JP2018502210A5 - - Google Patents
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- JP2018502210A5 JP2018502210A5 JP2017551361A JP2017551361A JP2018502210A5 JP 2018502210 A5 JP2018502210 A5 JP 2018502210A5 JP 2017551361 A JP2017551361 A JP 2017551361A JP 2017551361 A JP2017551361 A JP 2017551361A JP 2018502210 A5 JP2018502210 A5 JP 2018502210A5
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- reactor
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- compound
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003054 catalyst Substances 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 29
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 18
- 150000002430 hydrocarbons Chemical group 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 12
- -1 Aluminum compound Chemical class 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 239000012968 metallocene catalyst Substances 0.000 claims description 9
- 125000004122 cyclic group Chemical group 0.000 claims description 8
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000003607 modifier Substances 0.000 claims description 6
- 150000002902 organometallic compounds Chemical class 0.000 claims description 6
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 125000000524 functional group Chemical group 0.000 claims description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 230000002427 irreversible effect Effects 0.000 claims description 3
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 claims description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 2
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 claims description 2
- VFGRNTYELNYSKJ-UHFFFAOYSA-N 6-amino-1,3-dimethylpyrimidine-2,4-dione Chemical compound CN1C(N)=CC(=O)N(C)C1=O VFGRNTYELNYSKJ-UHFFFAOYSA-N 0.000 claims description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims description 2
- IJNJHTMAMLSRNR-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2].C1C(=CC2=CC=CC=C12)C1=C(C=CC=C1)C1=C(C=CC=C1)C=1CC2=CC=CC=C2C1 Chemical compound [Cl-].[Cl-].[Hf+2].C1C(=CC2=CC=CC=C12)C1=C(C=CC=C1)C1=C(C=CC=C1)C=1CC2=CC=CC=C2C1 IJNJHTMAMLSRNR-UHFFFAOYSA-L 0.000 claims description 2
- FITCHLIQALYVAP-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2].C1C(=CC2=CC=CC=C12)C1=C(C=CC=C1)C=1CC2=CC=CC=C2C1 Chemical compound [Cl-].[Cl-].[Hf+2].C1C(=CC2=CC=CC=C12)C1=C(C=CC=C1)C=1CC2=CC=CC=C2C1 FITCHLIQALYVAP-UHFFFAOYSA-L 0.000 claims description 2
- VPPWTYANHCUQIB-UHFFFAOYSA-L [Cl-].[Cl-].[Zr++].C1C(=Cc2c1cccc2-c1ccccc1)c1ccccc1C1=Cc2c(C1)cccc2-c1ccccc1 Chemical group [Cl-].[Cl-].[Zr++].C1C(=Cc2c1cccc2-c1ccccc1)c1ccccc1C1=Cc2c(C1)cccc2-c1ccccc1 VPPWTYANHCUQIB-UHFFFAOYSA-L 0.000 claims description 2
- BGSRVBPQJDDGKW-UHFFFAOYSA-L [Cl-].[Cl-].[Zr++].C1C(=Cc2cc(ccc12)-c1ccccc1)c1ccccc1C1=Cc2cc(ccc2C1)-c1ccccc1 Chemical compound [Cl-].[Cl-].[Zr++].C1C(=Cc2cc(ccc12)-c1ccccc1)c1ccccc1C1=Cc2cc(ccc2C1)-c1ccccc1 BGSRVBPQJDDGKW-UHFFFAOYSA-L 0.000 claims description 2
- BAZHQDBFTWDUEE-UHFFFAOYSA-L [Cl-].[Cl-].[Zr++].CC1C(=Cc2ccccc12)c1ccccc1C1=Cc2ccccc2C1C Chemical compound [Cl-].[Cl-].[Zr++].CC1C(=Cc2ccccc12)c1ccccc1C1=Cc2ccccc2C1C BAZHQDBFTWDUEE-UHFFFAOYSA-L 0.000 claims description 2
- VVNTYOZKYABLPP-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1=CC=C2CC(C3=CC=CC=C3C3=CC=CC=C3C=3CC4=CC=CC=C4C=3)=CC2=C1 Chemical compound [Cl-].[Cl-].[Zr+2].C1=CC=C2CC(C3=CC=CC=C3C3=CC=CC=C3C=3CC4=CC=CC=C4C=3)=CC2=C1 VVNTYOZKYABLPP-UHFFFAOYSA-L 0.000 claims description 2
