JP2020186411A - 熱伝導性プラスチック - Google Patents
熱伝導性プラスチック Download PDFInfo
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- JP2020186411A JP2020186411A JP2020139650A JP2020139650A JP2020186411A JP 2020186411 A JP2020186411 A JP 2020186411A JP 2020139650 A JP2020139650 A JP 2020139650A JP 2020139650 A JP2020139650 A JP 2020139650A JP 2020186411 A JP2020186411 A JP 2020186411A
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- Prior art keywords
- thermal conductivity
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- composition
- kyanite
- plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004033 plastic Substances 0.000 title claims abstract description 24
- 229920003023 plastic Polymers 0.000 title claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 239000000654 additive Substances 0.000 claims abstract description 12
- 230000000996 additive effect Effects 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 30
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 claims description 11
- 229910052850 kyanite Inorganic materials 0.000 claims description 11
- 239000010443 kyanite Substances 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 11
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 229920006122 polyamide resin Polymers 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 239000000945 filler Substances 0.000 abstract description 12
- 229910052605 nesosilicate Inorganic materials 0.000 abstract description 10
- 239000010703 silicon Substances 0.000 abstract description 6
- 229910052710 silicon Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract 1
- 150000004762 orthosilicates Chemical class 0.000 abstract 1
- 229920002292 Nylon 6 Polymers 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000002351 wastewater Substances 0.000 description 6
- 238000001000 micrograph Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 3
- 229910052909 inorganic silicate Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- -1 silicate anion Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 229920003319 Araldite® Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 229910052849 andalusite Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 229910052854 staurolite Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/14—Solid materials, e.g. powdery or granular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
SILBOND 4000 AST(登録商標;Quarzwerke社製):方珪石、約5μmのd50
TREMICA 1155−010 AST(登録商標;Quarzwerke社製):白雲母、約5μmのd50
熱可塑性材料の場合、充填剤を、押出機(Leistritz社製、ZSE 27 MAXX(登録商標))に通してポリカプロラクタム(PA6)と配合した。配合物から、射出成形(Dermag社製、Ergotech100/420−310(登録商標))により成形品を調製した。
80mm×80mm×2mmのシート
熱伝導率を測定するのに要する試験片を、シートから機械で製造した。押出の方向を横切る測定では(Z方向)、d=12.7mmのディスクを、シートの中心位置から回すことにより調製した。射出の方向の熱伝導率を測定するために(X方向)、それぞれ長さ12.7mmおよび幅2mmの6つのロッドを切断しなければならず、次いで、測定用の特殊な試料ホルダー中で、それを互いに留め、90°回転した。熱硬化性ポリマーでは、真空ミキサー(PC−Laborsysteme社製、Labotop(登録商標))により、充填剤をエポキシ樹脂(Huntsman社製、Araldite CY 184(登録商標)、Aradur HY 1235(登録商標)、促進剤DY062(登録商標))に混合した。成形組成物を、寸法250mm×250mm×2mmのシートに成形し、熱硬化した。これらのパーツから、寸法約20mm×20mm×2mmの試験片をのこぎりで切り出した。
