JP2019535505A - 溶液中で貴金属孤立原子を調製する方法及びその応用 - Google Patents
溶液中で貴金属孤立原子を調製する方法及びその応用 Download PDFInfo
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- JP2019535505A JP2019535505A JP2019524403A JP2019524403A JP2019535505A JP 2019535505 A JP2019535505 A JP 2019535505A JP 2019524403 A JP2019524403 A JP 2019524403A JP 2019524403 A JP2019524403 A JP 2019524403A JP 2019535505 A JP2019535505 A JP 2019535505A
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- Prior art keywords
- noble metal
- acid
- metal isolated
- iii
- preparing
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- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 81
- 238000000034 method Methods 0.000 title claims abstract description 76
- 239000000463 material Substances 0.000 claims abstract description 22
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 14
- 239000003223 protective agent Substances 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 7
- 238000007654 immersion Methods 0.000 claims abstract 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 104
- 239000000243 solution Substances 0.000 claims description 95
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 91
- 239000002253 acid Substances 0.000 claims description 56
- 229910052697 platinum Inorganic materials 0.000 claims description 46
- -1 (diphenyl) Phosphino Chemical group 0.000 claims description 37
- 239000002243 precursor Substances 0.000 claims description 37
- 229920001400 block copolymer Polymers 0.000 claims description 29
- 229910052741 iridium Inorganic materials 0.000 claims description 27
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 25
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 16
- 229910052700 potassium Inorganic materials 0.000 claims description 16
- 239000011591 potassium Substances 0.000 claims description 16
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical group [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 12
- MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
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- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 8
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 8
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- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine hydrate Chemical compound O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 8
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
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- PXURRFCLQDNZOY-UHFFFAOYSA-L carbon monoxide;dichlororuthenium;triphenylphosphane Chemical compound [Cl-].[Cl-].[Ru+2].[O+]#[C-].[O+]#[C-].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 PXURRFCLQDNZOY-UHFFFAOYSA-L 0.000 claims description 7
