JP2015086397A - 間接印刷のための乳化されたエレクトロレオロジーインク - Google Patents
間接印刷のための乳化されたエレクトロレオロジーインク Download PDFInfo
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- JP2015086397A JP2015086397A JP2014216386A JP2014216386A JP2015086397A JP 2015086397 A JP2015086397 A JP 2015086397A JP 2014216386 A JP2014216386 A JP 2014216386A JP 2014216386 A JP2014216386 A JP 2014216386A JP 2015086397 A JP2015086397 A JP 2015086397A
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Abstract
【解決手段】液相及び固相を含むエレクトロレオロジー流体の液相は、シリコーン油、植物油、鉱物油等の絶縁油を含有し、固相が有機粒子や、金属酸化物、非酸化物等の無機粒子を0.1〜60重量%の充填量で含み、更にアニオン性又はカチオン性界面活性剤を含み約25〜500nmの平均乳化液滴径を有する水性インク。前記インクは、約15〜約50mN/mの表面張力を有し、30℃で約2〜約20CPの粘度を有する、水性インク。
【選択図】なし
Description
本開示の乳化されたエレクトロレオロジーインクは、エレクトロレオロジー流体を含む。エレクトロレオロジー流体は、電場に供される場合にレオロジー特性の顕著な変化を示す液体媒体である。エレクトロレオロジー流体は、油中のデンプンまたは小麦粉の懸濁液を用いて1947年にWinslowによって初めて示された。一般に、エレクトロレオロジー流体は、誘電体流体中に懸濁した粒子を含む。本開示のER流体は、インクの総重量に基づいて約3重量%〜約20重量%、約5重量%〜約17重量%、または約10重量%〜約15重量%の量でインク中に存在し得る。本開示のER流体は、液相、固相、および任意の添加剤を含む。
本明細書のインク組成物は、水、または水と共溶媒または保湿剤と称される水溶性または水混和性有機構成成分との混合物を含んでいてもよく、この共溶媒としては、例えばアルコールおよびアルコール誘導体(脂肪族アルコール、芳香族アルコール、ジオール(dial)、グリコールエーテル、ポリグリコールエーテル、長鎖アルコール、一級脂肪族アルコール、二級脂肪族アルコール、1,2−アルコール、1,3−アルコール、1,5−アルコール、エチレングリコールアルキルエーテル、プロピレングリコールアルキルエーテル、メトキシル化グリセロール、エトキシル化グリセロール、ポリエチレングリコールアルキルエーテルの高級同族体などを含み、具体的な例としてはエチレングリコール、プロピレングリコール、ジエチレングリコール、グリセリン、ジプロピレングリコール、ポリエチレングリコール、ポリプロピレングリコール、トリメチロールプロパン、1,5−ペンタンジオール、2−メチル−1,3,−プロパンジオール、2−エチル−2−ヒドロキシメチル−1,3−プロパンジオール、3−メトキシブタノール、3−メチル−1,5−ペンタンジオール、1,3−プロパンジオール、1,4−ブタンジオール、2,4−ヘプタンジオールなどが挙げられる)であり;または好適にはアミド、エーテル、尿素、置換尿素、例えばチオ尿素、エチレン尿素、アルキル尿素、アルキルチオ尿素、ジアルキル尿素、およびジアルキルチオ尿素、カルボン酸およびそれらの塩、例えば2−メチルペンタン酸、2−エチル−3−プロピルアクリル酸、2−エチル−ヘキサン酸、3−エトキシプロピオン酸(proponic,acid)など、エステル、オルガノスルフィド、オルガノスルホキシド、スルホン(例えばスルホラン)、カルビトール、ブチルカルビトール、セロソルブ(cellusolve)、エーテル、トリプロピレングリコールモノメチルエーテル、エーテル誘導体、ヒドロキシエーテル、アミノアルコール、ケトン、N−メチルピロリジノン、2−ピロリジノン、シクロヘキシルピロリドン、アミド、スルホキシド、ラクトン、ポリ電解質、メチルスルホニルエタノール、イミダゾール、1,3−ジメチル−2−イミダゾリジノン、ベタイン、糖、例えば1−デオキシ−D−ガラクチトール、マンニトール、イノシトールなど、置換および非置換ホルムアミド、置換および非置換アセトアミド、および他の水溶性または水混和性材料、ならびにこれらの混合物である。