JP2019507149A5 - - Google Patents
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- Publication number
- JP2019507149A5 JP2019507149A5 JP2018543660A JP2018543660A JP2019507149A5 JP 2019507149 A5 JP2019507149 A5 JP 2019507149A5 JP 2018543660 A JP2018543660 A JP 2018543660A JP 2018543660 A JP2018543660 A JP 2018543660A JP 2019507149 A5 JP2019507149 A5 JP 2019507149A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- cycloalkyl
- alkoxy
- cyclopropyl
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- -1 nitro, amino Chemical group 0.000 claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 23
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 18
- 229910052736 halogen Inorganic materials 0.000 claims description 18
- 150000002367 halogens Chemical class 0.000 claims description 16
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 12
- 125000001072 heteroaryl group Chemical group 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 125000001424 substituent group Chemical group 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 claims description 8
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims description 8
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 8
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims description 8
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims description 8
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical group O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 241000607479 Yersinia pestis Species 0.000 claims description 7
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 claims description 4
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims description 4
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 4
- 125000004776 1-fluoroethyl group Chemical group [H]C([H])([H])C([H])(F)* 0.000 claims description 4
- 125000004778 2,2-difluoroethyl group Chemical group [H]C([H])(*)C([H])(F)F 0.000 claims description 4
- 125000004777 2-fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 claims description 4
- 150000001204 N-oxides Chemical class 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 4
- 125000004775 chlorodifluoromethyl group Chemical group FC(F)(Cl)* 0.000 claims description 4
- 125000004774 dichlorofluoromethyl group Chemical group FC(Cl)(Cl)* 0.000 claims description 4
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- 125000003226 pyrazolyl group Chemical group 0.000 claims description 4
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 4
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 claims description 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 4
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 claims description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- FKTXDTWDCPTPHK-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical group FC(F)(F)[C](F)C(F)(F)F FKTXDTWDCPTPHK-UHFFFAOYSA-N 0.000 claims description 2
- 125000006002 1,1-difluoroethyl group Chemical group 0.000 claims description 2
- 125000004972 1-butynyl group Chemical group [H]C([H])([H])C([H])([H])C#C* 0.000 claims description 2
- 125000006426 1-chlorocyclopropyl group Chemical group [H]C1([H])C([H])([H])C1(Cl)* 0.000 claims description 2
- 125000006420 1-fluorocyclopropyl group Chemical group [H]C1([H])C([H])([H])C1(F)* 0.000 claims description 2
- 125000006017 1-propenyl group Chemical group 0.000 claims description 2
- 125000000530 1-propynyl group Chemical group [H]C([H])([H])C#C* 0.000 claims description 2
- 125000004780 2-chloro-2,2-difluoroethyl group Chemical group [H]C([H])(*)C(F)(F)Cl 0.000 claims description 2
- 125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- 125000004189 3,4-dichlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(Cl)C([H])=C1* 0.000 claims description 2
- 125000004179 3-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(Cl)=C1[H] 0.000 claims description 2
- 125000006163 5-membered heteroaryl group Chemical group 0.000 claims description 2
- 230000000895 acaricidal effect Effects 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 claims description 2