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims description 7
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 7
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims description 6
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 claims description 6
- 239000010970 precious metal Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004721 Polyphenylene oxide Chemical group 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 5
- 229920000570 polyether Chemical group 0.000 claims description 5
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims description 4
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004912 1,5-cyclooctadiene Substances 0.000 claims description 4
- HXVNBWAKAOHACI-UHFFFAOYSA-N 2,4-dimethyl-3-pentanone Chemical compound CC(C)C(=O)C(C)C HXVNBWAKAOHACI-UHFFFAOYSA-N 0.000 claims description 4
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 4
- HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical compound CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 claims description 4
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 4
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 4
- HYTRYEXINDDXJK-UHFFFAOYSA-N Ethyl isopropyl ketone Chemical compound CCC(=O)C(C)C HYTRYEXINDDXJK-UHFFFAOYSA-N 0.000 claims description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 150000001299 aldehydes Chemical class 0.000 claims description 4
- 150000001350 alkyl halides Chemical class 0.000 claims description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 4
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 4
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- WIWBLJMBLGWSIN-UHFFFAOYSA-L dichlorotris(triphenylphosphine)ruthenium(ii) Chemical compound [Cl-].[Cl-].[Ru+2].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 WIWBLJMBLGWSIN-UHFFFAOYSA-L 0.000 claims description 4
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- 150000002170 ethers Chemical class 0.000 claims description 4
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- 239000003208 petroleum Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- FVZVCSNXTFCBQU-UHFFFAOYSA-N phosphanyl Chemical group [PH2] FVZVCSNXTFCBQU-UHFFFAOYSA-N 0.000 description 1
