JP2013517319A5 - - Google Patents
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- Publication number
- JP2013517319A5 JP2013517319A5 JP2012549378A JP2012549378A JP2013517319A5 JP 2013517319 A5 JP2013517319 A5 JP 2013517319A5 JP 2012549378 A JP2012549378 A JP 2012549378A JP 2012549378 A JP2012549378 A JP 2012549378A JP 2013517319 A5 JP2013517319 A5 JP 2013517319A5
- Authority
- JP
- Japan
- Prior art keywords
- use according
- zeolite
- earth metal
- catalyst
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 239000010457 zeolite Substances 0.000 claims description 9
- 229910021536 Zeolite Inorganic materials 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims 6
- -1 alkaline earth metal salts Chemical class 0.000 claims 5
- 229910052761 rare earth metal Inorganic materials 0.000 claims 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 230000018044 dehydration Effects 0.000 claims 1
- 238000006297 dehydration reaction Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000002808 molecular sieve Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 150000002910 rare earth metals Chemical class 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10151507.0 | 2010-01-25 | ||
| EP10151507A EP2348004A1 (en) | 2010-01-25 | 2010-01-25 | Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process |
| PCT/EP2011/050964 WO2011089263A1 (en) | 2010-01-25 | 2011-01-25 | Method for making a catalyst comprising a phosphorus modified zeolite to be used in an alcohols dehydration process |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014185813A Division JP2015034164A (ja) | 2010-01-25 | 2014-09-12 | アルコールの脱水反応で使用するリン変成ゼオライトを含む触媒の製造方法 |
| JP2015133219A Division JP2015211970A (ja) | 2010-01-25 | 2015-07-02 | アルコールの脱水反応で使用するリン変成ゼオライトを含む触媒の製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013517319A JP2013517319A (ja) | 2013-05-16 |
| JP2013517319A5 true JP2013517319A5 (enExample) | 2014-11-06 |
| JP5833569B2 JP5833569B2 (ja) | 2015-12-16 |
Family
ID=42243450
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012549378A Expired - Fee Related JP5833569B2 (ja) | 2010-01-25 | 2011-01-25 | アルコールの脱水反応で使用するリン変成ゼオライトを含む触媒の製造方法 |
| JP2014185813A Pending JP2015034164A (ja) | 2010-01-25 | 2014-09-12 | アルコールの脱水反応で使用するリン変成ゼオライトを含む触媒の製造方法 |
| JP2015133219A Pending JP2015211970A (ja) | 2010-01-25 | 2015-07-02 | アルコールの脱水反応で使用するリン変成ゼオライトを含む触媒の製造方法 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014185813A Pending JP2015034164A (ja) | 2010-01-25 | 2014-09-12 | アルコールの脱水反応で使用するリン変成ゼオライトを含む触媒の製造方法 |
| JP2015133219A Pending JP2015211970A (ja) | 2010-01-25 | 2015-07-02 | アルコールの脱水反応で使用するリン変成ゼオライトを含む触媒の製造方法 |
Country Status (18)
| Country | Link |
|---|---|
| US (4) | US8981173B2 (enExample) |
| EP (3) | EP2348004A1 (enExample) |
| JP (3) | JP5833569B2 (enExample) |
| KR (1) | KR101549733B1 (enExample) |
| CN (2) | CN102858718B (enExample) |
| AR (1) | AR080012A1 (enExample) |
| BR (1) | BR112012018501A8 (enExample) |
| CA (1) | CA2787548C (enExample) |
| CO (1) | CO6571890A2 (enExample) |
| DK (1) | DK2528881T3 (enExample) |
| EA (2) | EA023019B1 (enExample) |
| ES (1) | ES2657429T3 (enExample) |
| IN (1) | IN2012DN06276A (enExample) |
| MY (1) | MY159864A (enExample) |
| PE (1) | PE20130568A1 (enExample) |
| PL (1) | PL2528881T3 (enExample) |
| UA (1) | UA104077C2 (enExample) |
| WO (2) | WO2011089262A1 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2348004A1 (en) | 2010-01-25 | 2011-07-27 | Total Petrochemicals Research Feluy | Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process |
| US9314780B2 (en) | 2010-11-02 | 2016-04-19 | Saudi Basic Industries Corporation | Process for producing light olefins by using a ZSM-5-based catalyst |
