WO2014119067A1 - アンモニア分解用触媒 - Google Patents

アンモニア分解用触媒 Download PDF

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Publication number
WO2014119067A1
WO2014119067A1 PCT/JP2013/079511 JP2013079511W WO2014119067A1 WO 2014119067 A1 WO2014119067 A1 WO 2014119067A1 JP 2013079511 W JP2013079511 W JP 2013079511W WO 2014119067 A1 WO2014119067 A1 WO 2014119067A1
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Prior art keywords
catalyst
exhaust gas
ammonia
oxide
titanium oxide
Prior art date
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Ceased
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PCT/JP2013/079511
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English (en)
French (fr)
Japanese (ja)
Inventor
日数谷　進
なおえ 日野
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Kanadevia Corp
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Hitachi Zosen Corp
Hitachi Shipbuilding and Engineering Co Ltd
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Priority to CN201380071657.0A priority Critical patent/CN104955567B/zh
Priority to KR1020157020350A priority patent/KR20150110557A/ko
Priority to EP13873998.2A priority patent/EP2952255A4/en
Publication of WO2014119067A1 publication Critical patent/WO2014119067A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/204—Alkaline earth metals
    • B01D2255/2045—Calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20776—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20792—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/45—Gas separation or purification devices adapted for specific applications
    • B01D2259/4566—Gas separation or purification devices adapted for specific applications for use in transportation means
    • B01D2259/4575—Gas separation or purification devices adapted for specific applications for use in transportation means in aeroplanes or space ships
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9436—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Definitions