このように調製した試験片に対して、機械的性質および熱伝導度を測定した。
図1には、本発明の一実施形態に係る下廃水危害性物質の低減装置の構造が示されている。図1を参照すると、本発明の一実施形態に係る下廃水危害性物質の低減装置は、既存の処理場の前端又は後端に設けられて好気性微生物によって溶存性有機物を除去し、且つ、一部のアンモニア窒素を酸化させる酸化槽1、酸化槽1から供給される下廃水が処理される主分解部2a、前記酸化槽1内の下廃水を前記主分解部2に供給する下廃水供給ライン11及び前記主分解部2aにおいて分解された下廃水を前記酸化槽1に排出する分解済み下廃水及び活性電子排出ライン32を備える。
伝導率を生み出し、それらは比較材料のものより著しく良好であることを示す。方珪石に
比べて、本発明のネソケイ酸塩は明らかに柔らかく(より低いモース硬度)、そのため、
利用される装置、例えば配合機での摩耗を明らかに低減させる。
ck/Roell社製 Z 202(登録商標);振り子衝撃試験機Zwick/Roe
ll社製 HIT 25P(登録商標)):
材料を、走査型電子顕微鏡(Joel社製 JSM 7600F(登録商標))により検査した。図1から4は、異なる倍率でPA6および藍晶石試料3(60重量%)の顕微鏡写真を示す。
Claims (4)
- ポリアミド樹脂又はエポキシ樹脂であるプラスチック材料と、60重量%から80重量%の藍晶石である添加剤と、を含む組成物であって、前記添加剤は、d50粒径が2μmから20μmである、熱伝導率を高めるための組成物。
- 数種の前記添加剤が組み合わされて利用されることを特徴とする、請求項1に記載の熱伝導率を高めるための組成物。
- 前記添加剤がシラン処理されている、請求項1または請求項2に記載の熱伝導率を高めるための組成物。
- 60重量%から80重量%の藍晶石である前記添加剤と、前記プラスチック材料と、を混合する工程を含む、請求項1から請求項3のいずれか一項に記載される熱伝導率を高めるための組成物を調製するプロセス。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12197839 | 2012-12-18 | ||
EP12197839.9 | 2012-12-18 | ||
EP13182652 | 2013-09-02 | ||
EP13182652.1 | 2013-09-02 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018152695A Division JP7125005B2 (ja) | 2012-12-18 | 2018-08-14 | 熱伝導性プラスチック |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2020186411A true JP2020186411A (ja) | 2020-11-19 |
JP7107621B2 JP7107621B2 (ja) | 2022-07-27 |
Family
ID=49779920
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015547081A Pending JP2016500385A (ja) | 2012-12-18 | 2013-12-18 | 熱伝導性プラスチック |
JP2018152695A Active JP7125005B2 (ja) | 2012-12-18 | 2018-08-14 | 熱伝導性プラスチック |
JP2020139650A Active JP7107621B2 (ja) | 2012-12-18 | 2020-08-20 | 熱伝導性プラスチック |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015547081A Pending JP2016500385A (ja) | 2012-12-18 | 2013-12-18 | 熱伝導性プラスチック |
JP2018152695A Active JP7125005B2 (ja) | 2012-12-18 | 2018-08-14 | 熱伝導性プラスチック |
Country Status (15)
Country | Link |
---|---|
US (1) | US20150307764A1 (ja) |
EP (1) | EP2935432B1 (ja) |
JP (3) | JP2016500385A (ja) |
KR (1) | KR102267585B1 (ja) |
CN (1) | CN104937020A (ja) |
BR (1) | BR112015014269A2 (ja) |
CA (1) | CA2893795A1 (ja) |
HK (1) | HK1211046A1 (ja) |
MX (1) | MX367151B (ja) |
PL (1) | PL2935432T3 (ja) |
RU (1) | RU2662533C2 (ja) |
SI (1) | SI2935432T1 (ja) |
TW (1) | TWI541278B (ja) |
UA (1) | UA115158C2 (ja) |
WO (1) | WO2014095984A1 (ja) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI541278B (zh) * | 2012-12-18 | 2016-07-11 | 夸茲沃克公司 | 導熱性塑膠材料 |
PL2862894T3 (pl) | 2013-10-15 | 2018-06-29 | Lanxess Deutschland Gmbh | Termoplastyczne masy formierskie |
EP2924062B1 (de) * | 2014-03-27 | 2019-02-13 | LANXESS Deutschland GmbH | Flammwidrige Polyamidzusammensetzungen |
CN105199362B (zh) * | 2015-11-02 | 2016-11-30 | 海门市中德电子发展有限公司 | 一种抗紫外线的遮阳用聚碳酸酯板材的制备方法 |
CN105778462A (zh) * | 2016-04-06 | 2016-07-20 | 苏州甫众塑胶有限公司 | 一种易降解力学增强型复合塑胶材料及其制备方法 |
KR20190019912A (ko) | 2016-06-15 | 2019-02-27 | 콰르츠베르케 게엠베하 | 충전된 플라스틱 재료 |
JP2020152762A (ja) * | 2019-03-18 | 2020-09-24 | 三井化学株式会社 | 半芳香族ポリアミド樹脂組成物およびその成形体 |