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 2
- 238000002405 diagnostic procedure Methods 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000006341 heptafluoro n-propyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)* 0.000 claims description 2
- 230000000749 insecticidal effect Effects 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- CMWTZPSULFXXJA-VIFPVBQESA-N naproxen Chemical group C1=C([C@H](C)C(O)=O)C=CC2=CC(OC)=CC=C21 CMWTZPSULFXXJA-VIFPVBQESA-N 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 125000006344 nonafluoro n-butyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 claims description 2
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 claims description 2
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 claims description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 238000001356 surgical procedure Methods 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- BGNGWHSBYQYVRX-UHFFFAOYSA-N 4-(dimethylamino)benzaldehyde Chemical compound CN(C)C1=CC=C(C=O)C=C1 BGNGWHSBYQYVRX-UHFFFAOYSA-N 0.000 claims 1
- 125000006423 bromocyclopropyl group Chemical group 0.000 claims 1
- 230000001069 nematicidal effect Effects 0.000 claims 1
- 238000002560 therapeutic procedure Methods 0.000 claims 1
- 241001465754 Metazoa Species 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- 125000006424 1-bromocyclopropyl group Chemical group [H]C1([H])C([H])([H])C1(Br)* 0.000 description 1
- 125000000453 2,2,2-trichloroethyl group Chemical group [H]C([H])(*)C(Cl)(Cl)Cl 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16156360 | 2016-02-18 | ||
| EP16156360.6 | 2016-02-18 | ||
| PCT/EP2017/053488 WO2017140771A1 (en) | 2016-02-18 | 2017-02-16 | Pesticidally active pyrazole derivatives |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019507149A JP2019507149A (ja) | 2019-03-14 |
| JP2019507149A5 true JP2019507149A5 (enExample) | 2020-03-26 |
| JP6850300B2 JP6850300B2 (ja) | 2021-03-31 |
Family
ID=55398231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018543660A Expired - Fee Related JP6850300B2 (ja) | 2016-02-18 | 2017-02-16 | 殺有害生物活性ピラゾール誘導体 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10874104B2 (enExample) |
| EP (1) | EP3416959B1 (enExample) |
| JP (1) | JP6850300B2 (enExample) |
| CN (1) | CN108713016B (enExample) |
| AR (1) | AR107660A1 (enExample) |
| BR (1) | BR112018016794B1 (enExample) |
| CA (1) | CA3012901A1 (enExample) |
| CL (1) | CL2018002351A1 (enExample) |
| CO (1) | CO2018008470A2 (enExample) |
| EC (1) | ECSP18061607A (enExample) |
| ES (1) | ES2883591T3 (enExample) |
| MX (1) | MX2018009857A (enExample) |
| WO (1) | WO2017140771A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3070497A1 (en) | 2017-06-19 | 2018-12-27 | Syngenta Participations Ag | Pesticidally active pyrazole derivatives |
| EP3665167B1 (en) * | 2017-08-11 | 2022-11-30 | Syngenta Participations AG | Pesticidally active pyrazole derivatives |
| AR112673A1 (es) * | 2017-08-11 | 2019-11-27 | Syngenta Participations Ag | Derivados de pirazol activos como plaguicidas |
| WO2019030358A1 (en) * | 2017-08-11 | 2019-02-14 | Syngenta Participations Ag | ACTIVE PYRAZOLE DERIVATIVES ON THE PESTICIDE PLAN |
| WO2019068819A1 (en) | 2017-10-06 | 2019-04-11 | Syngenta Participations Ag | PYRROLE DERIVATIVES ACTIVE ON THE PESTICIDE PLAN |
| JP6714785B2 (ja) * | 2018-05-31 | 2020-06-24 | クミアイ化学工業株式会社 | 含フッ素ピラゾール誘導体の製造方法及びその中間体 |
| WO2020127345A1 (en) | 2018-12-21 | 2020-06-25 | Syngenta Participations Ag | Pesticidally active pyrazole derivatives |
| WO2020164993A1 (en) * | 2019-02-13 | 2020-08-20 | Syngenta Crop Protection Ag | Pesticidally active pyrazole derivatives |
Family Cites Families (47)
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|---|---|---|---|---|
| BR8600161A (pt) | 1985-01-18 | 1986-09-23 | Plant Genetic Systems Nv | Gene quimerico,vetores de plasmidio hibrido,intermediario,processo para controlar insetos em agricultura ou horticultura,composicao inseticida,processo para transformar celulas de plantas para expressar uma toxina de polipeptideo produzida por bacillus thuringiensis,planta,semente de planta,cultura de celulas e plasmidio |
