JP2021503430A5 - - Google Patents
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- JP2021503430A5 JP2021503430A5 JP2020527100A JP2020527100A JP2021503430A5 JP 2021503430 A5 JP2021503430 A5 JP 2021503430A5 JP 2020527100 A JP2020527100 A JP 2020527100A JP 2020527100 A JP2020527100 A JP 2020527100A JP 2021503430 A5 JP2021503430 A5 JP 2021503430A5
- Authority
- JP
- Japan
- Prior art keywords
- phase
- solid
- solid phase
- liquid phase
- reactants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000007790 solid phase Substances 0.000 claims 18
- 239000007789 gas Substances 0.000 claims 13
- 239000007791 liquid phase Substances 0.000 claims 13
- 238000000034 method Methods 0.000 claims 13
- 229910052751 metal Inorganic materials 0.000 claims 12
- 239000002184 metal Substances 0.000 claims 12
- 239000012071 phase Substances 0.000 claims 10
- 239000000376 reactant Substances 0.000 claims 10
- 239000007787 solid Substances 0.000 claims 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 8
- 150000003839 salts Chemical class 0.000 claims 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 6
- 229910052752 metalloid Inorganic materials 0.000 claims 6
- 150000002738 metalloids Chemical class 0.000 claims 6
- 239000002245 particle Substances 0.000 claims 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 6
- 239000007795 chemical reaction product Substances 0.000 claims 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 239000004215 Carbon black (E152) Substances 0.000 claims 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 4
- 230000003197 catalytic effect Effects 0.000 claims 4
- 229910052802 copper Inorganic materials 0.000 claims 4
- 239000010949 copper Substances 0.000 claims 4
- 229930195733 hydrocarbon Natural products 0.000 claims 4
- 150000002430 hydrocarbons Chemical class 0.000 claims 4
- 229910052742 iron Inorganic materials 0.000 claims 4
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims 4
- 229910052759 nickel Inorganic materials 0.000 claims 4
- 229910052697 platinum Inorganic materials 0.000 claims 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims 4
- 239000011780 sodium chloride Substances 0.000 claims 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910052787 antimony Inorganic materials 0.000 claims 2
- 229910052797 bismuth Inorganic materials 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910052737 gold Inorganic materials 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052738 indium Inorganic materials 0.000 claims 2
- 229910052745 lead Inorganic materials 0.000 claims 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- 150000004706 metal oxides Chemical class 0.000 claims 2
- 229910003455 mixed metal oxide Inorganic materials 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims 2
- 229910052763 palladium Inorganic materials 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- 239000008188 pellet Substances 0.000 claims 2
- 239000001103 potassium chloride Substances 0.000 claims 2
- 239000000047 product Substances 0.000 claims 2
- 229910052703 rhodium Inorganic materials 0.000 claims 2
- 239000010948 rhodium Substances 0.000 claims 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 2
- 229910052707 ruthenium Inorganic materials 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 2
- 229910001930 tungsten oxide Inorganic materials 0.000 claims 2
- 238000007614 solvation Methods 0.000 claims 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2023044002A JP2023076501A (ja) | 2017-11-16 | 2023-03-20 | 化学物質の同時反応と分離 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762586943P | 2017-11-16 | 2017-11-16 | |
| US62/586,943 | 2017-11-16 | ||
