JP2016529332A - 硬質フォーム、並びに関連した物品および方法 - Google Patents
硬質フォーム、並びに関連した物品および方法 Download PDFInfo
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Abstract
Description
・混合時間は、反応物質を混合するのに必要な時間を示す。
・クリームタイムは、反応物質の混合の開始から最初の明確なフォーム膨張の出現まで経過した時間である。多くの場合、これは、反応混合物が上昇を開始する際に変色によって明らかに気づくことができる。混合物をゆっくりと反応させることで、これは、観察の実践を必要とする。
・ゲルタイムは、反応物質の混合と非流動性で、半固体、ゼリー状の系の形成との間の時間間隔である。それは、フォームが、寸法的に安定であるのに充分なゲル強度となったときの時間である。ゲルタイムの後、フォームが上昇する速度が遅くなる。
・上昇時間は、混合開始から光学的に認識可能な上昇の終わりまでの時間である。このため、それは、フォーム膨張が終わるまでの時間である。上昇プロセスが完了する際、フォームの表面は依然として粘着性である。
・タックフリータイムは、混合の開始から、フォーム表面がもはや粘着性または粘質ではないほど充分に硬化したときまでに経過する時間である。タックでなくなる瞬間は、フォーム表面を木製の棒で繰り返し試験することによって決定することができる。
ポリウレタンフォーム系における粒子状ポリ(フェニレンエーテル)の量を最大にするために、粒子状ポリ(フェニレンエーテル)を、フォーム系のポリオール成分とイソシアネート成分の両方を通じて添加した。組成物、プロセスおよび特性を、表3に要約する.特性の結果は、粒子状ポリ(フェニレンエーテル)を有する本発明の実施例4〜6が、比較例Bと比較して、燃焼性の減少と吸水性の減少を示したことを示す。
Claims (20)
- 平均粒径が1〜40μmである粒子状ポリ(フェニレンエーテル)を、ポリウレタンまたはポリイソシアヌレートのフォームの合計質量に対して1〜50質量%含み、ASTM D 1622−03を用いて23℃で決定したコア密度が0.03〜0.7g/cm3であることを特徴とするポリウレタンまたはポリイソシアヌレートのフォーム。
- ASTM D 1622−03を用いて23℃で決定したコア密度が0.03〜0.06g/cm3であることを特徴とする請求項1に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 105〜125のイソシアネート指数によって特徴付けられる方法の生成物であるポリウレタンフォームであることを特徴とする請求項1に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 180〜350のイソシアネート指数によって特徴付けられる方法の生成物であるポリイソシアヌレートフォームであることを特徴とする請求項1に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記粒子状ポリ(フェニレンエーテル)が粒子状ポリ(2,6−ジメチル−1,4−フェニレンエーテル)であることを特徴とする請求項1乃至4のいずれか1項に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記粒子状ポリ(フェニレンエーテル)の平均粒径が2〜8μmであることを特徴とする請求項1乃至4のいずれか1項に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記粒子状ポリ(フェニレンエーテル)が、粒径分布の90体積%が1〜8μmの範囲内である粒径分布を有することを特徴とする請求項1乃至4のいずれか1項に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記粒子状ポリ(フェニレンエーテル)を5〜30質量%含むことを特徴とする請求項1乃至4のいずれか1項に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記ポリウレタンまたはポリイソシアヌレートのフォームが、
発泡剤および粒子状ポリ(フェニレンエーテル)の存在下でポリオールとイソシアネート化合物とを反応させて、ポリウレタンまたはポリイソシアヌレートのフォームを形成するステップを含む方法であって、
