(Cl)Br YNKZSBSRKWVMEZ-UHFFFAOYSA-N 0.000 description 1
- LHMHCLYDBQOYTO-UHFFFAOYSA-N bromofluoromethane Chemical compound FCBr LHMHCLYDBQOYTO-UHFFFAOYSA-N 0.000 description 1
- RJCQBQGAPKAMLL-UHFFFAOYSA-N bromotrifluoromethane Chemical compound FC(F)(F)Br RJCQBQGAPKAMLL-UHFFFAOYSA-N 0.000 description 1
- WXQLGASAPXDBOQ-UHFFFAOYSA-N carbon dioxide;fluoroform Chemical compound O=C=O.FC(F)F WXQLGASAPXDBOQ-UHFFFAOYSA-N 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical class F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000013178 mathematical model Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0057—Polyhaloalkanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/106—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/32—The mixture being azeotropic
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogenated Pyridines (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/092,317 US5340490A (en) | 1993-07-14 | 1993-07-14 | Azeotrope-like compositions of trifluoromethane and carbon dioxide or hexafluoroethane and carbon dioxide |
| US08/092.317 | 1993-07-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08507312A JPH08507312A (ja) | 1996-08-06 |
| JP2690199B2 true JP2690199B2 (ja) | 1997-12-10 |
Family
ID=22232669
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7504537A Expired - Fee Related JP2690199B2 (ja) | 1993-07-14 | 1994-05-27 | トリフルオロメタンと二酸化炭素又はヘキサフルオロエタンと二酸化炭素の共沸混合物様組成物 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5340490A (OSRAM) |
| EP (1) | EP0708806B1 (OSRAM) |
| JP (1) | JP2690199B2 (OSRAM) |
| KR (1) | KR100218061B1 (OSRAM) |
| AT (1) | ATE156510T1 (OSRAM) |
| AU (1) | AU683266B2 (OSRAM) |
| CA (1) | CA2165667A1 (OSRAM) |
| DE (1) | DE69404845T2 (OSRAM) |
| DK (1) | DK0708806T3 (OSRAM) |
| MX (1) | MX9404457A (OSRAM) |
| TW (1) | TW289047B (OSRAM) |
| WO (1) | WO1995002652A1 (OSRAM) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100190185B1 (ko) * | 1991-03-18 | 1999-06-01 | 크리스 로저 에이치 | 디플루오로메탄; 1,1,1-트리플루오로에탄; 또는 프로판을 함유하는 비공비성 냉매 조성물들 |
| GB9414133D0 (en) * | 1994-07-13 | 1994-08-31 | Ici Plc | Refrigerant compositions |
| GB9414136D0 (en) * | 1994-07-13 | 1994-08-31 | Ici Plc | Refrigerant compositions |
| GB9414110D0 (en) * | 1994-07-13 | 1994-08-31 | Ici Plc | Refrigeration compositions |
| GB9414134D0 (en) * | 1994-07-13 | 1994-08-31 | Ici Plc | Refrigerant compositions |
| US5718807A (en) * | 1994-09-20 | 1998-02-17 | E. I. Du Pont De Nemours And Company | Purification process for hexafluoroethane products |
| US5766503A (en) * | 1994-12-16 | 1998-06-16 | E. I. Du Pont De Nemours And Company | Refrigeration process using azeotropic compositions of perfluoroethane and trifluoromethane |
| US6034048A (en) * | 1995-03-01 | 2000-03-07 | Charvid Limited Liability Co. | Non-caustic cleaning composition using an alkali salt |
| US6194367B1 (en) | 1995-03-01 | 2001-02-27 | Charvid Limited Liability Co. | Non-caustic cleaning composition comprising peroxygen compound and specific silicate and method of making the same in free-flowing, particulate form |
| US5674957A (en) * | 1995-03-10 | 1997-10-07 | The University Of North Carolina At Chapel Hill | Nonaqueous polymerization of fluoromonomers |