実施形態において、共溶媒は、エチレングリコール、N−メチルピロリドン、メトキシル化グリセロール、エトキシル化グリセロール、スルホラン、メチルエチルケトン、イソプロパノール、2−ピロリジノン、ポリエチレングリコール、およびこれらの混合物からなる群から選択される。水と、水溶性または水混和性有機液体との混合物が液体ビヒクルとして選択される場合、水と有機物との比の範囲は、いずれかの好適なまたは所望の比、実施形態においては約100:0〜約30:70、約97:3〜約40:60、または約95:5〜約60:40であることができる。液体ビヒクルの非水構成成分は、一般に水(100℃)の場合よりも高い沸点を有する共溶媒として作用する。インクビヒクルの有機構成成分はまた、インクの表面張力を変更し、インク粘度を変更し、着色剤を溶解または分散し、および/またはインクの乾燥特徴に影響を与えるように作用し得る。
本明細書のインク組成物はまた、着色剤を含有してもよい。いずれかの好適なまたは所望の着色剤は、顔料、染料、染料分散液、顔料分散液、およびこれらの混合物および組み合わせを含んで、本明細書の実施形態において使用できる。
実施形態のインクは、いずれかの好適な技術およびプロセス、例えば成分の単純な混合によって調製されてもよい。1つのプロセスは、インク成分すべてを共に混合し、この混合物を濾過することによりインクを得ることを必要とする。インクは、成分を混合し、所望により加熱し、濾過し、続いていずれかの所望の追加添加剤を混合物に添加し、室温で適度な振とうにより均一な混合物が得られるまで、1つの実施形態においては約5〜約10分混合することによって調製できる。あるいは、任意のインク添加剤は、インク調製プロセスの間に他のインク成分と混合でき、これはいずれかの所望の手順に従って、例えばすべての成分を混合し、所望により加熱し、濾過することによって行われる。さらにインク調製方法の例は、以下の実施例に示される。
ER流体の調製
10.38gの尿素コーティングされたバリウムチタニルオキザラートナノ粒子(直径約5nm)を、197.32gのDow Corning 5cStシリコーン流体に添加し、5重量%充填量のナノ粒子を含有する207.7gのER流体懸濁液を与える。
インク配合物Aの調製(ER流体インクを蒸留水および保湿剤の混合物に乳化)
本開示のエレクトロレオロジー(ER)流体(20.8重量%,207.7g)および主に分岐ドデシルベンゼンスルホン酸ナトリウム(2.0重量%,20g)からなるNeogen RK(商標)アニオン性界面活性剤を、反応器中の脱イオン水(43.2重量%,432g)、スルファロン(28.3重量%,283g)および2−ピロリジノン(5.7重量%,57g)に添加し、圧力下で90℃に加熱し、約400RPMにて撹拌する。次いでER流体を含有する水性混合物を、毎分約1リットルにてGaulin15MRピストンホモジナイザーを通して、均質化圧力が約1,000psiになるように一次均質化バルブを完全に開放し、二次均質化バルブを部分的に閉じて約30分間ポンプ輸送する。次いで、一次均質化バルブを部分的に閉め、均質化圧力が約8,000psiまで増大するようにする。反応混合物を約90℃に維持し、約1L/分にて約60分間ホモジナイザーを通して循環させる。その後、ホモジナイザーを停止し、反応器混合物を室温まで約15℃/分で冷却し、生成物容器に放出する。ここでER流体は、水性インク中に約200nmの液滴径に分散する。
Claims (10)
- 液相および固相を含むエレクトロレオロジー流体;および
共溶媒;
を含む間接印刷プロセスに使用するための乳化されたエレクトロレオロジーインクであって、ここでインクは、約15〜約50mN/mの表面張力を有し、インクは、30℃で約2センチポイズ〜約20センチポイズの粘度を有する、インク。 - 前記エレクトロレオロジー流体が、前記インクの重量に基づいて、約3重量%〜約20重量%の量で存在する、請求項1に記載のインク。
- 前記液相が絶縁油を含む、請求項1に記載のインク。
- 前記絶縁油が、シリコーン油、植物油、鉱物油、パラフィン、およびこれらの混合物からなる群から選択される、請求項2に記載のインク。
- 前記固相が、無機粒子、有機粒子、またはこれらの混合物を含む、請求項1に記載のインク。
- 前記無機粒子が、金属性酸化物、非酸化物材料、およびこれらの混合物からなる群から選択される、請求項5に記載のインク。
- 前記液相中の前記固相の充填量が、約0.1〜約60重量%である、請求項1に記載のインク。
- アニオン性界面活性剤、カチオン性界面活性剤、または非イオン性界面活性剤からなる群から選択される、界面活性剤をさらに含む、請求項1に記載のインク。
- 前記インクが、約25nm〜約500nmの平均乳化液滴径を有する、請求項1に記載のインク。
- a)液相および分散相を含むエレクトロレオロジー流体;および