- PJGSXYOJTGTZAV-UHFFFAOYSA-N pinacolone Chemical compound CC(=O)C(C)(C)C PJGSXYOJTGTZAV-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- KZJPVUDYAMEDRM-UHFFFAOYSA-M silver;2,2,2-trifluoroacetate Chemical compound [Ag+].[O-]C(=O)C(F)(F)F KZJPVUDYAMEDRM-UHFFFAOYSA-M 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLSZOZPQTCFBIR-UHFFFAOYSA-J tetrabromopalladium Chemical compound Br[Pd](Br)(Br)Br YLSZOZPQTCFBIR-UHFFFAOYSA-J 0.000 description 1
- UAIHPMFLFVHDIN-UHFFFAOYSA-K trichloroosmium Chemical compound Cl[Os](Cl)Cl UAIHPMFLFVHDIN-UHFFFAOYSA-K 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Abstract
Description
実施例1で取得した白金単一原子溶液を87ml取り、1gのγ−Al2O3に添加して1時間十分に浸漬した。次に、40℃で減圧蒸留してエタノールと水を除去し、担持量1%の白金単一原子−アルミナ新素材を取得した。1wt%白金単一原子−アルミナ上におけるCOの赤外線吸収スペクトル図より、白金単一原子−アルミナ新素材の合成に成功したことが明らかとなった(解説:1800cm−1〜1900cm−1の間のピークが白金上におけるCOのブリッジ型吸収ピークに相当するのに対し、2086cm−1の吸収ピークは白金上におけるCOのリニア型の吸収ピークである。図面から明らかなように、ブリッジ型の吸収ピークは存在しないことから、結合した2つ又は2つ以上の白金原子は存在しないことが示された。また、COの圧力が大きくなっても2086cm−1箇所のピーク発生位置にブルーシフトは発生しなかった。これは、白金が単一原子の形態で存在することを意味しており、白金単一原子−アルミナ新素材の合成に成功したことが証明された)。
実施例1で取得した白金単一原子溶液を87ml取り、100gのγ−Al2O3に添加して1時間十分に浸漬した。次に、40℃で減圧蒸留してエタノールと水を除去し、担持量0.01%の白金単一原子−アルミナ新素材を取得した。0.01wt%白金単一原子−アルミナ新素材上におけるCOの赤外線吸収スペクトル図は図5に示す通りであった。
実施例1で取得した白金単一原子溶液を87ml取り、0.1gのγ−Al2O3に添加して1時間十分に浸漬した。次に、40℃で減圧蒸留してエタノールと水を除去し、担持量10%の白金単一原子−アルミナ新素材を取得した。10wt%白金単一原子−アルミナ新素材上におけるCOの赤外線吸収スペクトル図は図6に示す通りであった。
Claims (38)
- 溶液中で貴金属孤立原子を調製する方法であって、
保護剤、貴金属化合物の前駆体、還元剤及び溶媒を一定の比率で十分に混合し、一定の温度下で反応させることで貴金属孤立原子を取得する、とのステップにしたがい実行することを特徴とする方法。 - 前記貴金属孤立原子は白金族元素又はポスト白金族元素であり、
前記白金族元素は、パラジウム、ロジウム、イリジウム、ルテニウム、オスミウム又は白金であり、
前記ポスト白金族元素は銀又は金であることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。 - 前記貴金属化合物の前駆体は、白金化合物の前駆体、パラジウム化合物の前駆体、ロジウム化合物の前駆体、イリジウム化合物の前駆体、ルテニウム化合物の前駆体、オスミウム化合物の前駆体、金化合物の前駆体又は銀化合物の前駆体を含むことを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記白金化合物の前駆体は、塩化白金酸、塩化白金酸ナトリウム、塩化白金酸カリウム、塩化白金(II)、塩化白金(IV)、ジクロロ(エチレンジアミン)白金(II)、硝酸白金(II)、ジクロロ(1,5−シクロオクタジエン)白金(II)、トリクロロ(エチレン)白金(II)酸カリウム、ジクロロテトラアンミン白金(II)水和物、ジクロロビス(ベンゾニトリル)白金(II)、cis−ジクロロビス(トリフェニルホスフィン)白金(II)、又は、テトラクロロ白金(II)酸アンモニウムのうちの1つを含むことを特徴とする請求項3に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記パラジウム化合物の前駆体は、塩化パラジウム(II)、二硝酸パラジウム(II)、塩化パラジウム(II)酸、塩化テトラアンミンパラジウム(II)一水和物、trans−ジアンミンジクロロパラジウム(II)、ジニトロテトラアンミンパラジウム、酢酸パラジウム(II)、硫酸パラジウム(II)、トリフルオロ酢酸パラジウム(II)、アセチルアセトンパラジウム(II)、ヘキサクロロパラジウム(IV)酸カリウム、ヘキサクロロパラジウム酸(IV)アンモニウム、テトラアミンパラジウム(II)アセテート、テトラクロロパラジウム(II)酸ナトリウム、テトラクロロパラダート(II)・2カリウム、塩化パラジウム(II)アンモニウム、テトラシアノパラジウム(II)酸カリウム、テトラブロモパラジウム(II)酸カリウム、パラジウムピバラート、パラジウム(II)ジシアニド、パラジウム(II)ジブロミド、チオ硫酸パラジウム(II)、パラジウム(II)ジヨージド、パラジウム(II)スルフィド、[1,3−ビス(ジフェニルホスフィノ)プロパン]パラジウム(II)ジクロリド、ジクロロ(1,5−シクロオクタジエン)パラジウム(II)、(2,2’−ビピリジン)ジクロロパラジウム(II)、[1,2−ビス(ジフェニルホスフィノ)エタン]パラジウム(II)ジクロリド、[1,4−ビス(ジフェニルホスフィノ)ブタン]パラジウム(II)ジクロリド、又は、ジクロロ(エチレンジアミン)パラジウム(II)のうちの1つを含むことを特徴とする請求項3に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記ロジウム化合物の前駆体は、硝酸ロジウム(III)、ロジウム(III)アセチルアセトネート、μ−ジクロロテトラエチレンジロジウム(I)、ヘキサクロロロジウム(III)酸ナトリウム、塩化ロジウム三カリウム、ヘキサクロロロジウム酸(III)アンモニウム、塩化ロジウム(III)、クロロトリス(トリフェニルホスフィン)ロジウム(I)、トリス(エチレンジアミン)ロジウム(III)三塩化物、アセチルアセトナトビス(エチレン)ロジウム(I)、ジカルボニルアセチルアセトナートロジウム(I)、ジカルボニル(ペンタメチルシクロペンタジエニル)ロジウム(I)、又は、ビス(1,5−シクロオクタジエン)ロジウム(I)テトラフルオロボラートのうちの1つを含むことを特徴とする請求項3に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記イリジウム化合物の前駆体は、ヘキサクロロイリジン(IV)酸水和物、トリス(2,4−ペンタンジオナト)イリジウム(III)、ヘキサクロロイリジウム(III)酸ナトリウムN水和物、ヘキサクロロイリジウム(III)酸カリウム、ヘキサクロロイリジウム(IV)酸二アンモニウム、ヘキサニトロイリジン(III)酸カリウム、塩化イリジウム(III)水和物、臭化イリジウム(III)、1,5−シクロオクタジエン(アセチルアセトナート)イリジウム(I)、(1,5−シクロオクタジエン)(ヘキサフルオロアセチルアセトナト)イリジウム(I)、ペンタアミノクロロイリジウム(III)クロリド、ジクロロテトラキス[2−(2−ピリジル)フェニル]ジイリジウム(III)、(アセチルアセトナート)ジカルボニルイリジウム(I)、テトラフルオロホウ酸ビス(1,5‐シクロオクタジエン)イリジウム(I)、(1,5−シクロオクタジエン)(ピリジン)(トリシクロヘキシルホスフィン)イリジウム(I)ヘキサフルオロホスファート、又は、ビス[1,2−ビス(ジフェニスホスフィノ)エタン]カルボニルクロロイリジウム(I)のうちの1つを含むことを特徴とする請求項3に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記ルテニウム化合物の前駆体は、塩化ルテニウム(III)、ルテニウム(III)アセチルアセトナート、ニトロシル硝酸ルテニウム(III)溶液、塩化ヘキサアンミンルテニウム(II)、ヘキサクロロルテニウム酸(IV)アンモニウム、ヘキサシアノルテニウム(II)酸カリウム、テトラプロピルアンモニウムペルルテナート、塩化エチレンジアミン酢酸ルテニウム(III)、ペンタクロロアコルテニウム(III)カリウム、ヨウ化ルテニウム(III)水和物、トリス(トリフェニルホスフィン)ルテニウム(II)ジクロリド、塩化ヘキサアンミンルテニウム(III)、トリス(トリフェニルホスフィン)ルテニウム(II)ジクロリド、ジクロロジ−Μ−クロロビス[(1,2,3,6,7,8−Η−2,7−ジメチル−2,6−オクタジエン−1,8−ジイル]ジルテニウム(IV)、ジクロロトリス(1,10−フェナントロリン)ルテニウム(II)、ジカルボニルジクロロビス(トリフェニルホスフィン)ルテニウム(II)塩化物、又は、ペンタアンミンクロロルテニウム(III)クロリドのうちの1つを含むことを特徴とする請求項3に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記オスミウム化合物の前駆体は、オスミウム(VI)酸カリウム二水和物、ヘキサクロロオスミウム(IV)酸カリウム、ヘキサクロロオスミウム酸(IV)アンモニウム、ビス(ペンタメチルシクロペンタジエニル)オスミウム、オスミウム(III)トリクロリド、又は、ペンタアンミン(トリフルオロメタンスルホン酸)オスミウム(III)トリフルオロメタンスルホン酸のうちの1つを含むことを特徴とする請求項3に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記金化合物の前駆体は、金塩化カリウム、シアン化ナトリウム金(I)、クロロ金(I)、三酸化二金、トリクロロピリジン金(III)、トリクロロ金(III)、テトラクロロ金(III)酸ナトリウム、四塩化金酸、テトラクロロ金(III)酸アンモニウム、クロロ(ジメチルスルフィド)金(I)、クロロカルボニル金(I)、シアノ金(I)、金(III)トリブロミド、ヨード金(I)、又は、(トリフェニルホスフィン)金(I)クロリドのうちの1つを含むことを特徴とする請求項3に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記銀化合物の前駆体は、硝酸銀、乳酸銀(I)、クエン酸銀、塩素酸銀(I)、シアン酸銀(I)、臭素酸銀(I)、酢酸銀(I)、トリフルオロ酢酸銀(I)、銀アセチルアセトナート、ジシアノ銀酸カリウム、銀ペンタフルオロプロピオナート、銀(I)シアニド、又は、安息香酸銀(I)のうちの1つを含むことを特徴とする請求項3に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記還元剤は、アルコール系化合物、ブドウ糖、ギ酸、クエン酸、酒石酸、アスコルビン酸、ヒドラジン一水和物、水素化ホウ素又は水素ガスのいずれかであることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記アルコール系化合物は、メタノール、エタノール、プロパノール、イソプロパノール、1−ブタノール、イソブタノール、2−ブタノール、tert−ブタノール、エチレングリコール又はグリセロールのうちの1又は複数の混合物であることを特徴とする請求項12に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記