JP2019007007A5 - - Google Patents
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- Publication number
- JP2019007007A5 JP2019007007A5 JP2018123348A JP2018123348A JP2019007007A5 JP 2019007007 A5 JP2019007007 A5 JP 2019007007A5 JP 2018123348 A JP2018123348 A JP 2018123348A JP 2018123348 A JP2018123348 A JP 2018123348A JP 2019007007 A5 JP2019007007 A5 JP 2019007007A5
- Authority
- JP
- Japan
- Prior art keywords
- isobutene
- lewis acid
- lewis base
- feed
- lewis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 108
- 238000000034 method Methods 0.000 claims description 70
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 48
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 40
- 239000002879 Lewis base Substances 0.000 claims description 32
- 150000007527 lewis bases Chemical class 0.000 claims description 30
- 239000002841 Lewis acid Substances 0.000 claims description 23
- 150000007517 lewis acids Chemical class 0.000 claims description 23
- 238000006116 polymerization reaction Methods 0.000 claims description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 229920001083 polybutene Polymers 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 11
- 239000003999 initiator Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000011968 lewis acid catalyst Substances 0.000 claims description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 239000003849 aromatic solvent Substances 0.000 claims description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 239000001282 iso-butane Substances 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 4
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- -1 saturated C 4 hydrocarbons Chemical class 0.000 claims 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 125000006575 electron-withdrawing group Chemical group 0.000 claims 2
- 230000000977 initiatory effect Effects 0.000 claims 2
- GFJUOMJGSXRJJY-UHFFFAOYSA-N 2-methylprop-1-ene Chemical compound CC(C)=C.CC(C)=C GFJUOMJGSXRJJY-UHFFFAOYSA-N 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 230000000536 complexating effect Effects 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/635,278 | 2017-06-28 | ||
| US15/635,278 US10047174B1 (en) | 2017-06-28 | 2017-06-28 | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019007007A JP2019007007A (ja) | 2019-01-17 |
| JP2019007007A5 true JP2019007007A5 (enExample) | 2020-03-26 |
| JP6955474B2 JP6955474B2 (ja) | 2021-10-27 |
Family
ID=62530079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018123348A Active JP6955474B2 (ja) | 2017-06-28 | 2018-06-28 | 重合開始系および極めて反応性の高いオレフィン官能性ポリマーの製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10047174B1 (enExample) |
| EP (1) | EP3421508B1 (enExample) |
| JP (1) | JP6955474B2 (enExample) |
| KR (1) | KR102291980B1 (enExample) |
| CN (1) | CN109134718B (enExample) |
| CA (1) | CA3009864C (enExample) |
| SG (1) | SG10201805529TA (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10829573B1 (en) * | 2019-05-21 | 2020-11-10 | Infineum International Limited | Method for forming highly reactive olefin functional polymers |
| CN114051765B (zh) * | 2019-12-04 | 2024-05-28 | 日本碍子株式会社 | 陶瓷加热器 |
| EP3943516B1 (en) * | 2019-12-06 | 2023-11-01 | Lg Chem, Ltd. | Catalyst composition and method for preparing polyisobutene by using same |
| CN115725010A (zh) * | 2023-01-05 | 2023-03-03 | 浙江信汇新材料股份有限公司 | 一种中、高分子量聚异丁烯制备方法及其引发体系、应用 |
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| DE69513810T2 (de) | 1994-03-31 | 2000-05-25 | Infineum Usa Lp | Polymerisationsreaktionen von kohlenwasserstoffen mit lewissäure enthaltende trägerkatalysatoren |
| US5710225A (en) | 1996-08-23 | 1998-01-20 | The Lubrizol Corporation | Heteropolyacid catalyzed polymerization of olefins |
| DE19704482A1 (de) | 1997-02-06 | 1998-08-13 | Basf Ag | Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten |
| DE19734176A1 (de) | 1997-08-07 | 1999-02-11 | Basf Ag | Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten |
| US6407186B1 (en) | 1997-12-12 | 2002-06-18 | Basf Aktiengesellschaft | Method for producing low-molecular, highly reactive polyisobutylene |
| CA2330529A1 (en) | 1998-06-12 | 1999-12-16 | Univation Technologies Llc | Olefin polymerization process using activated lewis acid-base complexes |
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| WO2002040553A1 (de) | 2000-11-17 | 2002-05-23 | Basf Aktiengesellschaft | Verfahren zur desaktivierung und rückgewinnung von bortrifluorid bei der herstellung von polyisobutenen |
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| CN101955558B (zh) | 2009-07-15 | 2013-03-13 | 北京化工大学 | 制备高反应活性聚异丁烯及其共聚物的引发体系 |
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| BR112012020302B1 (pt) * | 2010-02-17 | 2021-08-17 | Basf Se | Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade |
| US8349977B2 (en) | 2010-02-17 | 2013-01-08 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
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| US8697820B2 (en) | 2011-08-11 | 2014-04-15 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
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| US9034998B2 (en) | 2011-12-16 | 2015-05-19 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9156924B2 (en) * | 2013-03-12 | 2015-10-13 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9631038B2 (en) * | 2013-10-11 | 2017-04-25 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9771442B2 (en) | 2015-05-13 | 2017-09-26 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
-
2017
- 2017-06-28 US US15/635,278 patent/US10047174B1/en active Active
-
2018
- 2018-05-18 EP EP18173300.7A patent/EP3421508B1/en active Active
- 2018-06-27 CN CN201810674938.XA patent/CN109134718B/zh active Active
- 2018-06-27 KR KR1020180073729A patent/KR102291980B1/ko active Active
- 2018-06-27 SG SG10201805529TA patent/SG10201805529TA/en unknown
- 2018-06-28 JP JP2018123348A patent/JP6955474B2/ja active Active
- 2018-06-28 CA CA3009864A patent/CA3009864C/en active Active
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