ここで、前記イソシアネート化合物は、平均で、1分子当たり少なくとも2個のイソシアネート基を含む、方法の生成物であることを特徴とする請求項1に記載のポリウレタンまたはポリイソシアヌレートのフォーム。 - 前記ポリオールが、エトキシ化糖類、プロポキシ化糖類、ブトキシ化糖類、エトキシ化グリセリン、プロポキシ化グリセリン、ブトキシ化グリセリン、エトキシ化ジエタノールアミン、プロポキシ化ジエタノールアミン、ブトキシ化ジエタノールアミン、エトキシ化トリエタノールアミン、プロポキシ化トリエタノールアミン、ブトキシ化トリエタノールアミン、エトキシ化トリメチロールプロパン、プロポキシ化トリメチロールプロパン、ブトキシ化トリメチロールプロパン、エトキシ化エリスリトール、プロポキシ化エリスリトール、ブトキシ化エリスリトール、エトキシ化ペンタエリスリトール、プロポキシ化ペンタエリスリトール、ブトキシ化ペンタエリスリトール、脂肪族ポリエステルジオール、芳香族ポリエステルポリオールまたはそれらの組み合わせを含むことを特徴とする請求項9に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記ポリオールが、プロポキシ化スクロース、プロポキシ化グリセリン、芳香族ポリエステルジオールまたはそれらの組み合わせを含むことを特徴とする請求項9に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記イソシアネート化合物が、1,4−テトラメチレンジイソシアネート、1,6−ヘキサメチレンジイソシアネート、2,2,4−トリメチル−1,6−ヘキサメチレンジイソシアネート、1,12−ドデカメチレンジイソシアネート、シクロヘキサン−1,3−ジイソシアネート、シクロヘキサン−1,4−ジイソシアネート、1−イソシアナト−2−イソシアナトメチルシクロペンタン、1−イソシアナト−3−イソシアナトメチル−3,5,5−トリメチル−シクロヘキサン、ビス(4−イソシアナトシクロヘキシル)メタン、2,4’−ジシクロヘキシル−メタンジイソシアネート、1,3−ビス(イソシアナトメチル)−シクロヘキサン、1,4−ビス−(イソシアナトメチル)−シクロヘキサン、ビス(4−イソシアナト−3−メチル−シクロヘキシル)メタン、α,α,α’,α’−テトラメチル−1,3−キシレンジイソシアネート、α,α,α’,α’−テトラメチル−1,4−キシレンジイソシアネート、1−イソシアナト−1−メチル−4(3)−イソシアナトメチルシクロヘキサン、2,4−ヘキサヒドロトルエンジイソシアネート、2,6−ヘキサヒドロトルエンジイソシアネート、1,3−フェニレンジイソシアネート、1,4−フェニレンジイソシアネート、2,4−トルエンジイソシアネート、2,6−トルエンジイソシアネート、2,4−ジフェニルメタンジイソシアネート、4,4’−ジフェニルメタンジイソシアネート、1,5−ジイソシアナトナフタレン、1分子当たり平均2個を超え、かつ4個以下のイソシアネート基を有するオリゴマーのジフェニルメタンジイソシアネート、またはそれらの組み合わせを含むことを特徴とする請求項9乃至11のいずれか1項に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記イソシアネート化合物が、1分子当たり平均2個を超え、かつ4個以下のイソシアネート基を有するオリゴマーのジフェニルメタンジイソシアネートを含むことを特徴とする請求項9乃至11のいずれか1項に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 前記ポリウレタンまたはポリイソシアヌレートのフォームが、ASTM D 1622−03を用いて23℃で決定した0.02〜0.06g/cm3のコア密度を有し;
前記粒子状ポリ(フェニレンエーテル)が粒子状ポリ(2,6−ジメチル−1,4−フェニレンエーテル)であり;
前記粒子状ポリ(フェニレンエーテル)の平均粒径が2〜8μmであり;
前記粒子状ポリ(フェニレンエーテル)が、粒子体積分布の90%が1〜8μmの範囲内である粒径分布を有し;
前記ポリウレタンまたはポリイソシアヌレートのフォームが粒子状ポリ(フェニレンエーテル)を5〜30質量%含み;
前記ポリウレタンまたはポリイソシアヌレートのフォームが、
ポリオールとイソシアネート化合物とを発泡剤および粒子状ポリ(フェニレンエーテル)の存在下で反応させて、前記ポリウレタンまたはポリイソシアヌレートのフォームを形成するステップを含む方法であって、
ここで、前記イソシアネート化合物は、平均で、1分子当たり少なくとも2個のイソシアネート基を含む、方法の生成物であり;
前記ポリオールが、プロポキシ化スクロース、プロポキシ化グリセリン、芳香族ポリエステルジオールまたはそれらの組み合わせを含み;
前記イソシアネート化合物が、1分子当たり平均2個を超え、かつ4個以下のイソシアネート基を有するオリゴマーのジフェニルメタンジイソシアネートを含む
