JP2016513141A - マイクロカプセル、一級又は二級アミン、及びホルムアルデヒドスカベンジャーを含む、処理組成物 - Google Patents
マイクロカプセル、一級又は二級アミン、及びホルムアルデヒドスカベンジャーを含む、処理組成物 Download PDFInfo
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- JP2016513141A JP2016513141A JP2015552908A JP2015552908A JP2016513141A JP 2016513141 A JP2016513141 A JP 2016513141A JP 2015552908 A JP2015552908 A JP 2015552908A JP 2015552908 A JP2015552908 A JP 2015552908A JP 2016513141 A JP2016513141 A JP 2016513141A
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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Abstract
Description
処理組成物は、持続性のある使用中の匂い効果をもたらすために、マイクロカプセルを含む。マイクロカプセルは、通常、マイクロカプセルスラリーの一部として処理組成物に添加される。処理組成物は、好ましくは、処理組成物の0.01重量%〜12.5重量%、好ましくは0.1重量%〜2.5重量%、より好ましくは0.15重量%〜1重量%の濃度のマイクロカプセルを含む。処理組成物は、好ましくは、マイクロカプセルコアに含まれる香料が、処理組成物の0.01重量%〜10重量%、好ましくは0.1重量%〜2重量%、より好ましくは0.15重量%〜0.75重量%の濃度で処理組成物中に存在するような濃度のマイクロカプセルを含む。
本発明の処理組成物は、洗剤組成物、好ましくは洗濯洗剤組成物であり得る。洗剤組成物は、洗浄性効果をもたらすための界面活性剤を含む。本発明の洗剤組成物は、アニオン性活性剤、非イオン性界面活性剤、及びこれらの混合物からなる群から選択される界面活性剤を、1重量%〜70重量%、好ましくは5重量%〜60重量%、より好ましくは10重量%〜50重量%、最も好ましくは15重量%〜45重量%含み得る。アニオン性界面活性剤の非イオン性界面活性剤に対する好ましい重量比は、100:0(即ち、非イオン性界面活性剤が存在しない)〜5:95、より好ましくは99:1〜1:4、最も好ましくは5:1〜1.5:1である。
処理組成物は、布地柔軟化組成物であってよい。このような布地柔軟化組成物は、布地柔軟化活性物質(「FSA」)を含む。好適な布地柔軟化活性物質としては、クワット(quats)、アミン、脂肪酸エステル、ショ糖エステル、シリコーン、分散性ポリオレフィン、粘土、多糖類、脂肪油、ポリマーラテックス、及びこれらの混合物からなる群から選択される物質が挙げられる。
処理組成物は、マイクロカプセルを含む。マイクロカプセルは、マイクロカプセルコアと、マイクロカプセルコアを取り囲むマイクロカプセル壁と、を含む。マイクロカプセル壁は、ホルムアルデヒドと少なくとも1つの他のモノマーとを架橋させることによって形成される。用語「マイクロカプセル」は、本明細書で使用するとき、最も広義で、マイクロカプセル壁に被包されているコアを含むことを意味する。次に、マイクロカプセルコアは、香料を含む。被包される香料は、アルデヒド、ケトン、及びこれらの混合物から選択される香料原材料と、任意で希釈剤と、を含む。
処理組成物は、少なくとも1つの一級又は二級アミンを含む。好適な一級又は二級アミンは、アルカノールアミン、ポリアミン、及びこれらの混合物から選択され得る。
本発明の処理組成物のマイクロカプセルは、ホルムアルデヒドと少なくとも1つの他のモノマーとを架橋させることによって作製される壁を含む。架橋反応が完了した後、遊離ホルムアルデヒドの残量が残る。架橋剤等の追加成分とともに更なるホルムアルデヒドを導入してもよい。更に、ホルムアルデヒドは、マイクロカプセルが経時劣化するにつれて放出される。理論に束縛されるものではないが、遊離ホルムアルデヒド濃度は、架橋マイクロカプセル壁における残留物の硬化及び末端基の加水分解に起因して上昇すると考えられる。したがって、遊離ホルムアルデヒド濃度が確実に許容可能な濃度のままであるように、ホルムアルデヒドスカベンジャーを処理組成物に添加する。