  • the present invention relates to an ammonia decomposition catalyst, and more specifically, ammonia having stable ammonia decomposition performance even in exhaust gas containing high-concentration sulfur oxide (SOx) such as exhaust gas from an internal combustion engine such as a marine diesel engine.
  • SOx high-concentration sulfur oxide
  • the present invention relates to a cracking catalyst.
  • engines used for ships and the like include marine propulsion engines, generator auxiliary engines, and incinerators, but the amount of exhaust gas from the two engines is large, and the engines include fossil fuels, particularly sulfur. Diesel engines that use A heavy oil and C heavy oil with a large amount of fuel are the mainstream, and nitrogen oxides (NOx) in exhaust gas are subject to regulation.
  • Diesel engines that use A heavy oil and C heavy oil with a large amount of fuel are the mainstream, and nitrogen oxides (NOx) in exhaust gas are subject to regulation.
  • NOx nitrogen oxides
  • a heat exchanger that recovers exhaust heat from an internal combustion engine such as a marine diesel engine may be installed downstream of the supercharger.
  • a heat exchanger is installed downstream of the denitration catalyst system using an ammonia-based reducing agent. When installed, substances derived from engine fuel, lubricating oil, and reducing agent accumulate on the heat exchanger, causing a blockage of the heat exchanger, and there is a problem that a continuous denitration system cannot be operated.
  • substances deposited on the heat exchanger include soot and calcium sulfate derived from fuel and lubricating oil, but ammonium sulfate and / or ammonium hydrogen sulfate are also detected. Moreover, it has been confirmed that these deposits are generated when an ammonia-based reducing agent is added.
  • Patent Documents 3 and 4 as an ammonia oxidation catalyst, a copper (Cu) supported catalyst, a composite oxide of titanium (Ti) and silicon (Si), vanadium (V), tungsten (W), and platinum ( A catalyst carrying Pt) is shown, and it is said that an SOx-containing exhaust gas is also effective.
  • SOx sulfur oxide
  • JP2011-149329A JP 2012-82804 A Japanese Patent Laid-Open No. 7-91644 Japanese Patent Laid-Open No. 7-289897
  • An object of the present invention is to solve the above-mentioned problems of the prior art, and to provide an ammonia decomposition catalyst having stable ammonia decomposition performance even in exhaust gas having a high sulfur oxide concentration such as exhaust gas from an internal combustion engine such as a marine diesel engine. Even if a heat exchanger for exhaust heat recovery is installed downstream of a denitration catalyst system using an ammonia-based reducing agent in purification processing of exhaust gas from internal combustion engines such as marine diesel engines The production of the derived ammonium sulfate and / or ammonium hydrogen sulfate can be suppressed, and these materials can be prevented from accumulating on the heat exchanger, thereby continuously preventing the heat exchanger from being blocked. It is an object of the present invention to provide an ammonia decomposition catalyst that enables operation of a denitration system for exhaust gas.
  • the present inventors have found that after purifying the exhaust gas of an internal combustion engine such as a marine diesel engine, after the denitration catalyst system using an ammonia-based reducing agent, sulfur oxidation As a catalyst for decomposing ammonia contained in exhaust gas with a high concentration of SOx, titanium oxide and vanadium oxide, or a denitration catalyst carrying titanium oxide, vanadium oxide and tungsten oxide as a catalyst base, and further catalytic activity It has been found that by using a catalyst supporting zinc, calcium and phosphorus as components, stable ammonia decomposition performance can be exhibited even when high concentration of SOx is contained in the exhaust gas. The invention has been completed.
  • the invention of claim 1 is a catalyst for decomposing ammonia in exhaust gas, wherein a denitration catalyst supporting titanium oxide and vanadium oxide is used as a catalyst base, and further as a catalyst active component. It is characterized by carrying zinc, calcium, and phosphorus.
  • the invention of claim 2 is a catalyst for decomposing ammonia in exhaust gas, comprising a denitration catalyst carrying titanium oxide, vanadium oxide and tungsten oxide as a catalyst base, and further zinc, calcium and phosphorus as catalytic active components. It is characterized by carrying.
  • the invention of claim 3 is the ammonia decomposition catalyst according to claim 1 or 2, characterized in that the exhaust gas is an exhaust gas of an internal combustion engine containing ammonia and sulfur oxides.
  • the denitration catalyst system using an ammonia reducing agent a high concentration of SOx (SO 2 and SO 3 )
  • SOx SO 2 and SO 3
  • a denitration catalyst using an ammonia-based reducing agent in purification treatment of exhaust gas from an internal combustion engine such as a marine diesel engine Even when a heat exchanger for exhaust heat recovery is installed downstream of the system, the production of ammonium sulfate and / or ammonium hydrogen sulfate derived from the reducing agent can be suppressed, and these substances accumulate on the heat exchanger. Therefore, the operation of the continuous exhaust gas denitration system can be performed without causing the heat exchanger to be blocked. An effect that becomes a function.
  • FIG 3 is a flow sheet of an ammonia decomposition experimental apparatus for evaluating the performance of the ammonia decomposition catalyst of the present invention.
  • a high concentration of SOx SO 2 and SO 3
  • a catalyst for decomposing ammonia in exhaust gas which comprises a denitration catalyst supporting titanium oxide and vanadium oxide as a catalyst base, and zinc (Zn), calcium (Ca), and phosphorus (P) as catalytic active components. It is characterized by carrying.
  • the present invention is a catalyst for decomposing ammonia in the exhaust gas, and a denitration catalyst supporting titanium oxide, vanadium oxide and tungsten oxide is used as a catalyst substrate, and zinc (Zn), calcium ( It is characterized by carrying Ca) and phosphorus (P).
  • ammonium vanadate (hereinafter referred to as AMV) is used as the vanadium precursor. It is preferable to use a powder.
  • the ammonium metavanadate powder preferably contains particles having a particle size of 10 ⁇ m or less in a cumulative content of 20% or more, preferably 25% or more.
  • AMV powder having a small particle size it is preferable to use a regenerated product from petroleum combustion ash such as heavy oil ash. This not only saves the time and effort of pulverization, but is also preferable because it is a recovered and recycled product, so that the production cost of the catalyst is very low.
  • AMT ammonium metatungstate
  • titania (titanium oxide) powder is added to a mixture of silica sol and water at a predetermined ratio to prepare a slurry.
  • ammonium metavanadate / AMV powder having a small particle size is added to the slurry at a predetermined ratio, and after stirring, the slurry is allowed to stand to adsorb ammonium metavanadate to titania.