| DE102011013909A1 (de) * | 2011-03-15 | 2012-09-20 | Süd-Chemie AG | Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine |
| DE102011013911A1 (de) * | 2011-03-15 | 2012-09-20 | Süd-Chemie AG | Verbessertes Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine |
| DE102011013908A1 (de) * | 2011-03-15 | 2012-09-20 | Süd-Chemie AG | Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen |
| ES2865106T3 (es) * | 2011-08-03 | 2021-10-15 | Total Res & Technology Feluy | Procedimiento de preparación de un catalizador que comprende una zeolita modificada con fósforo y uso de dicha zeolita |
| US9862653B2 (en) * | 2011-08-03 | 2018-01-09 | IFP Energies Nouvelles | Use of a catalyst comprising a phosphorous modified zeolite in an alcohol dehydration process |
| EA030477B1 (ru) * | 2011-08-03 | 2018-08-31 | Тотал Ресерч & Технолоджи Фелай | Катализатор на основе модифицированного фосфором цеолита с частичной alpo-структурой |
| JP5797545B2 (ja) * | 2011-12-26 | 2015-10-21 | 旭化成ケミカルズ株式会社 | 触媒前駆体の熱処理方法、触媒の製造方法、並びにプロピレンの製造方法 |
| EP2805933B1 (en) * | 2012-01-20 | 2016-12-14 | Mitsui Chemicals, Inc. | Method for producing olefin |
| US20140005455A1 (en) | 2012-06-29 | 2014-01-02 | Basf Se | Process for the conversion of oxygenates to olefins |
| RU2015102198A (ru) * | 2012-06-29 | 2016-08-20 | Басф Се | Катализатор и способ превращения оксигенатов в олефины |
| US9597669B2 (en) | 2012-06-29 | 2017-03-21 | Basf Se | Catalyst and process for the conversion of oxygenates to olefins |
| US10005702B2 (en) | 2012-06-29 | 2018-06-26 | Basf Se | Catalyst coating and process for the conversion of oxygenates to olefins |
| US9518229B2 (en) | 2012-07-20 | 2016-12-13 | Inaeris Technologies, Llc | Catalysts for thermo-catalytic conversion of biomass, and methods of making and using |
| JP5883753B2 (ja) * | 2012-09-24 | 2016-03-15 | 積水化学工業株式会社 | 塩化ビニルモノマーの製造方法 |
| US9636668B2 (en) | 2012-11-13 | 2017-05-02 | Basf Se | Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins |
| CN104918886B (zh) * | 2012-11-13 | 2018-08-10 | 巴斯夫欧洲公司 | 沸石材料的制备和在将氧合物转化成烯烃的方法中的用途 |
| US9522392B2 (en) * | 2013-03-15 | 2016-12-20 | Inaeris Technologies, Llc | Phosphorous promotion of zeolite-containing catalysts |
| WO2014196517A1 (ja) * | 2013-06-07 | 2014-12-11 | 三井化学株式会社 | オレフィンの製造方法、およびこれに用いられる脱水触媒 |
| WO2015091078A1 (de) | 2013-12-20 | 2015-06-25 | Clariant Produkte (Deutschland) Gmbh | Phosphorhaltiger katalysator zur umwandlung von oxygenaten in olefine |
| BR112016014313A8 (pt) * | 2013-12-20 | 2020-06-02 | Basf Se | catalisadores para a conversão de oxigenados em olefinas, processo para preparar um catalisador, processo para converter oxigenados em olefinas e uso de um catalisador |
| DE102014012920B3 (de) | 2014-09-05 | 2016-01-07 | miha bodytec GmbH | EMS-Trainingsvorrichtung, sowie EMS- Elektrode, EMS-Kleidungsstück, EMS-Reizerzeugungseinheit, EMS-Signalkabel und EMS-Unterbekleidungsstück dafür und Verfahren zum Betrieb eines EMS- Trainingsgeräts. |
| DE102014018607B4 (de) | 2014-12-16 | 2017-02-16 | miha bodytec GmbH | EMS-Trainingsvorrichtung, sowie Verfahren zum Betrieb einer EMS-Trainingsvorrichtung |
| DE102014018683B4 (de) | 2014-12-18 | 2017-11-02 | miha bodytec GmbH | EMS-Reizstromübertragungselement, sowie mit dem EMS-Reizstromübertragungselement ausgestattetes EMS-Kleidungsstück |
| BR112017014221A2 (pt) | 2014-12-31 | 2018-03-06 | Ifp Energies Now | processo para a preparação olefinas pela desidratação de álcoois com menores efeitos colaterais compreendendo a adição de ácidos orgânicos |
| WO2016107759A1 (en) | 2014-12-31 | 2016-07-07 | Total Research & Technology Feluy | Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of sulfur containing compounds |
| US10851028B2 (en) * | 2016-09-09 | 2020-12-01 | Total Research & Technology Feluy | Process for dehydration of mono-alcohol(s) using a modified crystalline aluminosilicate |