| US5618894A (en) * | 1995-03-10 | 1997-04-08 | The University Of North Carolina | Nonaqueous polymerization of fluoromonomers |
| US5728315A (en) * | 1996-05-01 | 1998-03-17 | Alliedsignal Inc. | Azeotrope-like compositions of trifluoromethane, carbon dioxide, ethane and hexafluoroethane |
| JP3319499B2 (ja) * | 1996-08-06 | 2002-09-03 | 出光興産株式会社 | 冷凍機用潤滑油組成物及び該組成物を用いた潤滑方法 |
| GB9708240D0 (en) * | 1997-04-23 | 1997-06-11 | Nycomed Imaging As | Improvements in or relating to contrast agents |
| US6074572A (en) * | 1999-04-06 | 2000-06-13 | Cryogen, Inc. | Gas mixture for cryogenic applications |
| US6346203B1 (en) | 2000-02-15 | 2002-02-12 | Pcbu Services, Inc. | Method for the suppression of fire |
| US6546740B1 (en) | 2000-05-19 | 2003-04-15 | Clemson University | Ternary refrigerant compositions which contain perfluoroorgano sulfur compounds as replacements for R-22 |
| US6574973B1 (en) | 2000-05-19 | 2003-06-10 | Electric Power Research Institute, Inc. | Ternary refrigerant compositions containing fluorinated ethers as replacements for R-22 |
| KR100405189B1 (ko) | 2001-02-16 | 2003-11-12 | 한국과학기술연구원 | 혼합냉매 조성물 |
| US6841087B2 (en) | 2002-04-19 | 2005-01-11 | Korea Institute Of Science And Technology | Refrigerant composition comprising difluoromethane, 1,1,1-trifluoroethane and 1,1,1,2-tetrafluoroethane |
| US6800216B2 (en) | 2002-07-24 | 2004-10-05 | Korea Institute Of Science And Technology | Refrigerant composition for replacing chlorodifluoromethane |
| US6776922B2 (en) * | 2002-07-24 | 2004-08-17 | Korea Institute Of Science And Technology | Refrigerant composition comprising difluoromethane, 1,1,1-trifluoroethane and 1,1-difluoroethane |
| US7238299B2 (en) * | 2002-11-01 | 2007-07-03 | Honeywell International Inc. | Heat transfer fluid comprising difluoromethane and carbon dioxide |
| RU2368410C1 (ru) * | 2008-05-07 | 2009-09-27 | Учреждение Российской академии наук Институт структурной макрокинетики и проблем материаловедения РАН | Газовый состав для предотвращения воспламенения и взрыва метановоздушных смесей |
| WO2010025452A1 (en) * | 2008-08-29 | 2010-03-04 | Micro Pure Solutions, Llc | Method for treating hydrogen sulfide-containing fluids |
| TWI432255B (zh) * | 2008-09-26 | 2014-04-01 | Asahi Kasei Chemicals Corp | The use of porous hollow fiber membranes for the manufacture of clarified biomedical culture media |
| RU2430763C1 (ru) * | 2010-02-10 | 2011-10-10 | Тимур Рафкатович Тимербулатов | Двухкомпонентный газовый состав для предотвращения воспламенения и взрыва метановоздушных смесей |
| RU2444391C1 (ru) * | 2010-07-30 | 2012-03-10 | Тимур Рафкатович Тимербулатов | Газовый состав для предотвращения воспламенения и взрыва метановоздушных смесей |
| RU2629559C1 (ru) * | 2016-10-24 | 2017-08-30 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" | Присадка к топливу |
| GB2562509B (en) * | 2017-05-17 | 2020-04-29 | Mexichem Fluor Sa De Cv | Heat transfer compositions |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2101993A (en) * | 1932-04-30 | 1937-12-14 | Gen Motors Corp | Refrigerant mixture and the method of using the same |
