JP2018521192A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2018521192A5 JP2018521192A5 JP2018503233A JP2018503233A JP2018521192A5 JP 2018521192 A5 JP2018521192 A5 JP 2018521192A5 JP 2018503233 A JP2018503233 A JP 2018503233A JP 2018503233 A JP2018503233 A JP 2018503233A JP 2018521192 A5 JP2018521192 A5 JP 2018521192A5
- Authority
- JP
- Japan
- Prior art keywords
- hydrocarbyl
- group
- polyolefin
- metal
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 31
- -1 cyclic anhydride Chemical class 0.000 claims description 29
- 229910052751 metal Inorganic materials 0.000 claims description 29
- 239000002184 metal Substances 0.000 claims description 29
- 229920000098 polyolefin Polymers 0.000 claims description 25
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- 239000003054 catalyst Substances 0.000 claims description 15
- 125000000524 functional group Chemical group 0.000 claims description 15
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 14
- 150000001336 alkenes Chemical class 0.000 claims description 10
- 239000012685 metal catalyst precursor Substances 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 10
- 239000003426 co-catalyst Substances 0.000 claims description 8
- 239000007800 oxidant agent Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 6
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 claims description 6
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910000085 borane Inorganic materials 0.000 claims description 5
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims description 4
- VQOXUMQBYILCKR-UHFFFAOYSA-N 1-Tridecene Chemical compound CCCCCCCCCCCC=C VQOXUMQBYILCKR-UHFFFAOYSA-N 0.000 claims description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 4
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 4
- ADOBXTDBFNCOBN-UHFFFAOYSA-N 1-heptadecene Chemical compound CCCCCCCCCCCCCCCC=C ADOBXTDBFNCOBN-UHFFFAOYSA-N 0.000 claims description 4
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 claims description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- PJLHTVIBELQURV-UHFFFAOYSA-N 1-pentadecene Chemical compound CCCCCCCCCCCCCC=C PJLHTVIBELQURV-UHFFFAOYSA-N 0.000 claims description 4
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 claims description 4
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 4
- 238000007306 functionalization reaction Methods 0.000 claims description 4
- 229910052735 hafnium Inorganic materials 0.000 claims description 4
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000007983 Tris buffer Substances 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 239000012018 catalyst precursor Substances 0.000 claims description 3
- 239000012986 chain transfer agent Substances 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 150000004678 hydrides Chemical class 0.000 claims description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 3
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- KLAWFKRMCIXRFS-UHFFFAOYSA-N 5-ethenylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C=C)CC1C=C2 KLAWFKRMCIXRFS-UHFFFAOYSA-N 0.000 claims description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 2
- IQEPEDROVHGOAR-UHFFFAOYSA-N C(C(C)C)[Al](CCC=C)CC(C)C Chemical compound C(C(C)C)[Al](CCC=C)CC(C)C IQEPEDROVHGOAR-UHFFFAOYSA-N 0.000 claims description 2
- HEMYFEFGZYYQSU-UHFFFAOYSA-N C=CCCCCCC[Zn]CCCCCCC=C Chemical compound C=CCCCCCC[Zn]CCCCCCC=C HEMYFEFGZYYQSU-UHFFFAOYSA-N 0.000 claims description 2
- ZXDAZVCFYFCCLZ-UHFFFAOYSA-N C=CCCCC[Zn]CCCCC=C Chemical compound C=CCCCC[Zn]CCCCC=C ZXDAZVCFYFCCLZ-UHFFFAOYSA-N 0.000 claims description 2
- VBJJUQSFOHZDHV-UHFFFAOYSA-N C=CCC[Zn]CCC=C Chemical compound C=CCC[Zn]CCC=C VBJJUQSFOHZDHV-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- GMDSGSPTIDDIAZ-UHFFFAOYSA-N bis(2-methylpropyl)-oct-7-enylalumane Chemical compound CC(C)C[Al](CC(C)C)CCCCCCC=C GMDSGSPTIDDIAZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000012711 chain transfer polymerization Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 229940069096 dodecene Drugs 0.000 claims description 2