- TZCWVBQRATXGSO-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1C(=CC2=CC=CC=C12)C1=C(C=CC=C1)C=1CC2=CC=CC=C2C1 Chemical compound [Cl-].[Cl-].[Zr+2].C1C(=CC2=CC=CC=C12)C1=C(C=CC=C1)C=1CC2=CC=CC=C2C1 TZCWVBQRATXGSO-UHFFFAOYSA-L 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- WSTNFGAKGUERTC-UHFFFAOYSA-N n-ethylhexan-1-amine Chemical compound CCCCCCNCC WSTNFGAKGUERTC-UHFFFAOYSA-N 0.000 claims description 2
- 230000002441 reversible effect Effects 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14199694 | 2014-12-22 | ||
| EP14199694.2 | 2014-12-22 | ||
| PCT/EP2015/080946 WO2016102548A1 (en) | 2014-12-22 | 2015-12-22 | Process for transitioning between incompatible catalysts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018502210A JP2018502210A (ja) | 2018-01-25 |
| JP2018502210A5 true JP2018502210A5 (OSRAM) | 2018-12-13 |
| JP6761810B2 JP6761810B2 (ja) | 2020-09-30 |
Family
ID=52349945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017551361A Active JP6761810B2 (ja) | 2014-12-22 | 2015-12-22 | 非相容性触媒間の移行方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9944727B2 (OSRAM) |
| EP (1) | EP3237459B1 (OSRAM) |
| JP (1) | JP6761810B2 (OSRAM) |
| KR (1) | KR102554874B1 (OSRAM) |
| CN (1) | CN107207649B (OSRAM) |
| BR (1) | BR112017013272A2 (OSRAM) |
| EA (1) | EA032875B1 (OSRAM) |
| SA (1) | SA517381799B1 (OSRAM) |
| WO (1) | WO2016102548A1 (OSRAM) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3394111B1 (en) * | 2015-12-22 | 2019-08-28 | SABIC Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| CN108884179B (zh) * | 2016-04-20 | 2021-09-21 | 尤尼威蒂恩技术有限责任公司 | 聚合物流动指数改性剂 |
| CN109937213B (zh) * | 2016-09-08 | 2021-03-02 | Sabic环球技术有限责任公司 | 通过不连续添加热失控减少剂制备聚烯烃的方法 |
| WO2019121701A1 (en) * | 2017-12-22 | 2019-06-27 | Sabic Global Technologies B.V. | Polypropylene composition for tapes |
| KR102060531B1 (ko) * | 2018-07-20 | 2020-02-11 | 금호석유화학 주식회사 | 고무 조성물의 제조방법 |
| KR102778829B1 (ko) * | 2019-11-29 | 2025-03-12 | 롯데케미칼 주식회사 | 폴리올레핀 제조방법 |
| CN114621369B (zh) * | 2020-12-10 | 2023-11-28 | 中国石油天然气股份有限公司 | 乙烯气相聚合牌号切换剂及其制备方法 |
| CN114621371B (zh) * | 2020-12-10 | 2023-11-28 | 中国石油天然气股份有限公司 | 气相法聚乙烯茂金属催化剂向铬系催化剂在线快速切换方法 |
| CN114621370B (zh) * | 2020-12-10 | 2023-11-28 | 中国石油天然气股份有限公司 | 一种气相法聚乙烯钛系向铬系催化剂在线快速切换方法 |
| EP4330294A1 (en) * | 2021-04-30 | 2024-03-06 | ExxonMobil Chemical Patents Inc. | Processes for transitioning between different polymerization catalysts in a polymerization reactor |
| CN113578205B (zh) * | 2021-09-29 | 2021-12-03 | 东营科宏化工有限公司 | 邻叔丁基环己醇制备用催化剂的添加装置及添加方法 |
| CN117567675B (zh) * | 2024-01-16 | 2024-04-23 | 新疆独山子石油化工有限公司 | 一种铬系聚乙烯转产茂金属聚乙烯的生产方法 |
| CN117567676B (zh) * | 2024-01-16 | 2024-04-16 | 新疆独山子石油化工有限公司 | 一种钛系聚乙烯转产茂金属聚乙烯的生产方法 |
| CN119306870A (zh) * | 2024-12-16 | 2025-01-14 | 新疆独山子石油化工有限公司 | 铬系聚乙烯转产聚烯烃弹性体的生产方法 |
| CN119306873A (zh) * | 2024-12-16 | 2025-01-14 | 新疆独山子石油化工有限公司 | 减少钛系聚乙烯转产聚烯烃弹性体中过渡料的生产方法 |
Family Cites Families (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3450183A (en) | 1964-10-02 | 1969-06-17 | Phillips Petroleum Co | Polymer recovery apparatus |
| US3594356A (en) | 1967-04-24 | 1971-07-20 | Phillips Petroleum Co | Polymer recovery process and apparatus |
| US4003712A (en) | 1970-07-29 | 1977-01-18 | Union Carbide Corporation | Fluidized bed reactor |
| US3687920A (en) | 1971-01-25 | 1972-08-29 | Union Carbide Corp | Polymerization of olefins with silane modified catalyst system |
| US4086408A (en) | 1973-12-20 | 1978-04-25 | Union Carbide Corporation | Ethylene polymerization with silane modified catalyst |