  • an aqueous solution of ammonium metatungstate hereinafter referred to as AMT is added to the slurry at a predetermined ratio to prepare a slurry.
  • a honeycomb structure formed by alternately laminating corrugated plates (corrugated plates) and flat plates is immersed in the slurry thus prepared, and the catalyst precursor material in the slurry is supported on the honeycomb structure and taken out from the slurry.
  • the honeycomb structure is dried and then fired to prepare a corrugated honeycomb structure type catalyst substrate.
  • a catalyst base comprising a corrugated honeycomb structure type denitration catalyst in which titanium oxide and vanadium oxide, or titanium oxide, vanadium oxide and tungsten oxide are supported, zinc, calcium, and
  • phosphorus for example, it is carried out as follows.
  • the catalyst substrate made of the above denitration catalyst is immersed in an aqueous solution of zinc nitrate [Zn (NO 3 ) 2 ], then taken out, dried at 110 ° C., and then fired in air at 400 ° C. to oxidize zinc.
  • the product (ZnO 2 ) is supported.
  • the catalyst base is immersed in an aqueous solution of calcium nitrate [Ca (NO 3 ) 2 ], then taken out, dried at 110 ° C., and then fired in air at 400 ° C. to carry calcium oxide (CaO).
  • the catalyst substrate is immersed in a phosphoric acid (P 2 O 4 ) aqueous solution and then taken out.
  • the catalyst substrate is dried at 110 ° C. and then calcined in air at 400 ° C., thereby supporting the phosphor oxide (P 2 O 3 ). To do.
  • the amount of each catalytically active component of the catalyst for decomposing ammonia in the exhaust gas of the present invention thus obtained is compared with the catalyst base comprising a denitration catalyst supporting titanium oxide and vanadium oxide or titanium oxide, vanadium oxide and tungsten oxide.
  • the catalyst base comprising a denitration catalyst supporting titanium oxide and vanadium oxide or titanium oxide, vanadium oxide and tungsten oxide.
  • zinc (Zn) 0.01 to 5.0% by weight, preferably 0.05 to 1.0% by weight
  • a denitration catalyst supporting titanium oxide and vanadium oxide or titanium oxide, vanadium oxide and tungsten oxide is used as a catalyst base, and zinc (Zn) as a catalyst active component is further added thereto.
  • a catalyst carrying calcium (Ca) and phosphorus (P) after the denitration catalyst system using an ammonia-based reducing agent, in the purification treatment of exhaust gas from an internal combustion engine such as a marine diesel engine, Even if the exhaust gas contains high concentrations of SOx (SO 2 and SO 3 ), stable ammonia decomposition performance can be exhibited.
  • Example 1 The catalyst for decomposing ammonia in exhaust gas according to the present invention was produced by the following procedure.
  • the denitration catalyst which is the catalyst base, is immersed in an aqueous solution of zinc nitrate [Zn (NO 3 ) 2 ] for 10 minutes, then taken out, dried at 110 ° C., and calcined in air at 400 ° C. to carry zinc oxide. did.
  • the denitration catalyst as the catalyst base is immersed in an aqueous solution of calcium nitrate [Ca (NO 3 ] 2 ) for 10 minutes, then taken out, dried at 110 ° C., and calcined in the air at 400 ° C. to thereby obtain calcium oxide.
  • Ca (NO 3 ] 2 calcium nitrate
  • the catalyst substrate denitration catalyst is immersed in an aqueous solution of phosphoric acid [H 3 PO 4 ] for 10 minutes, then taken out, dried at 110 ° C., and baked at 400 ° C. in air to carry phosphorus oxide. did.
  • each catalytically active component of the catalyst for decomposing ammonia supported on the denitration catalyst that is the catalyst substrate is in element conversion with respect to the catalyst substrate composed of the denitration catalyst supporting titanium oxide, vanadium oxide, and tungsten oxide, Zinc (Zn) was 0.2 wt%, calcium (Ca) was 0.7 wt%, and phosphorus (P) was 0.6 wt%.
  • Example 2 In the same manner as in Example 1, a catalyst for decomposing ammonia in exhaust gas according to the present invention is produced. The difference from Example 1 is that titanium oxide and vanadium oxide are used as a denitration catalyst as a catalyst substrate.
  • a commercially available corrugated honeycomb structure type denitration catalyst (trade name: NOXNON700, manufactured by Hitachi Zosen) is used.
  • the amount of each catalytically active component of the ammonia decomposition catalyst supported on the denitration catalyst, which is the catalyst substrate, is 0 in terms of element in terms of element (Zn) with respect to the catalyst substrate comprising the denitration catalyst supporting titanium oxide and vanadium oxide. 0.22 wt%, calcium (Ca) was 0.78 wt%, and phosphorus (P) was 0.67 wt%.
  • ammonia decomposition reactor of the experimental apparatus shown in FIG. 1 was filled with the catalyst for decomposing ammonia in exhaust gas according to the present invention produced in Examples 1 and 2, respectively.
  • Comparative Example 1 a commercially available corrugated honeycomb structure type denitration catalyst (trade name: NOXNON700, manufactured by Hitachi Zosen) in which vanadium oxide and tungsten oxide are supported on titanium oxide was filled. Then, a catalyst for decomposing ammonia made of a commercially available platinum-supported aluminum oxide (trade name: DASH20M, manufactured by N.E. Chemcat) was filled.
  • the area velocity in the ammonia decomposition reactor of the experimental apparatus was 50 (m / h), and the reaction temperature was 420 ° C.
  • the area velocity is the amount of processing gas per gas contact area of the honeycomb type catalyst, and is represented by the following equation.
  • Example 1 Comparative Example 2
  • the ammonia decomposition catalyst of Example 1 of the present invention can obtain a stable ammonia decomposition rate even after addition of SOx.
  • the exhaust gas after the denitration catalyst system using the ammonia reducing agent in the purification treatment of the exhaust gas of the internal combustion engine such as the marine diesel engine Even when high concentration SOx (SO 2 and SO 3 ) is contained, it exhibits stable ammonia decomposition performance, and in the purification treatment of exhaust gas etc. of internal combustion engines such as marine diesel engines, an ammonia-based reducing agent Even when a heat exchanger for exhaust heat recovery is installed downstream of a denitration catalyst system using a catalyst, the production of ammonium sulfate and / or ammonium hydrogen sulfate derived from the reducing agent can be suppressed, and these substances are heated. Can be prevented from accumulating on the exchanger, which prevents the exhaust gas Operation of nitric system that is capable confirmed.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
PCT/JP2013/079511 2013-01-29 2013-10-31 アンモニア分解用触媒 Ceased WO2014119067A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201380071657.0A CN104955567B (zh) 2013-01-29 2013-10-31 氨分解用催化剂
KR1020157020350A KR20150110557A (ko) 2013-01-29 2013-10-31 암모니아 분해용 촉매
EP13873998.2A EP2952255A4 (en) 2013-01-29 2013-10-31 CATALYST FOR THE DECOMPOSITION OF AMMONIA