保護剤は、シロキシ基及び親水性ポリマーを含むブロック共重合体であることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記保護剤は、シロキシ基及びポリエーテル基を含むブロック共重合体であることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- シロキシ基及びポリエーテル基を含むブロック共重合体は、ポリシロキサン−ポリグリコール系化合物であることを特徴とする請求項15に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記ポリシロキサン−ポリグリコール系化合物は、下記構造式のポリシロキサン−ポリエチレングリコールブロック共重合体であることが好ましいことを特徴とする請求項16に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記溶媒は、有機溶媒及び無機溶媒であることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記無機溶媒は、水、塩化チオニル、塩化スルフリル、ヒドラジン一水和物、硫酸クロリドフルオリド、塩酸、硝酸又は硫酸のうちの1又は複数の混合物であることを特徴とする請求項18に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記有機溶媒は、芳香族炭化水素類、脂肪族炭化水素類、脂環式炭化水素類、ハロゲン化アルキル類、アルコール類、エーテル類、エステル類、ケトン類、アルデヒド類、カルボン酸類、ニトリル類、ピリジン、又はフェノールのうちの1又は複数であることを特徴とする請求項18に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記芳香族炭化水素類は、ベンゼン、トルエン、エチルベンゼン、キシレン、トリメチルベンゼン、プロピルベンゼン、イソプロピルベンゼン、ナフタレン、アントラセン、又はフェナントレンのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記脂環式炭化水素類は、ペンタン、ヘキサン、ヘプタン、オクタン、ノナン、デカン、ウンデカン、ドデカン、トリデカン、テトラデカン、ペンタデカン、ヘキサデカン、ヘプタデカン、オクタデカン、ノナデカン又はエイコサンのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記脂環式炭化水素類は、シクロペンタン、シクロヘキサン、シクロヘプタン、シクロオクタン、シクロノナン、シクロデカン、シクロウンデカン、シクロドデカン又はシクロトリデカンのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記ハロゲン化アルキル類は、クロロメタン、ブロモメタン、クロロエタン、ブロモエタン、クロロプロパン、ブロモプロパン、1−クロロブタン、ブロモブタン、クロロペンタン、ブロモペンタン、クロロヘキサン、ブロモヘキサン、クロロヘプタン、ブロモヘプタン、クロロオクタン、ブロモオクタン、クロロノナン、ブロモノナン、クロロデカン、ブロモデカン、クロロベンゼン、ブロモベンゼン、塩化ベンジル、ベンジルブロミド、クロロエチルベンゼン又はブロモエチルベンゼンのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記アルコール類は、メタノール、エタノール、プロパノール、イソプロパノール、1−ブタノール、イソブタノール、2−ブタノール、tert−ブタノール、エチレングリコール又はグリセロールのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記エーテル類は、エーテル、ジプロピルエーテル、ジイソプロピルエーテル、ブチルエチルエーテル、ジブチルエーテル、ジペンチルエーテル、ジイソアミルエーテル、ジヘキシルエーテル、テトラヒドロフラン、1,4−ジオキサン、メタホルムアルデヒド、酸化プロピレン、ジクロロジエチルエーテル、又はジクロロジイソプロピルエーテルのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記エステル類は、ギ酸メチル、酢酸エチル、酢酸メチル、酢酸プロピル、酢酸ブチル、酢酸イソプロピル、酢酸アミル、酢酸イソブチル、酪酸エチル、酪酸プロピル、アクリル酸メチル、アクリル酸エチル、シュウ酸ジエチル、2−メチルプロパン酸エチル、2−メチル酪酸エチル、セバシン酸ジブチル、フタル酸ジメチル、又は、フタル酸ジブチルのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記ケトン類は、アセトン、2−ブタノン、2−ペンタノン、3−ペンタノン、アセチルアセトン、3−メチル−2−ブタノン、2−ヘキサノン、3−ヘキサノン、2−メチル−3−ペンタノン、3,3−ジメチル−2−ブタノン、4−メチル−2−ペンタノン、2−ヘプタノン、シクロペンタノン、シクロヘキサノン、3−ヘプタノン、4−ヘプタノン、2,4−ジメチル−3−ペンタノン、オクタノン、5−メチル−3−ヘプタノン、2,6−ジメチル−3−ヘプタノン、ノナノンのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記アルデヒド類は、アセトアルデヒド、プロピオンアルデヒド、アクロレイン、イソブチルアルデヒド、ブチルアルデヒド、ベンズアルデヒド、パラアルデヒド、シンナムアルデヒド、又はクロトンアルデヒドのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記カルボン酸類は、ギ酸、酢酸、プロピオン酸、酪酸、吉草酸、カプロン酸、ヘプタン酸、オクタン酸、ノナン酸、デカン酸、シュウ酸、アクリル酸、イソ酪酸、イソ吉草酸、