| LU70739A1 (OSRAM) | 1974-08-14 | 1976-08-19 | ||
| US4011382A (en) | 1975-03-10 | 1977-03-08 | Union Carbide Corporation | Preparation of low and medium density ethylene polymer in fluid bed reactor |
| GB1582955A (en) | 1976-07-28 | 1981-01-21 | Boc Ltd | Condensation of the vapour of a volatile liquid |
| US4101445A (en) | 1976-09-22 | 1978-07-18 | Union Carbide Corporation | Preparation of modified and activated chromocene catalysts for ethylene polymerization |
| US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
| US4482687A (en) | 1979-10-26 | 1984-11-13 | Union Carbide Corporation | Preparation of low-density ethylene copolymers in fluid bed reactor |
| US4372758A (en) | 1980-09-02 | 1983-02-08 | Union Carbide Corporation | Degassing process for removing unpolymerized monomers from olefin polymers |
| US5019633A (en) | 1980-12-24 | 1991-05-28 | Technology Corporation | Catalyst composition for polymerizing ethylene |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4460755A (en) | 1982-09-30 | 1984-07-17 | Union Carbide Corporation | Direct conversion of a polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst |
| US4560671A (en) | 1983-07-01 | 1985-12-24 | Union Carbide Corporation | Olefin polymerization catalysts adapted for gas phase processes |
| US4798081A (en) | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
| US4755495A (en) | 1986-02-27 | 1988-07-05 | Union Carbide Corporation | Process for activation of titanium and vanadium catalysts useful in ethylene polymerization |
| US4719193A (en) | 1986-09-30 | 1988-01-12 | Union Carbide Corporation | Processes for preparing polyethylene catalysts by heating catalyst precursors |
| US4727723A (en) | 1987-06-24 | 1988-03-01 | The M. W. Kellogg Company | Method for sub-cooling a normally gaseous hydrocarbon mixture |
| FR2618786B1 (fr) | 1987-07-31 | 1989-12-01 | Bp Chimie Sa | Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5035732A (en) | 1990-01-04 | 1991-07-30 | Stone & Webster Engineering Corporation | Cryogenic separation of gaseous mixtures |
| US5070055A (en) | 1990-06-29 | 1991-12-03 | Union Carbide Chemicals And Plastics Technology Corporation | Novel coimpregnated vanadium-zirconium catalyst for making polyethylene with broad or bimodal MW distribution |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5391656A (en) | 1993-09-24 | 1995-02-21 | Union Carbide Chemicals & Plastics Technology Corporation | Recovery of unreacted monomers in an olefin polymerization process |
| US5377490A (en) | 1994-02-04 | 1995-01-03 | Air Products And Chemicals, Inc. | Open loop mixed refrigerant cycle for ethylene recovery |
| US5442019A (en) * | 1994-03-25 | 1995-08-15 | Exxon Chemical Company | Process for transitioning between incompatible polymerization catalysts |
| US5421167A (en) | 1994-04-01 | 1995-06-06 | The M. W. Kellogg Company | Enhanced olefin recovery method |
| US5533437A (en) | 1995-01-20 | 1996-07-09 | Air Products And Chemicals, Inc. | Recovery of hydrocarbons from polyalkene product purge gas |
| US5672666A (en) | 1995-06-05 | 1997-09-30 | Exxon Chemical Patents Inc. | Process for transitioning between incompatible polymerization catalysts |
| US5626034A (en) | 1995-11-17 | 1997-05-06 | Manley; David | Mixed refrigerants in ethylene recovery |
| US5769927A (en) | 1997-01-24 | 1998-06-23 | Membrane Technology And Research, Inc. | Monomer recovery process |
