JP2021501478A - 有機−無機複合太陽電池および有機−無機複合太陽電池の製造方法 - Google Patents
有機−無機複合太陽電池および有機−無機複合太陽電池の製造方法 Download PDFInfo
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- JP2021501478A JP2021501478A JP2020524097A JP2020524097A JP2021501478A JP 2021501478 A JP2021501478 A JP 2021501478A JP 2020524097 A JP2020524097 A JP 2020524097A JP 2020524097 A JP2020524097 A JP 2020524097A JP 2021501478 A JP2021501478 A JP 2021501478A
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- 238000010422 painting Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
- 238000005019 vapor deposition process Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
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Abstract
Description
前記第1電極上に備えられた第1共通層と、
前記第1共通層上に備えられたペロブスカイト物質を含む光吸収層と、
前記光吸収層上に備えられた第2共通層と、
前記第2共通層上に接するように備えられた導電性粘着剤層とを含む有機−無機複合太陽電池を提供する。
導電性粘着剤層を用意するステップと、
前記第2共通層および導電性粘着剤層が接するように貼り合わせるステップとを含む有機−無機複合太陽電池の製造方法を提供する。
前記第1電極上に備えられた第1共通層と、
前記第1共通層上に備えられたペロブスカイト物質を含む光吸収層と、
前記光吸収層上に備えられた第2共通層と、
前記第2共通層上に接するように備えられた導電性粘着剤層とを含む有機−無機複合太陽電池を提供する。
[化学式1]
AMX3
[化学式2]
BaB'(1−a)M'X'zX''(3−z)
前記化学式1または2において、
BおよびB'は、互いに異なり、
A、BおよびB'は、それぞれCnH2n+1NH3 +、NH4 +、HC(NH2)2 +、Cs+、NF4 +、NCl4 +、PF4 +、PCl4 +、CH3PH3 +、CH3AsH3 +、CH3SbH3 +、PH4 +、AsH4 +、およびSbH4 +から選択される1価の陽イオンであり、
MおよびM'は、互いに同一または異なり、それぞれ独立して、Cu2+、Ni2+、Co2+、Fe2+、Mn2+、Cr2+、Pd2+、Cd2+、Ge2+、Sn2+、Pb2+、およびYb2+から選択される2価の金属イオンであり、
X、X'およびX''は、それぞれ独立して、ハロゲンイオンであり、
nは、1〜9の整数であり、
aは、0<a<1の実数であり、
zは、0<z<3の実数である。
導電性粘着剤層を用意するステップと、
前記第2共通層および導電性粘着剤層が接するように貼り合わせるステップとを含む有機−無機複合太陽電池の製造方法を提供する。
本明細書の一実施態様において、前記第1構造体を形成するステップは、
第1電極を用意するステップと、
前記第1電極上に第1共通層を形成するステップと、
前記第1共通層上にペロブスカイト物質を含む光吸収層を形成するステップと、
前記光吸収層上に第2共通層を形成するステップとを含む。
[化学式3]
AX
[化学式4]
B'aB''(1−a)X'zX''(1−z)
前記化学式3または化学式4において、
BおよびB'は、互いに異なり、A、BおよびB'は、それぞれCnH2n+1NH3 +、NH4 +、HC(NH2)2 +、Cs+、NF4 +、NCl4 +、PF4 +、PCl4 +、CH3PH3 +、CH3AsH3 +、CH3SbH3 +、PH4 +、AsH4 +、およびSbH4 +から選択される1価の陽イオンであり、
X'およびX''は、互いに異なり、
X、X'およびX''は、それぞれハロゲンイオンであり、
nは、1〜9の整数であり、
