JP2014197668A - ハードマスク表面処理 - Google Patents
ハードマスク表面処理 Download PDFInfo
- Publication number
- JP2014197668A JP2014197668A JP2014007972A JP2014007972A JP2014197668A JP 2014197668 A JP2014197668 A JP 2014197668A JP 2014007972 A JP2014007972 A JP 2014007972A JP 2014007972 A JP2014007972 A JP 2014007972A JP 2014197668 A JP2014197668 A JP 2014197668A
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- Prior art keywords
- hard mask
- surface treatment
- group
- contact angle
- water contact
- Prior art date
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/0271—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/002—Processes for applying liquids or other fluent materials the substrate being rotated
- B05D1/005—Spin coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/30—Processes for applying liquids or other fluent materials performed by gravity only, i.e. flow coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/033—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
- H01L21/0332—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their composition, e.g. multilayer masks, materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
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- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
- Materials For Photolithography (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Drying Of Semiconductors (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Abstract
Description
Claims (12)
- (−M−O−)nリンケージ(式中、Mは3族〜14族の金属であり、n>1である)を有する無機ドメインを含むハードマスク層の表面を処理するためのプロセスであって、表面処理組成物とハードマスクの表面を接触させてハードマスク表面をコーティングし、表面処理組成物が有機溶媒および表面活性部分を含む表面処理剤を含む、プロセス。
- Mが、チタン、ジルコニウム、ハフニウム、タングステン、タンタル、モリブデンおよびアルミニウムから選択される、請求項1に記載のプロセス。
- 前記ハードマスク表面が、表面処理組成物との接触前に第1の水接触角を有し、かかる接触後に第2の水接触角を有し、第2の水接触角が第1の水接触角より大きい、請求項1に記載のプロセス。
- 前記プロセスが、コーティングしたハードマスク表面を加熱する工程をさらに含む、請求項1に記載のプロセス。
- 前記加熱後のハードマスク表面が60〜70°の水接触角を有する、請求項4に記載のプロセス。
- 加熱工程後にさらにリンス工程を含む、請求項4に記載のプロセス。
- 前記表面処理剤がポリマー性であり、表面活性部分を含む1つまたは複数のペンダント基、表面活性部分を含む末端基、および1つまたは複数の表面活性部分を含むポリマー骨格を含む、請求項1に記載のプロセス。
- 前記表面活性部分が、ヒドロキシル基、チオール基、カルボキシル基、βジケト基、保護カルボキシル基および保護ヒドロキシル基から選択される基である、請求項1に記載のプロセス。
- 前記オリゴマーが、重合単位として、(メタ)アクリル酸、(メタ)アクリレートエステルおよびヒドロキシスチレンモノマーから選択されるモノマーを含む、請求項1に記載のプロセス。
- 前記ハードマスク層が電子装置基板上に配置される、請求項1に記載のプロセス。
- 電子装置基板上に配置されたハードマスク層であって、(−M−O−)nリンケージ(式中、Mは3族〜14族の金属であり、n>1である)を有し、≧60°の水接触角を有する表面を有する多数の無機ドメインを含む、ハードマスク層。
- オキシ金属ハードマスク層を有する基板を提供することと;有機溶媒ならびに保護ヒドロキシルおよび保護カルボキシルから選択される表面処理部分を含む表面処理剤を含む表面処理組成物によりハードマスク表面をコーティングすることと;比較的より低い表面エネルギーの第1の領域および比較的より高い表面エネルギーの第2の領域のパターンを有するハードマスク層を形成するのに十分な条件へ表面処理組成物コーティングをさらすこととを含む、パターン形成されたハードマスク層を形成するプロセス。
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US13/745,752 | 2013-01-19 | ||
US13/745,752 US9171720B2 (en) | 2013-01-19 | 2013-01-19 | Hardmask surface treatment |
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JP (1) | JP6491411B2 (ja) |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20170075410A (ko) * | 2015-12-23 | 2017-07-03 | 삼성전자주식회사 | 선택적 증착 층을 이용한 반도체 소자 형성 방법 및 관련된 소자 |
JP2018536096A (ja) * | 2015-09-29 | 2018-12-06 | ローム アンド ハース エレクトロニック マテリアルズ エルエルシーRohm and Haas Electronic Materials LLC | 複合材料多層構造を作製する方法 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9136123B2 (en) | 2013-01-19 | 2015-09-15 | Rohm And Haas Electronic Materials Llc | Hardmask surface treatment |
US9296879B2 (en) | 2013-09-03 | 2016-03-29 | Rohm And Haas Electronic Materials Llc | Hardmask |
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US11676633B2 (en) * | 2021-04-28 | 2023-06-13 | Seagate Technology Llc | Coated disk separator plate, electronic devices that include one or more coated disk separator plates, and related methods of making and using |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6303270B1 (en) * | 1999-03-01 | 2001-10-16 | The Curators Of The University Of Missouri | Highly plasma etch-resistant photoresist composition containing a photosensitive polymeric titania precursor |
WO2005001901A2 (en) * | 2003-06-11 | 2005-01-06 | Brewer Science, Inc. | Wet developable hard mask in conjunction with thin photoresist for micro photolithography |
