JP2019533683A - 殺真菌剤の組合せ - Google Patents
殺真菌剤の組合せ Download PDFInfo
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- JP2019533683A JP2019533683A JP2019522363A JP2019522363A JP2019533683A JP 2019533683 A JP2019533683 A JP 2019533683A JP 2019522363 A JP2019522363 A JP 2019522363A JP 2019522363 A JP2019522363 A JP 2019522363A JP 2019533683 A JP2019533683 A JP 2019533683A
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- JP
- Japan
- Prior art keywords
- fungicide
- combination
- inhibitor
- succinate dehydrogenase
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000417 fungicide Substances 0.000 title claims abstract description 140
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 93
- 239000003112 inhibitor Substances 0.000 claims abstract description 56
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims abstract description 50
- 102000019259 Succinate Dehydrogenase Human genes 0.000 claims abstract description 50
- 108010012901 Succinate Dehydrogenase Proteins 0.000 claims abstract description 50
- 239000012990 dithiocarbamate Substances 0.000 claims abstract description 37
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims abstract description 35
- 230000008686 ergosterol biosynthesis Effects 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims description 53
- 229940124186 Dehydrogenase inhibitor Drugs 0.000 claims description 44
- -1 Cufuraneb Chemical compound 0.000 claims description 36
- 239000005802 Mancozeb Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 8
- BNYCHCAYYYRJSH-UHFFFAOYSA-N 1h-pyrazole-5-carboxamide Chemical group NC(=O)C1=CC=NN1 BNYCHCAYYYRJSH-UHFFFAOYSA-N 0.000 claims description 7
- XTDZGXBTXBEZDN-UHFFFAOYSA-N 3-(difluoromethyl)-N-(9-isopropyl-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl)-1-methylpyrazole-4-carboxamide Chemical compound CC(C)C1C2CCC1C1=C2C=CC=C1NC(=O)C1=CN(C)N=C1C(F)F XTDZGXBTXBEZDN-UHFFFAOYSA-N 0.000 claims description 7
- GOFJDXZZHFNFLV-UHFFFAOYSA-N 5-fluoro-1,3-dimethyl-N-[2-(4-methylpentan-2-yl)phenyl]pyrazole-4-carboxamide Chemical compound CC(C)CC(C)C1=CC=CC=C1NC(=O)C1=C(F)N(C)N=C1C GOFJDXZZHFNFLV-UHFFFAOYSA-N 0.000 claims description 7
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- 208000031888 Mycoses Diseases 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- XQJQCBDIXRIYRP-UHFFFAOYSA-N N-{2-[1,1'-bi(cyclopropyl)-2-yl]phenyl}-3-(difluoromethyl)-1-methyl-1pyrazole-4-carboxamide Chemical compound FC(F)C1=NN(C)C=C1C(=O)NC1=CC=CC=C1C1C(C2CC2)C1 XQJQCBDIXRIYRP-UHFFFAOYSA-N 0.000 claims description 6
- 239000005815 Penflufen Substances 0.000 claims description 6
- 239000005834 Sedaxane Substances 0.000 claims description 6
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 claims description 5
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 claims description 5
- 239000005730 Azoxystrobin Substances 0.000 claims description 5
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- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical group CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 claims description 5
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- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 4
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- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 claims description 4