yは、0<y<1の実数であり、
zは、0<z<1の実数である。
[化学式5]
MX'''2
前記化学式5において、
Mは、Cu2+、Ni2+、Co2+、Fe2+、Mn2+、Cr2+、Pd2+、Cd2+、Ge2+、Sn2+、Pb2+、およびYb2+から選択される2価の金属イオンであり、
X'''は、ハロゲンイオンである。
(1)第1構造体の製造
基板上にPIワニスで基材を形成し、ITOスパッタリングにより80Ω/sq水準の第1電極を形成した。第1電極の形成された基材を超音波を利用してエタノールで20分間洗浄した。この後、前記ITO基板上に2wt%TiO2分散溶液((株)ナノ新素材社)をスピンコーティング方法でコーティングし、150℃で30分間熱処理することにより電子輸送層を形成した。電子輸送層上に約50wt%濃度の(HC(NH2)2)0.85(CH3NH3)0.15PbI2.55Br0.45ペロブスカイト(perovskite)の溶けているジメチルホルムアミド(DMF)溶液をスピンコーティングした後、100℃で30分間熱処理して黒色の光吸収層を形成した。次いで、前記光吸収層上に80mgのSpiro−OMeTAD(2,2',7,7'−tetrakis(N,N−di−p−methoxyphenylamine)−9,9'−spirobifluorene)、28.5μlのタート−ブチルピリジン(tert−butylpyridine、tBP)、および17.5μlのLiTFSI(bis(trifluoromethane)sulfonimide lithium salt)アセトニトリル(acetonitrile)溶液(520mg LiTFSI/1ml acetonitrile)を1mlのクロロベンゼン(chlorobenzene)に混合した溶液を前記スピンコーティングして正孔輸送層を形成することにより、第1構造体を製造した。
粘着層溶液を次のように調液した。ブチレンから誘導された高分子としてブチルゴム(Br068、EXXON社)50g、粘着付与剤として水添炭化水素樹脂(Eastotac H−100L)24g、多官能性の活性エネルギー線重合性化合物としてトリメチロールプロパントリアクリレート15g、およびラジカル開始剤として2,2−ジメトキシ−1,2−ジフェニルエタン−1−オン1g(Irgacure651、Ciba社)を投入して粘着剤組成物を形成した。その後、前述した物質100重量部対比50重量部のカーボンフレークを添加して分散し、トルエンで固形分20重量%程度となるように希釈して導電性粘着コーティング溶液を製造した。前記用意された溶液を離型PETフィルムの離型面に塗布し、100℃のオーブンにて30分間乾燥して厚さ50μmの導電性粘着剤層を形成した。その後、20μmの銅フィルムと貼り合わせて、PET離型層、導電性粘着剤層、銅フィルム構造の第2構造体を作製した。
前記方法で製造された第1構造体と第2構造体とを貼り合わせるために、加温型ロールラミネート機を用いた。100℃の温度で第1構造体とPET離型層を除去した第2構造体とを貼り合わせた後、真空貼着機器を用いて、25℃〜100℃の間の温度条件下、100Paの真空度と0.5MPaの圧力下で脱泡を進行させて、フレキシブルフィルム型有機−無機複合太陽電池を完成した。
基板上にPIワニスで基材を形成し、ITOスパッタリングにより80Ω/sq水準の第1電極を形成した。第1電極の形成された基材を超音波を利用してエタノールで20分間洗浄した。この後、前記ITO基板上に2wt%TiO2分散溶液((株)ナノ新素材社)をスピンコーティング方法でコーティングし、150℃で30分間熱処理することにより電子輸送層を形成した。電子輸送層上に約50wt%濃度の(HC(NH2)2)0.85(CH3NH3)0.15PbI2.55Br0.45ペロブスカイト(perovskite)の溶けているジメチルホルムアミド(DMF)溶液をスピンコーティングした後、100℃で30分間熱処理して黒色の光吸収層を形成した。次いで、前記光吸収層上に80mgのSpiro−OMeTAD(2,2',7,7'−tetrakis(N,N−di−p−methoxyphenylamine)−9,9'−spirobifluorene)、28.5μlのタート−ブチルピリジン(tert−butylpyridine、tBP)、および17.5μlのLiTFSI(bis(trifluoromethane)sulfonimide lithium salt)アセトニトリル(acetonitrile)溶液(520mg LiTFSI/1ml acetonitrile)を1mlのクロロベンゼン(chlorobenzene)に混合した溶液を前記スピンコーティングして正孔輸送層を形成した。その後、導電性カーボンペーストをバーコーティングして20μmの厚さに上部電極を形成し、最後に、商用封止フィルム(FSA DL−01、LG化学社)を常温ロールラミネート機で貼り合わせた後、真空貼着機器を用いて60℃、100Paの真空度と0.5MPaの圧力下で脱泡を進行させて、フレキシブルフィルム型有機−無機複合太陽電池を完成した。
