JP2017522457A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2017522457A5 JP2017522457A5 JP2017505073A JP2017505073A JP2017522457A5 JP 2017522457 A5 JP2017522457 A5 JP 2017522457A5 JP 2017505073 A JP2017505073 A JP 2017505073A JP 2017505073 A JP2017505073 A JP 2017505073A JP 2017522457 A5 JP2017522457 A5 JP 2017522457A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst layer
- compound
- valve metal
- coating
- metal substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 30
- 239000011248 coating agent Substances 0.000 claims description 24
- 238000000197 pyrolysis Methods 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 15
- 239000000758 substrate Substances 0.000 claims description 15
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 239000010936 titanium Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 229910052707 ruthenium Inorganic materials 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 10
- 239000000460 chlorine Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 6
- 229910052715 tantalum Inorganic materials 0.000 claims description 6
- 239000006104 solid solution Substances 0.000 claims description 5
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 150000003606 tin compounds Chemical class 0.000 claims description 2
- CMIQNFUKBYANIP-UHFFFAOYSA-N ruthenium tantalum Chemical compound [Ru].[Ta] CMIQNFUKBYANIP-UHFFFAOYSA-N 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 16
- 229910001936 tantalum oxide Inorganic materials 0.000 description 13
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 9
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 9
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 8
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- ROZSPJBPUVWBHW-UHFFFAOYSA-N [Ru]=O Chemical class [Ru]=O ROZSPJBPUVWBHW-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 235000003976 Ruta Nutrition 0.000 description 1
- 240000005746 Ruta graveolens Species 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 235000005806 ruta Nutrition 0.000 description 1
- 150000003304 ruthenium compounds Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2014A001363 | 2014-07-28 | ||
| ITMI20141363 | 2014-07-28 | ||
| PCT/EP2015/067273 WO2016016243A1 (en) | 2014-07-28 | 2015-07-28 | Catalytic coating and method of manufacturing thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017522457A JP2017522457A (ja) | 2017-08-10 |
| JP2017522457A5 true JP2017522457A5 (https=) | 2020-03-05 |
| JP6714576B2 JP6714576B2 (ja) | 2020-06-24 |
Family
ID=51628367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017505073A Expired - Fee Related JP6714576B2 (ja) | 2014-07-28 | 2015-07-28 | 触媒被覆及びその製造方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20170198403A1 (https=) |
| EP (1) | EP3175019B1 (https=) |
| JP (1) | JP6714576B2 (https=) |
| CN (1) | CN106471159B (https=) |
| AR (1) | AR101828A1 (https=) |
| ES (1) | ES2712403T3 (https=) |
| HU (1) | HUE041583T2 (https=) |
| PT (1) | PT3175019T (https=) |
| RU (1) | RU2689985C2 (https=) |
| TW (1) | TWI679256B (https=) |
| WO (1) | WO2016016243A1 (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT201800006544A1 (it) * | 2018-06-21 | 2019-12-21 | Anodo per evoluzione elettrolitica di cloro | |