| US5979177A (en) | 1998-01-06 | 1999-11-09 | Abb Lummus Global Inc. | Ethylene plant refrigeration system |
| US6271433B1 (en) | 1999-02-22 | 2001-08-07 | Stone & Webster Engineering Corp. | Cat cracker gas plant process for increased olefins recovery |
| US6712880B2 (en) | 2001-03-01 | 2004-03-30 | Abb Lummus Global, Inc. | Cryogenic process utilizing high pressure absorber column |
| US6576043B2 (en) | 2001-10-12 | 2003-06-10 | Air Products And Chemicals, Inc. | Recovery of nitrogen and light hydrocarbons from polyalkene purge gas |
| US6560989B1 (en) | 2002-06-07 | 2003-05-13 | Air Products And Chemicals, Inc. | Separation of hydrogen-hydrocarbon gas mixtures using closed-loop gas expander refrigeration |
| AU2003295724A1 (en) | 2002-12-27 | 2004-07-29 | Univation Technologies, Llc | Processes for transitioning between ziegler-natta and alumoxane-based single-site polymerization catalysts |
| US6897269B2 (en) * | 2002-12-27 | 2005-05-24 | Univation Technologies, Llc | Processes for transitioning between Ziegler-Natta and alumoxane-based single-site polymerization catalysts |
| US6858684B2 (en) | 2002-12-30 | 2005-02-22 | Univation Technologies, Llc | Processes for transitioning between various polymerization catalysts |
| US6949612B2 (en) | 2002-12-31 | 2005-09-27 | Univation Technologies, Llc | Processes for transitioning between metallocene and Ziegler-Natta polymerization catalysts |
| US6833416B2 (en) * | 2003-03-21 | 2004-12-21 | Univation Technologies, Llc | Methods of polymerizing olefin monomers with mixed catalyst systems |
| US7128827B2 (en) | 2004-01-14 | 2006-10-31 | Kellogg Brown & Root Llc | Integrated catalytic cracking and steam pyrolysis process for olefins |
| US20050159122A1 (en) | 2004-01-20 | 2005-07-21 | Mayer Robert S. | Radio with simultaneous buffering of multiple stations |
| US7316127B2 (en) | 2004-04-15 | 2008-01-08 | Abb Lummus Global Inc. | Hydrocarbon gas processing for rich gas streams |
| WO2005113615A2 (en) | 2004-05-20 | 2005-12-01 | Univation Technologies, Llc | Gas olefin polymerization process |
| ES2353894T3 (es) * | 2004-12-21 | 2011-03-08 | Univation Technologies, Llc | Procedimiento de transición entre catalizadores a base de ziegler-natta y a base de cromo. |
| US7629422B2 (en) * | 2004-12-21 | 2009-12-08 | Univation Technologies, Llc | Process for transitioning between Ziegler-Natta-based and chromium-based catalysts |
| EP1731535A1 (en) * | 2005-06-07 | 2006-12-13 | Saudi Basic Industries Corporation Inc. | Process for polymerization of olefins |
| EP2610269A1 (en) * | 2011-12-28 | 2013-07-03 | Saudi Basic Industries Corporation | Catalyst composition and method for preparing the same |
| KR20160095020A (ko) | 2013-11-29 | 2016-08-10 | 사우디 베이식 인더스트리즈 코포레이션 | 알파 올레핀 단량체의 연속 중합용 다중구역 반응기 |
-
2015
- 2015-12-22 WO PCT/EP2015/080946 patent/WO2016102548A1/en not_active Ceased
- 2015-12-22 JP JP2017551361A patent/JP6761810B2/ja active Active
- 2015-12-22 EA EA201791431A patent/EA032875B1/ru not_active IP Right Cessation
- 2015-12-22 CN CN201580075645.4A patent/CN107207649B/zh active Active
- 2015-12-22 US US15/537,997 patent/US9944727B2/en active Active
- 2015-12-22 EP EP15817346.8A patent/EP3237459B1/en active Active
- 2015-12-22 BR BR112017013272A patent/BR112017013272A2/pt not_active Application Discontinuation
- 2015-12-22 KR KR1020177020266A patent/KR102554874B1/ko active Active
-
2017
- 2017-06-22 SA SA517381799A patent/SA517381799B1/ar unknown
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