JP2016518491A - アルカリ性次亜塩素酸塩水性組成物中の腐食抑制剤としての高分子量ポリアクリル酸及びその方法 - Google Patents
アルカリ性次亜塩素酸塩水性組成物中の腐食抑制剤としての高分子量ポリアクリル酸及びその方法 Download PDFInfo
- Publication number
- JP2016518491A JP2016518491A JP2016509026A JP2016509026A JP2016518491A JP 2016518491 A JP2016518491 A JP 2016518491A JP 2016509026 A JP2016509026 A JP 2016509026A JP 2016509026 A JP2016509026 A JP 2016509026A JP 2016518491 A JP2016518491 A JP 2016518491A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- polyacrylic acid
- less
- molecular weight
- aqueous composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002125 Sokalan® Polymers 0.000 title claims abstract description 28
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000004584 polyacrylic acid Substances 0.000 title claims abstract description 27
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000005260 corrosion Methods 0.000 title claims description 16
- 230000007797 corrosion Effects 0.000 title claims description 16
- 238000000034 method Methods 0.000 title claims description 6
- 239000003112 inhibitor Substances 0.000 title description 3
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims description 5
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 4
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical group [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 4
- 230000002401 inhibitory effect Effects 0.000 claims description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
- 239000000178 monomer Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- -1 acrylyl esters Chemical class 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- JQRRFDWXQOQICD-UHFFFAOYSA-N biphenylen-1-ylboronic acid Chemical compound C12=CC=CC=C2C2=C1C=CC=C2B(O)O JQRRFDWXQOQICD-UHFFFAOYSA-N 0.000 description 2
- 239000008397 galvanized steel Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/105—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances combined with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/06—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in markedly alkaline liquids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/173—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/16—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions using inhibitors
- C23G1/18—Organic inhibitors
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/08—Corrosion inhibition
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
Description
Claims (10)
- 少なくとも11のpHを有し、(a)2〜15重量%の金属次亜塩素酸塩、及び(b)少なくとも40,000の重量平均分子量を有する0.2〜4重量%のポリアクリル酸を含む、水性組成物。
- 前記水性組成物が、少なくとも12のpHを有する、請求項1に記載の前記組成物。
- 前記ポリアクリル酸が、少なくとも100,000の重量平均分子量を有する、請求項2に記載の前記組成物。
- 0.5〜2重量%の前記ポリアクリル酸を含む、請求項3に記載の前記組成物。
- 前記金属次亜塩素酸塩が、次亜塩素酸ナトリウムである、請求項4に記載の前記組成物。
- 4〜11重量%の次亜塩素酸ナトリウムを含む、請求項5に記載の前記組成物。
- 少なくとも40,000の数平均分子量を有する0.2〜4重量%のポリアクリル酸を添加することによって、少なくとも11のpH及び2〜15重量%の金属次亜塩素酸塩を有する水性組成物の腐食を抑制するための方法。
- 前記水性組成物が、液体排水管洗浄剤である、請求項7に記載の前記方法。
- 前記排水管洗浄剤が、少なくとも12のpHを有する、請求項8に記載の前記方法。
