JP2016533017A5 - - Google Patents
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- JP2016533017A5 JP2016533017A5 JP2016539627A JP2016539627A JP2016533017A5 JP 2016533017 A5 JP2016533017 A5 JP 2016533017A5 JP 2016539627 A JP2016539627 A JP 2016539627A JP 2016539627 A JP2016539627 A JP 2016539627A JP 2016533017 A5 JP2016533017 A5 JP 2016533017A5
- Authority
- JP
- Japan
- Prior art keywords
- oxide
- anode
- nickel
- copper
- fuel cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 88
- 239000000446 fuel Substances 0.000 claims description 82
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 73
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 72
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 70
- 239000003792 electrolyte Substances 0.000 claims description 65
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 54
- 239000005751 Copper oxide Substances 0.000 claims description 52
- 229910000431 copper oxide Inorganic materials 0.000 claims description 52
- 150000002910 rare earth metals Chemical class 0.000 claims description 52
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 50
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 48
- 239000010949 copper Substances 0.000 claims description 45
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 44
- 229910052802 copper Inorganic materials 0.000 claims description 44
- 229910052759 nickel Inorganic materials 0.000 claims description 40
- 239000000758 substrate Substances 0.000 claims description 40
- 239000002184 metal Substances 0.000 claims description 37
- 229910052751 metal Inorganic materials 0.000 claims description 36
- 238000005245 sintering Methods 0.000 claims description 30
- 239000002131 composite material Substances 0.000 claims description 25
- 229910001220 stainless steel Inorganic materials 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 18
- 229910044991 metal oxide Inorganic materials 0.000 claims description 16
- 150000004706 metal oxides Chemical class 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 14
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 claims description 8
- 229910021526 gadolinium-doped ceria Inorganic materials 0.000 claims description 8
- LDSIKPHVUGHOOI-UHFFFAOYSA-N copper;oxonickel Chemical compound [Ni].[Cu]=O LDSIKPHVUGHOOI-UHFFFAOYSA-N 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 239000000976 ink Substances 0.000 description 31
- 239000000919 ceramic Substances 0.000 description 24
- 238000010304 firing Methods 0.000 description 15
- 239000001301 oxygen Substances 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
- 230000002829 reductive effect Effects 0.000 description 12
- 239000011195 cermet Substances 0.000 description 11
- 239000012298 atmosphere Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 230000008018 melting Effects 0.000 description 9
- 238000002844 melting Methods 0.000 description 9
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(i) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 238000005336 cracking Methods 0.000 description 6
- 238000001878 scanning electron micrograph Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- 229910002484 Ce0.9Gd0.1O1.95 Inorganic materials 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 229910000423 chromium oxide Inorganic materials 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 239000002001 electrolyte material Substances 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 5
- -1 oxygen ion Chemical class 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 229910000428 cobalt oxide Inorganic materials 0.000 description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000002161 passivation Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 4
- 238000000629 steam reforming Methods 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000006056 electrooxidation reaction Methods 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- PACGUUNWTMTWCF-UHFFFAOYSA-N [Sr].[La] Chemical compound [Sr].[La] PACGUUNWTMTWCF-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 229910052963 cobaltite Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 239000010416 ion conductor Substances 0.000 description 2