- 150000002118 epoxides Chemical class 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 230000000171 quenching effect Effects 0.000 claims description 2
- KYOZLPKCURERER-UHFFFAOYSA-N tris(but-3-enyl)alumane Chemical compound C=CCC[Al](CCC=C)CCC=C KYOZLPKCURERER-UHFFFAOYSA-N 0.000 claims description 2
- RRWJQXJVEHEZJR-UHFFFAOYSA-N tris(oct-7-enyl)alumane Chemical compound C=CCCCCCC[Al](CCCCCCC=C)CCCCCCC=C RRWJQXJVEHEZJR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims 1
- QBLGPUPHRFDAMT-UHFFFAOYSA-N C(C)[Zn]CCC=C Chemical compound C(C)[Zn]CCC=C QBLGPUPHRFDAMT-UHFFFAOYSA-N 0.000 claims 1
- ZMVFRPYKRCLPGS-UHFFFAOYSA-N C(C)[Zn]CCCCCCC=C Chemical compound C(C)[Zn]CCCCCCC=C ZMVFRPYKRCLPGS-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- DYSCYJQZDQCNEG-UHFFFAOYSA-N hex-5-enyl-bis(2-methylpropyl)alumane Chemical compound C(C(C)C)[Al](CCCCC=C)CC(C)C DYSCYJQZDQCNEG-UHFFFAOYSA-N 0.000 claims 1
- 125000001145 hydrido group Chemical group *[H] 0.000 claims 1
- 230000002441 reversible effect Effects 0.000 claims 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 6
- OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 4
- 229910007926 ZrCl Inorganic materials 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
- HXHXUOYNZWHFLT-UHFFFAOYSA-N C(CCCC=C)[Al](CCCCC=C)CCCCC=C Chemical compound C(CCCC=C)[Al](CCCCC=C)CCCCC=C HXHXUOYNZWHFLT-UHFFFAOYSA-N 0.000 description 1
- VHNNPTGLWYHNHE-UHFFFAOYSA-N C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 VHNNPTGLWYHNHE-UHFFFAOYSA-N 0.000 description 1
- QSBPXEDWBXHWKP-UHFFFAOYSA-N CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 QSBPXEDWBXHWKP-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- FJMJPZLXUXRLLD-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 FJMJPZLXUXRLLD-UHFFFAOYSA-L 0.000 description 1
- 150000001501 aryl fluorides Chemical class 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15177975 | 2015-07-23 | ||
| EP15177975.8 | 2015-07-23 | ||
| PCT/EP2016/067527 WO2017013246A1 (en) | 2015-07-23 | 2016-07-22 | Process for the preparation of a polyolefin having one or multiple pending functionalities |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018521192A JP2018521192A (ja) | 2018-08-02 |
| JP2018521192A5 true JP2018521192A5 (enExample) | 2019-06-20 |
| JP6866346B2 JP6866346B2 (ja) | 2021-04-28 |
Family
ID=53758058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018503233A Active JP6866346B2 (ja) | 2015-07-23 | 2016-07-22 | 一又は複数の懸垂官能基を有するポリオレフィンの調製方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20180251585A1 (enExample) |
| EP (1) | EP3325523A1 (enExample) |
| JP (1) | JP6866346B2 (enExample) |
| CN (1) | CN108137748B (enExample) |
| WO (1) | WO2017013246A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3387047B1 (en) * | 2015-12-09 | 2020-01-01 | SABIC Global Technologies B.V. | Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains |
| KR20220005012A (ko) * | 2019-04-16 | 2022-01-12 | 사빅 글로벌 테크놀러지스 비.브이. | 폴리올레핀 매트릭스 및 감지 화합물을 기반으로 한 센서 |
| WO2021121795A1 (en) | 2019-12-19 | 2021-06-24 | Sabic Global Technologies B.V. | Polyacrylate-based graft copolymer |
| CN111116811B (zh) * | 2020-01-03 | 2022-07-05 | 天津大学 | 一种1-丁烯/降冰片烯共聚物及其制备方法 |
| EP4271718A1 (en) | 2020-12-29 | 2023-11-08 | ExxonMobil Chemical Patents Inc. | Polyolefin-based ionomers and production thereof |
| US12195563B2 (en) * | 2020-12-29 | 2025-01-14 | Exxonmobil Chemical Patents Inc. | Polyolefin-based ionomers and production thereof |
| KR20240108522A (ko) * | 2021-11-22 | 2024-07-09 | 사빅 글로벌 테크놀러지스 비.브이. | 관능화 폴리올레핀의 제조를 위한 용액 공정 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002503732A (ja) * | 1998-02-11 | 2002-02-05 | ザ ダウ ケミカル カンパニー | 改良されたオレフィン重合方法 |
| KR100280373B1 (ko) * | 1998-09-18 | 2001-02-01 | 김충섭 | 메탈로센 촉매에 의한 관능성 말단기를 갖는 폴리에틸렌의 제조방법 |
