JP6637075B2 - 自動食器洗浄洗剤 - Google Patents
自動食器洗浄洗剤 Download PDFInfo
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- JP6637075B2 JP6637075B2 JP2017563500A JP2017563500A JP6637075B2 JP 6637075 B2 JP6637075 B2 JP 6637075B2 JP 2017563500 A JP2017563500 A JP 2017563500A JP 2017563500 A JP2017563500 A JP 2017563500A JP 6637075 B2 JP6637075 B2 JP 6637075B2
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- 229920000642 polymer Polymers 0.000 claims description 39
- 239000002270 dispersing agent Substances 0.000 claims description 28
- 150000003839 salts Chemical class 0.000 claims description 25
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 21
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 17
- -1 aminocarboxylate compound Chemical class 0.000 claims description 17
- 239000007844 bleaching agent Substances 0.000 claims description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 13
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- DCCWEYXHEXDZQW-BYPYZUCNSA-N (2s)-2-[bis(carboxymethyl)amino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O DCCWEYXHEXDZQW-BYPYZUCNSA-N 0.000 claims description 9
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
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- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- HSXUNHYXJWDLDK-UHFFFAOYSA-N 2-hydroxypropane-1-sulfonic acid Chemical compound CC(O)CS(O)(=O)=O HSXUNHYXJWDLDK-UHFFFAOYSA-N 0.000 description 2
- MAGFQRLKWCCTQJ-UHFFFAOYSA-N 4-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(C=C)C=C1 MAGFQRLKWCCTQJ-UHFFFAOYSA-N 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 2
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- 238000001994 activation Methods 0.000 description 2
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- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
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- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 2
- 235000008960 ketchup Nutrition 0.000 description 2
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- 239000006072 paste Substances 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
Landscapes
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- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Description
本出願は、2015年3月20日に出願された欧州特許出願第15290079.1号に対する優先権を主張する。
分散剤ポリマー1.14,000〜18,000のMwを有する、72重量%のアクリル酸及び28重量%の2−アクリルアミド−2−メチルプロパンスルホン酸ナトリウム塩を基とするコポリマー。ポリマーは、既知の方法を使用して当業者により調製され得る。典型的な手順は、以下の通りである。
この実施例において、洗剤配合物を、食べ物汚れがない状態で試験する。よって、この実施例は、無機質垢の堆積を調査する。MDGA、ADSA、またはGLDAを含有する配合物3及び4(表1)を、この実施例で試験する。食べ物汚れが存在しないため、配合物3及び4には酵素を添加しない。粉末状構成成分を予備混合し、液体構成成分と共に食器洗浄機に添加して、不適合材料の事前反応を防ぐ。
食べ物汚れこの実施例で使用されたSTIWAの食べ物汚れ試料は、表4に示される(「STIWA」は、試験グループStiftung Warentestにより設定された標準物食べ物汚れである)。
この実施例において、水の硬度の点で米国での条件よりも概して過酷である西ヨーロッパで典型的に使用される清浄条件下で性能を試験する。加えて、食べ物汚れ組成物において卵黄をより多く使用することにより、試験の課題をさらに増やす(卵黄は斑形成を高める)。この実施例の試験条件は、以下の通りである。
試験された配合物は、表8に示される。各サイクルにおいて、全ての粉末成分を一緒に混合し、機械に液体構成成分と同時に添加する。
外気で乾燥させた後、ガラスを、訓練を受けた観察者により汚れ形成及び斑形成の両方について、1(清浄)〜5(大量の汚れ有り)に評価する(評価システムの詳細については上記を参照されたい)。結果は、以下の表に示される。発明の配合物は、ASDAを含有する。比較の配合物は、MGDAまたはGLDAを含有するが、ASDAを含有しない。
この実施例において、ASDAを含有する自動食器洗浄洗剤(ADW)に対するステンレス鋼の耐食性を、MGDAまたはGLDA(及びASDA不含)の配合物と比較する。
