JP2019044010A - 親水性コーティング用樹脂組成物 - Google Patents
親水性コーティング用樹脂組成物 Download PDFInfo
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- JP2019044010A JP2019044010A JP2017165914A JP2017165914A JP2019044010A JP 2019044010 A JP2019044010 A JP 2019044010A JP 2017165914 A JP2017165914 A JP 2017165914A JP 2017165914 A JP2017165914 A JP 2017165914A JP 2019044010 A JP2019044010 A JP 2019044010A
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- resin composition
- hydrophilic
- hydrophilic coating
- epoxy compound
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- 238000000576 coating method Methods 0.000 title claims abstract description 82
- 239000011248 coating agent Substances 0.000 title claims abstract description 70
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- 239000004593 Epoxy Substances 0.000 claims abstract description 26
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 19
- 125000001033 ether group Chemical group 0.000 claims abstract description 10
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 239000000758 substrate Substances 0.000 claims description 20
- -1 polyoxyethylene group Polymers 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 17
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 125000003003 spiro group Chemical group 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 125000002723 alicyclic group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
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- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
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- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
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- 239000000203 mixture Substances 0.000 description 3
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- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
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- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
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- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
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- 125000005442 diisocyanate group Chemical group 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
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- 230000001771 impaired effect Effects 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
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- 238000002360 preparation method Methods 0.000 description 2
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- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
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Abstract
Description
を表す。)
で表される単官能エポキシ化合物であることが好ましい。
本発明の親水性コーティング用樹脂組成物は、(A)エーテル基を有するポリウレタン樹脂90〜70重量%、及び、(B)ポリオキシアルキレン基及び炭素数1〜30の炭化水素基を有する単官能エポキシ化合物10〜30重量%を含有することを特徴とする。
を表す。)
で表される単官能エポキシ化合物が好ましい。
