CN102822124B - 制造用于mto工艺的包含磷改性沸石的催化剂的方法 - Google Patents

制造用于mto工艺的包含磷改性沸石的催化剂的方法 Download PDF

Info

Publication number
CN102822124B
CN102822124B CN201180015677.7A CN201180015677A CN102822124B CN 102822124 B CN102822124 B CN 102822124B CN 201180015677 A CN201180015677 A CN 201180015677A CN 102822124 B CN102822124 B CN 102822124B
Authority
CN
China
Prior art keywords
zeolite
catalyst
phosphorus
metal salts
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201180015677.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN102822124A (zh
Inventor
N.内斯特伦科
S.范唐克
D.米诺克斯
J-P.达思
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Petrochemicals Research Feluy SA
Original Assignee
Total Petrochemicals Research Feluy SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Petrochemicals Research Feluy SA filed Critical Total Petrochemicals Research Feluy SA
Publication of CN102822124A publication Critical patent/CN102822124A/zh
Application granted granted Critical
Publication of CN102822124B publication Critical patent/CN102822124B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201180015677.7A 2010-01-25 2011-01-25 制造用于mto工艺的包含磷改性沸石的催化剂的方法 Expired - Fee Related CN102822124B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10151507.0 2010-01-25
EP10151507A EP2348004A1 (en) 2010-01-25 2010-01-25 Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process
PCT/EP2011/050963 WO2011089262A1 (en) 2010-01-25 2011-01-25 Method for making a catalyst comprising a phosphorus modified zeolite to be used in a mto process

Publications (2)

Publication Number Publication Date
CN102822124A CN102822124A (zh) 2012-12-12
CN102822124B true CN102822124B (zh) 2015-06-17

Family

ID=42243450

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201180015677.7A Expired - Fee Related CN102822124B (zh) 2010-01-25 2011-01-25 制造用于mto工艺的包含磷改性沸石的催化剂的方法
CN201180015678.1A Expired - Fee Related CN102858718B (zh) 2010-01-25 2011-01-25 制造用于醇脱水工艺的包含磷改性沸石的催化剂的方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201180015678.1A Expired - Fee Related CN102858718B (zh) 2010-01-25 2011-01-25 制造用于醇脱水工艺的包含磷改性沸石的催化剂的方法

Country Status (18)