| CA1340685C (en) | 1988-07-29 | 1999-07-27 | Frederick Meins | Dna sequences encoding polypeptides having beta-1,3-glucanase activity |
| US5169629A (en) | 1988-11-01 | 1992-12-08 | Mycogen Corporation | Process of controlling lepidopteran pests, using bacillus thuringiensis isolate denoted b.t ps81gg |
| CA2005658A1 (en) | 1988-12-19 | 1990-06-19 | Eliahu Zlotkin | Insecticidal toxins, genes encoding these toxins, antibodies binding to them and transgenic plant cells and plants expressing these toxins |
| DE69034081T2 (de) | 1989-03-24 | 2004-02-12 | Syngenta Participations Ag | Krankheitsresistente transgene Pflanze |
| GB8910624D0 (en) | 1989-05-09 | 1989-06-21 | Ici Plc | Bacterial strains |
| CA2015951A1 (en) | 1989-05-18 | 1990-11-18 | Mycogen Corporation | Novel bacillus thuringiensis isolates active against lepidopteran pests, and genes encoding novel lepidopteran-active toxins |
| DE69018772T2 (de) | 1989-11-07 | 1996-03-14 | Pioneer Hi Bred Int | Larven abtötende Lektine und darauf beruhende Pflanzenresistenz gegen Insekten. |
| US5639949A (en) | 1990-08-20 | 1997-06-17 | Ciba-Geigy Corporation | Genes for the synthesis of antipathogenic substances |
| UA48104C2 (uk) | 1991-10-04 | 2002-08-15 | Новартіс Аг | Фрагмент днк, який містить послідовність,що кодує інсектицидний протеїн, оптимізовану для кукурудзи,фрагмент днк, який забезпечує направлену бажану для серцевини стебла експресію зв'язаного з нею структурного гена в рослині, фрагмент днк, який забезпечує специфічну для пилку експресію зв`язаного з нею структурного гена в рослині, рекомбінантна молекула днк, спосіб одержання оптимізованої для кукурудзи кодуючої послідовності інсектицидного протеїну, спосіб захисту рослин кукурудзи щонайменше від однієї комахи-шкідника |
| US5530195A (en) | 1994-06-10 | 1996-06-25 | Ciba-Geigy Corporation | Bacillus thuringiensis gene encoding a toxin active against insects |
| US5536701A (en) | 1994-10-11 | 1996-07-16 | Monsanto Company | 3-pyrazolyloxypyridazines, herbicidal compositions and uses thereof |
| US5631072A (en) | 1995-03-10 | 1997-05-20 | Avondale Incorporated | Method and means for increasing efficacy and wash durability of insecticide treated fabric |
| DE69925610T2 (de) | 1998-09-15 | 2006-04-27 | Syngenta Participations Ag | Als herbicide verwendbare pyridin-ketone |
| JP2004506432A (ja) | 2000-08-25 | 2004-03-04 | シンジェンタ・パティシペーションズ・アクチェンゲゼルシャフト | Ｂａｃｉｌｌｕｓｔｈｕｒｉｎｇｉｅｎｓｉｓ殺虫性結晶タンパク質由来の新規殺虫性毒素 |
| AU2002345250A1 (en) | 2001-06-22 | 2003-01-08 | Syngenta Participations Ag | Plant disease resistance genes |
| US7230167B2 (en) | 2001-08-31 | 2007-06-12 | Syngenta Participations Ag | Modified Cry3A toxins and nucleic acid sequences coding therefor |
| WO2003034823A1 (en) | 2001-10-25 | 2003-05-01 | Siamdutch Mosquito Netting Company Limited | Treatment of fabric materials with an insecticide |
| AU2002361696A1 (en) | 2001-12-17 | 2003-06-30 | Syngenta Participations Ag | Novel corn event |
| US7005432B2 (en) | 2002-05-16 | 2006-02-28 | Hoffman-La Roche Inc. | Substituted imidazol-pyridazine derivatives |
| US7326736B2 (en) | 2002-11-04 | 2008-02-05 | Giner Electrochemical Systems, Llc | Composite proton exchange membrane and method of manufacturing the same |
| US20050132500A1 (en) | 2003-12-22 | 2005-06-23 | Basf Aktiengesellschaft | Composition for impregnation of fibers, fabrics and nettings imparting a protective activity against pests |
| DE102004023894A1 (de) | 2004-05-12 | 2005-12-08 | Basf Ag | Verfahren zur Behandlung von flexiblen Substraten |
| DK1848694T3 (da) | 2005-02-07 | 2010-01-25 | Hoffmann La Roche | Heterocykliske substituerede phenylmethanoner som inhibitorer af glycintransporter |
| DE102005007160A1 (de) | 2005-02-16 | 2006-08-24 | Basf Ag | Pyrazolcarbonsäureanilide, Verfahren zu ihrer Herstellung und sie enthaltende Mittel zur Bekämpfung von Schadpilzen |
| DE102005020889A1 (de) | 2005-05-04 | 2006-11-09 | Fritz Blanke Gmbh & Co.Kg | Verfahren zur antimikrobiellen Ausrüstung von textilen Flächengebilden |
