JP2013533804A - NOxの選択的還元用の銅含有ZSM−34、OFF及び/又はERIゼオライト系材料 - Google Patents

NOxの選択的還元用の銅含有ZSM−34、OFF及び/又はERIゼオライト系材料 Download PDF

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Publication number
JP2013533804A
JP2013533804A JP2013519191A JP2013519191A JP2013533804A JP 2013533804 A JP2013533804 A JP 2013533804A JP 2013519191 A JP2013519191 A JP 2013519191A JP 2013519191 A JP2013519191 A JP 2013519191A JP 2013533804 A JP2013533804 A JP 2013533804A
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JP
Japan
Prior art keywords
copper
zeolitic material
zsm
eri
containing zsm
Prior art date
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Withdrawn
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JP2013519191A
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English (en)
Japanese (ja)
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JP2013533804A5 (enExample
Inventor
ブル,アイバー
ミュラー,ウルリヒ
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BASF SE
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BASF SE
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Publication of JP2013533804A publication Critical patent/JP2013533804A/ja
Publication of JP2013533804A5 publication Critical patent/JP2013533804A5/ja
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B01J29/52Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing iron group metals, noble metals or copper
    • B01J29/56Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00Heat treatments such as Calcining; Fusing ; Pyrolysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2067Urea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/202Alkali metals
    • B01D2255/2022Potassium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/012Diesel engines and lean burn gasoline engines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
JP2013519191A 2010-07-15 2011-07-05 NOxの選択的還元用の銅含有ZSM−34、OFF及び/又はERIゼオライト系材料 Withdrawn JP2013533804A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10169676 2010-07-15
EP10169676.3 2010-07-15
PCT/IB2011/052980 WO2012007874A1 (en) 2010-07-15 2011-07-05 Copper containing zsm-34, off and/or eri zeolitic material for selective reduction of nox

Publications (2)

Publication Number Publication Date
JP2013533804A true JP2013533804A (ja) 2013-08-29
JP2013533804A5 JP2013533804A5 (enExample) 2014-08-21

Family

ID=45468997

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2013519191A Withdrawn JP2013533804A (ja) 2010-07-15 2011-07-05 NOxの選択的還元用の銅含有ZSM−34、OFF及び/又はERIゼオライト系材料

Country Status (6)

Country Link
EP (1) EP2593223A4 (enExample)
JP (1) JP2013533804A (enExample)
KR (1) KR20130044322A (enExample)
CN (1) CN103180041A (enExample)
BR (1) BR112013001046A2 (enExample)
WO (1) WO2012007874A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017510443A (ja) * 2014-03-24 2017-04-13 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company 排気ガス処理のための方法及びシステム

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9527751B2 (en) 2011-11-11 2016-12-27 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
JP6416096B2 (ja) * 2012-09-28 2018-10-31 パシフィック インダストリアル デベロップメント コーポレイション 選択触媒還元反応における触媒として使用するためのstt型ゼオライトの調製方法
US9925492B2 (en) 2014-03-24 2018-03-27 Mellanox Technologies, Ltd. Remote transactional memory
KR20170132158A (ko) * 2015-03-25 2017-12-01 존슨 맛쎄이 퍼블릭 리미티드 컴파니 귀금속 및 OFF 프레임워크 유형을 갖는 분자체를 포함하는 수동 NOx 흡착제
US11014077B2 (en) * 2016-05-03 2021-05-25 Umicore Ag & Co. Kg Active SCR catalyst
CN110997138A (zh) * 2017-06-09 2020-04-10 巴斯夫公司 用于NOx减排的具有受控孔隙率的催化洗涂层
CN112955255B (zh) * 2018-10-30 2023-07-21 巴斯夫公司 在预交换铜沸石材料上的原位铜离子交换
CN115138391B (zh) * 2021-03-29 2025-05-09 高化学株式会社 低温羰基化分子筛催化剂及其用途
CN113198525B (zh) * 2021-05-08 2023-05-09 北京工业大学 一种低温条件下笑气分解和NOx催化还原协同净化的催化剂及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2671551B2 (ja) * 1990-03-16 1997-10-29 トヨタ自動車株式会社 排気浄化用触媒の製造方法
JP3276678B2 (ja) * 1992-07-02 2002-04-22 出光興産株式会社 排ガス浄化用触媒及びこれを使用した排ガスの浄化方法
US5254322A (en) * 1992-08-10 1993-10-19 Mobil Oil Corporation Method for reducing automotive NOx emissions in lean burn internal combustion engine exhaust using a transition metal-containing zeolite catalyst which is in-situ crystallized
CN100515561C (zh) * 2003-12-16 2009-07-22 广东工业大学 一种高效净化汽车尾气催化剂及制备方法
KR101394774B1 (ko) * 2005-12-14 2014-05-15 바스프 카탈리스트 엘엘씨 SCR에서의 NOx 환원이 개선된 제올라이트 촉매
DK3278863T3 (da) * 2007-04-26 2020-02-17 Johnson Matthey Plc Overgangsmetal/aei-zeolit-scr-katalysator

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017510443A (ja) * 2014-03-24 2017-04-13 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company 排気ガス処理のための方法及びシステム
JP2019188395A (ja) * 2014-03-24 2019-10-31 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Publiclimited Company 排気ガス処理のための方法及びシステム

Also Published As

Publication number Publication date
EP2593223A1 (en) 2013-05-22
EP2593223A4 (en) 2014-02-12
WO2012007874A1 (en) 2012-01-19
KR20130044322A (ko) 2013-05-02
CN103180041A (zh) 2013-06-26
BR112013001046A2 (pt) 2016-05-24

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