KR102291980B1 - 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 중합체의 제조 방법 - Google Patents
중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 중합체의 제조 방법 Download PDFInfo
- Publication number
- KR102291980B1 KR102291980B1 KR1020180073729A KR20180073729A KR102291980B1 KR 102291980 B1 KR102291980 B1 KR 102291980B1 KR 1020180073729 A KR1020180073729 A KR 1020180073729A KR 20180073729 A KR20180073729 A KR 20180073729A KR 102291980 B1 KR102291980 B1 KR 102291980B1
- Authority
- KR
- South Korea
- Prior art keywords
- isobutene
- feedstock
- lewis acid
- mass
- lewis base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C08F10/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
- C08F110/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/635,278 | 2017-06-28 | ||
| US15/635,278 US10047174B1 (en) | 2017-06-28 | 2017-06-28 | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20190001936A KR20190001936A (ko) | 2019-01-07 |
| KR102291980B1 true KR102291980B1 (ko) | 2021-08-23 |
Family
ID=62530079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020180073729A Active KR102291980B1 (ko) | 2017-06-28 | 2018-06-27 | 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 중합체의 제조 방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10047174B1 (enExample) |
| EP (1) | EP3421508B1 (enExample) |
| JP (1) | JP6955474B2 (enExample) |
| KR (1) | KR102291980B1 (enExample) |
| CN (1) | CN109134718B (enExample) |
| CA (1) | CA3009864C (enExample) |
| SG (1) | SG10201805529TA (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10829573B1 (en) * | 2019-05-21 | 2020-11-10 | Infineum International Limited | Method for forming highly reactive olefin functional polymers |
| CN114051765B (zh) * | 2019-12-04 | 2024-05-28 | 日本碍子株式会社 | 陶瓷加热器 |
| EP3943516B1 (en) * | 2019-12-06 | 2023-11-01 | Lg Chem, Ltd. | Catalyst composition and method for preparing polyisobutene by using same |
| CN115725010A (zh) * | 2023-01-05 | 2023-03-03 | 浙江信汇新材料股份有限公司 | 一种中、高分子量聚异丁烯制备方法及其引发体系、应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130158217A1 (en) | 2011-12-16 | 2013-06-20 | Infineum International Limited | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| KR102004502B1 (ko) | 2013-03-12 | 2019-07-26 | 유니버시티 오브 매사추세츠 | 고도로 반응성인 올레핀 작용성 폴리머를 생성하기 위한 중합화 개시 시스템 및 방법 |
| KR102065510B1 (ko) | 2013-10-11 | 2020-01-13 | 유니버시티 오브 매사추세츠 | 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법 |
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| US2682531A (en) | 1951-03-31 | 1954-06-29 | Standard Oil Dev Co | Zirconium tetrachloride-ether complexes as low temperature polymerization catalyst |
| JPS4839599A (enExample) | 1971-09-20 | 1973-06-11 | ||
| US3850897A (en) | 1971-11-26 | 1974-11-26 | Snam Progetti | Procedure for the production of polymers and copolymers of isobutylene |
| CA2019908A1 (en) | 1989-12-28 | 1991-06-28 | Rudolf Lukas | Graft copolymers and the method and initiation system for preparation thereof |
| GB9025839D0 (en) | 1990-11-28 | 1991-01-09 | Bp Chem Int Ltd | Cationic polymerisation of 1-olefins |
| US5286823A (en) | 1991-06-22 | 1994-02-15 | Basf Aktiengesellschaft | Preparation of highly reactive polyisobutenes |
| WO1994018389A1 (en) | 1993-02-15 | 1994-08-18 | Eka Nobel Ab | A method for reducing the content of organic solvent in cellulose-reactive hydrophobing agents |
