CN108137748B - 用于制备具有一个或多个侧官能团的聚烯烃的方法 - Google Patents

用于制备具有一个或多个侧官能团的聚烯烃的方法 Download PDF

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Publication number
CN108137748B
CN108137748B CN201680052874.9A CN201680052874A CN108137748B CN 108137748 B CN108137748 B CN 108137748B CN 201680052874 A CN201680052874 A CN 201680052874A CN 108137748 B CN108137748 B CN 108137748B
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hydrocarbyl
metal
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catalyst
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CN108137748A (zh
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M·鲍雅伊
R·达查特奥
L·亚辛斯卡-沃尔克
M·A·祖德维尔德
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SABIC Global Technologies BV
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/06—Oxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09—Long chain branches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201680052874.9A 2015-07-23 2016-07-22 用于制备具有一个或多个侧官能团的聚烯烃的方法 Active CN108137748B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15177975 2015-07-23
EP15177975.8 2015-07-23
PCT/EP2016/067527 WO2017013246A1 (en) 2015-07-23 2016-07-22 Process for the preparation of a polyolefin having one or multiple pending functionalities

Publications (2)

Publication Number Publication Date
CN108137748A CN108137748A (zh) 2018-06-08
CN108137748B true CN108137748B (zh) 2021-05-04

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Country Link
US (1) US20180251585A1 (enExample)
EP (1) EP3325523A1 (enExample)
JP (1) JP6866346B2 (enExample)
CN (1) CN108137748B (enExample)
WO (1) WO2017013246A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3387047B1 (en) * 2015-12-09 2020-01-01 SABIC Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
KR20220005012A (ko) * 2019-04-16 2022-01-12 사빅 글로벌 테크놀러지스 비.브이. 폴리올레핀 매트릭스 및 감지 화합물을 기반으로 한 센서
WO2021121795A1 (en) 2019-12-19 2021-06-24 Sabic Global Technologies B.V. Polyacrylate-based graft copolymer
CN111116811B (zh) * 2020-01-03 2022-07-05 天津大学 一种1-丁烯/降冰片烯共聚物及其制备方法
EP4271718A1 (en) 2020-12-29 2023-11-08 ExxonMobil Chemical Patents Inc. Polyolefin-based ionomers and production thereof
US12195563B2 (en) * 2020-12-29 2025-01-14 Exxonmobil Chemical Patents Inc. Polyolefin-based ionomers and production thereof
KR20240108522A (ko) * 2021-11-22 2024-07-09 사빅 글로벌 테크놀러지스 비.브이. 관능화 폴리올레핀의 제조를 위한 용액 공정

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002503732A (ja) * 1998-02-11 2002-02-05 ザ ダウ ケミカル カンパニー 改良されたオレフィン重合方法
KR100280373B1 (ko) * 1998-09-18 2001-02-01 김충섭 메탈로센 촉매에 의한 관능성 말단기를 갖는 폴리에틸렌의 제조방법
BR0013051A (pt) * 1999-07-29 2002-04-02 Dow Chemical Co Processo para preparar interpolìmeros de olefinas funcionalizados com silano melhorados, produtos obtidos, derivados destes e seu uso
US20080281063A9 (en) * 1999-12-30 2008-11-13 Sukhadia Ashish M Ethylene polymers and copolymers with high optical opacity and methods of making the same
DE60139117D1 (de) * 2000-09-12 2009-08-13 Mitsui Chemicals Inc Verzweigtes polyolefin, verfahren zur herstellung desselben sowie das verzweigte polyolefin enthaltende thermoplastische harzzusammensetzung
JP3943959B2 (ja) * 2002-02-26 2007-07-11 日本ポリプロ株式会社 プロピレン−アルケニルジアルキルアルミニウム共重合体
JP3891905B2 (ja) * 2002-08-28 2007-03-14 日本ポリプロ株式会社 末端ビニル基含有プロピレン−アルケニルアルミニウム共重合体の製造方法および共重合体
JP4439323B2 (ja) * 2004-04-26 2010-03-24 独立行政法人産業技術総合研究所 極性基含有共重合体及びその製造方法
JP4615248B2 (ja) * 2004-05-07 2011-01-19 毅 塩野 極性基含有環状オレフィン系共重合体の製造方法
JP2007262338A (ja) * 2006-03-29 2007-10-11 Japan Polypropylene Corp 極性基を有すプロピレン系共重合体又はその組成物を用いた塗装用成形品
JP2007261211A (ja) * 2006-03-29 2007-10-11 Japan Polypropylene Corp プロピレン系共重合体又はその組成物を用いた接着性樹脂積層体
KR101115671B1 (ko) * 2007-03-28 2012-02-15 주식회사 엘지화학 고밀도 폴리올레핀 제조용 전중합체 촉매, 그 제조방법 및 그 전중합체 촉매를 사용하는 고강도 폴리올레핀의 제조방법
KR101226427B1 (ko) * 2007-08-16 2013-01-24 주식회사 엘지화학 폴리올레핀 제조용 촉매 조성물 및 이를 이용하여 내환경응력균열성이 개선된 폴리올레핀의 제조방법
US8580902B2 (en) * 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
KR101381879B1 (ko) * 2011-04-25 2014-04-10 한국생산기술연구원 극성기를 함유한 올레핀-방향족 비닐계 공중합체 또는 삼원공중합체의 제조방법
EP3034544B1 (en) * 2014-12-17 2019-10-16 SABIC Global Technologies B.V. A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains
EP3037437A1 (en) * 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a polyolefin having one or multiple end-functionalized branches.
EP3037438A1 (en) * 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a branched polyolefin

Also Published As

Publication number Publication date
EP3325523A1 (en) 2018-05-30
JP6866346B2 (ja) 2021-04-28
US20180251585A1 (en) 2018-09-06
JP2018521192A (ja) 2018-08-02
WO2017013246A1 (en) 2017-01-26
CN108137748A (zh) 2018-06-08

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