JP2015510885A - アルファ，ベータ−不飽和カルボン酸およびそのエステルの調製 - Google Patents

アルファ，ベータ−不飽和カルボン酸およびそのエステルの調製 Download PDF

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Publication number
JP2015510885A
JP2015510885A JP2014561076A JP2014561076A JP2015510885A JP 2015510885 A JP2015510885 A JP 2015510885A JP 2014561076 A JP2014561076 A JP 2014561076A JP 2014561076 A JP2014561076 A JP 2014561076A JP 2015510885 A JP2015510885 A JP 2015510885A
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acid
catalyst
dehydroxylation
reaction
type zeolite
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JP2015510885A5 (cg-RX-API-DMAC7.html
Inventor
セナン・エイ・オズメラル
ジョセフ・ピー・グラス
ラジェシュ・ダサリ
セトラク・タニールヤン
ラメシュ・ディオラム・バガト
モハン・レディ・カシレディ
ラムニク・シン
ビジャイ・ニャナデシカン
ロバート・エル・オーガスティン
サントシュ・モア
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Myriant Corp
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Myriant Corp
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Publication of JP2015510885A publication Critical patent/JP2015510885A/ja
Publication of JP2015510885A5 publication Critical patent/JP2015510885A5/ja
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/605—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/64—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2014561076A 2012-03-07 2013-03-06 アルファ，ベータ−不飽和カルボン酸およびそのエステルの調製 Withdrawn JP2015510885A (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261608053P 2012-03-07 2012-03-07
US61/608,053 2012-03-07
US201313819035A 2013-02-26 2013-02-26
US13/819,035 2013-02-26
PCT/US2013/029368 WO2013134385A1 (en) 2012-03-07 2013-03-06 Preparation of alpha, beta-unsaturated carboxylic acids and esters thereof

Publications (2)

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JP2015510885A true JP2015510885A (ja) 2015-04-13
JP2015510885A5 JP2015510885A5 (cg-RX-API-DMAC7.html) 2016-04-28

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JP2014561076A Withdrawn JP2015510885A (ja) 2012-03-07 2013-03-06 アルファ，ベータ−不飽和カルボン酸およびそのエステルの調製

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EP (1) EP2822923A4 (cg-RX-API-DMAC7.html)
JP (1) JP2015510885A (cg-RX-API-DMAC7.html)
KR (1) KR20140131589A (cg-RX-API-DMAC7.html)
CN (1) CN104159883A (cg-RX-API-DMAC7.html)
CA (1) CA2866003A1 (cg-RX-API-DMAC7.html)
IN (1) IN2014DN07484A (cg-RX-API-DMAC7.html)
WO (1) WO2013134385A1 (cg-RX-API-DMAC7.html)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015518481A (ja) * 2012-04-11 2015-07-02 ザ プロクター アンド ギャンブルカンパニー アクリル酸又はその誘導体を生成する方法
JP2017014144A (ja) * 2015-06-30 2017-01-19 国立研究開発法人産業技術総合研究所 アクリル酸等のα、β−不飽和カルボン酸、その誘導体の製造法
JP2018522840A (ja) * 2015-06-10 2018-08-16 ミリアント・コーポレイションＭｙｒｉａｎｔ Ｃｏｒｐｏｒａｔｉｏｎ 主要副生成物としてのアセトアルデヒドを用いたアクリル酸の新規製造方法
JP2019069433A (ja) * 2017-10-06 2019-05-09 ザ プロクター アンド ギャンブル カンパニー 固体触媒の再生方法
KR20200079316A (ko) * 2017-11-17 2020-07-02 푸락 바이오켐 비.브이. 메틸 락테이트로부터 메틸 아크릴레이트의 제조 방법