Claims (13)
- 第1電極と、
前記第1電極上に備えられた第1共通層と、
前記第1共通層上に備えられたペロブスカイト物質を含む光吸収層と、
前記光吸収層上に備えられた第2共通層と、
前記第2共通層上に接するように備えられた導電性粘着剤層とを含む有機−無機複合太陽電池。 - 前記導電性粘着剤層上に基材をさらに含むものである、請求項1に記載の有機−無機複合太陽電池。
- 前記基材は、バリアフィルムを含むものである、請求項2に記載の有機−無機複合太陽電池。
- 前記基材は、保護フィルムをさらに含むものである、請求項3に記載の有機−無機複合太陽電池。
- 前記ペロブスカイト物質は、下記化学式1または化学式2で表される化合物である、請求項1〜4のいずれか1項に記載の有機−無機複合太陽電池:
[化学式1]
AMX3
[化学式2]
BaB'(1−a)M'X'zX''(3−z)
前記化学式1または2において、
BおよびB'は、互いに異なり、
A、BおよびB'は、それぞれCnH2n+1NH3 +、NH4 +、HC(NH2)2 +、Cs+、NF4 +、NCl4 +、PF4 +、PCl4 +、CH3PH3 +、CH3AsH3 +、CH3SbH3 +、PH4 +、AsH4 +、およびSbH4 +から選択される1価の陽イオンであり、
MおよびM'は、互いに同一または異なり、それぞれ独立して、Cu2+、Ni2+、Co2+、Fe2+、Mn2+、Cr2+、Pd2+、Cd2+、Ge2+、Sn2+、Pb2+、およびYb2+から選択される2価の金属イオンであり、
X、X'およびX''は、それぞれ独立して、ハロゲンイオンであり、
nは、1〜9の整数であり、
aは、0<a<1の実数であり、
zは、0<z<3の実数である。 - 前記導電性粘着剤層は、導電性物質および粘着物質を含むものである、請求項1〜5のいずれか1項に記載の有機−無機複合太陽電池。
- 前記導電性物質は、炭素ベースの物質または金属粒子を含むものである、請求項6に記載の有機−無機複合太陽電池。
- 前記炭素ベースの物質は、カーボンブラック、カーボンナノチューブ(CNT)、グラファイト(Graphite)、グラフェン(Graphene)、活性炭、多孔性炭素(Mesoporous Carbon)、炭素繊維(Carbon fiber)、およびカーボンナノワイヤ(Carbon nano wire)のうちの少なくとも1つである、請求項7に記載の有機−無機複合太陽電池。
- 前記導電性粘着剤層の面抵抗値は、0.01Ω/sq〜100Ω/sqである、請求項1〜8のいずれか1項に記載の有機−無機複合太陽電池。
- 第1電極と、第1共通層と、ペロブスカイト物質を含む光吸収層と、第2共通層とを含む第1構造体を形成するステップと、
導電性粘着剤層を用意するステップと、
前記第2共通層および導電性粘着剤層が接するように貼り合わせるステップとを含む、請求項1〜9のいずれか1項に記載の有機−無機複合太陽電池の製造方法。 - 前記第1構造体を形成するステップは、
第1電極を用意するステップと、
前記第1電極上に第1共通層を形成するステップと、
前記第1共通層上にペロブスカイト物質を含む光吸収層を形成するステップと、
前記光吸収層上に第2共通層を形成するステップとを含むものである、請求項10に記載の有機−無機複合太陽電池の製造方法。 - 前記導電性粘着剤層が前記第2共通層と接する部分の反対面に基材がさらに備えられるものである、請求項10または11に記載の有機−無機複合太陽電池の製造方法。
- 前記第2共通層および導電性粘着剤層が接するように貼り合わせるステップは、20℃〜100℃でロールを用いるものである、請求項10〜12のいずれか1項に記載の有機−無機複合太陽電池の製造方法。
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