JP2014144424A - アンモニア分解用触媒 - Google Patents

アンモニア分解用触媒 Download PDF

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Publication number
JP2014144424A
JP2014144424A JP2013014366A JP2013014366A JP2014144424A JP 2014144424 A JP2014144424 A JP 2014144424A JP 2013014366 A JP2013014366 A JP 2013014366A JP 2013014366 A JP2013014366 A JP 2013014366A JP 2014144424 A JP2014144424 A JP 2014144424A
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JP
Japan
Prior art keywords
catalyst
exhaust gas
ammonia
oxide
denitration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2013014366A
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English (en)
Japanese (ja)
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JP2014144424A5 (enExample
Inventor
Susumu Hizuya
進 日数谷
Naoe Hino
なおえ 日野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanadevia Corp
Original Assignee
Hitachi Zosen Corp
Hitachi Shipbuilding and Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Zosen Corp, Hitachi Shipbuilding and Engineering Co Ltd filed Critical Hitachi Zosen Corp
Priority to JP2013014366A priority Critical patent/JP2014144424A/ja
Priority to PCT/JP2013/079511 priority patent/WO2014119067A1/ja
Priority to EP13873998.2A priority patent/EP2952255A4/en
Priority to CN201380071657.0A priority patent/CN104955567B/zh
Priority to KR1020157020350A priority patent/KR20150110557A/ko
Publication of JP2014144424A publication Critical patent/JP2014144424A/ja
Publication of JP2014144424A5 publication Critical patent/JP2014144424A5/ja
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/204—Alkaline earth metals
    • B01D2255/2045—Calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20776—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20792—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/45—Gas separation or purification devices adapted for specific applications
    • B01D2259/4566—Gas separation or purification devices adapted for specific applications for use in transportation means
    • B01D2259/4575—Gas separation or purification devices adapted for specific applications for use in transportation means in aeroplanes or space ships
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9436—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
JP2013014366A 2013-01-29 2013-01-29 アンモニア分解用触媒 Pending JP2014144424A (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2013014366A JP2014144424A (ja) 2013-01-29 2013-01-29 アンモニア分解用触媒
PCT/JP2013/079511 WO2014119067A1 (ja) 2013-01-29 2013-10-31 アンモニア分解用触媒
EP13873998.2A EP2952255A4 (en) 2013-01-29 2013-10-31 CATALYST FOR THE DECOMPOSITION OF AMMONIA
CN201380071657.0A CN104955567B (zh) 2013-01-29 2013-10-31 氨分解用催化剂
KR1020157020350A KR20150110557A (ko) 2013-01-29 2013-10-31 암모니아 분해용 촉매

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2013014366A JP2014144424A (ja) 2013-01-29 2013-01-29 アンモニア分解用触媒

Publications (2)

Publication Number Publication Date
JP2014144424A true JP2014144424A (ja) 2014-08-14
JP2014144424A5 JP2014144424A5 (enExample) 2016-03-03

Family

ID=51261802

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2013014366A Pending JP2014144424A (ja) 2013-01-29 2013-01-29 アンモニア分解用触媒

Country Status (5)

Country Link
EP (1) EP2952255A4 (enExample)
JP (1) JP2014144424A (enExample)
KR (1) KR20150110557A (enExample)
CN (1) CN104955567B (enExample)
WO (1) WO2014119067A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105749943A (zh) * 2016-02-26 2016-07-13 东营信拓汽车消声器有限公司 一种低温烟气脱硝催化剂粉体及其制备方法
JP2017154090A (ja) * 2016-03-02 2017-09-07 三菱日立パワーシステムズ株式会社 金属水銀の酸化反応および窒素酸化物の還元反応用触媒、ならびに排ガスの浄化方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN122098633B (zh) * 2026-04-24 2026-07-24 中德晨晰环保工程有限公司 一种改性钒铁脱硝催化剂的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5258067A (en) * 1975-11-10 1977-05-13 Hitachi Ltd Method of oxidative decomposing ammonia
JP2004237244A (ja) * 2003-02-07 2004-08-26 Mitsubishi Heavy Ind Ltd 排ガス中の水銀除去方法およびそのシステム
JP2012035208A (ja) * 2010-08-09 2012-02-23 Babcock Hitachi Kk 触媒用金属基板およびこれを用いた脱硝触媒

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3727668B2 (ja) 1993-09-17 2005-12-14 三菱重工業株式会社 排ガスボイラ
JP2916377B2 (ja) 1994-03-02 1999-07-05 株式会社日本触媒 アンモニア分解用触媒およびその触媒を用いるアンモニアの分解方法
US5877330A (en) * 1995-06-08 1999-03-02 Nippon Shokubai Co., Ltd. Vanadium-containing catalysts, process for manufacturing and use of the same
JP2005342710A (ja) * 2004-05-07 2005-12-15 Mitsubishi Chemical Engineering Corp 耐熱性脱硝触媒
KR101595963B1 (ko) * 2008-09-17 2016-02-19 가부시기가이샤 닛뽕쇼꾸바이 암모니아 분해 촉매, 그 제조방법 및 암모니아 처리방법
JP5547936B2 (ja) * 2008-09-17 2014-07-16 株式会社日本触媒 アンモニア分解触媒およびその製造方法、ならびに、アンモニア処理方法
JP2011149329A (ja) 2010-01-21 2011-08-04 Mitsubishi Heavy Ind Ltd 舶用内燃機関
KR101197452B1 (ko) * 2010-08-31 2012-11-05 희성촉매 주식회사 내구성이 증진된 선택적 촉매환원 촉매
JP5995400B2 (ja) 2010-10-14 2016-09-21 三菱重工業株式会社 舶用排気ガス脱硝装置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5258067A (en) * 1975-11-10 1977-05-13 Hitachi Ltd Method of oxidative decomposing ammonia
JP2004237244A (ja) * 2003-02-07 2004-08-26 Mitsubishi Heavy Ind Ltd 排ガス中の水銀除去方法およびそのシステム
JP2012035208A (ja) * 2010-08-09 2012-02-23 Babcock Hitachi Kk 触媒用金属基板およびこれを用いた脱硝触媒

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105749943A (zh) * 2016-02-26 2016-07-13 东营信拓汽车消声器有限公司 一种低温烟气脱硝催化剂粉体及其制备方法
JP2017154090A (ja) * 2016-03-02 2017-09-07 三菱日立パワーシステムズ株式会社 金属水銀の酸化反応および窒素酸化物の還元反応用触媒、ならびに排ガスの浄化方法

Also Published As

Publication number Publication date
EP2952255A4 (en) 2016-10-26
EP2952255A1 (en) 2015-12-09
CN104955567A (zh) 2015-09-30
WO2014119067A1 (ja) 2014-08-07
CN104955567B (zh) 2018-08-28
KR20150110557A (ko) 2015-10-02

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