| BR0013051A (pt) * | 1999-07-29 | 2002-04-02 | Dow Chemical Co | Processo para preparar interpolìmeros de olefinas funcionalizados com silano melhorados, produtos obtidos, derivados destes e seu uso |
| US20080281063A9 (en) * | 1999-12-30 | 2008-11-13 | Sukhadia Ashish M | Ethylene polymers and copolymers with high optical opacity and methods of making the same |
| DE60139117D1 (de) * | 2000-09-12 | 2009-08-13 | Mitsui Chemicals Inc | Verzweigtes polyolefin, verfahren zur herstellung desselben sowie das verzweigte polyolefin enthaltende thermoplastische harzzusammensetzung |
| JP3943959B2 (ja) * | 2002-02-26 | 2007-07-11 | 日本ポリプロ株式会社 | プロピレン−アルケニルジアルキルアルミニウム共重合体 |
| JP3891905B2 (ja) * | 2002-08-28 | 2007-03-14 | 日本ポリプロ株式会社 | 末端ビニル基含有プロピレン−アルケニルアルミニウム共重合体の製造方法および共重合体 |
| JP4439323B2 (ja) * | 2004-04-26 | 2010-03-24 | 独立行政法人産業技術総合研究所 | 極性基含有共重合体及びその製造方法 |
| JP4615248B2 (ja) * | 2004-05-07 | 2011-01-19 | 毅 塩野 | 極性基含有環状オレフィン系共重合体の製造方法 |
| JP2007262338A (ja) * | 2006-03-29 | 2007-10-11 | Japan Polypropylene Corp | 極性基を有すプロピレン系共重合体又はその組成物を用いた塗装用成形品 |
| JP2007261211A (ja) * | 2006-03-29 | 2007-10-11 | Japan Polypropylene Corp | プロピレン系共重合体又はその組成物を用いた接着性樹脂積層体 |
| KR101115671B1 (ko) * | 2007-03-28 | 2012-02-15 | 주식회사 엘지화학 | 고밀도 폴리올레핀 제조용 전중합체 촉매, 그 제조방법 및 그 전중합체 촉매를 사용하는 고강도 폴리올레핀의 제조방법 |
| KR101226427B1 (ko) * | 2007-08-16 | 2013-01-24 | 주식회사 엘지화학 | 폴리올레핀 제조용 촉매 조성물 및 이를 이용하여 내환경응력균열성이 개선된 폴리올레핀의 제조방법 |
| US8580902B2 (en) * | 2008-08-01 | 2013-11-12 | Exxonmobil Chemical Patents Inc. | Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom |
| KR101381879B1 (ko) * | 2011-04-25 | 2014-04-10 | 한국생산기술연구원 | 극성기를 함유한 올레핀-방향족 비닐계 공중합체 또는 삼원공중합체의 제조방법 |
| EP3034544B1 (en) * | 2014-12-17 | 2019-10-16 | SABIC Global Technologies B.V. | A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains |
| EP3037437A1 (en) * | 2014-12-23 | 2016-06-29 | SABIC Global Technologies B.V. | Process for the preparation of a polyolefin having one or multiple end-functionalized branches. |
| EP3037438A1 (en) * | 2014-12-23 | 2016-06-29 | SABIC Global Technologies B.V. | Process for the preparation of a branched polyolefin |
-
2016
- 2016-07-22 JP JP2018503233A patent/JP6866346B2/ja active Active
- 2016-07-22 EP EP16750406.7A patent/EP3325523A1/en not_active Withdrawn
- 2016-07-22 WO PCT/EP2016/067527 patent/WO2017013246A1/en not_active Ceased
- 2016-07-22 US US15/746,955 patent/US20180251585A1/en not_active Abandoned
- 2016-07-22 CN CN201680052874.9A patent/CN108137748B/zh active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2018521192A5 (enExample) | ||
| JP2018500430A5 (enExample) | ||
| JP2018500431A5 (enExample) | ||
| CN1279070C (zh) | 聚丙烯的生产 | |
| CN103339162A (zh) | 烯烃嵌段共聚物 | |
| CN111491957A (zh) | 制备半结晶聚烯烃离聚物的方法 | |
| JP2018505946A5 (enExample) | ||
| US10934370B2 (en) | Hybrid supported metallogen catalyst, method for preparing olefin polymer by using same, and olefin polymer having improved melt strength | |
| US6316561B1 (en) | Process for producing olefin polymers | |
| JP2006502260A5 (enExample) | ||
| JP2017160196A5 (enExample) | ||
| CN108350114B (zh) | 聚丙烯 | |
| CN110914316B (zh) | 聚丙烯及其制备方法 | |
| CN115956093B (zh) | 包含杂化过渡金属化合物的催化剂、使用其制备的烯烃聚合物及它们的制备方法 | |
| KR20200077331A (ko) | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리올레핀의 제조 방법 | |
| WO2017063116A1 (zh) | 一种有机硅烷的应用以及聚烯烃树脂及其制备方法 | |
| JP4813811B2 (ja) | オレフィン重合のための触媒組成物およびそれを用いた重合プロセス | |
| CN113795525A (zh) | 烯烃基聚合物 | |
| US20130267407A1 (en) | Method of preparing metallocene catalysts | |
| JP2005105147A (ja) | ランダム共重合体及びその製造方法 | |
| KR101561381B1 (ko) | 폴리부텐-1 단독 중합체 또는 공중합체의 제조방법 | |
| KR102034914B1 (ko) | 폴리올레핀 중합 방법, 그로부터 제조된 반-결정성 에틸렌계 중합체, 및 그러한 중합체로부터 제조된 물품 | |
| JP2018532026A (ja) | 有機シランの使用、並びにポリオレフィン釜内アロイ及びその製造方法 | |
| CN113795524A (zh) | 聚丙烯基复合材料 | |
| WO2017123469A1 (en) | High melt flow polypropylene homopolymers for fiber applications |