| PCT/US2018/061474 WO2019099795A1 (en) | 2017-11-16 | 2018-11-16 | Simultaneous reaction and separation of chemicals |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023044002A Division JP2023076501A (ja) | 2017-11-16 | 2023-03-20 | 化学物質の同時反応と分離 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2021503430A JP2021503430A (ja) | 2021-02-12 |
| JP2021503430A5 true JP2021503430A5 (enExample) | 2021-12-23 |
| JP7250016B2 JP7250016B2 (ja) | 2023-03-31 |
Family
ID=66540384
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020527100A Active JP7250016B2 (ja) | 2017-11-16 | 2018-11-16 | 化学物質の同時反応と分離 |
| JP2023044002A Pending JP2023076501A (ja) | 2017-11-16 | 2023-03-20 | 化学物質の同時反応と分離 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023044002A Pending JP2023076501A (ja) | 2017-11-16 | 2023-03-20 | 化学物質の同時反応と分離 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US11814285B2 (enExample) |
| EP (1) | EP3710152A4 (enExample) |
| JP (2) | JP7250016B2 (enExample) |
| KR (1) | KR102616282B1 (enExample) |
| CN (1) | CN111936227A (enExample) |
| AU (1) | AU2018370138A1 (enExample) |
| CA (1) | CA3082819A1 (enExample) |
| WO (1) | WO2019099795A1 (enExample) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7329534B2 (ja) * | 2018-04-09 | 2023-08-18 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 溶融塩ベースの触媒系を用いた高温熱分解 |
| CN112351834A (zh) * | 2018-05-21 | 2021-02-09 | 加利福尼亚大学董事会 | 天然气利用熔融盐转化为化学物质和电力 |
| US11453584B2 (en) | 2018-06-29 | 2022-09-27 | Palo Alto Research Center Incorporated | High throughput methane pyrolysis reactor for low-cost hydrogen production |
| EP3693337A1 (en) * | 2019-02-05 | 2020-08-12 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk Onderzoek TNO | Use of molten salt to separate carbon from a molten metal catalyst |
| CN110632165B (zh) * | 2019-10-21 | 2024-03-15 | 天津大学 | 生物质燃烧气溶胶制备与检测一体装置及其方法 |
| KR102631165B1 (ko) * | 2019-11-28 | 2024-01-30 | 삼성중공업 주식회사 | 액상유기화합물 해저저장시스템 |
| JP2023504617A (ja) * | 2019-12-06 | 2023-02-06 | シーゼロ インコーポレイテッド | 溶融塩反応器の改良 |
| US11987497B2 (en) * | 2019-12-06 | 2024-05-21 | Palo Alto Research Center Incorporated | Liquid metal condensate catalyzed hydrocarbon pyrolysis |
| JP7353172B2 (ja) * | 2019-12-27 | 2023-09-29 | 三菱重工業株式会社 | 水素及びカーボンを製造する方法 |
| CN113042074B (zh) * | 2019-12-27 | 2023-07-25 | 上海科技大学 | 一种催化剂及其制备方法与应用 |
| KR102841175B1 (ko) * | 2020-01-28 | 2025-07-30 | 아주대학교산학협력단 | 수소 생산용 탄화수소 열분해 반응기 |
| JP7491505B2 (ja) | 2020-02-05 | 2024-05-28 | Eneos株式会社 | 一酸化炭素の生成方法、前駆体の製造方法およびケミカルルーピングシステム用材料 |
| EP3868708A1 (en) | 2020-02-21 | 2021-08-25 | L 2 Consultancy B.V. | Method and system for direct thermal decomposition of a hydrocarbon compound into carbon and hydrogen |
| WO2021183959A1 (en) * | 2020-03-13 | 2021-09-16 | C-Zero Llc | Methods of pneumatic carbon removal |
| CN111606315A (zh) * | 2020-07-06 | 2020-09-01 | 中国石油化工股份有限公司 | 一种降低碳素中金属含量的方法 |
| CN111732076A (zh) * | 2020-07-06 | 2020-10-02 | 中国石油化工股份有限公司 | 一种利用液态催化剂催化裂解烃类的方法 |
| CN111632616A (zh) * | 2020-07-06 | 2020-09-08 | 中国石油化工股份有限公司 | 一种液态催化剂及其应用 |
| EP3950294A1 (en) * | 2020-08-05 | 2022-02-09 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Melt pyrolysis of hydrocarbon feedstock containing nitrogen and/or hydrogen sulphide |
| US20230303932A1 (en) * | 2020-08-12 | 2023-09-28 | Czero Inc. | Metallic based hydrocarbon pyrolysis |
| US20230340336A1 (en) * | 2020-08-19 | 2023-10-26 | The Regents Of The University Of California | Chemical reaction and conversion in thermally heterogeneous and non-steady-state chemical reactors |
| CN114135367B (zh) * | 2020-09-03 | 2023-03-28 | 长城汽车股份有限公司 | 一种甲烷转化气生成装置及汽车 |
| US11560645B2 (en) * | 2020-09-25 | 2023-01-24 | Palo Alto Research Center Incorporated | Carbon fiber fabrication systems and methods |
| CN114718698B (zh) * | 2021-01-05 | 2024-07-23 | 长城汽车股份有限公司 | 尾气后处理系统、方法及具有该尾气后处理系统的车辆 |