- 前記ポリアクリル酸が、少なくとも100,000の重量平均分子量を有し、前記水性組成物が、0.5〜2重量%の前記ポリアクリル酸を含み、前記水性組成物が、4〜11重量%の次亜塩素酸ナトリウムを含む、請求項9に記載の前記方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361812855P | 2013-04-17 | 2013-04-17 | |
US61/812,855 | 2013-04-17 | ||
PCT/US2014/034094 WO2014172318A1 (en) | 2013-04-17 | 2014-04-15 | High molecular weight polyacrylic acids as corrosion inhibitors in an alkaline hypochlorite aqueous composition and method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016518491A true JP2016518491A (ja) | 2016-06-23 |
JP6474787B2 JP6474787B2 (ja) | 2019-02-27 |
Family
ID=50686241
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016509026A Active JP6474787B2 (ja) | 2013-04-17 | 2014-04-15 | アルカリ性次亜塩素酸塩水性組成物中の腐食抑制剤としての高分子量ポリアクリル酸及びその方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20160040102A1 (ja) |
EP (1) | EP2956571B1 (ja) |
JP (1) | JP6474787B2 (ja) |
CN (1) | CN105143516A (ja) |
AU (1) | AU2014254124B2 (ja) |
BR (1) | BR112015025070A2 (ja) |
WO (1) | WO2014172318A1 (ja) |
Citations (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6059081A (ja) * | 1983-09-09 | 1985-04-05 | Kurita Water Ind Ltd | 防食方法 |
JPS63273700A (ja) * | 1987-04-03 | 1988-11-10 | サンド アクチェンゲゼルシャフト | 液体漂白剤含有洗剤組成物 |
JPS644699A (en) * | 1987-06-12 | 1989-01-09 | Unilever Nv | Liquid detergent composition for dish washing machine |
JPH0243299A (ja) * | 1988-06-09 | 1990-02-13 | Procter & Gamble Co:The | 漂白剤安定性非イオン界面活性剤を含有する液体自動皿洗い洗剤組成物 |
JPH0270799A (ja) * | 1988-06-09 | 1990-03-09 | Procter & Gamble Co:The | 銀保護を与える液体自動皿洗い洗剤組成物 |
JPH02289699A (ja) * | 1989-02-13 | 1990-11-29 | Procter & Gamble Co:The | ガラス食品保護を与える液体自動皿洗い組成物 |
US5053158A (en) * | 1989-05-18 | 1991-10-01 | Colgate-Palmolive Company | Linear viscoelastic aqueous liquid automatic dishwasher detergent composition |
EP0541203A1 (en) * | 1991-11-08 | 1993-05-12 | Colgate-Palmolive Company | Linear viscoelastic aqueous liquid automatic dishwasher detergent composition |
JPH0680999A (ja) * | 1991-12-30 | 1994-03-22 | Unilever Nv | 自動食器洗浄機用液体組成物 |
JPH06235000A (ja) * | 1993-01-11 | 1994-08-23 | Clorox Co | 漂白臭の減少した濃厚化次亜塩素酸塩溶液とその製造及び使用方法 |
US5688756A (en) * | 1993-07-27 | 1997-11-18 | The Clorox Company | Gelled hypochlorite-based cleaner |
EP0812909A1 (en) * | 1996-06-10 | 1997-12-17 | The Procter & Gamble Company | Use of a polycarboxylate polymer to reduce bleach malodour on skin |
JPH11501067A (ja) * | 1995-02-28 | 1999-01-26 | ケイ ケミカル カンパニー | 食器洗浄用濃縮液体ゲル洗剤 |
JP2001525452A (ja) * | 1997-12-04 | 2001-12-11 | ザ ビー.エフ.グッドリッチ カンパニー | 濃化漂白剤組成物 |
JP2006150267A (ja) * | 2004-11-30 | 2006-06-15 | Aquas Corp | ボイラ水系処理剤、及び、それを用いたボイラ水系の処理方法 |
JP2006225742A (ja) * | 2005-02-21 | 2006-08-31 | Aquas Corp | ボイラ水系処理剤、及び、それを用いたボイラ水系の処理方法 |
JP2012532245A (ja) * | 2009-07-06 | 2012-12-13 | プレストーン プロダクツ コーポレイション | アルミニウム構成部分を有する伝熱系の洗浄のための方法および組成 |
JP2013053182A (ja) * | 2011-09-01 | 2013-03-21 | Kao Corp | アルマイト用洗浄剤組成物 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4388204A (en) * | 1982-03-23 | 1983-06-14 | The Drackett Company | Thickened alkali metal hypochlorite compositions |