| AP2007004257A0 (en) | 2005-06-03 | 2007-12-31 | Basf Ag | Composition for impregnation of fibres fabrics andnettings imparting a protective activity against pests |
| BRPI0617739B1 (pt) | 2005-10-25 | 2017-11-21 | Syngenta Participations Ag | Heterocyclic amide derivatives useful as microbiocides, composition comprising them and method of controlling or preventing infestation of useful plants by phytopathogenic microorganisms |
| WO2007060525A2 (en) | 2005-11-28 | 2007-05-31 | Pfizer Products Inc. | Process for preparing bicyclic pyrazolyl and imidazolyl compounds |
| WO2007090739A1 (de) | 2006-02-03 | 2007-08-16 | Basf Se | Verfahren zum behandeln von substraten |
| MY147339A (en) | 2007-06-12 | 2012-11-30 | Basf Se | Aqueous formulation and process for the impregnation of non-living-materials imparting a protective activity against pests |
| EP3790302B1 (en) | 2007-08-22 | 2024-12-11 | Wireless Future Technologies Inc. | Exchange of scheduling strategies for interference coordination |
| EP2184273A1 (de) | 2008-11-05 | 2010-05-12 | Bayer CropScience AG | Halogen-substituierte Verbindungen als Pestizide |
| MA34805B1 (fr) | 2010-11-23 | 2014-01-02 | Pfizer | Dérivés de 4-(5-cyano-pyrazole-1-yl)-pipéridine en tant que modulateurs du gpr119 |
| EP2651921A1 (en) * | 2010-12-17 | 2013-10-23 | Syngenta Participations AG | Insecticidal compounds |
| TWI528899B (zh) | 2010-12-29 | 2016-04-11 | 杜邦股份有限公司 | 中離子性殺蟲劑 |
| JP2014510049A (ja) * | 2011-02-09 | 2014-04-24 | シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト | 殺虫性化合物 |
| UY33895A (es) * | 2011-02-09 | 2012-09-28 | Syngenta Participations Ag | Compuestos insecticidas, método para combatir y controlar insectos, ácaros, nematodos o moluscos, y composición insecticida, acaricida o nematicida |
| JP6321042B2 (ja) | 2013-02-06 | 2018-05-09 | バイエル・クロップサイエンス・アクチェンゲゼルシャフト | 新規なハロゲン置換された化合物 |
| EP2964631B1 (de) * | 2013-03-04 | 2017-08-30 | Bayer Animal Health GmbH | Halogen-substituierte n-[3-(1h-pyrazol-4-yl)phenylmethyl]-sulfonamid-derivate und verwandte verbindungen als pestizide zur verwendung im pflanzenschutz, in der veterinärmedizin und im materialschutz |
| AR098311A1 (es) | 2013-11-05 | 2016-05-26 | Bayer Cropscience Ag | Compuestos para el control de artrópodos |
| DK3066080T5 (en) * | 2013-11-05 | 2018-09-17 | Bayer Cropscience Ag | SUBSTITUTED BENZAMIDES FOR TREATMENT OF ARTHROPODS |
| AR101816A1 (es) * | 2014-04-02 | 2017-01-18 | Bayer Cropscience Ag | Derivados de 3-[(pirazol-5-il)-heteroaril]-benzamidas como agentes pesticidas |
| AR100821A1 (es) * | 2014-06-18 | 2016-11-02 | Bayer Cropscience Ag | Pirazolil-triazolil-piridinas como agentes plaguicidas |
| AR100817A1 (es) | 2014-06-18 | 2016-11-02 | Bayer Cropscience Ag | Pirazoles y tetrazoles sustituidos con halógeno |
| AR101448A1 (es) * | 2014-08-08 | 2016-12-21 | Bayer Cropscience Ag | Compuestos sustituidos por halógeno |
| UY36249A (es) * | 2014-08-08 | 2016-01-29 | Bayer Cropscience Ag | Compuestos sustituidos con halógeno novedosos |
-
2017
- 2017-02-16 CO CONC2018/0008470A patent/CO2018008470A2/es unknown
- 2017-02-16 EP EP17704288.4A patent/EP3416959B1/en active Active
- 2017-02-16 CA CA3012901A patent/CA3012901A1/en not_active Abandoned
- 2017-02-16 ES ES17704288T patent/ES2883591T3/es active Active
- 2017-02-16 CN CN201780011903.1A patent/CN108713016B/zh not_active Expired - Fee Related
- 2017-02-16 JP JP2018543660A patent/JP6850300B2/ja not_active Expired - Fee Related
- 2017-02-16 MX MX2018009857A patent/MX2018009857A/es unknown
- 2017-02-16 WO PCT/EP2017/053488 patent/WO2017140771A1/en not_active Ceased
- 2017-02-16 US US15/999,052 patent/US10874104B2/en not_active Expired - Fee Related
- 2017-02-16 BR BR112018016794-0A patent/BR112018016794B1/pt not_active IP Right Cessation
- 2017-02-17 AR ARP170100406A patent/AR107660A1/es unknown
-
2018
- 2018-08-15 EC ECSENADI201861607A patent/ECSP18061607A/es unknown
- 2018-08-16 CL CL2018002351A patent/CL2018002351A1/es unknown
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