WO2024017478A1 (de) | 2022-07-21 | 2024-01-25 | Wacker Chemie Ag | Wärmeleitfähiger kunststoff |
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JP2007311628A (ja) * | 2006-05-19 | 2007-11-29 | Kureha Elastomer Co Ltd | 伝熱性弾性シート |
JP2012153774A (ja) * | 2011-01-25 | 2012-08-16 | Shin-Etsu Chemical Co Ltd | 高熱伝導性シリコーンゴムスポンジ組成物の製造方法 |
JP2016500385A (ja) * | 2012-12-18 | 2016-01-12 | グラーツヴェルケ ゲーエムベーハー | 熱伝導性プラスチック |
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USRE28646E (en) * | 1963-05-31 | 1975-12-09 | einforced polyamides and process of preparation thereof | |
SE340695B (ja) * | 1963-05-31 | 1971-11-29 | Monsanto Co | |
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-
2013
- 2013-12-16 TW TW102146404A patent/TWI541278B/zh active
- 2013-12-18 MX MX2015007283A patent/MX367151B/es active IP Right Grant
- 2013-12-18 RU RU2015129581A patent/RU2662533C2/ru active
- 2013-12-18 JP JP2015547081A patent/JP2016500385A/ja active Pending
- 2013-12-18 KR KR1020157015987A patent/KR102267585B1/ko active IP Right Grant
- 2013-12-18 SI SI201330355A patent/SI2935432T1/sl unknown
- 2013-12-18 BR BR112015014269A patent/BR112015014269A2/pt not_active Application Discontinuation
- 2013-12-18 PL PL13808027T patent/PL2935432T3/pl unknown
- 2013-12-18 US US14/653,660 patent/US20150307764A1/en not_active Abandoned
- 2013-12-18 WO PCT/EP2013/077066 patent/WO2014095984A1/de active Application Filing
- 2013-12-18 CA CA2893795A patent/CA2893795A1/en not_active Abandoned
- 2013-12-18 EP EP13808027.0A patent/EP2935432B1/de active Active
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JPH11293094A (ja) * | 1998-02-13 | 1999-10-26 | Mitsubishi Electric Corp | Sf6ガス絶縁機器用エポキシ樹脂組成物およびその成形物 |
JP2000063670A (ja) * | 1998-08-24 | 2000-02-29 | Suzuki Sogyo Co Ltd | 熱伝導性シリコーンゴム組成物およびその成形体 |
JP2007311628A (ja) * | 2006-05-19 | 2007-11-29 | Kureha Elastomer Co Ltd | 伝熱性弾性シート |
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JP2016500385A (ja) * | 2012-12-18 | 2016-01-12 | グラーツヴェルケ ゲーエムベーハー | 熱伝導性プラスチック |
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Also Published As
Publication number | Publication date |
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RU2662533C2 (ru) | 2018-07-26 |
CA2893795A1 (en) | 2014-06-26 |
WO2014095984A1 (de) | 2014-06-26 |
UA115158C2 (uk) | 2017-09-25 |
EP2935432A1 (de) | 2015-10-28 |
CN104937020A (zh) | 2015-09-23 |
US20150307764A1 (en) | 2015-10-29 |
MX2015007283A (es) | 2015-08-12 |
JP2016500385A (ja) | 2016-01-12 |
TW201428036A (zh) | 2014-07-16 |
JP2018204026A (ja) | 2018-12-27 |
HK1211046A1 (en) | 2016-05-13 |
SI2935432T1 (sl) | 2016-11-30 |
KR20150098626A (ko) | 2015-08-28 |
TWI541278B (zh) | 2016-07-11 |
KR102267585B1 (ko) | 2021-06-21 |
PL2935432T3 (pl) | 2017-01-31 |
EP2935432B1 (de) | 2016-08-17 |
BR112015014269A2 (pt) | 2017-07-11 |
JP7107621B2 (ja) | 2022-07-27 |
RU2015129581A (ru) | 2017-01-24 |
MX367151B (es) | 2019-08-07 |
JP7125005B2 (ja) | 2022-08-24 |
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