JP2017527674A - フリーラジカル重合法及びそれによる物品 - Google Patents

フリーラジカル重合法及びそれによる物品 Download PDF

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Publication number
JP2017527674A
JP2017527674A JP2017514669A JP2017514669A JP2017527674A JP 2017527674 A JP2017527674 A JP 2017527674A JP 2017514669 A JP2017514669 A JP 2017514669A JP 2017514669 A JP2017514669 A JP 2017514669A JP 2017527674 A JP2017527674 A JP 2017527674A
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Prior art keywords
curable composition
meth
free radical
substrate
acrylate
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Ceased
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JP2017514669A
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Japanese (ja)
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JP2017527674A5 (enExample
Inventor
ザッカリー ジェイ． トンプソン，
ザッカリー ジェイ． トンプソン，
吉彦 田坂
吉彦 田坂
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3M Innovative Properties Co
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3M Innovative Properties Co
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Publication of JP2017527674A publication Critical patent/JP2017527674A/ja
Publication of JP2017527674A5 publication Critical patent/JP2017527674A5/ja
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/106—Esters of polycondensation macromers
    • C08F222/1065—Esters of polycondensation macromers of alcohol terminated (poly)urethanes, e.g. urethane(meth)acrylates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/26—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of manganese, iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1812—C12-(meth)acrylate, e.g. lauryl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/343—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate in the form of urethane links
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2248—Oxides; Hydroxides of metals of copper

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2017514669A 2014-09-16 2015-09-14 フリーラジカル重合法及びそれによる物品 Ceased JP2017527674A (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462051076P 2014-09-16 2014-09-16
US62/051,076 2014-09-16
US201462051486P 2014-09-17 2014-09-17
US62/051,486 2014-09-17
PCT/US2015/049962 WO2016044151A1 (en) 2014-09-16 2015-09-14 Free-radical polymerization methods and articles thereby

Publications (2)

Publication Number Publication Date
JP2017527674A true JP2017527674A (ja) 2017-09-21
JP2017527674A5 JP2017527674A5 (enExample) 2018-10-18

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Application Number Title Priority Date Filing Date
JP2017514669A Ceased JP2017527674A (ja) 2014-09-16 2015-09-14 フリーラジカル重合法及びそれによる物品

Country Status (7)

Country Link
US (1) US10413935B2 (enExample)
EP (1) EP3194455B1 (enExample)
JP (1) JP2017527674A (enExample)
KR (1) KR20170058962A (enExample)
CN (1) CN107075001B (enExample)
TW (1) TWI681977B (enExample)
WO (1) WO2016044151A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2514139A (en) 2013-05-14 2014-11-19 Aghababaie Lin & Co Ltd Apparatus for fabrication of three dimensional objects
US10166725B2 (en) 2014-09-08 2019-01-01 Holo, Inc. Three dimensional printing adhesion reduction using photoinhibition
KR20170062509A (ko) 2014-09-30 2017-06-07 쓰리엠 이노베이티브 프로퍼티즈 캄파니 자유 라디칼 중합 방법 및 그에 의한 물품
US11141919B2 (en) 2015-12-09 2021-10-12 Holo, Inc. Multi-material stereolithographic three dimensional printing
US10935891B2 (en) 2017-03-13 2021-03-02 Holo, Inc. Multi wavelength stereolithography hardware configurations
GB2564956B (en) 2017-05-15 2020-04-29 Holo Inc Viscous film three-dimensional printing systems and methods
US10245785B2 (en) 2017-06-16 2019-04-02 Holo, Inc. Methods for stereolithography three-dimensional printing
WO2019116201A1 (en) 2017-12-13 2019-06-20 3M Innovative Properties Company Optically clear adhesives containing a trialkyl borane complex initiator and photoacid
JP7373490B2 (ja) 2018-01-31 2023-11-02 スリーエム イノベイティブ プロパティズ カンパニー 光解離性バルビツール酸系化合物
TWI794400B (zh) 2018-01-31 2023-03-01 美商3M新設資產公司 用於連續移動帶材的紅外光透射檢查
KR102696084B1 (ko) 2018-01-31 2024-08-19 쓰리엠 이노베이티브 프로퍼티즈 컴파니 제조된 웨브의 검사를 위한 가상 카메라 어레이
US12163070B2 (en) 2018-02-09 2024-12-10 3M Innovative Properties Company Primer-initiated cure of structural adhesive film
CN111699229B (zh) 2018-02-09 2023-02-28 3M创新有限公司 膜引发的结构性粘合剂膜固化
CN117067579A (zh) 2018-12-26 2023-11-17 霍洛公司 用于三维打印系统和方法的传感器
US12247145B2 (en) 2020-03-06 2025-03-11 3M Innovative Properties Company Adjustable hybrid PSA/structural adhesive bonds by patterned surface-initiated cure