本発明の親水性コーティング用樹脂組成物には、硬化触媒を配合することもできる。硬化触媒としては、特に限定されず従来公知のものを使用することができるが、例えば、ジブチル錫ジラウレート、ジブチル錫ジアセテート等の錫化合物、オクチル酸ビスマス等のビスマス化合物、テトラオクチルチタネート、チタンエチルアセトアセテート等のチタン化合物、ジルコニウムモノアセチルアセテート、ジルコニウムテトラアセチルアセテート等のジルコニウム化合物、トリエチレンジアミン、1,4−ジアザビシクロ[2,2,2]オクタン(DABCO)等のアミン類等が挙げられる。これらは単独で用いても良いし、2種以上を併用しても良い。
溶剤としては、特に限定はなく、水系又は有機溶剤系の何れも好適に使用できるが、例えば、トルエン、エチルベンゼン、トリメチルベンゼン、キシレン等の芳香族炭化水素系溶剤、ペンタン、ヘキサン、シクロヘキサン等の脂肪族炭化水素系溶剤、アセトン、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノン等のケトン系溶剤、メタノール、エタノール、イソプロパノール、エチレングリコール、ジエチレングリコール、トリエチレングリコール、プロピレングリコール等のアルコール系溶剤、メチルセロソルブ、エチルセロソルブ、ブチルセロソルブ、メチルジグリコール、エチルジグリコール、ブチルジグリコール、プロピレングリコールモノメチルエーテル等のグリコールエーテル系溶剤、酢酸エチル、酢酸ブチル、プロピレングリコールモノメチルエーテルアセテート等のエステル系溶剤、水等が挙げられる。また、芳香族炭化水素系溶剤として使用できる市販品としては、ソルベッソ100、ソルベッソ150、ソルベッソ200等が挙げられる。これらは単独で用いても良いし、2種以上を併用しても良い。
レベリング剤としては、特に限定されないが、例えば、ポリオキシエチレンアルキルエーテル類、ポリオキシエチレンアリールエーテル類、シリコン系界面活性剤、ノニオン系界面活性剤、フッ素系界面活性剤、アクリル系界面活性剤等が挙げられる。これらは単独で用いても良いし、2種以上を併用しても良い。
本発明の親水処理部材は、基材上に、本発明の親水性コーティング用樹脂組成物から形成される親水性塗膜を有することを特徴とする。
下記の実施例及び比較例においては、以下の材料を使用した。
<ポリウレタン樹脂>
(A−1)エーテル系ポリウレタン :スーパーフレックス130、第一工業製薬株式会社製
(A−2)エーテル系ポリウレタン :スーパーフレックス170、第一工業製薬株式会社製
(A−3)エーテル系ポリウレタン :X−7096、日華化学株式会社製
(A−4)ポリカーボネート系ポリウレタン:HA−170日華化学株式会社製
<単官能エポキシ化合物>
(B−1)ラウリルアルコール(EO)15グリシジルエーテル:EX−171、ナガセケムテックス株式会社製
(B−2)ポリオキシエチレン(23)ラウリルエーテル :エマルゲン123P、花王株式会社製
表1に示す固形分重量比で各成分を混合し、親水性コーティング用樹脂組成物を得た。なお、固形分濃度は20%であって、残部は水である。得られた親水性コーティング用樹脂組成物を、バーコーター(No.6)を用いて基材としてのアルミニウム板上に塗布した。塗布した基材を240℃の熱風乾燥機に入れ、30秒間加熱処理を行い、親水性塗膜を形成した。塗膜の厚みは、1.5μmであった。乾燥後、基材を室温まで冷却したものを試験片とした。得られた試験片を用いて、後述する方法により物性の評価を行った。結果を表1に示す。
試験片上に純水を約20μL滴下し、接触角測定器(協和界面化学株式会社製、CA−D型接触角計)を用いて接触角を測定した。
作製直後の試験片を3L/分の流水中に浸し、24時間後、前述の方法により接触角を測定した。なお、比較例3〜5の試験片では膜荒れが生じ、接触角を測定できなかった。
JIS K5600に準拠して、試験片作製直後のアルミニウム基材に対する親水性塗膜の密着性を確認し、下記の基準により2段階で評価した。
○:剥離無し
×:剥離有り
作製したコーティング液を、室温で一週間放置した後の外観を確認し、下記の基準により2段階で評価した。
○:変化無
×:沈降有
親水性塗膜の表面状態を観察するため、AFM(SIIナノテクノロジー社製、SPI3800Ne)測定したところ、図2に示すポリウレタン樹脂のみから成る組成(比較例1)と比較して、図1に示す実施例2では塗膜が基材表面に微細な凹凸構造を形成しており、表面ラフネスが増加していることが確認出来た。表面ラフネスは、実施例2の塗膜では0.90nm、比較例1の塗膜では0.53nmであった。微細な凹凸構造の影響によって表面のぬれ性が変化することが知られているが(Wenzelの法則)、本発明の親水性塗膜もこの法則に基づきぬれ性(親水性)が大幅に向上しているものと推察される。
Claims (6)
- (A)エーテル基を有するポリウレタン樹脂90〜70重量%、及び、(B)ポリオキシアルキレン基及び炭素数1〜30の炭化水素基を有する単官能エポキシ化合物10〜30重量%を含有する親水性コーティング用樹脂組成物。
- 単官能エポキシ化合物(B)のポリオキシアルキレン基が、ポリオキシエチレン基である請求項1の親水性コーティング用樹脂組成物。
- 単官能エポキシ化合物(B)の炭化水素基が、鎖状炭化水素基である請求項1又は2のいずれかに記載の親水性コーティング用樹脂組成物。
- 単官能エポキシ化合物(B)が下記一般式(1)
を表す。)
で表される単官能エポキシ化合物である請求項1〜3のいずれか1項に記載の親水性コーティング用樹脂組成物。 - 基材上に、請求項1〜4のいずれか1項に記載の親水性コーティング用樹脂組成物から形成される親水性塗膜を有することを特徴とする親水処理部材。
- 基材がアルミニウム又はアルミニウム合金からなる請求項5に記載の親水処理部材。
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DE112020001208T5 (de) | 2019-03-11 | 2021-11-25 | Livedo Corporation | Gefalteter absorbierender Artikel und Einzelverpackung für absorbierenden Artikel |
US11970118B2 (en) | 2019-07-02 | 2024-04-30 | Murata Manufacturing Co., Ltd. | Optical unit and vehicle including optical unit |
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