本発明の組成物は、部位と本発明の処理組成物とを接触させることによって、この部位に長時間匂い効果をもたらす方法において用いることができる。典型的に、長時間の匂い効果は、25℃でアルミニウム箔に包んだ状態で1週間、好ましくは2週間、より好ましくは4週間、棚で布地を保存した後、乾燥部位を擦った際に香料の匂い効果を提供することである。
A)pH測定:
pHは、取扱説明書に従って較正したジェル充填プローブ(例えば、Toledoプローブ、部品番号52 000 100)を備えるSartarius PT−10P pHメータを用いて、25℃で、未希釈組成物に対して測定する。
匂い検出閾値は、本明細書で以下に説明される制御されたガスクロマトグラフィー(GC)条件で測定する。このパラメータは、香料分野で一般的に使用される値を指し、幾つかの匂い物質が存在するという有意な検出が行われる最低濃度である。例えば、「Compilation of Odor and Taste Threshold Value Data(ASTM DS 48 A)」、F.A.Fazzalari編,International Business Machines,Hopwell Junction,NY及びCalkin et al.,Perfumery,Practice and Principles,John Willey & Sons,Inc.,243頁以下(1994)を参照されたい。本発明の目的のために、匂い検出閾値を、以下の方法に従って測定する:
ガスクロマトグラフは、シリンジで注入した材料の正確な体積、精密なスプリット比、並びに既知の濃度及び鎖長分布の炭化水素標準を用いた炭化水素反応を決定するために特徴付けられる。空気流量を正確に測定し、ヒトの吸入の時間が0.02分間持続すると仮定して、サンプリングした体積を計算する。任意の時点の検出器における正確な濃度は既知であるため、吸入された体積当たりの質量、したがって材料の濃度も既知である。香料材料のODTを決定するために、逆算した濃度でスニッフポートに溶液を送達する。官能試験員がGC溶出物を嗅ぎ、匂いを感知したときの保持時間を同定する。全ての官能試験員の平均から感知能の閾値を決定する。検出器において10ppb等の特定の濃度を得るために、必要な量の分析物をカラムに注入する。匂い検出閾値を決定するための典型的なガスクロマトグラフパラメータを以下に列挙する。
GC:FID検出器を備える5890 Series II
7673オートサンプラー
カラム:J&W Scientific DB−1
長さ30メートル、ID 0.25mm、膜厚1マイクロメートル
方法:
分割注入:17/1スプリット比
オートサンプラー:1.13マイクロリットル/注入
カラム流量:1.10mL/分
空気流:345mL/分
入口温度:245℃
検出器温度:285℃
温度情報
初期温度:50℃
速度:5℃/分
最終温度:280℃
最終時間:6分
主な仮定:一嗅ぎ当たり0.02分間
GC空気をサンプル希釈物に添加する。
3 Sokalan PG 640(BASF製)
4 −NH当たり20個のエトキシレート基を含むポリエチレンイミン(MW=600)
5 被包されていない香料は、17.8重量%のアルデヒド及びケトンを含んでいた。
サンプルに気泡が確実に入らないように、プラスチックキュベット(寸法12.5×12.5×45mm、BRAND製、カタログ番号7590 05)に分析する処理組成物を充填した。Hunterlab Color Quest XEを用いて色を測定し、前記測定は、反射モードで、D65/10光条件下にて、9.5mmの開口で行った。「作ったばかりの」処理組成物(作製し、21℃で保存した1時間後に測定)及びエージングした処理組成物の両方について、Labスケールで色を測定した。色ΔEの変化として表される変色を、以下の等式を用いてLab値から計算した:ΔE=(ΔL2+Δa2+Δb2)1/2:
メラミンとホルムアルデヒドとの架橋から形成されるマイクロカプセル壁、及び香料を含有するアルデヒド又はケトンを含むコアを有するマイクロカプセルと、尿素、ピロガロール、及び1,2ヘキサンジオールから選択されるホルムアルデヒドスカベンジャーと、を含む本発明の処理組成物の非限定的な例を、以下の表に開示する:
7 蛍光増白剤は、Tinopal(登録商標)AMS−GX、Tinopal(登録商標)CBS−X、若しくはTinopal(登録商標)TAS−X B36、又はこれらの混合物のいずれかであってよく、全てCiba Specialty Chemicals(Basel,Switzerland)によって供給される。