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05919A (ja) * 1991-06-19 1993-01-08 G C:Kk 歯質用接着剤
JPH0899815A (ja) * 1994-09-29 1996-04-16 Terumo Corp 歯質用接着材
JP2009067814A (ja) * 2007-09-10 2009-04-02 Toray Fine Chemicals Co Ltd 可視光硬化型接着剤組成物
JP2012005829A (ja) * 2010-06-22 2012-01-12 Heraeus Medical Gmbh ペースト様骨セメント
JP2013181146A (ja) * 2012-03-02 2013-09-12 Denki Kagaku Kogyo Kk 硬化性樹脂組成物

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1495520B2 (de) 1964-05-02 1970-06-25 Deutsche Gold- U. Silber-Scheideanstalt, Vorm. Roessler, 6000 Frankfurt Verfahren zum Polymerisieren
RO61951A (fr) 1969-05-29 1977-12-15 Bayer Ag Procede pour durcissement les masses de formages et de revetement en base polyesterique
US3844790A (en) 1972-06-02 1974-10-29 Du Pont Photopolymerizable compositions with improved resistance to oxygen inhibition
US4032594A (en) 1975-06-10 1977-06-28 Exxon Research And Engineering Company Polymeric stabilizers for polyvinyl chloride resin
US4356296A (en) 1981-02-25 1982-10-26 The United States Of America As Represented By The Secretary Of The Navy Fluorinated diacrylic esters and polymers therefrom
US4539048A (en) 1983-02-09 1985-09-03 Jos. Cavedon Company Inc. Aluminum zirconium metallo-organic complexes useful as coupling agents
US4473671A (en) 1983-09-01 1984-09-25 Johnson & Johnson Products, Inc. Formable orthopedic casts and splints
US4642126A (en) 1985-02-11 1987-02-10 Norton Company Coated abrasives with rapidly curable adhesives and controllable curvature
DE3516256A1 (de) 1985-05-07 1986-11-13 Bayer Ag, 5090 Leverkusen (meth)-acrylsaeureester und ihre verwendung
DE3516257A1 (de) 1985-05-07 1986-11-13 Bayer Ag, 5090 Leverkusen (meth)-acrylsaeureester und ihre verwendung
US4648843A (en) 1985-07-19 1987-03-10 Minnesota Mining And Manufacturing Company Method of dental treatment using poly(ethylenically unsaturated) carbamoyl isocyanurates and dental materials made therewith
US4652274A (en) 1985-08-07 1987-03-24 Minnesota Mining And Manufacturing Company Coated abrasive product having radiation curable binder
US4755251A (en) 1987-02-09 1988-07-05 Ashland Oil, Inc. Bonding method employing primer for fiberglass reinforced polyester
DE3844619A1 (de) 1988-12-10 1990-07-12 Goldschmidt Ag Th Verwendung von perfluoroalkylgruppen aufweisenden (meth-)acrylsaeureestern in der dentaltechnik
US5026902A (en) 1988-12-10 1991-06-25 Th. Goldschmidt AG & GDF Gesellschaft fur Dentale Forschung u. Innovationen GmbH Dental compsition of perfluoroalkyl group-containing (meth-)acrylate esters
US5076844A (en) 1988-12-10 1991-12-31 Goldschmidt AG & GDF Gesellschaft fur Dentale Forschung u. Innovationen GmbH Perfluoroalkyl group-containing (meth-)acrylate esters, their synthesis and use in dental technology
US5290172A (en) * 1991-11-06 1994-03-01 Gc Corporation Method for preparing a tooth surface for bonding
JP3419069B2 (ja) 1993-03-29 2003-06-23 シーケイ・ウイトコ・コーポレーシヨン シリル化エポキシ樹脂の水分散液