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JP2013014366A JP2014144424A (ja) 2013-01-29 2013-01-29 アンモニア分解用触媒
JP2013-014366 2013-01-29

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CN105749943A (zh) * 2016-02-26 2016-07-13 东营信拓汽车消声器有限公司 一种低温烟气脱硝催化剂粉体及其制备方法
JP6697287B2 (ja) * 2016-03-02 2020-05-20 三菱日立パワーシステムズ株式会社 金属水銀の酸化反応および窒素酸化物の還元反応用触媒、ならびに排ガスの浄化方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0791644A (ja) 1993-09-17 1995-04-04 Mitsubishi Heavy Ind Ltd 排ガスボイラ
JPH07289897A (ja) 1994-03-02 1995-11-07 Nippon Shokubai Co Ltd アンモニア分解用触媒およびその触媒を用いるアンモニアの分解方法
WO1996041678A1 (fr) * 1995-06-08 1996-12-27 Nippon Shokubai Co., Ltd. Catalyseur contenant du vanadium, procede pour sa preparation et son utilisation
JP2005342710A (ja) * 2004-05-07 2005-12-15 Mitsubishi Chemical Engineering Corp 耐熱性脱硝触媒
JP2010094668A (ja) * 2008-09-17 2010-04-30 Nippon Shokubai Co Ltd アンモニア分解触媒およびその製造方法、ならびに、アンモニア処理方法
JP2011149329A (ja) 2010-01-21 2011-08-04 Mitsubishi Heavy Ind Ltd 舶用内燃機関
JP2012035208A (ja) * 2010-08-09 2012-02-23 Babcock Hitachi Kk 触媒用金属基板およびこれを用いた脱硝触媒
JP2012082804A (ja) 2010-10-14 2012-04-26 Mitsubishi Heavy Ind Ltd 舶用排気ガス脱硝装置

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5258067A (en) * 1975-11-10 1977-05-13 Hitachi Ltd Method of oxidative decomposing ammonia
JP4175465B2 (ja) * 2003-02-07 2008-11-05 三菱重工業株式会社 排ガス中の水銀除去方法およびそのシステム
US20110176988A1 (en) * 2008-09-17 2011-07-21 Junji Okamura Ammonia decomposition catalysts and their production processes, as well as ammonia treatment method
KR101197452B1 (ko) * 2010-08-31 2012-11-05 희성촉매 주식회사 내구성이 증진된 선택적 촉매환원 촉매

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0791644A (ja) 1993-09-17 1995-04-04 Mitsubishi Heavy Ind Ltd 排ガスボイラ
JPH07289897A (ja) 1994-03-02 1995-11-07 Nippon Shokubai Co Ltd アンモニア分解用触媒およびその触媒を用いるアンモニアの分解方法
WO1996041678A1 (fr) * 1995-06-08 1996-12-27 Nippon Shokubai Co., Ltd. Catalyseur contenant du vanadium, procede pour sa preparation et son utilisation
JP2005342710A (ja) * 2004-05-07 2005-12-15 Mitsubishi Chemical Engineering Corp 耐熱性脱硝触媒
JP2010094668A (ja) * 2008-09-17 2010-04-30 Nippon Shokubai Co Ltd アンモニア分解触媒およびその製造方法、ならびに、アンモニア処理方法
JP2011149329A (ja) 2010-01-21 2011-08-04 Mitsubishi Heavy Ind Ltd 舶用内燃機関
JP2012035208A (ja) * 2010-08-09 2012-02-23 Babcock Hitachi Kk 触媒用金属基板およびこれを用いた脱硝触媒
JP2012082804A (ja) 2010-10-14 2012-04-26 Mitsubishi Heavy Ind Ltd 舶用排気ガス脱硝装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2952255A4

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CN104955567B (zh) 2018-08-28
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CN104955567A (zh) 2015-09-30
EP2952255A4 (en) 2016-10-26
EP2952255A1 (en) 2015-12-09

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