| JP7621071B2 (ja) * | 2020-07-20 | 2025-01-24 | デノラ・ペルメレック株式会社 | 酸素発生用電極 |
| JP7168729B1 (ja) * | 2021-07-12 | 2022-11-09 | デノラ・ペルメレック株式会社 | 工業用電解プロセス用電極 |
| WO2024184552A1 (en) * | 2023-03-09 | 2024-09-12 | Magneto Special Anodes B.V. | Mixed metal oxide coatings applied using spatial atomic layer deposition and uses thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3776834A (en) * | 1972-05-30 | 1973-12-04 | Leary K O | Partial replacement of ruthenium with tin in electrode coatings |
| US3853739A (en) * | 1972-06-23 | 1974-12-10 | Electronor Corp | Platinum group metal oxide coated electrodes |
| BRPI0818104B1 (pt) * | 2007-11-16 | 2018-11-21 | Akzo Nobel Nv | processo de produção de clorato de metal álcali |
| IT1391767B1 (it) * | 2008-11-12 | 2012-01-27 | Industrie De Nora Spa | Elettrodo per cella elettrolitica |
| ITMI20101098A1 (it) * | 2010-06-17 | 2011-12-18 | Industrie De Nora Spa | Elettrodo per elettroclorazione |
| IT1403585B1 (it) * | 2010-11-26 | 2013-10-31 | Industrie De Nora Spa | Anodo per evoluzione elettrolitica di cloro |
| CN102174704B (zh) * | 2011-02-20 | 2012-12-12 | 中国船舶重工集团公司第七二五研究所 | 一种含钽中间层金属氧化物电极的制备方法 |
| JP5008043B1 (ja) * | 2011-09-13 | 2012-08-22 | 学校法人同志社 | 塩素発生用陽極 |
-
2015
- 2015-06-18 TW TW104119668A patent/TWI679256B/zh not_active IP Right Cessation
- 2015-07-21 AR ARP150102307A patent/AR101828A1/es active IP Right Grant
- 2015-07-28 WO PCT/EP2015/067273 patent/WO2016016243A1/en not_active Ceased
- 2015-07-28 PT PT15742289T patent/PT3175019T/pt unknown
- 2015-07-28 CN CN201580034498.6A patent/CN106471159B/zh active Active
- 2015-07-28 JP JP2017505073A patent/JP6714576B2/ja not_active Expired - Fee Related
- 2015-07-28 EP EP15742289.0A patent/EP3175019B1/en active Active
- 2015-07-28 ES ES15742289T patent/ES2712403T3/es active Active
- 2015-07-28 HU HUE15742289A patent/HUE041583T2/hu unknown
- 2015-07-28 RU RU2017106084A patent/RU2689985C2/ru active
- 2015-07-28 US US15/321,419 patent/US20170198403A1/en not_active Abandoned
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103210122B (zh) | 用于氯的电解析出的阳极 | |
| CN101235513B (zh) | 一种新型涂层钛阳极 | |
| JP6152139B2 (ja) | 電解用途用の電極 | |
| CN101880891B (zh) | 一种高稳定性电解制氯用dsa阳极及其制备方法 | |
| CN107002257B (zh) | 用于氯气的电解析出的阳极 | |
| CA2347728C (fr) | Cathode utilisable pour l'electrolyse de solutions aqueuses | |
| CN101532147A (zh) | 一种纳米晶金属氧化物复合电极及其制备方法 | |
| PT2344682E (pt) | Elétrodo para célula de eletrólise | |
| TWI550136B (zh) | 在電解法中適於釋氧之電極及其製法和從水溶液電極沈積金屬之方法 | |
| JP2017522457A5 (https=) | ||
| TW201819687A (zh) | 電解用電極 | |
| JP6714576B2 (ja) | 触媒被覆及びその製造方法 | |
| CA1058552A (en) | Electrodes | |
| TWI453305B (zh) | 電解用電極的製造方法 | |
| US20210238757A1 (en) | Anode for electrolytic evolution of chlorine | |
| Mazhari Abbasi et al. | Optimizing the TiO2 content to obtain the highest corrosion resistance in Ir-Ru-Ta-based mixed metal oxide coating in oxygen evolution reaction application | |
| EA029324B1 (ru) | Электрод для выделения кислорода в промышленных электрохимических процессах | |
| US4223049A (en) | Superficially mixed metal oxide electrodes | |
| TW201800508A (zh) | 閥金屬基材或其合金之防腐塗料及其製法和電化電池凸緣之翻新方法 | |
| JPH0238671B2 (https=) | ||
| JPH0238670B2 (https=) | ||
| JP5988310B2 (ja) | 基材の１つまたは複数の面のコーティング | |
| HK1184508B (en) | Anode for electrolytic evolution of chlorine |