| WO1994028036A1 (en) | 1993-05-20 | 1994-12-08 | Exxon Chemical Patents Inc. | Heterogeneous lewis acid-type catalysts |
| JP3203917B2 (ja) | 1993-11-30 | 2001-09-04 | ソニー株式会社 | プロジェクタ用アクティブマトリクス液晶表示パネル |
| DE69513810T2 (de) | 1994-03-31 | 2000-05-25 | Infineum Usa Lp | Polymerisationsreaktionen von kohlenwasserstoffen mit lewissäure enthaltende trägerkatalysatoren |
| US5710225A (en) | 1996-08-23 | 1998-01-20 | The Lubrizol Corporation | Heteropolyacid catalyzed polymerization of olefins |
| DE19704482A1 (de) | 1997-02-06 | 1998-08-13 | Basf Ag | Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten |
| DE19734176A1 (de) | 1997-08-07 | 1999-02-11 | Basf Ag | Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten |
| US6407186B1 (en) | 1997-12-12 | 2002-06-18 | Basf Aktiengesellschaft | Method for producing low-molecular, highly reactive polyisobutylene |
| CA2330529A1 (en) | 1998-06-12 | 1999-12-16 | Univation Technologies Llc | Olefin polymerization process using activated lewis acid-base complexes |
| US6346585B1 (en) | 1999-06-24 | 2002-02-12 | The Lubrizol Corporation | Ammonium heteropolyacid catalized polymerization of olefins |
| US6407170B1 (en) | 1999-06-24 | 2002-06-18 | The Lubrizol Corporation | Dispersants prepared from high polydispersity olefin polymers |
| US6562913B1 (en) | 1999-09-16 | 2003-05-13 | Texas Petrochemicals Lp | Process for producing high vinylidene polyisobutylene |
| DE19952030A1 (de) | 1999-10-28 | 2001-05-03 | Basf Ag | Verfahren zur Herstellung von hochreaktiven Polyisobutenen |
| US6858690B2 (en) | 1999-11-15 | 2005-02-22 | Exxonmobil Chemical Patents Inc. | Process for polymerizing cationically polymerizable monomers |
| DE10035298A1 (de) | 2000-07-18 | 2002-01-31 | Basf Ag | Verfahren zur Herstellung von Polysiobutenen |
| KR100486044B1 (ko) | 2000-11-13 | 2005-04-29 | 대림산업 주식회사 | 폴리부텐의 제조방법 |
| WO2002040553A1 (de) | 2000-11-17 | 2002-05-23 | Basf Aktiengesellschaft | Verfahren zur desaktivierung und rückgewinnung von bortrifluorid bei der herstellung von polyisobutenen |
| DE10061715A1 (de) | 2000-12-12 | 2002-06-13 | Basf Ag | Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens |
| DE10118182A1 (de) | 2001-04-11 | 2002-10-17 | Basf Ag | Verfahren zur Aufarbeitung eines flüssigen Reaktionsaustrages der kationischen Polymerisation von Isobuten |
| DE10211418A1 (de) | 2002-03-15 | 2003-09-25 | Bayer Ag | Verfahren zur Herstellung hochreaktiver Polyisobutene |
| AU2003254173A1 (en) | 2002-08-13 | 2004-02-25 | Exxonmobil Chemical Patents Inc. | Process for polymerizing cationically polymerizable monomers |
| AU2003297458A1 (en) | 2002-12-20 | 2004-07-22 | Exxonmobil Chemical Patents Inc. | Polymerization processes |
| CN100402558C (zh) | 2002-12-20 | 2008-07-16 | 埃克森美孚化学专利公司 | 聚合方法 |
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| DE10303212A1 (de) | 2003-01-24 | 2004-08-05 | Basf Ag | Verfahren zur Herstellung von Polyisobuten |
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| US20080269440A1 (en) | 2005-01-05 | 2008-10-30 | Rudolf Faust | Polymerization of Olefins |
| DE102005055818A1 (de) | 2005-11-21 | 2007-05-24 | Basf Ag | Verfahren zur Herstellung von hochreaktiven Isobutenhomo- oder -copolymeren mittels metallhaltiger Katalysatorkomplexe |
