IN2014DN07484A - - Google Patents

Info

Publication number
IN2014DN07484A
IN2014DN07484A IN7484DEN2014A IN2014DN07484A IN 2014DN07484 A IN2014DN07484 A IN 2014DN07484A IN 7484DEN2014 A IN7484DEN2014 A IN 7484DEN2014A IN 2014DN07484 A IN2014DN07484 A IN 2014DN07484A
Authority
IN
India
Prior art keywords
reactions
esteriiication
type zeolite
dehydroxylation
reaction pathways
Prior art date
Application number
Inventor
A Cenan Ozmeral
Joseph P Glas
Rajesh Dasari
Setrak Tanielyan
Ramesh Deoram Bhagat
Mohan Reddy Kasireddy
Ramnik Singh
Vijay Gnanadesikan
Robert L Augustine
Santosh More
Original Assignee
Myriant Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Myriant Corp filed Critical Myriant Corp
Publication of IN2014DN07484A publication Critical patent/IN2014DN07484A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/605—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/64—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

An L-type zeolite, a modified L-type zeolite, or any combination thereof may be useful in catalytically preparing ,α,ß-unsaturated carboxylic acids and/or esters thereof through reaction pathways that include dehydroxylation reactions and optionally esteriiication reactions. In some reaction pathways, dehydroxylation reactions and esteriiication reactions may be performed sequen tially or concurrently.
IN7484DEN2014 2012-03-07 2013-03-06 IN2014DN07484A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261608053P 2012-03-07 2012-03-07
US201313819035A 2013-02-26 2013-02-26
PCT/US2013/029368 WO2013134385A1 (en) 2012-03-07 2013-03-06 Preparation of alpha, beta-unsaturated carboxylic acids and esters thereof

Publications (1)

Publication Number Publication Date
IN2014DN07484A true IN2014DN07484A (en) 2015-04-24

Family

ID=49117293

Family Applications (1)

Application Number Title Priority Date Filing Date
IN7484DEN2014 IN2014DN07484A (en) 2012-03-07 2013-03-06

Country Status (7)

Country Link
EP (1) EP2822923A4 (en)
JP (1) JP2015510885A (en)
KR (1) KR20140131589A (en)
CN (1) CN104159883A (en)
CA (1) CA2866003A1 (en)
IN (1) IN2014DN07484A (en)
WO (1) WO2013134385A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9452967B2 (en) * 2012-04-11 2016-09-27 The Procter & Gamble Company Process for production of acrylic acid or its derivatives
JP2016534131A (en) 2013-09-03 2016-11-04 ミリアント・コーポレイションＭｙｒｉａｎｔ Ｃｏｒｐｏｒａｔｉｏｎ Process for producing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol
WO2015058116A1 (en) 2013-10-17 2015-04-23 Cargill, Incorporated Methods for producing alkyl hydroxyalkanoates
DK3145902T3 (en) * 2014-05-19 2018-10-01 Iowa Corn Promotion Board PROCEDURE FOR CONTINUOUS PREPARATION OF ETHYLENGYLYCOL FROM CARBOHYDRATES
US10239819B2 (en) 2014-10-17 2019-03-26 Cargill, Incorporated Methods for producing an ester of an alpha, beta-unsaturated carboxylic acid
US10308582B2 (en) * 2014-12-02 2019-06-04 Archer Daniels Midland Company Process for making acrylic acid from dextrose
MY195498A (en) * 2015-06-10 2023-01-26 Ptt Global Chemical Public Co Ltd Novel method to produce acrylic acid with acetaldehyde as the main by-product
JP6694641B2 (en) * 2015-06-30 2020-05-20 国立研究開発法人産業技術総合研究所 Process for producing α, β-unsaturated carboxylic acid such as acrylic acid and its derivatives
CN106582784B (en) * 2015-10-14 2019-11-08 中国石油化工股份有限公司 Acrylate catalyst
WO2017108890A1 (en) * 2015-12-21 2017-06-29 Purac Biochem Bv Process for manufacturing acrylic acid
CN106905155B (en) * 2017-03-29 2020-04-10 万华化学集团股份有限公司 Method for generating butyl acrylate by cracking butyl acrylate heavy component
US10308568B2 (en) 2017-05-01 2019-06-04 Chevron Phillips Chemical Company Lp Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity
US11273434B2 (en) 2017-10-06 2022-03-15 The Procter & Gamble Company Regeneration method of solid catalyst
KR102474492B1 (en) * 2017-11-17 2022-12-06 푸락 바이오켐 비.브이. Method for producing methyl acrylate from methyl lactate
CN111253251B (en) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 Method for preparing lactate
CN111253237B (en) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 Method for preparing methylglyoxal by catalyzing sugar
CN111253239B (en) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 Method for preparing lactic acid by catalyzing methylglyoxal
CN111253226B (en) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 Method for preparing lactic acid by catalyzing dihydroxyacetone and/or glyceraldehyde
CN111253252B (en) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 Method for preparing lactate by catalyzing sugar
CN111253259B (en) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 Method for preparing lactate by catalyzing dihydroxyacetone and/or glyceraldehyde
CN111253248B (en) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 Method for preparing lactate by catalyzing methylglyoxal
CN111250157B (en) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 Method for preparing lactic acid by catalyzing sugar
CN111253238B (en) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 Method for preparing lactic acid
CN110201716B (en) * 2019-05-21 2022-04-19 南京工业大学 An ordered mesoporous C/SiO2 supported heteropolyacid catalyst modified by an alcoholamine group and its preparation method and application
CN111905802B (en) * 2020-06-15 2022-01-18 厦门大学 Method for preparing lactate by using molybdenum-alkali metal/alkaline earth metal modified Lewis acid catalyst
CN115608406B (en) * 2021-07-13 2023-12-08 中国石油化工股份有限公司 Catalyst for synthesizing methyl methacrylate and preparation method and application thereof

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4617405A (en) * 1984-09-25 1986-10-14 A. E. Staley Manufacturing Company Preparation of alpha, beta-unsaturated carbonyl compounds
US4729978A (en) * 1987-05-04 1988-03-08 Texaco Inc. Catalyst for dehydration of lactic acid to acrylic acid
FR2882053B1 (en) * 2005-02-15 2007-03-23 Arkema Sa METHOD FOR DEHYDRATING GLYCEROL IN ACROLENE
FR2884818B1 (en) * 2005-04-25 2007-07-13 Arkema Sa PROCESS FOR THE PREPARATION OF ACRYLIC ACID FROM GLYCEROL
FR2884817B1 (en) * 2005-04-25 2007-06-22 Arkema Sa PROCESS FOR THE PREPARATION OF ACRYLIC ACID FROM GLYCEROL
CN101352688A (en) * 2007-07-23 2009-01-28 湖南大学 Catalyst and Reaction Process of Dehydration of Lactic Acid to Acrylic Acid
EP2695672B1 (en) * 2009-09-18 2023-09-06 Arkema France Process for preparing acrolein by dehydration of glycerin in the presence of a catalyst
CN103080328B (en) * 2010-09-07 2015-06-10 麦兰特公司 Catalytic dehydration of lactic acid and lactic acid esters

Also Published As

Publication number Publication date
EP2822923A4 (en) 2015-11-04
CA2866003A1 (en) 2013-09-12
JP2015510885A (en) 2015-04-13
WO2013134385A1 (en) 2013-09-12
CN104159883A (en) 2014-11-19
KR20140131589A (en) 2014-11-13
EP2822923A1 (en) 2015-01-14

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