ことを特徴とする請求項1に記載のポリウレタンまたはポリイソシアヌレートのフォーム。 - 105〜125のイソシアネート指数によって特徴付けられる方法の生成物であるポリウレタンフォームであることを特徴とする請求項14に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- 180〜350のイソシアネート指数によって特徴付けられる方法の生成物であるポリウレタンフォームであることを特徴とする請求項14に記載のポリウレタンまたはポリイソシアヌレートのフォーム。
- ポリウレタンまたはポリイソシアヌレートのフォームを含む断熱性の物品であって、前記ポリウレタンまたはポリイソシアヌレートのフォームが、その合計質量に対して、平均粒径が1〜40μmである粒子状ポリ(フェニレンエーテル)を1〜50質量%含み、前記フォームがASTM D 1622−03を用いて23℃で決定した0.03〜0.7g/cm3のコア密度を有することを特徴とする物品。
- ポリウレタンまたはポリイソシアヌレートのフォームを形成する方法であって、
発泡剤および粒子状ポリ(フェニレンエーテル)の存在下でポリオールとイソシアネート化合物とを反応させて、ポリウレタンまたはポリイソシアヌレートのフォームを形成するステップを含み;
ここで、前記イソシアネート化合物は、平均で、1分子当たり少なくとも2個のイソシアネート基を含み;
前記粒子状ポリ(フェニレンエーテル)は1〜40μmの平均粒径を有し;
前記ポリウレタンまたはポリイソシアヌレートのフォームは粒子状ポリ(フェニレンエーテル)を1〜50質量%含む
ことを特徴とする方法。 - 前記ポリオールと、前記イソシアネート化合物と、もし存在する場合には水が、180〜350のイソシアネート指数をもたらすのに充分な量で存在することを特徴とする請求項18に記載の方法。
- 前記ポリウレタンまたはポリイソシアヌレートのフォームが、ASTM D 1622−03を用いて23℃で決定した0.02〜0.06g/cm3のコア密度を有し;
前記粒子状ポリ(フェニレンエーテル)が粒子状ポリ(2,6−ジメチル−1,4−フェニレンエーテル)であり;
前記粒子状ポリ(フェニレンエーテル)の平均粒径が2〜8μmであり;
前記粒子状ポリ(フェニレンエーテル)が、粒子体積分布の90%が1〜8μmの範囲内である粒径分布を有し;
前記ポリウレタンまたはポリイソシアヌレートのフォームが粒子状ポリ(フェニレンエーテル)を5〜30質量%含み;
前記ポリオールが、プロポキシ化スクロース、プロポキシ化グリセリン、芳香族ポリエステルジオールまたはそれらの組み合わせを含み;
前記イソシアネート化合物が、1分子当たり平均2個を超え、かつ4個以下のイソシアネート基を有するオリゴマーのジフェニルメタンジイソシアネートを含む
ことを特徴とする請求項18に記載の方法。
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- 2014-06-24 CN CN201910204954.7A patent/CN110041690A/zh active Pending
- 2014-06-24 CN CN201480039997.XA patent/CN105377988A/zh active Pending
- 2014-06-24 WO PCT/US2014/043773 patent/WO2015012989A1/en active Application Filing
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EP3036288A4 (en) | 2017-03-29 |
EP3036288A1 (en) | 2016-06-29 |
EP3036288B1 (en) | 2020-02-19 |
KR20160028461A (ko) | 2016-03-11 |
CN105377988A (zh) | 2016-03-02 |
JP6158431B2 (ja) | 2017-07-05 |
WO2015012989A1 (en) | 2015-01-29 |
CN110041690A (zh) | 2019-07-23 |
KR101669073B1 (ko) | 2016-10-25 |
US20150028247A1 (en) | 2015-01-29 |
US9493621B2 (en) | 2016-11-15 |
US20160145405A1 (en) | 2016-05-26 |
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