AU763355B2 (en) * 1998-08-20 2003-07-17 Kuraray Co., Ltd. Bonding compositions for dental use
IE980775A1 (en) 1998-09-17 2000-03-22 Loctite R & D Ltd Auto-oxidation systems for air-activatable polymerisable compositions
DE19860364C2 (de) 1998-12-24 2001-12-13 3M Espe Ag Polymerisierbare Dentalmassen auf der Basis von zur Aushärtung befähigten Siloxanverbindungen, deren Verwendung und Herstellung
DE19860361A1 (de) 1998-12-24 2000-06-29 Espe Dental Ag Vernetzbare Monomere auf Cyclosiloxanbasis, deren Herstellung und deren Verwendung in polymerisierbaren Massen
DE19928238A1 (de) 1999-06-21 2000-12-28 Espe Dental Ag Polymerisierbare Dentalmasse
JP4636656B2 (ja) * 1999-07-08 2011-02-23 株式会社松風 歯科用接着剤組成物
DE19934407A1 (de) 1999-07-22 2001-01-25 Espe Dental Ag Hydrolysierbare und polymerisierbare Silane mit geringer Viskosität und deren Verwendung
DE10026432A1 (de) 2000-05-29 2002-02-14 3M Espe Ag Präpolymere (Meth)acrylate mit polycyclischen oder aromatischen Segmenten
US6838535B2 (en) 2001-03-23 2005-01-04 University Of Pennsylvania Process for the living radical polymerization of chlorine containing monomers
US7025954B2 (en) * 2002-05-20 2006-04-11 Esstech, Inc. Materials for reshaping of essentially rigid keratinaceous surfaces
JP4596798B2 (ja) 2004-03-15 2010-12-15 株式会社トクヤマ 歯科用硬化性組成物及びその保存方法
US7968667B2 (en) 2004-09-02 2011-06-28 The Yokohama Rubber Co., Ltd. Adhesive compositions for optical fibers
US7879924B2 (en) * 2006-02-03 2011-02-01 Kabushiki Kaisha Shofu Dental composite resin cement, dental primer and dental adhesive kit containing them
ATE532797T1 (de) 2006-05-31 2011-11-15 3M Innovative Properties Co Polymerisierbare zusammensetzungen enthaltend salze aus barbitursäure-derivaten
JP5276916B2 (ja) * 2008-07-08 2013-08-28 株式会社松風 歯科用ツーペースト型自己接着性レジンセメント
CN103534623B (zh) 2011-03-29 2016-02-17 富士胶片株式会社 光学膜、3d影像显示元件以及3d影像显示系统
DE102011077510A1 (de) 2011-06-14 2012-12-20 Tesa Se Primer zur Verbesserung der Adhäsion von Klebebändern auf schwer verklebbaren Kunststoffen und Metallen
BR112014020560B1 (pt) * 2012-02-23 2021-03-02 3M Innovative Properties Company adesivo acrílico estrutural
EP2976369B1 (en) 2013-03-19 2018-02-07 3M Innovative Properties Company Free-radical polymerization methods and articles prepared thereby
EP3172244B1 (en) 2014-07-22 2020-05-13 3M Innovative Properties Company Free-radical polymerization methods and articles thereby

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05919A (ja) * 1991-06-19 1993-01-08 G C:Kk 歯質用接着剤
JPH0899815A (ja) * 1994-09-29 1996-04-16 Terumo Corp 歯質用接着材
JP2009067814A (ja) * 2007-09-10 2009-04-02 Toray Fine Chemicals Co Ltd 可視光硬化型接着剤組成物
JP2012005829A (ja) * 2010-06-22 2012-01-12 Heraeus Medical Gmbh ペースト様骨セメント
JP2013181146A (ja) * 2012-03-02 2013-09-12 Denki Kagaku Kogyo Kk 硬化性樹脂組成物

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EP3194455A1 (en) 2017-07-26
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US10413935B2 (en) 2019-09-17
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