- 230000037427 ion transport Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000011533 mixed conductor Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010405 reoxidation reaction Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910002132 La0.6Sr0.4Co0.2Fe0.8O3-δ Inorganic materials 0.000 description 1
- 229910002131 La0.6Sr0.4Co0.2Fe0.8O3–δ Inorganic materials 0.000 description 1
- 229910002130 La0.6Sr0.4Co0.2Fe0.8O3−δ Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 241000968352 Scandia <hydrozoan> Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004814 ceramic processing Methods 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001652 electrophoretic deposition Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- HJGMWXTVGKLUAQ-UHFFFAOYSA-N oxygen(2-);scandium(3+) Chemical compound [O-2].[O-2].[O-2].[Sc+3].[Sc+3] HJGMWXTVGKLUAQ-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000007569 slipcasting Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1315746.6 | 2013-09-04 | ||
| GB1315746.6A GB2517928B (en) | 2013-09-04 | 2013-09-04 | Metal supported solid oxide fuel cell |
| PCT/GB2014/052549 WO2015033104A1 (en) | 2013-09-04 | 2014-08-20 | Metal supported solid oxide fuel cell |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019149074A Division JP7089494B2 (ja) | 2013-09-04 | 2019-08-15 | 金属支持固体酸化物燃料電池 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2016533017A JP2016533017A (ja) | 2016-10-20 |
| JP2016533017A5 true JP2016533017A5 (enExample) | 2018-11-29 |
Family
ID=49397283
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016539627A Withdrawn JP2016533017A (ja) | 2013-09-04 | 2014-08-20 | 金属支持固体酸化物燃料電池 |
| JP2019149074A Active JP7089494B2 (ja) | 2013-09-04 | 2019-08-15 | 金属支持固体酸化物燃料電池 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019149074A Active JP7089494B2 (ja) | 2013-09-04 | 2019-08-15 | 金属支持固体酸化物燃料電池 |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US9236614B2 (enExample) |
| EP (1) | EP3042411B1 (enExample) |
| JP (2) | JP2016533017A (enExample) |
| KR (1) | KR102256568B1 (enExample) |
| CN (1) | CN105531861B (enExample) |
| CA (1) | CA2922744C (enExample) |
| DK (1) | DK3042411T3 (enExample) |
| ES (1) | ES2868189T3 (enExample) |
| GB (1) | GB2517928B (enExample) |
| HU (1) | HUE055456T2 (enExample) |
| MX (1) | MX382669B (enExample) |
| RU (1) | RU2672093C2 (enExample) |
| SG (1) | SG11201601152YA (enExample) |
| WO (1) | WO2015033104A1 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6581836B2 (ja) | 2015-08-03 | 2019-09-25 | 本田技研工業株式会社 | メタルサポートセル |
| CN105206855B (zh) * | 2015-09-10 | 2018-03-30 | 刘备之 | 一种用于制氧的复合电解质膜 |
| TWI558568B (zh) * | 2015-11-03 | 2016-11-21 | 行政院原子能委員會核能研究所 | 透氣金屬基板、金屬支撐固態氧化物燃料電池及其製作方法 |
| GB2550317B (en) * | 2016-03-09 | 2021-12-15 | Ceres Ip Co Ltd | Fuel cell |
| CA3017847A1 (en) * | 2016-03-18 | 2017-09-21 | Osaka Gas Co., Ltd. | Electrochemical element for a solid oxide fuel cell |
| US20200295379A2 (en) * | 2016-07-19 | 2020-09-17 | Georgia Tech Research Corporation | Intermediate-Temperature Fuel Cell Tailored for Efficient Utilization of Methane |
| CN108145144B (zh) * | 2017-12-27 | 2023-08-15 | 武汉科技大学 | 一种控制钢液卷渣的钢包工作衬 |
| JP7470038B2 (ja) * | 2018-03-30 | 2024-04-17 | 大阪瓦斯株式会社 | 電気化学素子の金属支持体、電気化学素子、電気化学モジュール、電気化学装置、エネルギーシステム、固体酸化物形燃料電池、固体酸化物形電解セルおよび金属支持体の製造方法 |
| US12119526B2 (en) * | 2018-03-30 | 2024-10-15 | Osaka Gas Co., Ltd. | Metal support for electrochemical element, electrochemical element, electrochemical module, electrochemical device, energy system, solid oxide fuel cell, solid oxide electrolytic cell, and method for manufacturing metal support |
| JP7300672B2 (ja) * | 2018-09-21 | 2023-06-30 | パナソニックＩｐマネジメント株式会社 | 燃料電池システムおよびその運転方法 |
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| JP7301768B2 (ja) * | 2020-03-18 | 2023-07-03 | 東芝エネルギーシステムズ株式会社 | 電気化学セル、電気化学セルスタックおよび電気化学セル用電解質 |
| JP7561511B2 (ja) * | 2020-03-27 | 2024-10-04 | 大阪瓦斯株式会社 | 電気化学素子の金属支持体、電気化学素子、電気化学モジュール、電気化学装置、エネルギーシステム、固体酸化物形燃料電池、および固体酸化物形電解セル |
| CN111584910B (zh) * | 2020-04-24 | 2022-11-01 | 合肥学院 | 一种CeO2基复合固体电解质材料及其制备方法 |
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| EP4430016A1 (en) | 2021-11-08 | 2024-09-18 | Rhodia Operations | Cerium-gadolinium composite oxide |
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