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 4
- IBSNKSODLGJUMQ-SDNWHVSQSA-N picoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC(C(F)(F)F)=N1 IBSNKSODLGJUMQ-SDNWHVSQSA-N 0.000 claims description 4
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 claims description 3
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- 229940118790 boscalid Drugs 0.000 claims description 3
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- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 3
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 claims description 3
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- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 3
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 claims description 3
- SAPGTCDSBGMXCD-UHFFFAOYSA-N (2-chlorophenyl)-(4-fluorophenyl)-pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(F)C=C1 SAPGTCDSBGMXCD-UHFFFAOYSA-N 0.000 claims description 2
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- CKPCAYZTYMHQEX-NBVRZTHBSA-N (e)-1-(2,4-dichlorophenyl)-n-methoxy-2-pyridin-3-ylethanimine Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=N/OC)/CC1=CC=CN=C1 CKPCAYZTYMHQEX-NBVRZTHBSA-N 0.000 claims description 2
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- PDPWCKVFIFAQIQ-UHFFFAOYSA-N 2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide Chemical compound CNC(=O)C(OC)C1=CC=CC=C1COC1=CC(C)=CC=C1C PDPWCKVFIFAQIQ-UHFFFAOYSA-N 0.000 claims description 2
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- BFTGQIQVUVTBJU-UHFFFAOYSA-N 5,6-dihydroimidazo[2,1-c][1,2,4]dithiazole-3-thione Chemical compound C1CN2C(=S)SSC2=N1 BFTGQIQVUVTBJU-UHFFFAOYSA-N 0.000 claims description 2
- PCCSBWNGDMYFCW-UHFFFAOYSA-N 5-methyl-5-(4-phenoxyphenyl)-3-(phenylamino)-1,3-oxazolidine-2,4-dione Chemical compound O=C1C(C)(C=2C=CC(OC=3C=CC=CC=3)=CC=2)OC(=O)N1NC1=CC=CC=C1 PCCSBWNGDMYFCW-UHFFFAOYSA-N 0.000 claims description 2
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- HOERQTQCTISLFR-UHFFFAOYSA-N [(3-chloro-2,6-dimethoxybenzoyl)-ethylamino] benzoate Chemical compound COC=1C=CC(Cl)=C(OC)C=1C(=O)N(CC)OC(=O)C1=CC=CC=C1 HOERQTQCTISLFR-UHFFFAOYSA-N 0.000 claims description 2
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- AKNQMEBLVAMSNZ-UHFFFAOYSA-N azaconazole Chemical group ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCCO1 AKNQMEBLVAMSNZ-UHFFFAOYSA-N 0.000 claims description 2
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Classifications
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- A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
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- A61F2/00—Filters implantable into blood vessels; Prostheses, i.e. artificial substitutes or replacements for parts of the body; Appliances for connecting them with the body; Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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Abstract
Description
(a)少なくとも1種のジチオカルバメート系殺真菌剤と、
(b)少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、
(c)エルゴステロール生合成阻害剤及び/又はキノンアウトサイド阻害剤から選択される少なくとも1種の他の系の殺真菌剤と
を含む、殺真菌剤の組合せを提供する。
(a)少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、
(b)少なくとも1種のジチオカルバメート系殺真菌剤と、
(c)少なくとも1種のキノンアウトサイド阻害剤と、
(d)少なくとも1種の農芸化学的に許容可能な賦形剤と
、を含む、組成物を提供してもよい。
