JP2016503122A5 - - Google Patents
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- JP2016503122A5 JP2016503122A5 JP2015553053A JP2015553053A JP2016503122A5 JP 2016503122 A5 JP2016503122 A5 JP 2016503122A5 JP 2015553053 A JP2015553053 A JP 2015553053A JP 2015553053 A JP2015553053 A JP 2015553053A JP 2016503122 A5 JP2016503122 A5 JP 2016503122A5
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- JP
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- Prior art keywords
- resin composition
- compound
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- weight
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000001875 compounds Chemical class 0.000 claims description 61
- 239000011342 resin composition Substances 0.000 claims description 51
- 229920000642 polymer Polymers 0.000 claims description 41
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 37
- 229920002635 polyurethane Polymers 0.000 claims description 32
- 239000004814 polyurethane Substances 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 150000003077 polyols Chemical class 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 21
- 230000003472 neutralizing effect Effects 0.000 claims description 19
- 150000002433 hydrophilic molecules Chemical class 0.000 claims description 17
- 239000012736 aqueous medium Substances 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- 239000004970 Chain extender Substances 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 229920000582 polyisocyanurate Polymers 0.000 claims description 9
- 239000011495 polyisocyanurate Substances 0.000 claims description 9
- 229920005862 polyol Polymers 0.000 claims description 9
- 229920000515 polycarbonate Polymers 0.000 claims description 6
- 239000004417 polycarbonate Substances 0.000 claims description 6
- 150000007529 inorganic bases Chemical class 0.000 claims description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001450 anions Chemical group 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims description 2
- 125000003010 ionic group Chemical group 0.000 claims description 2
- 238000006386 neutralization reaction Methods 0.000 claims description 2
- 230000000269 nucleophilic effect Effects 0.000 claims description 2
- 229920005906 polyester polyol Polymers 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004815 dispersion polymer Substances 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 2
- 241000272470 Circus Species 0.000 description 1
- -1 Compound compound Chemical class 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004442 gravimetric analysis Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13151649.4A EP2757118A1 (en) | 2013-01-17 | 2013-01-17 | Radiation curable aqueous compositions with reversible drying. |
| EP13151649.4 | 2013-01-17 | ||
| PCT/EP2014/050506 WO2014111349A1 (en) | 2013-01-17 | 2014-01-13 | Radiation curable aqueous compositions with reversible drying |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018081305A Division JP2018138670A (ja) | 2013-01-17 | 2018-04-20 | 可逆性乾燥を伴う放射線硬化性水性組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016503122A JP2016503122A (ja) | 2016-02-01 |
| JP2016503122A5 true JP2016503122A5 (enExample) | 2018-02-01 |
| JP6573554B2 JP6573554B2 (ja) | 2019-09-11 |
Family
ID=47563247
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015553053A Active JP6573554B2 (ja) | 2013-01-17 | 2014-01-13 | 可逆性乾燥を伴う放射線硬化性水性組成物 |
| JP2018081305A Withdrawn JP2018138670A (ja) | 2013-01-17 | 2018-04-20 | 可逆性乾燥を伴う放射線硬化性水性組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018081305A Withdrawn JP2018138670A (ja) | 2013-01-17 | 2018-04-20 | 可逆性乾燥を伴う放射線硬化性水性組成物 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10487236B2 (enExample) |
| EP (2) | EP2757118A1 (enExample) |
| JP (2) | JP6573554B2 (enExample) |
| KR (1) | KR102100532B1 (enExample) |
| CN (1) | CN104955861B (enExample) |
| IL (1) | IL238940B (enExample) |
| TW (1) | TWI600710B (enExample) |
| WO (1) | WO2014111349A1 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6802712B2 (ja) | 2014-06-23 | 2020-12-16 | カーボン,インコーポレイテッド | 三次元物体の製造に使用する多様な硬化機構を有するポリウレタン樹脂 |
| KR20170115070A (ko) | 2015-02-05 | 2017-10-16 | 카본, 인크. | 비연속 노광에 의한 적층체 제조방법 |
| US10391711B2 (en) | 2015-03-05 | 2019-08-27 | Carbon, Inc. | Fabrication of three dimensional objects with multiple operating modes |
| US9458334B1 (en) | 2015-07-01 | 2016-10-04 | Electronics For Imaging, Inc. | Aqueous radiation curable ink composition |
| JP7069006B2 (ja) | 2015-09-04 | 2022-05-17 | カーボン,インコーポレイテッド | 積層造形用シアネートエステル二重硬化樹脂 |
| US10975193B2 (en) | 2015-09-09 | 2021-04-13 | Carbon, Inc. | Epoxy dual cure resins for additive manufacturing |
| US10647873B2 (en) | 2015-10-30 | 2020-05-12 | Carbon, Inc. | Dual cure article of manufacture with portions of differing solubility |
| WO2017079502A1 (en) | 2015-11-05 | 2017-05-11 | Carbon, Inc. | Silicone dual cure resins for additive manufacturing |
| WO2017112483A2 (en) | 2015-12-22 | 2017-06-29 | Carbon, Inc. | Accelerants for additive manufacturing with dual cure resins |
| WO2017112751A1 (en) | 2015-12-22 | 2017-06-29 | Carbon, Inc. | Blocked silicone dual cure resins for additive manufacturing |
| JP6944935B2 (ja) | 2015-12-22 | 2021-10-06 | カーボン,インコーポレイテッド | 二重硬化樹脂を用いた積層造形による複数の中間体からの複合生産物の製作 |
| US10343331B2 (en) | 2015-12-22 | 2019-07-09 | Carbon, Inc. | Wash liquids for use in additive manufacturing with dual cure resins |
| US10501572B2 (en) | 2015-12-22 | 2019-12-10 | Carbon, Inc. | Cyclic ester dual cure resins for additive manufacturing |
| EP3341792A1 (en) | 2015-12-22 | 2018-07-04 | Carbon, Inc. | Dual precursor resin systems for additive manufacturing with dual cure resins |
| WO2017112571A1 (en) | 2015-12-22 | 2017-06-29 | Carbon, Inc. | Dual cure additive manufacturing of rigid intermediates that generate semi-rigid, flexible, or elastic final products |
| US10500786B2 (en) | 2016-06-22 | 2019-12-10 | Carbon, Inc. | Dual cure resins containing microwave absorbing materials and methods of using the same |
| US10653135B2 (en) * | 2016-07-11 | 2020-05-19 | Covestro Llc | Methods for treating seeds with an aqueous composition and seeds treated therewith |
| US10941308B2 (en) | 2016-07-27 | 2021-03-09 | Sun Chemical Corporation | Water-based electrically-insulating energy-curable fluids |
| KR20190062529A (ko) * | 2016-10-13 | 2019-06-05 | 바스프 코팅스 게엠베하 | 지방족 모노카르복실산의 염을 기재로 하는 코팅재 시스템 |
| CN110023056B (zh) * | 2016-11-21 | 2021-08-24 | 卡本有限公司 | 通过递送反应性组分用于后续固化来制造三维物体的方法 |
| WO2018165090A1 (en) | 2017-03-09 | 2018-09-13 | Carbon, Inc. | Tough, high temperature polymers produced by stereolithography |
| US10316213B1 (en) | 2017-05-01 | 2019-06-11 | Formlabs, Inc. | Dual-cure resins and related methods |
| WO2018237038A1 (en) | 2017-06-21 | 2018-12-27 | Carbon, Inc. | Method of additive manufacturing |
| EP3677650B1 (en) | 2017-08-29 | 2022-09-28 | FUJIFILM Corporation | Ink composition, method for producing same, and image forming method |
| EP3728483B1 (en) * | 2017-12-22 | 2025-01-01 | Henkel AG & Co. KGaA | Undercoating and articles of manufacture coated therewith |
| JP2021516180A (ja) * | 2018-03-02 | 2021-07-01 | フォームラブス, インコーポレーテッドFormlabs, Inc. | 潜在性硬化樹脂および関連する方法 |
| US11053400B2 (en) | 2018-07-13 | 2021-07-06 | Sun Chemical Corporation | Electron beam-curable compositions comprising poly(alkoxylates) |
| US11504903B2 (en) | 2018-08-28 | 2022-11-22 | Carbon, Inc. | 1K alcohol dual cure resins for additive manufacturing |
| CN110498898A (zh) * | 2019-07-24 | 2019-11-26 | 浙江瑞通光电材料有限公司 | 一步法合成的紫外光固化的水溶性聚氨酯丙烯酸酯低聚物及其方法 |
| CN111072898B (zh) * | 2019-12-06 | 2022-03-11 | 上海华峰新材料研发科技有限公司 | 合成革用水性高透明性聚氨酯染料树脂及其制备方法 |
| CN113185910A (zh) * | 2021-05-20 | 2021-07-30 | 东莞市冠力胶业有限公司 | 一种水性替塑胶的涂布工艺 |
| US20250145756A1 (en) | 2022-03-18 | 2025-05-08 | Basf Se | Re-dispersible or re-soluble aqueous ethylenically unsaturated aqueous polyurethane compositions with improved water-resistance |
| CN120752275A (zh) * | 2023-02-21 | 2025-10-03 | 巴斯夫涂料有限公司 | 连续生产水性聚氨酯-聚脲分散体的方法和水性聚氨酯-聚脲分散体 |
| WO2024175286A1 (en) * | 2023-02-21 | 2024-08-29 | Basf Coatings Gmbh | Process for continuous production of aqueous polyurethane-polyurea dispersions |
| CN116135933B (zh) * | 2023-04-03 | 2024-02-09 | 苏州市贝特利高分子材料股份有限公司 | 一种水性丝网印刷油墨及其制备方法 |
| KR102815088B1 (ko) * | 2024-04-01 | 2025-05-29 | 구자은 | 필름 형성 및 박리성이 우수한 화장용 수분산 폴리우레탄, 그 제조 방법, 및 이를 포함하는 화장료 조성물 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1081906A (en) | 1975-09-02 | 1980-07-22 | Hans H. Kuhn | Fugitive tints |
| US4284729A (en) | 1980-03-31 | 1981-08-18 | Milliken Research Corporation | Process for coloring thermosetting resins |
| US4507407A (en) | 1984-06-25 | 1985-03-26 | Milliken Research Corporation | Process for in situ coloration of thermosetting resins |
| CA1243669A (en) | 1984-06-25 | 1988-10-25 | Edward W. Kluger | Reactive colorants |
| US4761502A (en) | 1986-09-08 | 1988-08-02 | Milliken Research Corporation | Polyalkyleneoxytrifluoromethylaniline compounds |
| US4751254A (en) | 1987-01-20 | 1988-06-14 | Milliken Research Corporation | Process for in situ coloration of thermosetting resins |
| US4846846A (en) | 1988-06-20 | 1989-07-11 | Milliken Research Corporation | Process for preparing polyurethane resins colored with anthraquinone colorants and products produced thereby |
| JP3310331B2 (ja) * | 1992-06-05 | 2002-08-05 | 大日本インキ化学工業株式会社 | 新規なエネルギー線硬化性樹脂組成物 |
| US5643356A (en) | 1993-08-05 | 1997-07-01 | Kimberly-Clark Corporation | Ink for ink jet printers |
| EP0732382B1 (en) | 1995-03-17 | 1999-06-02 | Toyo Ink Manufacturing Co., Ltd. | Inkjet ink and process for the production thereof |
| US5864002A (en) | 1996-10-18 | 1999-01-26 | Milliken Research Corporation | Process for coloring polymer resins and products thereof |
| DE19957604A1 (de) * | 1999-11-30 | 2001-05-31 | Bayer Ag | Polyurethan-Emulsionen |
| AU1057402A (en) * | 2000-10-25 | 2002-05-06 | Akzo Nobel Nv | Photoactivatable water borne coating composition |
| KR20040030831A (ko) | 2001-07-20 | 2004-04-09 | 유씨비 소시에떼아노님 | 조사 경화성 중합체 잉크 조성물 |
| US20040242763A1 (en) * | 2001-11-28 | 2004-12-02 | Michel Tielemans | Radiation-curable polyurethane dispersion |
| DE10360043A1 (de) * | 2003-12-18 | 2005-07-21 | Basf Ag | Mit Polyadditionsprodukten umhüllte Pigmente, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP2007002051A (ja) | 2005-06-22 | 2007-01-11 | Yokohama Rubber Co Ltd:The | アンダーコーティング剤組成物 |
| EP1845143A1 (en) | 2006-04-14 | 2007-10-17 | Cytec Surface Specialties, S.A. | Aqueous radiation curable polyurethane compositions |
| GB0612803D0 (en) * | 2006-06-28 | 2006-08-09 | Lucite Int Uk Ltd | Polymeric composition |
| DE102007026196A1 (de) | 2007-06-04 | 2008-12-11 | Basf Se | Verfahren zur Herstellung wasseremulgierbarer Polyurethanacrylate |
| JP4403312B2 (ja) * | 2008-05-22 | 2010-01-27 | Dic株式会社 | 水性複合樹脂組成物、それを含むコーティング剤、及びそれを用いた積層体 |
| EP2143748A1 (en) | 2008-07-10 | 2010-01-13 | Cytec Surface Specialties, S.A. | Aqueous radiation curable polyurethane compositions |
| DE102010003308A1 (de) * | 2009-03-31 | 2011-01-13 | Basf Se | Strahlungshärtbare wasseremulgierbare Polyurethan(meth)acrylate |
| CN102549060B (zh) * | 2009-07-31 | 2016-01-20 | 3M创新有限公司 | 含有多元醇化合物的含氟聚合物组合物及其制备方法 |
| GB201007043D0 (en) * | 2010-04-28 | 2010-06-09 | 3M Innovative Properties Co | Process for producing ptfe and articles thereof |
| EP2468782A1 (en) * | 2010-12-27 | 2012-06-27 | Cytec Surface Specialties, S.A. | Radiation curable compositions |
| JP5903765B2 (ja) * | 2011-03-15 | 2016-04-13 | 東ソー株式会社 | 高親水性の水性ポリウレタン樹脂分散組成物 |
| CN103608375B (zh) | 2011-06-14 | 2015-09-09 | 巴斯夫欧洲公司 | 可辐射固化聚氨酯水分散体 |
-
2013
- 2013-01-17 EP EP13151649.4A patent/EP2757118A1/en not_active Withdrawn
-
2014
- 2014-01-13 EP EP14700609.2A patent/EP2945973B2/en active Active
- 2014-01-13 KR KR1020157022045A patent/KR102100532B1/ko active Active
- 2014-01-13 WO PCT/EP2014/050506 patent/WO2014111349A1/en not_active Ceased
- 2014-01-13 US US14/648,456 patent/US10487236B2/en active Active
- 2014-01-13 JP JP2015553053A patent/JP6573554B2/ja active Active
- 2014-01-13 CN CN201480003673.0A patent/CN104955861B/zh active Active
- 2014-01-15 TW TW103101407A patent/TWI600710B/zh active
-
2015
- 2015-05-21 IL IL238940A patent/IL238940B/en active IP Right Grant
-
2018
- 2018-04-20 JP JP2018081305A patent/JP2018138670A/ja not_active Withdrawn
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