US5413727A (en) * | 1985-06-14 | 1995-05-09 | Colgate Palmolive Co. | Thixotropic aqueous compositions containing long chain saturated fatty acid stabilizers |
GB9505675D0 (en) * | 1995-03-21 | 1995-05-10 | Diversey Corp | Cleaning compositions |
US5783537A (en) * | 1996-03-05 | 1998-07-21 | Kay Chemical Company | Enzymatic detergent composition and method for degrading and removing bacterial cellulose |
GB2325243A (en) * | 1997-05-13 | 1998-11-18 | Procter & Gamble | Removing tarnish from tarnished silverware |
US6660702B2 (en) * | 2000-12-08 | 2003-12-09 | The Clorox Company | Binary foaming drain cleaner |
US20050079990A1 (en) * | 2003-10-10 | 2005-04-14 | Stephen Chan | Cleaning compositions with both viscous and elastic properties |
WO2012085830A2 (en) * | 2010-12-21 | 2012-06-28 | Ecolab Usa Inc. | CORROSION INHIBITION OF HYPOCHLORITE SOLUTIONS USING POLYACRYLATE AND Ca, Zn AND Ca, SUGAR ACIDS AND Ca |
-
2014
- 2014-04-15 EP EP14722964.5A patent/EP2956571B1/en active Active
- 2014-04-15 US US14/784,311 patent/US20160040102A1/en not_active Abandoned
- 2014-04-15 AU AU2014254124A patent/AU2014254124B2/en not_active Ceased
- 2014-04-15 WO PCT/US2014/034094 patent/WO2014172318A1/en active Application Filing
- 2014-04-15 JP JP2016509026A patent/JP6474787B2/ja active Active
- 2014-04-15 CN CN201480021980.1A patent/CN105143516A/zh active Pending
- 2014-04-15 BR BR112015025070A patent/BR112015025070A2/pt not_active Application Discontinuation
Patent Citations (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6059081A (ja) * | 1983-09-09 | 1985-04-05 | Kurita Water Ind Ltd | 防食方法 |
JPS63273700A (ja) * | 1987-04-03 | 1988-11-10 | サンド アクチェンゲゼルシャフト | 液体漂白剤含有洗剤組成物 |
JPS644699A (en) * | 1987-06-12 | 1989-01-09 | Unilever Nv | Liquid detergent composition for dish washing machine |
JPH0243299A (ja) * | 1988-06-09 | 1990-02-13 | Procter & Gamble Co:The | 漂白剤安定性非イオン界面活性剤を含有する液体自動皿洗い洗剤組成物 |
JPH0270799A (ja) * | 1988-06-09 | 1990-03-09 | Procter & Gamble Co:The | 銀保護を与える液体自動皿洗い洗剤組成物 |
JPH02289699A (ja) * | 1989-02-13 | 1990-11-29 | Procter & Gamble Co:The | ガラス食品保護を与える液体自動皿洗い組成物 |
US5053158A (en) * | 1989-05-18 | 1991-10-01 | Colgate-Palmolive Company | Linear viscoelastic aqueous liquid automatic dishwasher detergent composition |
EP0541203A1 (en) * | 1991-11-08 | 1993-05-12 | Colgate-Palmolive Company | Linear viscoelastic aqueous liquid automatic dishwasher detergent composition |
JPH0680999A (ja) * | 1991-12-30 | 1994-03-22 | Unilever Nv | 自動食器洗浄機用液体組成物 |
JPH06235000A (ja) * | 1993-01-11 | 1994-08-23 | Clorox Co | 漂白臭の減少した濃厚化次亜塩素酸塩溶液とその製造及び使用方法 |
US5688756A (en) * | 1993-07-27 | 1997-11-18 | The Clorox Company | Gelled hypochlorite-based cleaner |
JPH11501067A (ja) * | 1995-02-28 | 1999-01-26 | ケイ ケミカル カンパニー | 食器洗浄用濃縮液体ゲル洗剤 |
EP0812909A1 (en) * | 1996-06-10 | 1997-12-17 | The Procter & Gamble Company | Use of a polycarboxylate polymer to reduce bleach malodour on skin |