(a)少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、
(b)少なくとも1種のジチオカルバメート系殺真菌剤と、
(c)少なくとも1種のエルゴステロール生合成阻害剤と、
(d)少なくとも1種の農芸化学的に許容可能な賦形剤と
、を含む、組成物を提供してもよい。
(a)少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、
(b)少なくとも1種のジチオカルバメート系殺真菌剤と、
(c)少なくとも1種のキノンアウトサイド阻害剤と、
(d)少なくとも1種のエルゴステロール生合成阻害剤と、
(e)少なくとも1種の農芸化学的に許容可能な賦形剤と
、を含む、組成物を提供してもよい。
(a)ベンゾビンジフルピル、ビキサフェン、フルキサピロキサド、フラメトピル、イソピラザム、ペンフルフェン、ペンチオピラド、及びセダキサンから選択される少なくとも1種のピラゾールカルボキサミドと、
(b)少なくとも1種のキノンアウトサイド阻害剤及び/又は少なくとも1種のエルゴステロール生合成阻害剤と、
(c)少なくとも1種のジチオカルバメート系殺真菌剤と
を含み、殺真菌剤が農芸化学的に許容可能な量で組み合わされている組成物を提供することができる。
(a)少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、
(b)少なくとも1種のキノンアウトサイド阻害剤及び/又は少なくとも1種のエルゴステロール生合成阻害剤と、
(c)少なくとも1種類のジチオカルバメート系殺真菌剤と
を含む組合せを適用することを含む、方法を提供することができる。
Claims (17)
- 少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、少なくとも1種のジチオカルバメート系殺真菌剤と、少なくとも1種の他の系の殺真菌剤とを含む、殺真菌剤の組合せ。
- 前記ジチオカルバメート系殺真菌剤が、アモバム、アソメート、アジチラム、カルバモルフ、クフラネブ、クプロバム、ジスルフィラム、フェルバム、メタム、ナバム、テコラム、チラム、ウルバシド、ジラム、ダゾメット、エテム、ミルネブ、マンカッパー、マンコゼブ、マネブ、メチラム、ポリカルバメート、プロピネブ及びジネブから選択される、請求項1に記載の組合せ。
- 前記ジチオカルバメート系殺真菌剤が、マンコゼブである、請求項2に記載の組合せ。
- 前記コハク酸脱水素酵素阻害剤系殺真菌剤が、コハク酸脱水素酵素阻害剤系殺真菌剤のピラゾールカルボキサミド群から選択される、請求項1に記載の組合せ。
- 前記ピラゾールカルボキサミド群の前記コハク酸脱水素酵素阻害剤系殺真菌剤が、ベンゾビンジフルピル、ビキサフェン、フルキサピロキサド、フラメトピル、イソピラザム、ペンフルフェン、ペンチオピラド、及びセダキサンから選択される、請求項4に記載の組合せ。
- 少なくとも1種の他の系の殺真菌剤が、エルゴステロール生合成阻害剤系殺真菌剤及びキノンアウトサイド阻害剤系殺真菌剤のうちの少なくとも1種である、請求項1に記載の組合せ。
- 前記エルゴステロール生合成阻害剤系殺真菌剤が、アザコナゾール、ビテルタノール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、ジニコナゾール、エポキシコナゾール、エタコナゾール、フェンブコナゾール、フルキンコナゾール、フルシラゾール、フルトリアホール、ヘキサコナゾール、イミベンコナゾール、イプコナゾール、メトコナゾール、ミクロブタニル、ペンコナゾール、プロピコナゾール、シメコナゾール、テブコナゾール、テトラコナゾール、トリアジメフォン、トリアジメノール、トリチコナゾール、プロチオコナゾール、イマザリル、オキスポコナゾール、ペフラゾエート、プロクロラズ、トリフルミゾール、フェナリモル、ヌアリモル、ピリフェノックス、ピリスオキサゾール、トリホリン、及びこれらの混合物から選択される、請求項6に記載の組合せ。
- 前記キノンアウトサイド(Qo)阻害剤系殺真菌剤が、アゾキシストロビン、クモキシストロビン、エノキサストロビン、フルフェノキシストロビン、ピコキシストロビン、ピラオキシストロビン、マンデストロビン、ピラクロストロビン、ピラメトストロビン、トリクロピリカルブ、クレソキシムメチル、ジモキシストロビン、フェナミノストロビン、メトミノストロビン、トリフロキシストロビン、ファモキサドン、フルオキサストロビン、フェナミドン、ピリベンカルブ、及びこれらの混合物から選択される、請求項6に記載の組合せ。
- 少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、少なくとも1種のジチオカルバメート系殺真菌剤と、少なくとも2種の他の系の殺真菌剤とを含む、殺真菌剤の組合せ。
- (a)マンコゼブと、
(b)イソピラザム、ベンゾビンジフルピル、ペンチオピラド、ボスカリド、フルインダピル、ビキサフェン、フルキサピロキサド、フラメトピル、ペンフルフェン、又はセダキサンと、
(c)シプロコナゾール、ジフェノコナゾール、エポキシコナゾール、ヘキサコナゾール、ヘキサコナゾール、テブコナゾール、テトラコナゾール、プロチオコナゾール、アゾキシストロビン、ピコキシストロビン、ピラクロストロビン、クレソキシムメチル、トリフロキシストロビン、又はこれらの組合せと
を含む、請求項1に記載の組合せ。 - (a)マンコゼブと、
(b)ベンゾビンジフルピル、イソピラザム、又はペンチオピラドと、
(c)プロチオコナゾール及び/又はアゾキシストロビンと
を含む、請求項1に記載の組合せ。 - (a)少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、
(b)少なくとも1種のジチオカルバメート系殺真菌剤と、
(c)少なくとも1種のエルゴステロール生合成阻害剤及び/又は少なくとも1種のキノンアウトサイド阻害剤と、
(d)少なくとも1種の農芸化学的に許容可能な賦形剤と
を含む、組成物。 - 前記組成物が、湿潤性粉末、顆粒、粉塵、可溶性(液体)濃縮物、懸濁濃縮物、水中油型エマルション、油中水型エマルション、乳化性濃縮物、カプセル懸濁液、ZC製剤、油分散物への配合用である、請求項12に記載の組成物。
- 前記組合せは、(1〜80):(1〜80):(1〜80):(1:80)の比率での前記殺真菌剤を混合したものである、請求項1〜11のいずれか一項に記載の組合せ。
- 前記組成物中のコハク酸脱水素酵素阻害剤系殺真菌剤の総量は、0.1〜99重量%の範囲内であり、前記組成物中のジチオカルバメート系殺真菌剤の総量は、0.1〜99重量%の範囲内であり、前記組成物中のエルゴステロール生合成阻害剤の総量は、0.1〜99重量%の範囲内であり、前記組成物中のキノンアウトサイド阻害剤の総量は、0.1〜99重量%の範囲内である、請求項1〜11および14のいずれか一項に記載の組合せ。
- 前記組成物が、葉面散布用又は植物繁殖材料に適用するためのものである、請求項12または13に記載の組成物。
- 真菌病害を防除するための方法であって、
(a)少なくとも1種のコハク酸脱水素酵素阻害剤系殺真菌剤と、
(b)少なくとも1種のキノンアウトサイド阻害剤及び/又は少なくとも1種のエルゴステロール生合成阻害剤と、
(c)少なくとも1種のジチオカルバメート系殺真菌剤と
を含む組合せを、植物の部位に適用することを含む、方法。
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