| US2641579A (en) * | 1951-03-02 | 1953-06-09 | Du Pont | Azeotropic refrigerant composition of monochlorodifluoromethane and chloropentafluoroethane |
| US3804759A (en) * | 1971-12-27 | 1974-04-16 | J Becker | Aerosol fire extinguisher and method |
| JPS51125995A (en) * | 1975-04-24 | 1976-11-02 | Daikin Ind Ltd | Fire extinguishing agent |
| US4724679A (en) * | 1986-07-02 | 1988-02-16 | Reinhard Radermacher | Advanced vapor compression heat pump cycle utilizing non-azeotropic working fluid mixtures |
| JPH0256029A (ja) * | 1988-08-20 | 1990-02-26 | Fujitsu Ltd | 汎用レジスタ切換方式 |
| US5040609A (en) * | 1989-10-04 | 1991-08-20 | E. I. Du Pont De Nemours And Company | Fire extinguishing composition and process |
| US5141654A (en) * | 1989-11-14 | 1992-08-25 | E. I. Du Pont De Nemours And Company | Fire extinguishing composition and process |
| US5120770A (en) * | 1989-11-29 | 1992-06-09 | Doyle Earl N | Use of liquid carbon dioxide as a blowing agent in the production of open-cell polyurethane foam |
| DE4116274C2 (de) * | 1991-05-17 | 1998-03-19 | Forschungszentrum Fuer Kaeltet | Kältemittel |
| JPH0542230A (ja) * | 1991-08-13 | 1993-02-23 | Daikin Ind Ltd | 消火剤 |
| US5162381A (en) * | 1991-12-10 | 1992-11-10 | Allied-Signal Inc. | Process for preparing thermalplastic foam |
| EP0649453B1 (en) * | 1992-07-10 | 1997-05-14 | E.I. Du Pont De Nemours And Company | Azeotropic compositions of perfluoroethane and trifluoromethane |
| US5275751A (en) * | 1992-12-22 | 1994-01-04 | Alliedsignal Inc. | Azeotrope-like compositions of trifluoromethane, carbon dioxide and sulfur hexafluoride |
-
1993
- 1993-07-14 US US08/092,317 patent/US5340490A/en not_active Expired - Fee Related
-
1994
- 1994-05-27 KR KR1019960700154A patent/KR100218061B1/ko not_active Expired - Fee Related
- 1994-05-27 AT AT94917492T patent/ATE156510T1/de not_active IP Right Cessation
- 1994-05-27 DE DE69404845T patent/DE69404845T2/de not_active Expired - Fee Related
- 1994-05-27 CA CA002165667A patent/CA2165667A1/en not_active Abandoned
- 1994-05-27 WO PCT/US1994/006003 patent/WO1995002652A1/en not_active Ceased
- 1994-05-27 EP EP94917492A patent/EP0708806B1/en not_active Expired - Lifetime
- 1994-05-27 DK DK94917492.4T patent/DK0708806T3/da active
- 1994-05-27 JP JP7504537A patent/JP2690199B2/ja not_active Expired - Fee Related
- 1994-05-27 AU AU69193/94A patent/AU683266B2/en not_active Expired - Fee Related
- 1994-06-14 MX MX9404457A patent/MX9404457A/es not_active Application Discontinuation
- 1994-06-17 TW TW083105522A patent/TW289047B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| DK0708806T3 (da) | 1997-10-27 |
| EP0708806A1 (en) | 1996-05-01 |
| TW289047B (OSRAM) | 1996-10-21 |
| DE69404845T2 (de) | 1997-11-27 |
| CA2165667A1 (en) | 1995-01-26 |
| US5340490A (en) | 1994-08-23 |
| KR100218061B1 (ko) | 1999-09-01 |
| MX9404457A (es) | 1995-01-31 |
| AU683266B2 (en) | 1997-11-06 |
| JPH08507312A (ja) | 1996-08-06 |
| WO1995002652A1 (en) | 1995-01-26 |
| AU6919394A (en) | 1995-02-13 |
| DE69404845D1 (de) | 1997-09-11 |
| ATE156510T1 (de) | 1997-08-15 |
| EP0708806B1 (en) | 1997-08-06 |
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