| KR102023246B1 (ko) * | 2017-10-26 | 2019-09-19 | 전남대학교산학협력단 | 세륨산화물이 담지된 fer 제올라이트 촉매를 이용하여 mto 반응에서 선택적으로 c4-c6 올레핀 및 파라핀의 수율을 향상시키는 방법 |
| CN109704356B (zh) * | 2017-10-26 | 2021-05-11 | 中国石油化工股份有限公司 | Eu-1沸石分子筛的合成方法 |
| JP7222743B2 (ja) * | 2018-02-14 | 2023-02-15 | 三菱ケミカル株式会社 | ゼオライト触媒及び該ゼオライト触媒を用いた低級オレフィンの製造方法 |
| US11118050B2 (en) | 2018-12-07 | 2021-09-14 | The Goodyear Tire & Rubber Company | Functionalized polymer, rubber composition and pneumatic tire |
| US11117997B2 (en) * | 2018-12-07 | 2021-09-14 | The Goodyear Tire & Rubber Company | Functionalized polymer, rubber composition and pneumatic tire |
| CN110882718B (zh) * | 2019-12-05 | 2022-06-28 | 大连海鑫化工有限公司 | 金属改性mfi@mfi核壳型分子筛催化剂及其制备 |
| CN111545243A (zh) * | 2020-06-02 | 2020-08-18 | 贵州理工学院 | 一种复合光热催化剂及其制备方法和应用 |
| DK181711B1 (en) | 2023-03-29 | 2024-10-28 | Topsoe As | Process and plant for the conversion of oxygenates to C5+ hydrocarbons boiling in the jet fuel boiling range |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3911041A (en) | 1974-09-23 | 1975-10-07 | Mobil Oil Corp | Conversion of methanol and dimethyl ether |
| US3972832A (en) | 1974-09-23 | 1976-08-03 | Mobil Oil Corporation | Phosphorus-containing zeolite catalyst |
| US4356338A (en) | 1979-07-27 | 1982-10-26 | Mobil Oil Corporation | Extending catalyst life by treating with phosphorus and/or steam |
| US4433189A (en) * | 1982-03-18 | 1984-02-21 | Mobil Oil Corporation | Catalytic conversion of methanol to light olefins |
| JPH07106317B2 (ja) * | 1987-02-13 | 1995-11-15 | 触媒化成工業株式会社 | 炭化水素油の接触分解用触媒組成物の製造方法 |
| AU652222B2 (en) * | 1991-03-12 | 1994-08-18 | Mobil Oil Corporation | Preparation of cracking catalysts, and cracking process using them |
| US5231064A (en) | 1991-03-12 | 1993-07-27 | Mobil Oil Corp. | Cracking catalysts comprising phosphorus and method of preparing and using the same |
| US5171921A (en) | 1991-04-26 | 1992-12-15 | Arco Chemical Technology, L.P. | Production of olefins |
| EP0568913A3 (en) | 1992-05-03 | 1995-03-22 | Dalian Chemical Physics Inst | Process for the conversion of methanol to light olefins and catalysts used therefor. |
| US6797851B2 (en) | 2001-08-30 | 2004-09-28 | Exxonmobil Chemical Patents Inc. | Two catalyst process for making olefin |
| US6644015B2 (en) * | 2001-10-29 | 2003-11-11 | Hmx, Inc. | Turbojet with precompressor injected oxidizer |
| US6872680B2 (en) * | 2002-03-20 | 2005-03-29 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
| EP1396481A1 (en) | 2002-08-14 | 2004-03-10 | ATOFINA Research | Production of olefins |
| EP1508555A1 (en) | 2003-08-19 | 2005-02-23 | Total Petrochemicals Research Feluy | Production of olefins |
| US7408092B2 (en) | 2004-11-12 | 2008-08-05 | Uop Llc | Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst |
| US7662737B2 (en) * | 2005-12-22 | 2010-02-16 | Saudi Basic Industries Corporation | Bound phosphorus-modified zeolite catalyst, method of preparing and method of using thereof |
| JP4951263B2 (ja) * | 2006-04-05 | 2012-06-13 | 出光興産株式会社 | オレフィン類の製造方法 |
| JP4904076B2 (ja) * | 2006-04-24 | 2012-03-28 | 出光興産株式会社 | 含酸素化合物からのオレフィン類の製造方法 |
| EP2025402A1 (en) | 2007-07-31 | 2009-02-18 | Total Petrochemicals Research Feluy | Phosphorus modified molecular sieves, their use in conversion of organics to olefins |
| EP1970361A1 (en) | 2007-03-13 | 2008-09-17 | Total Petrochemicals Research Feluy | MTO process based on MeAPO molecular sieves combined with an OCP process to make olefins |
| EP1970351A1 (en) | 2007-03-13 | 2008-09-17 | Total Petrochemicals Research Feluy | Method of preparing metalloaluminophosphate (Meapo) molecular sieve |
| EP1970350A1 (en) | 2007-03-13 | 2008-09-17 | Total Petrochemicals Research Feluy | Metalloaluminophosphate molecular sieves with lamellar crystal morphology and their preparation |
