JP2015510885A5 - - Google Patents
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- Publication number
- JP2015510885A5 JP2015510885A5 JP2014561076A JP2014561076A JP2015510885A5 JP 2015510885 A5 JP2015510885 A5 JP 2015510885A5 JP 2014561076 A JP2014561076 A JP 2014561076A JP 2014561076 A JP2014561076 A JP 2014561076A JP 2015510885 A5 JP2015510885 A5 JP 2015510885A5
- Authority
- JP
- Japan
- Prior art keywords
- type zeolite
- modified
- combination
- dehydroxylation
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 claims 17
- 239000010457 zeolite Substances 0.000 claims 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 9
- 229910021536 Zeolite Inorganic materials 0.000 claims 8
- 239000003054 catalyst Substances 0.000 claims 7
- 238000005906 dihydroxylation reaction Methods 0.000 claims 7
- 239000002253 acid Substances 0.000 claims 4
- 238000006243 chemical reaction Methods 0.000 claims 4
- 229910017053 inorganic salt Inorganic materials 0.000 claims 4
- 239000000376 reactant Substances 0.000 claims 4
- 239000003377 acid catalyst Substances 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 3
- 229910052809 inorganic oxide Inorganic materials 0.000 claims 3
- 239000001488 sodium phosphate Substances 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 238000005886 esterification reaction Methods 0.000 claims 2
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims 2
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- ZQKXOSJYJMDROL-UHFFFAOYSA-H aluminum;trisodium;diphosphate Chemical compound [Na+].[Na+].[Na+].[Al+3].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZQKXOSJYJMDROL-UHFFFAOYSA-H 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000012159 carrier gas Substances 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims 1
- 229910000397 disodium phosphate Inorganic materials 0.000 claims 1
- 235000019800 disodium phosphate Nutrition 0.000 claims 1
- 230000032050 esterification Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims 1
- 235000019799 monosodium phosphate Nutrition 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 239000012071 phase Substances 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 229910001414 potassium ion Inorganic materials 0.000 claims 1
- 229910000160 potassium phosphate Inorganic materials 0.000 claims 1
- 235000011009 potassium phosphates Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims 1
- 229910001415 sodium ion Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000007790 solid phase Substances 0.000 claims 1
- 229940071182 stannate Drugs 0.000 claims 1
- 125000005402 stannate group Chemical group 0.000 claims 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims 1
- 235000019801 trisodium phosphate Nutrition 0.000 claims 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261608053P | 2012-03-07 | 2012-03-07 | |
| US61/608,053 | 2012-03-07 | ||
| US201313819035A | 2013-02-26 | 2013-02-26 | |
| US13/819,035 | 2013-02-26 | ||
| PCT/US2013/029368 WO2013134385A1 (en) | 2012-03-07 | 2013-03-06 | Preparation of alpha, beta-unsaturated carboxylic acids and esters thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015510885A JP2015510885A (ja) | 2015-04-13 |
| JP2015510885A5 true JP2015510885A5 (cg-RX-API-DMAC7.html) | 2016-04-28 |
Family
ID=49117293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014561076A Withdrawn JP2015510885A (ja) | 2012-03-07 | 2013-03-06 | アルファ,ベータ−不飽和カルボン酸およびそのエステルの調製 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP2822923A4 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2015510885A (cg-RX-API-DMAC7.html) |
| KR (1) | KR20140131589A (cg-RX-API-DMAC7.html) |
| CN (1) | CN104159883A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2866003A1 (cg-RX-API-DMAC7.html) |
| IN (1) | IN2014DN07484A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2013134385A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9452967B2 (en) * | 2012-04-11 | 2016-09-27 | The Procter & Gamble Company | Process for production of acrylic acid or its derivatives |
| WO2015034948A1 (en) | 2013-09-03 | 2015-03-12 | Myriant Corporation | A process for manufacturing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol |
| US9944586B2 (en) | 2013-10-17 | 2018-04-17 | Cargill, Incorporated | Methods for producing alkyl hydroxyalkanoates |
| SG11201609633PA (en) * | 2014-05-19 | 2016-12-29 | Iowa Corn Promotion Board | Process for the continuous production of ethylene glycol from carbohydrates |
| US10239819B2 (en) | 2014-10-17 | 2019-03-26 | Cargill, Incorporated | Methods for producing an ester of an alpha, beta-unsaturated carboxylic acid |
| AU2015355368B2 (en) * | 2014-12-02 | 2019-04-18 | Archer Daniels Midland Company | Process for making acrylic acid from dextrose |
| JP6850264B2 (ja) * | 2015-06-10 | 2021-03-31 | ピーティーティー グローバル ケミカル パブリック カンパニー リミテッド | 主要副生成物としてのアセトアルデヒドを用いたアクリル酸の新規製造方法 |
| JP6694641B2 (ja) * | 2015-06-30 | 2020-05-20 | 国立研究開発法人産業技術総合研究所 | アクリル酸等のα、β−不飽和カルボン酸、その誘導体の製造法 |
| CN106582784B (zh) * | 2015-10-14 | 2019-11-08 | 中国石油化工股份有限公司 | 丙烯酸酯催化剂 |
| ES2789750T3 (es) | 2015-12-21 | 2020-10-26 | Purac Biochem Bv | Proceso de fabricación de ácido acrílico |
| CN106905155B (zh) * | 2017-03-29 | 2020-04-10 | 万华化学集团股份有限公司 | 一种裂解丙烯酸丁酯重组分生成丙烯酸丁酯的方法 |
| US10308568B2 (en) | 2017-05-01 | 2019-06-04 | Chevron Phillips Chemical Company Lp | Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity |
| US11273434B2 (en) * | 2017-10-06 | 2022-03-15 | The Procter & Gamble Company | Regeneration method of solid catalyst |
| JP2021503444A (ja) * | 2017-11-17 | 2021-02-12 | ピュラック バイオケム ビー. ブイ. | 乳酸メチルからアクリル酸メチルを製造する方法 |
| CN111253252B (zh) * | 2018-11-30 | 2023-04-11 | 中国石油化工股份有限公司 | 一种催化糖制备乳酸酯的方法 |
| CN111253259B (zh) * | 2018-11-30 | 2023-04-07 | 中国石油化工股份有限公司 | 一种催化二羟基丙酮和/或甘油醛制备乳酸酯的方法 |
| CN111253239B (zh) * | 2018-11-30 | 2023-04-07 | 中国石油化工股份有限公司 | 一种催化丙酮醛制备乳酸的方法 |
| CN111253238B (zh) * | 2018-11-30 | 2023-03-10 | 中国石油化工股份有限公司 | 一种制备乳酸的方法 |
| CN111253237B (zh) * | 2018-11-30 | 2023-04-07 | 中国石油化工股份有限公司 | 一种催化糖制备丙酮醛的方法 |
| CN111253251B (zh) * | 2018-11-30 | 2023-04-11 | 中国石油化工股份有限公司 | 一种制备乳酸酯的方法 |
| CN111250157B (zh) * | 2018-11-30 | 2023-04-07 | 中国石油化工股份有限公司 | 一种催化糖制备乳酸的方法 |
| CN111253248B (zh) * | 2018-11-30 | 2023-04-11 | 中国石油化工股份有限公司 | 一种催化丙酮醛制备乳酸酯的方法 |
| CN111253226B (zh) * | 2018-11-30 | 2023-03-10 | 中国石油化工股份有限公司 | 一种催化二羟基丙酮和/或甘油醛制备乳酸的方法 |
| CN110201716B (zh) * | 2019-05-21 | 2022-04-19 | 南京工业大学 | 一种醇胺基团改性的有序介孔C/SiO2负载杂多酸催化剂及其制备方法和应用 |
| CN111905802B (zh) * | 2020-06-15 | 2022-01-18 | 厦门大学 | 一种使用钼-碱金属/碱土金属修饰的路易斯酸催化剂制乳酸酯的方法 |
| CN115608406B (zh) * | 2021-07-13 | 2023-12-08 | 中国石油化工股份有限公司 | 用于合成甲基丙烯酸甲酯的催化剂及其制备方法和应用 |
| CN119793523A (zh) * | 2023-10-10 | 2025-04-11 | 中国石油化工股份有限公司 | 酯化催化剂及其制备方法以及在甲基丙烯酸甲酯合成反应中的应用 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4617405A (en) * | 1984-09-25 | 1986-10-14 | A. E. Staley Manufacturing Company | Preparation of alpha, beta-unsaturated carbonyl compounds |
| US4729978A (en) * | 1987-05-04 | 1988-03-08 | Texaco Inc. | Catalyst for dehydration of lactic acid to acrylic acid |
| FR2882053B1 (fr) * | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acrolene |
| FR2884818B1 (fr) * | 2005-04-25 | 2007-07-13 | Arkema Sa | Procede de preparation d'acide acrylique a partir de glycerol |
| FR2884817B1 (fr) * | 2005-04-25 | 2007-06-22 | Arkema Sa | Procede de preparation d'acide acrylique a partir de glycerol |
| CN101352688A (zh) * | 2007-07-23 | 2009-01-28 | 湖南大学 | 乳酸脱水制丙烯酸催化剂及反应工艺 |
| US20130053595A1 (en) * | 2009-09-18 | 2013-02-28 | Arkema France | Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin |
| EP2614152A4 (en) * | 2010-09-07 | 2015-04-15 | Myriant Corp | CATALYTIC DEHYDRATION OF MILKY ACID AND MILKIC ACID ESTERS |
-
2013
- 2013-03-06 IN IN7484DEN2014 patent/IN2014DN07484A/en unknown
- 2013-03-06 JP JP2014561076A patent/JP2015510885A/ja not_active Withdrawn
- 2013-03-06 WO PCT/US2013/029368 patent/WO2013134385A1/en not_active Ceased
- 2013-03-06 CA CA2866003A patent/CA2866003A1/en not_active Abandoned
- 2013-03-06 CN CN201380013134.0A patent/CN104159883A/zh active Pending
- 2013-03-06 EP EP13758082.5A patent/EP2822923A4/en not_active Withdrawn
- 2013-03-06 KR KR20147028049A patent/KR20140131589A/ko not_active Withdrawn
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