共溶媒;
を含む乳化されたエレクトロレオロジーインクを提供する工程であって、ここで、前記インクが、約15〜約50mN/mの表面張力を有し、前記インクが、30℃にて約2センチポイズ〜約20センチポイズの粘度を有する、工程;
b)前記インクを中間基材に適用する工程;
c)前記インクを加熱する工程;
d)電場を前記インクに適用することによって、整列された粒子を有する向上した粘度のインクフィルムを形成する工程;および
e)前記インクフィルムを前記中間基材から最終基材に適用する工程
を含む乳化されたエレクトロレオロジーインクで印刷する方法。
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JPH08165448A (ja) * | 1994-12-13 | 1996-06-25 | Fujikura Kasei Co Ltd | インクジェット記録用インク組成物 |
JPH08187927A (ja) * | 1994-11-09 | 1996-07-23 | Nippon Oil Co Ltd | 印刷による転写方法 |
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US20120256135A1 (en) * | 2011-04-08 | 2012-10-11 | The Regents Of The University Of Michigan | Electrorheological fluids and methods |
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KR100851279B1 (ko) | 2006-12-07 | 2008-08-08 | 한국전자통신연구원 | 전기 유변 유체를 이용한 점자 디스플레이 장치 및 그 제조방법 |
US9177691B2 (en) | 2011-09-19 | 2015-11-03 | Baker Hughes Incorporated | Polarizable nanoparticles and electrorheological fluid comprising same |
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Patent Citations (6)
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JPH054342A (ja) * | 1991-06-26 | 1993-01-14 | Seiko Epson Corp | 記録装置 |
US5910269A (en) * | 1994-10-20 | 1999-06-08 | Nippon Shokubai Co., Ltd. | Electrorheological fluid composition including hydrocarbon compound having at least one unsaturated bond |
JPH08187927A (ja) * | 1994-11-09 | 1996-07-23 | Nippon Oil Co Ltd | 印刷による転写方法 |
JPH08165448A (ja) * | 1994-12-13 | 1996-06-25 | Fujikura Kasei Co Ltd | インクジェット記録用インク組成物 |
JP2006102975A (ja) * | 2004-09-30 | 2006-04-20 | Fuji Photo Film Co Ltd | 吐出装置及び画像記録装置 |
US20120256135A1 (en) * | 2011-04-08 | 2012-10-11 | The Regents Of The University Of Michigan | Electrorheological fluids and methods |
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US9605166B2 (en) | 2017-03-28 |
JP6328031B2 (ja) | 2018-05-23 |
CA2867686C (en) | 2018-07-24 |
DE102014221984A1 (de) | 2015-04-30 |
CA2867686A1 (en) | 2015-04-30 |
KR20150051140A (ko) | 2015-05-11 |
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