| GB2605797A (en) * | 2021-04-13 | 2022-10-19 | Hiiroc X Developments Ltd | Liquid metal reactor and reaction method |
| WO2022261452A1 (en) * | 2021-06-11 | 2022-12-15 | Czero Inc. | Prevention of solid deposition on internal structures of reactors |
| KR102433433B1 (ko) * | 2021-07-07 | 2022-08-18 | 주식회사 제로시스 | 수소 생산 장치 |
| CN113441092A (zh) * | 2021-08-12 | 2021-09-28 | 成都市润和盛建石化工程技术有限公司 | 一种采用列管式固定床熔盐加热反应器的丙烷脱氢方法及系统 |
| IT202100022781A1 (it) * | 2021-09-02 | 2023-03-02 | Nuovo Pignone Tecnologie Srl | Wellsite Methane Pyrolyzer and Wellsite Methane Pyrolysis Alternative to Flaring |
| KR102419495B1 (ko) * | 2021-09-03 | 2022-07-11 | 주식회사 제로시스 | 수소 생산 장치 |
| WO2023054752A1 (ko) * | 2021-09-29 | 2023-04-06 | 한국생산기술연구원 | 액체금속을 이용한 온실가스 저감 장치 및 이의 작동방법 |
| CN115974057A (zh) * | 2021-10-14 | 2023-04-18 | 科泽新材料股份有限公司 | 一种低成本制备高质量大片径少层石墨烯粉体的方法 |
| CN113897077A (zh) * | 2021-11-16 | 2022-01-07 | 航天环境工程有限公司 | 一种裂解炭黑高温等离子体连续纯化装置 |
| KR102416196B1 (ko) * | 2021-12-28 | 2022-07-05 | 에너진(주) | 메탄의 열분해장치 |
| CN114477133B (zh) * | 2022-01-27 | 2023-06-06 | 武汉大学 | 一种用于熔盐中碳材料分离的气浮法 |
| EP4238639A1 (de) * | 2022-03-01 | 2023-09-06 | Burckhardt Compression AG | Vorrichtung und verfahren zur pyrolyse wasserstoffhaltiger verbindungen |
| CA3245581A1 (en) * | 2022-03-11 | 2023-09-14 | Acceleware Ltd. | PYROLYSIS SYSTEM AND METHOD USING AN ELECTROMAGNETIC REACTOR |
| US20230349015A1 (en) * | 2022-04-27 | 2023-11-02 | Saudi Arabian Oil Company | Co-production of hydrogen, carbon, electricity, and steel with carbon dioxide capture |
| WO2023220731A2 (en) * | 2022-05-13 | 2023-11-16 | The Regents Of The University Of California | Halogen mediated production of hydrogen and carbon from hydrocarbons |
| IT202200014503A1 (it) * | 2022-07-08 | 2024-01-08 | Nextchem Tech S P A | Processo e apparato per la separazione, la rimozione e la purificazione del carbonio solido da un reattore di produzione di idrogeno da cracking di metano e/o di idrocarburi a bassa emissione di co2 |
| EP4303177A1 (en) | 2022-07-08 | 2024-01-10 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Molten metal catalysed pyrolysis |
| KR20240035230A (ko) | 2022-09-08 | 2024-03-15 | (주)대양이티에스 | 정보제공용 디스플레이부를 구비한 공기청정기 |
| KR102635413B1 (ko) | 2022-09-08 | 2024-02-13 | (주)대양이티에스 | 디스플레이부를 구비한 공기청정기에 멀티미디어 콘텐츠를 제공하는 시스템 |
| KR102617738B1 (ko) | 2022-09-08 | 2023-12-27 | (주)대양이티에스 | 디스플레이부를 구비한 공기청정기를 이용한 멀티미디어 콘텐츠 제공방법 |
| US12390781B2 (en) | 2022-09-15 | 2025-08-19 | Xerox Corporation | Systems and methods for hydrocarbon pyrolysis |
| CN115744823B (zh) * | 2023-01-09 | 2023-04-14 | 清华大学 | 一种碳氢燃料热解与水蒸气重整耦合制合成气方法及制合成气系统 |
| KR20250138236A (ko) * | 2023-01-26 | 2025-09-19 | 씨제로 인크. | 열 통합된 탄소 및 수소의 화학적 루핑 형성 |
| WO2024192463A1 (en) * | 2023-03-17 | 2024-09-26 | Future Fuels CRC Ltd | A process for producing hydrogen |
| WO2024250060A1 (en) * | 2023-06-06 | 2024-12-12 | Lge Pty Ltd | A method for the conversion of methane |
| WO2025189278A1 (en) * | 2024-03-15 | 2025-09-18 | The University Of British Columbia | Solid carbon-molten media separation in hydrocarbon pyrolysis reactor systems |
| CN120268408B (zh) * | 2025-06-11 | 2025-08-22 | 西南石油大学 | 一种污泥裂解气制碳材料熔融催化剂及其制备方法与应用 |
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| US2449359A (en) | 1945-01-25 | 1948-09-14 | Socony Vacuum Oil Co Inc | Manufacture of carbon monoxide and hydrogen from methane |
| US2760847A (en) | 1951-11-13 | 1956-08-28 | Houdry Process Corp | Production of hydrogen and carbon |
| US3374052A (en) * | 1965-12-20 | 1968-03-19 | Dept Of Chemical Engineering | System for solid particles-fluid contact operations |
| US3679577A (en) * | 1968-11-29 | 1972-07-25 | Shell Oil Co | Molten salt hydrofining process |