JP2005537502A (ja) * | 2002-06-25 | 2005-12-08 | ブルーワー サイエンス アイ エヌ シー. | マイクロエレクトロニクスの用途のための現像液に可溶なアルコキシド金属塗布膜 |
WO2006059652A1 (ja) * | 2004-12-01 | 2006-06-08 | Sanyo Electric Co., Ltd. | 有機金属ポリマー材料 |
JP2007256928A (ja) * | 2006-01-29 | 2007-10-04 | Rohm & Haas Electronic Materials Llc | オーバーコートされるフォトレジストと共に使用するための被覆組成物 |
JP2011508254A (ja) * | 2007-12-20 | 2011-03-10 | エイゼット・エレクトロニック・マテリアルズ・ユーエスエイ・コーポレイション | 反射防止膜上にコートされたフォトレジストに像を形成する方法 |
US20120223418A1 (en) * | 2011-02-28 | 2012-09-06 | Stowers Jason K | Solution processible hardmasks for high resolution lithography |
WO2013006314A2 (en) * | 2011-07-07 | 2013-01-10 | Brewer Science Inc. | Metal-oxide films from small molecules for lithographic applications |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6136501A (en) | 1998-08-28 | 2000-10-24 | Shipley Company, L.L.C. | Polymers and photoresist compositions comprising same |
US6583067B2 (en) * | 2001-07-03 | 2003-06-24 | United Microelectronics Corp. | Method of avoiding dielectric layer deterioration with a low dielectric constant |
EP1720072B1 (en) | 2005-05-01 | 2019-06-05 | Rohm and Haas Electronic Materials, L.L.C. | Compositons and processes for immersion lithography |
US8901016B2 (en) * | 2010-12-28 | 2014-12-02 | Asm Japan K.K. | Method of forming metal oxide hardmask |
CN102591142B (zh) * | 2012-02-29 | 2013-03-27 | 青岛理工大学 | 用于蓝宝石衬底图形化的纳米压印装置及方法 |
US9070548B2 (en) | 2012-03-06 | 2015-06-30 | Rohm And Haas Electronic Materials Llc | Metal hardmask compositions |
US8795774B2 (en) | 2012-09-23 | 2014-08-05 | Rohm And Haas Electronic Materials Llc | Hardmask |
US9136123B2 (en) | 2013-01-19 | 2015-09-15 | Rohm And Haas Electronic Materials Llc | Hardmask surface treatment |
US20150024522A1 (en) | 2013-07-22 | 2015-01-22 | Rohm And Haas Electronic Materials Llc | Organometal materials and process |
US8927439B1 (en) | 2013-07-22 | 2015-01-06 | Rohm And Haas Electronic Materials Llc | Organoaluminum materials for forming aluminum oxide layer from coating composition that contains organic solvent |
-
2013
- 2013-01-19 US US13/745,752 patent/US9171720B2/en active Active
-
2014
- 2014-01-20 KR KR1020140006711A patent/KR102219454B1/ko active IP Right Grant
- 2014-01-20 JP JP2014007972A patent/JP6491411B2/ja active Active
- 2014-01-20 CN CN201410153572.3A patent/CN103941538B/zh active Active
- 2014-01-20 TW TW103101936A patent/TWI543250B/zh active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6303270B1 (en) * | 1999-03-01 | 2001-10-16 | The Curators Of The University Of Missouri | Highly plasma etch-resistant photoresist composition containing a photosensitive polymeric titania precursor |
JP2005537502A (ja) * | 2002-06-25 | 2005-12-08 | ブルーワー サイエンス アイ エヌ シー. | マイクロエレクトロニクスの用途のための現像液に可溶なアルコキシド金属塗布膜 |
WO2005001901A2 (en) * | 2003-06-11 | 2005-01-06 | Brewer Science, Inc. | Wet developable hard mask in conjunction with thin photoresist for micro photolithography |
WO2006059652A1 (ja) * | 2004-12-01 | 2006-06-08 | Sanyo Electric Co., Ltd. | 有機金属ポリマー材料 |
JP2007256928A (ja) * | 2006-01-29 | 2007-10-04 | Rohm & Haas Electronic Materials Llc | オーバーコートされるフォトレジストと共に使用するための被覆組成物 |
JP2011508254A (ja) * | 2007-12-20 | 2011-03-10 | エイゼット・エレクトロニック・マテリアルズ・ユーエスエイ・コーポレイション | 反射防止膜上にコートされたフォトレジストに像を形成する方法 |
US20120223418A1 (en) * | 2011-02-28 | 2012-09-06 | Stowers Jason K | Solution processible hardmasks for high resolution lithography |
WO2013006314A2 (en) * | 2011-07-07 | 2013-01-10 | Brewer Science Inc. | Metal-oxide films from small molecules for lithographic applications |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018536096A (ja) * | 2015-09-29 | 2018-12-06 | ローム アンド ハース エレクトロニック マテリアルズ エルエルシーRohm and Haas Electronic Materials LLC | 複合材料多層構造を作製する方法 |
KR20170075410A (ko) * | 2015-12-23 | 2017-07-03 | 삼성전자주식회사 | 선택적 증착 층을 이용한 반도체 소자 형성 방법 및 관련된 소자 |
KR102471161B1 (ko) * | 2015-12-23 | 2022-11-25 | 삼성전자주식회사 | 선택적 증착 층을 이용한 반도체 소자 형성 방법 및 관련된 소자 |
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CN103941538A (zh) | 2014-07-23 |
JP6491411B2 (ja) | 2019-03-27 |
TW201442101A (zh) | 2014-11-01 |
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