| EP2027918A1 (en) | 2007-07-31 | 2009-02-25 | Total Petrochemicals Research Feluy | Mixtures of molecular sieves comprising MeAPO, their use in conversion of organics to olefins |
| EP2082802A1 (en) * | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining a catalyst composite |
| MX2010008722A (es) | 2008-02-07 | 2010-11-30 | Total Petrochemicals Res Feluy | Deshidratacion de alcoholes en presencia de un componente inerte. |
| US20110137096A1 (en) | 2008-02-07 | 2011-06-09 | Total Petrochemicals Research Feluy | Process to Make Olefins from Ethanol |
| KR101227221B1 (ko) | 2008-02-07 | 2013-01-28 | 토탈 리서치 앤드 테크놀로지 펠루이 | 에탄올로부터의 올레핀의 제조 방법 |
| MX2010008723A (es) | 2008-02-07 | 2010-11-30 | Total Petrochemicals Res Feluy | Deshidratacion de alcoholes en silicatos cristalinos. |
| EP2143700A1 (en) * | 2008-06-25 | 2010-01-13 | Total Petrochemicals Research Feluy | Process to make olefins from oxygenates |
| EP2300396B1 (en) | 2008-06-25 | 2019-08-07 | Total Research & Technology Feluy | Process to make olefins from oxygenates |
| EA020577B1 (ru) * | 2008-06-25 | 2014-12-30 | Тотал Ресерч Энд Текнолоджи Фелюи | Способ получения олефинов из оксигенатов |
| WO2010100069A1 (en) * | 2009-03-03 | 2010-09-10 | Total Petrochemicals Research Feluy | Process to make olefins from organics and paraffins |
| EP2348004A1 (en) | 2010-01-25 | 2011-07-27 | Total Petrochemicals Research Feluy | Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process |
-
2010
- 2010-01-25 EP EP10151507A patent/EP2348004A1/en not_active Withdrawn
-
2011
- 2011-01-25 EP EP11700691.6A patent/EP2528880B1/en not_active Not-in-force
- 2011-01-25 US US13/522,623 patent/US8981173B2/en not_active Expired - Fee Related
- 2011-01-25 US US13/522,633 patent/US9067199B2/en not_active Expired - Fee Related
- 2011-01-25 DK DK11701105.6T patent/DK2528881T3/en active
- 2011-01-25 UA UAA201209973A patent/UA104077C2/ru unknown
- 2011-01-25 EA EA201270694A patent/EA023019B1/ru not_active IP Right Cessation
- 2011-01-25 WO PCT/EP2011/050963 patent/WO2011089262A1/en not_active Ceased
- 2011-01-25 JP JP2012549378A patent/JP5833569B2/ja not_active Expired - Fee Related
- 2011-01-25 PE PE2012001054A patent/PE20130568A1/es active IP Right Grant
- 2011-01-25 CN CN201180015678.1A patent/CN102858718B/zh not_active Expired - Fee Related
- 2011-01-25 EP EP11701105.6A patent/EP2528881B1/en not_active Not-in-force
- 2011-01-25 WO PCT/EP2011/050964 patent/WO2011089263A1/en not_active Ceased
- 2011-01-25 MY MYPI2012003115A patent/MY159864A/en unknown
- 2011-01-25 KR KR1020127019712A patent/KR101549733B1/ko not_active Expired - Fee Related
- 2011-01-25 ES ES11701105.6T patent/ES2657429T3/es active Active
- 2011-01-25 PL PL11701105T patent/PL2528881T3/pl unknown
- 2011-01-25 CN CN201180015677.7A patent/CN102822124B/zh not_active Expired - Fee Related
- 2011-01-25 EA EA201270686A patent/EA023291B1/ru not_active IP Right Cessation
- 2011-01-25 AR ARP110100231A patent/AR080012A1/es not_active Application Discontinuation
- 2011-01-25 CA CA2787548A patent/CA2787548C/en not_active Expired - Fee Related
- 2011-01-25 BR BR112012018501A patent/BR112012018501A8/pt not_active IP Right Cessation
- 2011-01-25 IN IN6276DEN2012 patent/IN2012DN06276A/en unknown
-
2012
- 2012-07-24 CO CO12124045A patent/CO6571890A2/es active IP Right Grant
-
2014
- 2014-09-12 JP JP2014185813A patent/JP2015034164A/ja active Pending
-
2015
- 2015-01-08 US US14/592,756 patent/US9260356B2/en not_active Expired - Fee Related
- 2015-05-21 US US14/718,533 patent/US20150251970A1/en not_active Abandoned
- 2015-07-02 JP JP2015133219A patent/JP2015211970A/ja active Pending
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