腐食試験を、ステンレス鋼SS430試験片で行い、試験片を、代表的な市販のOneidaブランドのステンレス鋼の食卓用金物から調製する。ASTM Designation:G31−72(「金属の実験室浸漬腐食試験の標準的実施」(Standard Practice for Laboratory Immersion Corrosion Testing of Metals))、ASTM Designation:G1−03(「腐食試験片の調製、清浄、評価の標準プラクティス」(Standard Practice for Preparing,Cleaning,and Evaluating Corrosion Test Specimens))、及びNACE Standard TM−01−69(「試験方法−加工業界における金属の実験室腐食試験」(Test Method−Laboratory Corrosion Testing of Metals for the Process Industries))に従って、試験を実質的に実行する。
(態様)
(態様1)
自動食器洗浄洗剤組成物であって、
アスパラギン酸二酢酸またはその塩と、
2,000〜100,000のMwを有する(メタ)アクリルポリマーを含む分散剤ポリマーと、
ビルダーと、
界面活性剤と、を含む、自動食器洗浄洗剤組成物。
(態様2)
水溶性ケイ酸塩をさらに含む、態様1に記載の組成物。
(態様3)
前記分散剤が、(メタ)アクリル酸のホモポリマー、メタクリル酸及びアクリル酸のコポリマー、1つ以上の他のエチレン性不飽和モノマーとの(メタ)アクリル酸のコポリマー、それらの塩、またはそれらの混合物を含む、態様1また2に記載の組成物。
(態様4)
前記1つ以上の他のエチレン性不飽和モノマーが、アクリルまたは(メタ)アクリル酸のエステル(例えば、アクリル酸エチル、アクリル酸ブチル)、スチレンモノマー(例えば、スチレン)、スルホン化モノマー(例えば、2−アクリルアミド−2−メチルプロパンスルホン酸(AMPS)、2−(メタ)アクリルアミド−2−メチルプロパンスルホン酸、4−スチレンスルホン酸、ビニルスルホン酸、3−アリルオキシ、2−ヒドロキシ1−プロパンスルホン酸(HAPS)、2−スルホエチル(メタ)アクリル酸、2−スルホプロピル(メタ)アクリル酸、3−スルホプロピル(メタ)アクリル酸、及び4−スルホブチル(メタ)アクリル酸、それらの塩)、置換(メタ)アクリルアミド(例えば、tert−ブチルアクリルアミド)、及びそれらの塩のうちの1つ以上から選択される、態様3に記載の組成物。
(態様5)
前記分散剤ポリマーが、50〜95重量パーセントのアクリル酸、及び5〜50重量パーセントの2−アクリルアミド−2−メチルプロパンスルホン酸ナトリウム塩の重合単位に由来するコポリマーを含む、態様1〜4のいずれか一項に記載の組成物。
(態様6)
前記分散剤ポリマーが、アクリル酸の重合単位に由来するホモポリマーを含む、態様1〜3のいずれか一項に記載の組成物。
(態様7)
各々が、前記組成物の総重量に基づいて、
10〜40重量パーセントの前記アスパラギン酸二酢酸またはその塩と、
0.1〜10重量パーセントの水溶性ケイ酸塩と、
1〜10重量パーセントの前記分散剤ポリマーと、
1〜60重量パーセントの前記ビルダーと、
1〜10重量パーセントの前記界面活性剤と、を含む、態様1〜6のいずれか一項に記載の組成物。
(態様8)
漂白剤、ならびに任意に漂白活性化剤、及び/もしくは漂白触媒;酵素;またはアミノカルボン酸塩化合物のうちの1つ以上をさらに含む、態様1〜7のいずれか一項に記載の組成物。
(態様9)
前記組成物が、0.2重量パーセント未満のリンを含有する、態様1〜8のいずれか一項に記載の組成物。
(態様10)
自動食器洗浄機内で物品を清浄する方法であって、態様1〜9のいずれか一項に記載の組成物を前記物品に適用することを含む、方法。
Claims (7)
- 自動食器洗浄洗剤組成物であって、
各々が、前記組成物の総重量に基づいて、
10〜40重量パーセントのアスパラギン酸二酢酸またはその塩と、
3〜8重量パーセントの水溶性ケイ酸塩と、
2,000〜100,000のMwを有するアクリルポリマーを含む1〜4重量パーセントの分散剤ポリマーと、
1〜60重量パーセントのビルダーと、
1〜10重量パーセントの界面活性剤と、を含み
前記分散剤ポリマーが、50〜95重量パーセントのアクリル酸、及び5〜50重量パーセントの2−アクリルアミド−2−メチルプロパンスルホン酸ナトリウム塩の重合単位に由来するコポリマーを含む、自動食器洗浄洗剤組成物。 - 前記分散剤ポリマーが、(メタ)アクリル酸のホモポリマー、メタクリル酸及びアクリル酸のコポリマー、それらの塩、またはそれらの混合物をさらに含む、請求項1に記載の組成物。
- 前記分散剤ポリマーが、アクリル酸のホモポリマー、その塩、またはそれらの混合物をさらに含む請求項1に記載の組成物。
- 各々が、前記組成物の総重量に基づいて、
10〜40重量パーセントの前記アスパラギン酸二酢酸またはその塩と、
5〜6重量パーセントの水溶性ケイ酸塩と、
1〜4重量パーセントの前記分散剤ポリマーと、
1〜60重量パーセントの前記ビルダーと、
1〜10重量パーセントの前記界面活性剤と、を含む、請求項1〜3のいずれか一項に記載の組成物。 - 漂白剤、ならびに任意に漂白活性化剤、及び/もしくは漂白触媒;酵素;またはアミノカルボン酸塩化合物のうちの1つ以上をさらに含む、請求項1〜4のいずれか一項に記載の組成物。
- 前記組成物中のリンが、0.2重量パーセント未満である、請求項1〜5のいずれか一項に記載の組成物。
- 自動食器洗浄機内で物品を清浄する方法であって、請求項1〜6のいずれか一項に記載の組成物を前記物品に適用することを含む、方法。
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PCT/US2016/018935 WO2016153668A1 (en) | 2015-03-20 | 2016-02-22 | Automatic dishwashing detergent |
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CN110023473A (zh) * | 2016-12-16 | 2019-07-16 | 罗门哈斯公司 | 用于控制自动洗碗系统中污斑沾染的添加剂 |
PL3601512T3 (pl) | 2017-03-30 | 2021-10-25 | Dow Global Technologies Llc | Kompozycje do automatycznego mycia naczyń z mieszanką środka dyspergującego |
JP7162002B2 (ja) * | 2017-03-30 | 2022-10-27 | ダウ グローバル テクノロジーズ エルエルシー | 自動食器洗浄配合物用分散剤系 |
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BR112017018859A2 (pt) | 2018-04-24 |
EP3271446B1 (en) | 2022-07-27 |
BR112017018859B1 (pt) | 2022-12-13 |
US10392585B2 (en) | 2019-08-27 |
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