8 メラミンとホルムアルデヒドとの架橋から形成される壁を有し、香料を含有するアルデヒド又はケトンを含む、マイクロカプセルを35重量%含む、香料マイクロカプセルスラリー。
9 液体洗濯処理組成物に直接添加するか、又はマイクロカプセルスラリーに添加し、次いで、それを処理組成物に添加する。
Claims (15)
- 処理組成物であって、
(a)マイクロカプセルコア及び前記マイクロカプセルコアを被包するマイクロカプセル壁を含むマイクロカプセルであって、
(i)前記マイクロカプセル壁が、ホルムアルデヒドを少なくとも1つの他のモノマーと架橋させることによって形成され、
(ii)前記マイクロカプセルコアが、香料を含み、前記香料が、アルデヒド、ケトン、及びこれらの混合物からなる群から選択される香料原材料を含む、マイクロカプセルと、
(b)一級又は二級アミンと、
(c)尿素、ピロガロール、1,2ヘキサンジオール、及びこれらの混合物からなる群から選択されるホルムアルデヒドスカベンジャーと、
を含む、処理組成物。 - 前記マイクロカプセル壁の前記少なくとも1つの他のモノマーが、メラミン、尿素、グリコウリル、ベンゾグアニン、ジヒドロキシエチレンウレア、ヒドロキシ(アルコキシ)アルキレンウレアモノマー、及びこれらの混合物からなる群から選択される、請求項1に記載の処理組成物。
- 前記処理組成物の0.01重量%〜12.5重量%の濃度で前記マイクロカプセルを含む、請求項1又は2に記載の処理組成物。
- 前記マイクロカプセルコアに含まれる前記香料が、アルデヒド、ケトン、及びこれらの混合物からなる群から選択される前記香料原材料を0.1重量%〜100重量%含む、請求項1〜3のいずれか一項に記載の処理組成物。
- 前記香料原材料が、
(a)エチルバニリン[CAS番号:121−32−4]、トリプラール[CAS番号:68039−49−6]、ヘキシルシンナミックアルデヒド[CAS番号:101−86−0]、ウンデシレンアルデヒド[CAS番号:112−45−8]、パラ三級ブチルシンナミックアルデヒド[CAS番号:80−54−6]、ピノアセトアルデヒド[CAS番号:33885−51−7]、ピニルイソブチルアルデヒド[CAS番号:33885−52−8]、リラール[CAS番号:31906−04−4]、ヒドロシトロネラール[CAS番号:107−75−5]、メチルノニルアセトアルデヒド[CAS番号:110−41−8]、メチルオクチルアセトアルデヒド[CAS番号:19009−56−4]、2−[4−メチルフェニル)メチレン]−ヘプタナール[CAS番号:84697−09−6]、アミルシンナミックアルデヒド[CAS番号:7493−78−9]、ノニルアルデヒド[CAS番号:124−19−6]、2,6,10−トリメチル−9−ウンデセナール[CAS番号:141−13−9]、デシルアルデヒド[CAS番号:112−31−2]、ラウリンアルデヒド[CAS番号:112−54−9]、ウンデシルアルデヒド[CAS番号:1123−44−7]、サイマール[CAS番号:103−95−7]、2,4−ジメチル−3−シクロヘキセン−1−カルバルデヒド[CAS番号:68039−49−6]、3−(3−イソプロピルフェニル)ブタナール[CAS番号:125109−85−5]、シトラール[CAS番号:5392−40−5]、2,6−ジメチル−5−ヘプテナール[CAS番号:106−72−9]、p−トリルアセトアルデヒド[CAS番号:104−09−6]、アニスアルデヒド[CAS番号:123−11−5]、バニリン[CAS番号:121−33−5]、2−メチル−3−(4−メトキシフェニル)プロパナール[CAS番号:5462−06−6]、3−(プクメニル)プロピオンアルデヒド[CAS番号:7775−00−0]、3−(4−エチルフェニル)−2,2−ジメチルプロパナール[CAS番号:67634−14−4]、3−(1,3−ベンゾジオキソール−5−イル)−2−メチルプロパナール[CAS番号:1205−17−0]、リモネンアルデヒド[CAS番号:6784−13−0]、8,8−ジメチル−2,3,4,5,6,7−ヘキサヒドロ−1H−ナフタレン−2−カルバルデヒド[CAS番号:68991−97−9]、1−メチル−3−(4−メチルペンタ−3−エニル)シクロヘキサー3−エン−1−カルバルデヒド[CAS番号:52475−86−2]、及びこれらの混合物からなる群から選択される香料アルデヒド;
(b)ベンジルアセトン[CAS番号:2550−26−7]、α−イオノン[CAS番号:12741−3]、β−イオノン[CAS番号:14901−07−6]、γメチルイオノン[CAS番号:127−51−5]、イソダマスコーン[CAS番号:39872−57−6]、α−ダマスコーン[CAS番号:24720−09−0]、β−ダマスコーン[CAS番号:23726−91−2]、δ−ダマスコーン[CAS番号:57378−68−4]、ダマセノン[CAS番号:23696−85−7]、メチルセドリルケトン[CAS番号:32388−55−9]、ジヒドロジャスモン[CAS番号:11128−08−1]、ヘキシルシクロペンタノン[CAS番号:13074−65−2]、2−ヘプチルシクロペンタノン[CAS番号:137−03−1]、2−ペンチル−シクロペンタノン[CAS番号:4819−67−4]、3−メチル−2−ペンチルシクロペンタノン[CAS番号:13074−63−0]、2−ヘキシリデンシクロペンタノン[CAS番号:17373−86−6]、1−(5,5−ジメチル−1−シクロヘキセニル)ペンタ−4−エン−1−オン[CAS番号:56973−85−4]、メチル−β−ナフチルケトン[CAS番号:93−08−3]、β−ナフチルメチルエーテル[CAS番号:93−04−9]、4−メトキシアセトフェノン[CAS番号:100−06−1]、4−メチルアセトフェノン[CAS番号:122−06−1]、カシュメラン[CAS番号:33704−61−9]、4−(4−ヒドロキシフェニル)−2−ブタノン[CAS番号:5471−51−2]、メントン[CAS番号:1074−95−9]、3,4,5,6,−ペンタメチル−3−ヘプテン−2−オン[CAS番号:81786−73−4]、シス−ジャスモン[CAS番号:488−10−8]、メチルジヒドロジャスモネート[CAS番号:24851−98−7]、パラメチルアセトフェノン[CAS番号:122−00−9]、2−シクロヘキシル−1,6−ヘプタジエン−3−オン[CAS番号:313973−37−4]、2,4,4,7−テトラメチル−オクタ−6−エン3−オン[CAS番号:74338−72−0]、左旋性カルボン[CAS番号:6485−40−1]、及びこれらの混合物からなる群から選択される香料ケトン;並びに
(c)これらの混合物、
から選択される、請求項1〜4のいずれか一項に記載の処理組成物。 - 前記ホルムアルデヒドスカベンジャーが尿素である、請求項1〜5のいずれか一項に記載の処理組成物。
- 前記処理組成物の0.005重量%〜0.8重量%の濃度で前記ホルムアルデヒドスカベンジャーを含む、請求項1〜6のいずれか一項に記載の処理組成物。
- 前記処理組成物が、洗濯洗剤組成物、布地柔軟化組成物、及びこれらの組み合わせからなる群から選択される布地処理組成物である、請求項1〜7のいずれか一項に記載の処理組成物。
- 前記処理組成物が、被包されていない香料組成物を更に含み、前記被包されていない香料組成物が、アルデヒド、ケトン、及びこれらの混合物からなる群から選択される香料原材料を含む、請求項1〜8のいずれか一項に記載の処理組成物。
- 前記処理組成物が、ポリアミンを更に含む、請求項1〜9のいずれか一項に記載の処理組成物。
- 請求項1〜10のいずれか一項に記載の処理組成物を含む単位用量物品であって、前記処理組成物が、20重量%未満の水を含み、前記処理組成物が、水溶性又は水分散性のフィルムに封入される、単位用量物品。
- 透明又は半透明の容器に収容されている請求項1〜10のいずれか一項に記載の処理組成物又は請求項11に記載の単位用量物品を含む、包装された製品。
- マイクロカプセルを含む処理組成物における変色を防ぐための、尿素、ピロガロール、1,2ヘキサンジオール、及びこれらの混合物からなる群から選択されるホルムアルデヒドスカベンジャーの使用であって、前記マイクロカプセルが、マイクロカプセルコア及び前記マイクロカプセルコアを被包するマイクロカプセル壁を含み、
(i)前記マイクロカプセル壁が、ホルムアルデヒドを少なくとも1つの他のモノマーと架橋させることによって形成され、
(ii)前記マイクロカプセルコアが、香料を含み、前記香料が、アルデヒド、ケトン、及びこれらの混合物からなる群から選択される香料原材料を含む、使用。 - 部位と請求項1〜10のいずれか一項に記載の処理組成物とを接触させることによって、前記部位に長時間の匂い効果を提供する、方法。
- 前記部位が布地であり、前記布地を、好ましくは、自動洗浄機内で前記処理組成物と接触させる、請求項14に記載の方法。
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