| US4107036A (en) | 1974-08-23 | 1978-08-15 | Ruhrchemie Aktiengesellschaft | Separation of carbon black by liquid hydrocarbons |
| FR2381550A1 (fr) * | 1977-02-23 | 1978-09-22 | Serep | Separateur fonctionnant par gravite et depression pour des melanges de deux liquides non miscibles |
| US4421631A (en) * | 1981-10-02 | 1983-12-20 | Rockwell International Corporation | Hydrocarbon treatment process |
| CA2004219A1 (en) | 1988-11-30 | 1990-05-31 | Michael Dunster | Production of hydrogen from hydrocarbonaceous feedstock |
| US5177304A (en) | 1990-07-24 | 1993-01-05 | Molten Metal Technology, Inc. | Method and system for forming carbon dioxide from carbon-containing materials in a molten bath of immiscible metals |
| US5767165A (en) * | 1995-03-16 | 1998-06-16 | Steinberg; Meyer | Method for converting natural gas and carbon dioxide to methanol and reducing CO2 emissions |
| US20070253886A1 (en) | 2004-04-06 | 2007-11-01 | Universite De Sherbrooke | Carbon sequestration and dry reforming process and catalysts to produce same |
| CA2561539C (en) * | 2006-09-28 | 2016-11-08 | Hydro Processing & Mining Ltd. | Apparatus and method for efficient particle to gas bubble attachment in a slurry |
| CA2682402C (en) * | 2007-04-12 | 2015-07-14 | Cefco, Llc | Process and apparatus for carbon capture and elimination of multi-pollutants in flue gas from hydrocarbon fuel sources and recovery of multiple by-products |
| US8088434B2 (en) * | 2007-06-09 | 2012-01-03 | Cxnanophysics, Llc | Templated growth of graphenic materials |
| AU2009270801B2 (en) | 2008-07-18 | 2014-04-24 | Reaction 35, Llc | Continuous process for converting natural gas to liquid hydrocarbons |
| US9061909B2 (en) | 2009-09-10 | 2015-06-23 | The University Of Tokyo | Method for simultaneously producing carbon nanotubes and hydrogen, and device for simultaneously producing carbon nanotubes and hydrogen |
| US8309049B2 (en) * | 2009-10-19 | 2012-11-13 | Battelle Energy Alliance, Llc | Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor |
| TWI429584B (zh) | 2010-08-12 | 2014-03-11 | Wei Hsin Chen | 一種超重力旋轉填充床產生氫氣的裝置與方法 |
| US8895468B2 (en) * | 2011-09-20 | 2014-11-25 | Basf Corporation | Chromia alumina catalysts for alkane dehydrogenation |
| EP2807338A4 (en) | 2012-01-03 | 2016-03-09 | Exxonmobil Upstream Res Co | METHOD FOR PRODUCING HYDROCARBONS WITH CAVEMONS |
| NO2749379T3 (enExample) * | 2012-04-16 | 2018-07-28 | ||
| AU2014318458B2 (en) | 2013-09-16 | 2018-02-01 | Savannah River Nuclear Solutions, Llc | Mass transfer apparatus and method for separation of gases |
| KR101520920B1 (ko) | 2013-12-20 | 2015-05-18 | 한국생산기술연구원 | 액체금속 베드 내에서 촉매 담지체를 이용한 열분해 및 가스화 장치 |
| CA2894376C (en) | 2014-06-17 | 2017-02-28 | Kemira Oyj | Method for separating hydrocarbons and use of molten salt |
| TW201800332A (zh) * | 2016-02-01 | 2018-01-01 | 西維吉尼亞大學研究股份有限公司 | 由天然氣及其他烴類製造碳及氫之方法 |
| US9776860B2 (en) | 2016-02-22 | 2017-10-03 | The Johns Hopkins University | Method of carbon dioxide-free hydrogen production from hydrocarbon decomposition over metal salts |
-
2018
- 2018-11-16 EP EP18877318.8A patent/EP3710152A4/en not_active Withdrawn
- 2018-11-16 KR KR1020207017370A patent/KR102616282B1/ko active Active
- 2018-11-16 CN CN201880084615.3A patent/CN111936227A/zh active Pending
- 2018-11-16 US US16/764,226 patent/US11814285B2/en active Active
- 2018-11-16 WO PCT/US2018/061474 patent/WO2019099795A1/en not_active Ceased
- 2018-11-16 CA CA3082819A patent/CA3082819A1/en active Pending
- 2018-11-16 JP JP2020527100A patent/JP7250016B2/ja active Active
- 2018-11-16 AU AU2018370138A patent/AU2018370138A1/en not_active Abandoned
-
2023
- 2023-03-20 JP JP2023044002A patent/JP2023076501A/ja active Pending
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