テトラデシル酸、又はオレイン酸のうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記ニトリル類は、アセトニトリル、プロパンニトリル、ブチロニトリル、イソブチロニトリル、又はアクリロニトリルのうちの1又は複数であることを特徴とする請求項20に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記還元剤と貴金属化合物の前駆体との物質量の比は、1〜107:1であることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記還元剤と溶媒の物質量の比率は、1:105〜30:1の範囲で変化することを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記貴金属孤立原子が保護剤の質量に対し占める比率は任意の比率であることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記温度は、−70〜200℃の範囲であることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 前記反応時間は、0.5〜200hの範囲であることを特徴とする請求項1に記載の溶液中で貴金属孤立原子を調製する方法。
- 貴金属孤立原子の応用であって、
貴金属孤立原子を固体媒体に担持して貴金属孤立原子−固体媒体新素材を形成し、その調製過程において、
1)担体を貴金属孤立原子溶液と十分に混合して浸漬する浸漬ステップと、
2)−30〜200℃で真空減圧処理し、貴金属孤立原子溶液中の還元剤と溶媒を除去する還元剤及び溶媒除去ステップ、を含む浸漬法を採用することを特徴とする貴金属孤立原子の応用。 - 貴金属孤立原子の担持量は0.01〜50%であることを特徴とする請求項37に記載の貴金属孤立原子の応用。
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JP2009255064A (ja) * | 2008-03-21 | 2009-11-05 | Toyota Central R&D Labs Inc | 自動車排ガス浄化用触媒及びその製造方法 |
WO2014142252A1 (ja) * | 2013-03-14 | 2014-09-18 | 独立行政法人産業技術総合研究所 | ジシロキサンを配位子とする金属錯体および担持金属錯体、その製造方法、並びに、それを用いて調製した担持金属触媒 |
JP2020506285A (ja) * | 2016-11-11 | 2020-02-27 | 中国科学院大▲連▼化学物理研究所Dalian Institute Of Chemical Physics,Chinese Academy Of Sciences | 溶液中で安定的な貴金属孤立原子材料 |
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CN103566935A (zh) * | 2013-01-08 | 2014-02-12 | 湖南大学 | 一种具有高催化性能单原子分散催化剂的制备方法 |
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US4582817A (en) * | 1981-04-27 | 1986-04-15 | National Distillers And Chemical Corporation | Process for the preparation of alkyl nonadienoate esters |
CN1463813A (zh) * | 2002-06-24 | 2003-12-31 | 中国科学院大连化学物理研究所 | 一种纳米贵金属及其制备方法和应用 |
JP2004307455A (ja) * | 2003-02-17 | 2004-11-04 | Sekisui Chem Co Ltd | ゼロ価遷移金属錯体及びこれを出発物質とする有機金属化合物の合成方法 |
JP2009255064A (ja) * | 2008-03-21 | 2009-11-05 | Toyota Central R&D Labs Inc | 自動車排ガス浄化用触媒及びその製造方法 |
WO2014142252A1 (ja) * | 2013-03-14 | 2014-09-18 | 独立行政法人産業技術総合研究所 | ジシロキサンを配位子とする金属錯体および担持金属錯体、その製造方法、並びに、それを用いて調製した担持金属触媒 |
JP2020506285A (ja) * | 2016-11-11 | 2020-02-27 | 中国科学院大▲連▼化学物理研究所Dalian Institute Of Chemical Physics,Chinese Academy Of Sciences | 溶液中で安定的な貴金属孤立原子材料 |
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JP6886018B2 (ja) | 2021-06-16 |
CN108067632B (zh) | 2019-11-08 |
WO2018085959A1 (zh) | 2018-05-17 |
CN108067632A (zh) | 2018-05-25 |
CA3045348A1 (en) | 2018-05-17 |
EP3539655A4 (en) | 2020-06-03 |
US20210260658A1 (en) | 2021-08-26 |
EP3539655A1 (en) | 2019-09-18 |
KR20190085956A (ko) | 2019-07-19 |
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