| WO2008095933A1 (de) | 2007-02-09 | 2008-08-14 | Basf Se | Verfahren zur polymerisation von ethylenisch ungesättigten monomeren |
| US8394897B2 (en) | 2008-03-25 | 2013-03-12 | Chevron Oronite Company Llc | Production of vinylidene-terminated polyolefins via quenching with monosulfides |
| US20090258803A1 (en) | 2008-04-14 | 2009-10-15 | Harrison James J | Copolymers made with quasi-living polyolefins and unsaturated acidic reagents, dispersants using same, and methods of making same |
| US8063154B2 (en) | 2008-06-24 | 2011-11-22 | The University Of Southern Mississippi | Preparation of exo-olefin terminated polyolefins via quenching with alkoxysilanes or ethers |
| CN101613423B (zh) | 2008-06-27 | 2011-05-18 | 北京化工大学 | 一种用于合成高反应活性聚异丁烯的引发体系 |
| WO2010139684A1 (de) | 2009-06-05 | 2010-12-09 | Basf Se | Verbindung aus einem protonierten aromaten und einem schwach koordinierenden anion als polymerisationskatalysator für isobuten oder ein isobuten-haltiges monomerengemisch |
| CN101955558B (zh) | 2009-07-15 | 2013-03-13 | 北京化工大学 | 制备高反应活性聚异丁烯及其共聚物的引发体系 |
| EP2496613B1 (de) | 2009-11-04 | 2015-07-01 | Basf Se | Verfahren zur herstellung von homo- oder copolymeren |
| WO2011087057A1 (ja) | 2010-01-13 | 2011-07-21 | 新日本製鐵株式会社 | 成形性に優れた高強度鋼板及びその製造方法 |
| BR112012020302B1 (pt) * | 2010-02-17 | 2021-08-17 | Basf Se | Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade |
| US8349977B2 (en) | 2010-02-17 | 2013-01-08 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
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| US8697820B2 (en) | 2011-08-11 | 2014-04-15 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
| ITBO20110731A1 (it) | 2011-12-16 | 2013-06-17 | Sorma S P A | Macchina per il confezionamento di prodotti in involucri a rete |
| US9771442B2 (en) | 2015-05-13 | 2017-09-26 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
-
2017
- 2017-06-28 US US15/635,278 patent/US10047174B1/en active Active
-
2018
- 2018-05-18 EP EP18173300.7A patent/EP3421508B1/en active Active
- 2018-06-27 CN CN201810674938.XA patent/CN109134718B/zh active Active
- 2018-06-27 KR KR1020180073729A patent/KR102291980B1/ko active Active
- 2018-06-27 SG SG10201805529TA patent/SG10201805529TA/en unknown
- 2018-06-28 JP JP2018123348A patent/JP6955474B2/ja active Active
- 2018-06-28 CA CA3009864A patent/CA3009864C/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130158217A1 (en) | 2011-12-16 | 2013-06-20 | Infineum International Limited | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| KR102004502B1 (ko) | 2013-03-12 | 2019-07-26 | 유니버시티 오브 매사추세츠 | 고도로 반응성인 올레핀 작용성 폴리머를 생성하기 위한 중합화 개시 시스템 및 방법 |
| KR102065510B1 (ko) | 2013-10-11 | 2020-01-13 | 유니버시티 오브 매사추세츠 | 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3421508A1 (en) | 2019-01-02 |
| CA3009864A1 (en) | 2018-12-28 |
| SG10201805529TA (en) | 2019-01-30 |
| CA3009864C (en) | 2020-08-11 |
| CN109134718B (zh) | 2021-03-23 |
| JP6955474B2 (ja) | 2021-10-27 |
| US10047174B1 (en) | 2018-08-14 |
| JP2019007007A (ja) | 2019-01-17 |
| KR20190001936A (ko) | 2019-01-07 |
| EP3421508B1 (en) | 2020-12-30 |
| CN109134718A (zh) | 2019-01-04 |
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