JP2001525452A (ja) * | 1997-12-04 | 2001-12-11 | ザ ビー.エフ.グッドリッチ カンパニー | 濃化漂白剤組成物 |
JP2006150267A (ja) * | 2004-11-30 | 2006-06-15 | Aquas Corp | ボイラ水系処理剤、及び、それを用いたボイラ水系の処理方法 |
JP2006225742A (ja) * | 2005-02-21 | 2006-08-31 | Aquas Corp | ボイラ水系処理剤、及び、それを用いたボイラ水系の処理方法 |
JP2012532245A (ja) * | 2009-07-06 | 2012-12-13 | プレストーン プロダクツ コーポレイション | アルミニウム構成部分を有する伝熱系の洗浄のための方法および組成 |
JP2013053182A (ja) * | 2011-09-01 | 2013-03-21 | Kao Corp | アルマイト用洗浄剤組成物 |
Also Published As
Publication number | Publication date |
---|---|
EP2956571B1 (en) | 2019-05-22 |
AU2014254124A1 (en) | 2015-11-12 |
AU2014254124B2 (en) | 2018-05-17 |
CN105143516A (zh) | 2015-12-09 |
US20160040102A1 (en) | 2016-02-11 |
EP2956571A1 (en) | 2015-12-23 |
JP6474787B2 (ja) | 2019-02-27 |
BR112015025070A2 (pt) | 2017-07-18 |
WO2014172318A1 (en) | 2014-10-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4923634A (en) | Cooling water corrosion inhibition method | |
JP6637075B2 (ja) | 自動食器洗浄洗剤 | |
CN103352226B (zh) | 一种用于防止黄铜制品腐蚀的缓蚀剂 | |
CN103642612A (zh) | 一种飞机管道用清洗剂及制备方法 | |
JPH0215184A (ja) | モリブデン酸塩組成物による腐食抑制法 | |
JPWO2012132892A1 (ja) | 逆浸透膜用スケール防止剤及びスケール防止方法 | |
CN109295464A (zh) | 一种多功能环保稀土清洗剂及其制备方法 | |
JP2016534208A (ja) | 相乗的にスケールを抑制する自動食器洗浄用洗剤 | |
JP2019515134A (ja) | 材料の腐食除去が低減される金属表面の防食処理のための方法 | |
JP6474787B2 (ja) | アルカリ性次亜塩素酸塩水性組成物中の腐食抑制剤としての高分子量ポリアクリル酸及びその方法 | |
RU2458184C1 (ru) | Ингибитор коррозии | |
JP2008240132A (ja) | 腐食抑制剤 | |
JP4859158B2 (ja) | 水処理組成物 | |
JPS6342381A (ja) | 銅および銅合金の腐食を抑制する方法 | |
EP1088794A2 (en) | Polymers containing styrene and unsaturated polycarboxylates as monomers for high stressed water treatment application | |
EP2609185B1 (en) | Liquid cleaner for automated instrument processing | |
JP6407616B2 (ja) | 開放循環式冷却水システムの初期処理方法 | |
JP2006334495A (ja) | シリカ系汚れの付着防止剤、該付着防止剤用共重合体及び付着防止方法 | |
JP2012525242A (ja) | マレイン酸のホモポリマーおよびその塩のスケール防止剤および粘着防止剤としての使用 | |
US11220567B2 (en) | Hydrophobically modified acrylic rheology modifiers having high carbon number hydrophobes | |
JP5682727B2 (ja) | 冷却水系の水処理方法及び水処理剤 | |
JPH02133587A (ja) | 硫化物の作用抑制法 | |
JP4866275B2 (ja) | 金属製品用洗浄剤及び金属製品用洗浄剤水溶液 | |
JP2017222889A (ja) | 脱スケール剤 | |
JPH01299700A (ja) | 水系における金属類の腐食及びスケールの同時防止剤 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20160602 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170327 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180426 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180501 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180725 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190107 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190130 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6474787 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S802 | Written request for registration of partial abandonment of right |
Free format text: JAPANESE INTERMEDIATE CODE: R311802 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |