JP2015532611A5 - - Google Patents
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- Publication number
- JP2015532611A5 JP2015532611A5 JP2015523587A JP2015523587A JP2015532611A5 JP 2015532611 A5 JP2015532611 A5 JP 2015532611A5 JP 2015523587 A JP2015523587 A JP 2015523587A JP 2015523587 A JP2015523587 A JP 2015523587A JP 2015532611 A5 JP2015532611 A5 JP 2015532611A5
- Authority
- JP
- Japan
- Prior art keywords
- solution
- alcohol
- layer
- colloidal
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000243 solution Substances 0.000 claims 45
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 25
- 229910052751 metal Inorganic materials 0.000 claims 16
- 239000002184 metal Substances 0.000 claims 15
- 150000004770 chalcogenides Chemical class 0.000 claims 11
- 239000002105 nanoparticle Substances 0.000 claims 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 9
- 230000001476 alcoholic effect Effects 0.000 claims 9
- 239000007864 aqueous solution Substances 0.000 claims 8
- 238000000034 method Methods 0.000 claims 8
- 239000000758 substrate Substances 0.000 claims 8
- 239000002904 solvent Substances 0.000 claims 6
- -1 chalcogenide salt Chemical class 0.000 claims 5
- 239000000084 colloidal system Substances 0.000 claims 5
- 239000007787 solid Substances 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- 238000009835 boiling Methods 0.000 claims 4
- 239000006185 dispersion Substances 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 4
- 229910052717 sulfur Inorganic materials 0.000 claims 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims 3
- 229910052802 copper Inorganic materials 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 239000012528 membrane Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 231100000252 nontoxic Toxicity 0.000 claims 3
- 230000003000 nontoxic effect Effects 0.000 claims 3
- 239000002243 precursor Substances 0.000 claims 3
- 229910052718 tin Inorganic materials 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- 239000011701 zinc Substances 0.000 claims 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 229910052787 antimony Inorganic materials 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 229910052732 germanium Inorganic materials 0.000 claims 2
- 239000011521 glass Substances 0.000 claims 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 229910052711 selenium Inorganic materials 0.000 claims 2
- 239000004065 semiconductor Substances 0.000 claims 2
- 239000006228 supernatant Substances 0.000 claims 2
- 229910052714 tellurium Inorganic materials 0.000 claims 2
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims 1
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 235000011941 Tilia x europaea Nutrition 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- 239000006096 absorbing agent Substances 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000012159 carrier gas Substances 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 claims 1
- 230000008025 crystallization Effects 0.000 claims 1
- 238000000280 densification Methods 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229910003437 indium oxide Inorganic materials 0.000 claims 1
- 239000004571 lime Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- GKCNVZWZCYIBPR-UHFFFAOYSA-N sulfanylideneindium Chemical compound [In]=S GKCNVZWZCYIBPR-UHFFFAOYSA-N 0.000 claims 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims 1
- 230000003746 surface roughness Effects 0.000 claims 1
- 238000004073 vulcanization Methods 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1257242A FR2993792B1 (fr) | 2012-07-26 | 2012-07-26 | Film de chalcogenure(s) metallique(s) cristallise(s) a gros grains, solution colloidale de particules amorphes et procedes de preparation. |
| FR1257242 | 2012-07-26 | ||
| PCT/FR2013/051597 WO2014016489A2 (fr) | 2012-07-26 | 2013-07-04 | Film de chalcogenure(s) metallique(s) cristallise(s) a gros grains, solution colloïdale de particules amorphes et procedes de preparation |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018052441A Division JP6629374B2 (ja) | 2012-07-26 | 2018-03-20 | 粗大粒結晶化金属カルコゲニド膜、非晶質粒子のコロイド溶液および調製方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015532611A JP2015532611A (ja) | 2015-11-12 |
| JP2015532611A5 true JP2015532611A5 (enExample) | 2016-04-21 |
| JP6312668B2 JP6312668B2 (ja) | 2018-04-18 |
Family
ID=47501354
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015523587A Active JP6312668B2 (ja) | 2012-07-26 | 2013-07-04 | 非晶質粒子のコロイド溶液の調製方法 |
| JP2018052441A Expired - Fee Related JP6629374B2 (ja) | 2012-07-26 | 2018-03-20 | 粗大粒結晶化金属カルコゲニド膜、非晶質粒子のコロイド溶液および調製方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018052441A Expired - Fee Related JP6629374B2 (ja) | 2012-07-26 | 2018-03-20 | 粗大粒結晶化金属カルコゲニド膜、非晶質粒子のコロイド溶液および調製方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (3) | US9731262B2 (enExample) |
| EP (1) | EP2877277B1 (enExample) |
| JP (2) | JP6312668B2 (enExample) |
| FR (1) | FR2993792B1 (enExample) |
| WO (1) | WO2014016489A2 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104028285A (zh) * | 2014-05-17 | 2014-09-10 | 北京工业大学 | Cu2ZnSnS4/La2Ti2O7异质结光催化复合材料的制备方法 |
| FR3022074B1 (fr) | 2014-06-05 | 2018-02-16 | Imra Europe Sas | Procede de preparation de couche mince d'absorbeur a base de sulfure(s) et seleniures(s) de cuivre, zinc et etain, couche mince recuite et dispositif photovoltaique obtenus. |
| US10888836B2 (en) * | 2014-07-25 | 2021-01-12 | Chemical and Metal Technologies LLC | Extraction of target materials using CZTS sorbent |
| US10730012B2 (en) * | 2014-07-25 | 2020-08-04 | Chemical and Metal Technologies LLC | Extraction of target materials using CZTS sorbent |
| US10283357B2 (en) * | 2014-12-01 | 2019-05-07 | The University Of Chicago | Compositionally matched molecular solders for semiconductors |
| US9825214B1 (en) * | 2016-06-22 | 2017-11-21 | Mainstream Engineering Corporation | Films and the like produced from particles by processing with electron beams, and a method for production thereof |
| US11167262B2 (en) * | 2017-09-29 | 2021-11-09 | Korea Institute Of Science And Technology | Amorphous nanostructure composed of inorganic polymer and method for manufacturing the same |
| WO2019066466A1 (ko) * | 2017-09-29 | 2019-04-04 | 한국과학기술연구원 | 무기 고분자로 이루어진 비정질 나노구조체 및 그 제조방법 |
| KR102432093B1 (ko) * | 2017-10-20 | 2022-08-16 | 한국과학기술연구원 | 무기 고분자로 이루어진 비정질 나노구조체 및 그 제조방법 |
| KR102458627B1 (ko) * | 2018-08-21 | 2022-10-25 | 한국과학기술연구원 | 비정질 나노구조체를 이용하여 제조된 프랙탈 형상의 합금 나노구조체 및 그 제조방법 |
| KR102407233B1 (ko) | 2018-08-21 | 2022-06-10 | 한국과학기술연구원 | 지지체의 나노 사이즈 기공 내에 나노입자가 고르게 분산된 복합체 및 이의 제조방법 |
| CN111474142B (zh) * | 2020-05-21 | 2021-08-03 | 中南大学 | 一种利用近红外1550nm激光器检测微塑料浓度的方法 |
| CN113321555A (zh) * | 2021-07-05 | 2021-08-31 | 多农多收技术研究(江苏)有限公司 | 一种可以有效阻止粮食作物对土壤中镉吸收的药剂及方法 |
| CN115108581B (zh) * | 2022-07-05 | 2024-03-15 | 许昌学院 | 一种常温制备铜锌锡硫纳米晶的化学方法 |
| CN115231608B (zh) * | 2022-07-06 | 2024-03-15 | 许昌学院 | 一种常温制备多元硫化物纳米晶的化学方法 |
| KR102671502B1 (ko) * | 2022-11-28 | 2024-05-30 | 전남대학교산학협력단 | 이중 버퍼층을 구비하는 박막 태양전지 및 이의 제조방법 |
| WO2024242138A1 (ja) * | 2023-05-25 | 2024-11-28 | カルコジェニック株式会社 | ＳｎＳ分散液及びその製造方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4645619A (en) * | 1985-05-28 | 1987-02-24 | Xerox Corporation | Process for the preparation of colloidal dispersions of chalcogens and chalcogenide alloys |
| US6126740A (en) * | 1995-09-29 | 2000-10-03 | Midwest Research Institute | Solution synthesis of mixed-metal chalcogenide nanoparticles and spray deposition of precursor films |
| JP2005032475A (ja) | 2003-07-08 | 2005-02-03 | Sharp Corp | 有機色素を光増感剤とする半導体薄膜電極、それを用いた色素増感型光電変換素子および光電気化学太陽電池 |
| JP2007119535A (ja) * | 2005-10-25 | 2007-05-17 | Matsushita Electric Works Ltd | 光機能ナノ材料、その作製方法、発光ダイオード及び太陽電池 |
| US20080314738A1 (en) * | 2007-06-19 | 2008-12-25 | International Business Machines Corporation | Electrolytic Device Based on a Solution-Processed Electrolyte |
| JP5697449B2 (ja) | 2008-09-04 | 2015-04-08 | 株式会社カネカ | 透明電極付き基板および透明電極付き基板の製造方法 |
| WO2010048581A2 (en) * | 2008-10-24 | 2010-04-29 | Life Technologies Corporation | Stable nanoparticles and methods of making and using such particles |
| JP2010140812A (ja) * | 2008-12-12 | 2010-06-24 | Sekisui Chem Co Ltd | 機能素子及びその製造方法並びに色素増感太陽電池 |
| EP2430112B1 (en) * | 2009-04-23 | 2018-09-12 | The University of Chicago | Materials and methods for the preparation of nanocomposites |
| US7972899B2 (en) | 2009-07-30 | 2011-07-05 | Sisom Thin Films Llc | Method for fabricating copper-containing ternary and quaternary chalcogenide thin films |
| EP2504854A2 (en) * | 2009-11-25 | 2012-10-03 | E.I. Du Pont De Nemours And Company | CZTS/Se PRECURSOR INKS AND METHODS FOR PREPARING CZTS/Se THIN FILMS AND CZTS/Se-BASED PHOTOVOLTAIC CELLS |
| WO2011066205A1 (en) * | 2009-11-25 | 2011-06-03 | E. I. Du Pont De Nemours And Company | Aqueous process for producing crystalline copper chalcogenide nanoparticles, the nanoparticles so-produced, and inks and coated substrates incorporating the nanoparticles |
| JP5454214B2 (ja) | 2010-02-22 | 2014-03-26 | Ｔｄｋ株式会社 | 化合物半導体バッファ層の製造方法及び化合物半導体薄膜太陽電池の製造方法 |
| US9117964B2 (en) | 2010-06-29 | 2015-08-25 | Merck Patent Gmbh | Preparation of semiconductor films |
| US8617915B2 (en) * | 2010-09-20 | 2013-12-31 | International Business Machines Corporation | Annealing thin films |
| US20130037110A1 (en) * | 2011-08-10 | 2013-02-14 | International Business Machines Corporation | Particle-Based Precursor Formation Method and Photovoltaic Device Thereof |
| TWI460869B (zh) * | 2011-12-30 | 2014-11-11 | Ind Tech Res Inst | 太陽能電池光吸收層之製法 |
| FR3001467B1 (fr) * | 2013-01-29 | 2016-05-13 | Imra Europe Sas | Procede de preparation de couche mince d'absorbeur a base de sulfure(s) de cuivre, zinc et etain, couche mince recuite et dispositif photovoltaique obtenu |
-
2012
- 2012-07-26 FR FR1257242A patent/FR2993792B1/fr not_active Expired - Fee Related
-
2013
- 2013-07-04 US US14/413,316 patent/US9731262B2/en not_active Expired - Fee Related
- 2013-07-04 JP JP2015523587A patent/JP6312668B2/ja active Active
- 2013-07-04 WO PCT/FR2013/051597 patent/WO2014016489A2/fr not_active Ceased
- 2013-07-04 EP EP13745450.0A patent/EP2877277B1/fr not_active Not-in-force
-
2017
- 2017-07-21 US US15/655,952 patent/US10632441B2/en not_active Expired - Fee Related
-
2018
- 2018-03-20 JP JP2018052441A patent/JP6629374B2/ja not_active Expired - Fee Related
-
2020
- 2020-03-17 US US16/820,984 patent/US20200215509A1/en not_active Abandoned
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