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WO2015034948A1 (en) 2013-09-03 2015-03-12 Myriant Corporation A process for manufacturing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol
US9944586B2 (en) 2013-10-17 2018-04-17 Cargill, Incorporated Methods for producing alkyl hydroxyalkanoates
SG11201609633PA (en) * 2014-05-19 2016-12-29 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates
US10239819B2 (en) 2014-10-17 2019-03-26 Cargill, Incorporated Methods for producing an ester of an alpha, beta-unsaturated carboxylic acid
AU2015355368B2 (en) * 2014-12-02 2019-04-18 Archer Daniels Midland Company Process for making acrylic acid from dextrose
CN106582784B (zh) * 2015-10-14 2019-11-08 中国石油化工股份有限公司 丙烯酸酯催化剂
ES2789750T3 (es) 2015-12-21 2020-10-26 Purac Biochem Bv Proceso de fabricación de ácido acrílico
CN106905155B (zh) * 2017-03-29 2020-04-10 万华化学集团股份有限公司 一种裂解丙烯酸丁酯重组分生成丙烯酸丁酯的方法
US10308568B2 (en) 2017-05-01 2019-06-04 Chevron Phillips Chemical Company Lp Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity
CN111253252B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种催化糖制备乳酸酯的方法
CN111253259B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化二羟基丙酮和/或甘油醛制备乳酸酯的方法
CN111253239B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化丙酮醛制备乳酸的方法
CN111253238B (zh) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 一种制备乳酸的方法
CN111253237B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化糖制备丙酮醛的方法
CN111253251B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种制备乳酸酯的方法
CN111250157B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化糖制备乳酸的方法
CN111253248B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种催化丙酮醛制备乳酸酯的方法
CN111253226B (zh) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 一种催化二羟基丙酮和/或甘油醛制备乳酸的方法
CN110201716B (zh) * 2019-05-21 2022-04-19 南京工业大学 一种醇胺基团改性的有序介孔C/SiO2负载杂多酸催化剂及其制备方法和应用
CN111905802B (zh) * 2020-06-15 2022-01-18 厦门大学 一种使用钼-碱金属/碱土金属修饰的路易斯酸催化剂制乳酸酯的方法
CN115608406B (zh) * 2021-07-13 2023-12-08 中国石油化工股份有限公司 用于合成甲基丙烯酸甲酯的催化剂及其制备方法和应用
CN119793523A (zh) * 2023-10-10 2025-04-11 中国石油化工股份有限公司 酯化催化剂及其制备方法以及在甲基丙烯酸甲酯合成反应中的应用

Family Cites Families (8)

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US4617405A (en) * 1984-09-25 1986-10-14 A. E. Staley Manufacturing Company Preparation of alpha, beta-unsaturated carbonyl compounds
US4729978A (en) * 1987-05-04 1988-03-08 Texaco Inc. Catalyst for dehydration of lactic acid to acrylic acid
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
FR2884818B1 (fr) * 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
FR2884817B1 (fr) * 2005-04-25 2007-06-22 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
CN101352688A (zh) * 2007-07-23 2009-01-28 湖南大学 乳酸脱水制丙烯酸催化剂及反应工艺
US20130053595A1 (en) * 2009-09-18 2013-02-28 Arkema France Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
EP2614152A4 (en) * 2010-09-07 2015-04-15 Myriant Corp CATALYTIC DEHYDRATION OF MILKY ACID AND MILKIC ACID ESTERS

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015518481A (ja) * 2012-04-11 2015-07-02 ザ プロクター アンド ギャンブルカンパニー アクリル酸又はその誘導体を生成する方法
JP2018522840A (ja) * 2015-06-10 2018-08-16 ミリアント・コーポレイションＭｙｒｉａｎｔ Ｃｏｒｐｏｒａｔｉｏｎ 主要副生成物としてのアセトアルデヒドを用いたアクリル酸の新規製造方法
JP2017014144A (ja) * 2015-06-30 2017-01-19 国立研究開発法人産業技術総合研究所 アクリル酸等のα、β−不飽和カルボン酸、その誘導体の製造法
JP2019069433A (ja) * 2017-10-06 2019-05-09 ザ プロクター アンド ギャンブル カンパニー 固体触媒の再生方法
JP7001433B2 (ja) 2017-10-06 2022-02-03 ザ プロクター アンド ギャンブル カンパニー 固体触媒の再生方法
US11273434B2 (en) 2017-10-06 2022-03-15 The Procter & Gamble Company Regeneration method of solid catalyst
KR20200079316A (ko) * 2017-11-17 2020-07-02 푸락 바이오켐 비.브이. 메틸 락테이트로부터 메틸 아크릴레이트의 제조 방법
JP2021503444A (ja) * 2017-11-17 2021-02-12 ピュラック バイオケム ビー． ブイ． 乳酸メチルからアクリル酸メチルを製造する方法
JP2022160637A (ja) * 2017-11-17 2022-10-19 ピュラック バイオケム ビー． ブイ． 乳酸メチルからアクリル酸メチルを製造する方法
KR102474492B1 (ko) 2017-11-17 2022-12-06 푸락 바이오켐 비.브이. 메틸 락테이트로부터 메틸 아크릴레이트의 제조 방법

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Publication number Publication date
EP2822923A1 (en) 2015-01-14
IN2014DN07484A (cg-RX-API-DMAC7.html) 2015-04-24
CN104159883A (zh) 2014-11-19
WO2013134385A1 (en) 2013-09-12
KR20140131589A (ko) 2014-11-13
EP2822923A4 (en) 2015-11-04
CA2866003A1 (en) 2013-09-12

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