Country Link
US (4) US8981173B2 (enExample)
EP (3) EP2348004A1 (enExample)
JP (3) JP5833569B2 (enExample)
KR (1) KR101549733B1 (enExample)
CN (2) CN102822124B (enExample)
AR (1) AR080012A1 (enExample)
BR (1) BR112012018501A8 (enExample)
CA (1) CA2787548C (enExample)
CO (1) CO6571890A2 (enExample)
DK (1) DK2528881T3 (enExample)
EA (2) EA023291B1 (enExample)
ES (1) ES2657429T3 (enExample)
IN (1) IN2012DN06276A (enExample)
MY (1) MY159864A (enExample)
PE (1) PE20130568A1 (enExample)
PL (1) PL2528881T3 (enExample)
UA (1) UA104077C2 (enExample)
WO (2) WO2011089262A1 (enExample)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2348004A1 (en) 2010-01-25 2011-07-27 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process
EP2635376A1 (en) 2010-11-02 2013-09-11 Saudi Basic Industries Corporation Process for producing light olefins by using a zsm - 5 - based catalyst
DE102011013911A1 (de) * 2011-03-15 2012-09-20 Süd-Chemie AG Verbessertes Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine
DE102011013909A1 (de) * 2011-03-15 2012-09-20 Süd-Chemie AG Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine
DE102011013908A1 (de) * 2011-03-15 2012-09-20 Süd-Chemie AG Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen
EA030477B1 (ru) 2011-08-03 2018-08-31 Тотал Ресерч & Технолоджи Фелай Катализатор на основе модифицированного фосфором цеолита с частичной alpo-структурой
EP2739390B1 (en) * 2011-08-03 2021-03-10 Total Research & Technology Feluy Method of converting at least an alcohol into light olefins
EA028645B1 (ru) * 2011-08-03 2017-12-29 Тотал Ресерч & Технолоджи Фелай Способ приготовления катализатора на основе модифицированного фосфором цеолита и применение такого цеолита
JP5797545B2 (ja) * 2011-12-26 2015-10-21 旭化成ケミカルズ株式会社 触媒前駆体の熱処理方法、触媒の製造方法、並びにプロピレンの製造方法
CN104053639A (zh) * 2012-01-20 2014-09-17 三井化学株式会社 烯烃的制造方法
BR112014031391B1 (pt) * 2012-06-29 2020-12-08 Basf Se processos para a preparação de um catalisador para a conversão de oxigenados em olefinas
US10005702B2 (en) 2012-06-29 2018-06-26 Basf Se Catalyst coating and process for the conversion of oxygenates to olefins
US9597669B2 (en) 2012-06-29 2017-03-21 Basf Se Catalyst and process for the conversion of oxygenates to olefins
US20140005455A1 (en) 2012-06-29 2014-01-02 Basf Se Process for the conversion of oxygenates to olefins
US9518229B2 (en) 2012-07-20 2016-12-13 Inaeris Technologies, Llc Catalysts for thermo-catalytic conversion of biomass, and methods of making and using
JP5883753B2 (ja) * 2012-09-24 2016-03-15 積水化学工業株式会社 塩化ビニルモノマーの製造方法
EP2920112A4 (en) * 2012-11-13 2016-12-07 Basf Se PREPARATION AND USE OF A ZEOLITE MATERIAL IN A PROCESS FOR CONVERTING OXYGENATES IN OLEFINE
US9636668B2 (en) * 2012-11-13 2017-05-02 Basf Se Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins
US9522392B2 (en) * 2013-03-15 2016-12-20 Inaeris Technologies, Llc Phosphorous promotion of zeolite-containing catalysts
WO2014196517A1 (ja) * 2013-06-07 2014-12-11 三井化学株式会社 オレフィンの製造方法、およびこれに用いられる脱水触媒
JP6545172B2 (ja) 2013-12-20 2019-07-17 クラリアント・プロドゥクテ・（ドイチュラント）・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 含酸素化合物をオレフィンに転換するためのリン含有触媒
US10201806B2 (en) 2013-12-20 2019-02-12 Basf Se Catalyst and process for the conversion of oxygenates to olefins
DE102014012920B3 (de) 2014-09-05 2016-01-07 miha bodytec GmbH EMS-Trainingsvorrichtung, sowie EMS- Elektrode, EMS-Kleidungsstück, EMS-Reizerzeugungseinheit, EMS-Signalkabel und EMS-Unterbekleidungsstück dafür und Verfahren zum Betrieb eines EMS- Trainingsgeräts.
DE102014018607B4 (de) 2014-12-16 2017-02-16 miha bodytec GmbH EMS-Trainingsvorrichtung, sowie Verfahren zum Betrieb einer EMS-Trainingsvorrichtung
DE102014018683B4 (de) 2014-12-18 2017-11-02 miha bodytec GmbH EMS-Reizstromübertragungselement, sowie mit dem EMS-Reizstromübertragungselement ausgestattetes EMS-Kleidungsstück
WO2016107758A1 (en) 2014-12-31 2016-07-07 Total Research & Technology Feluy Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of organic acids
BR112017014234A2 (pt) 2014-12-31 2018-03-06 Ifp Energies Now processo para a preparação olefinas pela desidratação de álcoois com menores efeitos colaterais compreendendo a adição de compostos contendo enxofre
UA123237C2 (uk) * 2016-09-09 2021-03-03 Тотал Ресьоч Е Текнолоджі Фелюі Спосіб дегідратації моноспирту(ів) з використанням модифікованого кристалічного алюмосилікату
CN109704356B (zh) * 2017-10-26 2021-05-11 中国石油化工股份有限公司 Eu-1沸石分子筛的合成方法
KR102023246B1 (ko) * 2017-10-26 2019-09-19 전남대학교산학협력단 세륨산화물이 담지된 fer 제올라이트 촉매를 이용하여 mto 반응에서 선택적으로 c4-c6 올레핀 및 파라핀의 수율을 향상시키는 방법
JP7222743B2 (ja) * 2018-02-14 2023-02-15 三菱ケミカル株式会社 ゼオライト触媒及び該ゼオライト触媒を用いた低級オレフィンの製造方法
US11118050B2 (en) 2018-12-07 2021-09-14 The Goodyear Tire & Rubber Company Functionalized polymer, rubber composition and pneumatic tire
US11117997B2 (en) * 2018-12-07 2021-09-14 The Goodyear Tire & Rubber Company Functionalized polymer, rubber composition and pneumatic tire
CN110882718B (zh) * 2019-12-05 2022-06-28 大连海鑫化工有限公司 金属改性mfi@mfi核壳型分子筛催化剂及其制备
CN111545243A (zh) * 2020-06-02 2020-08-18 贵州理工学院 一种复合光热催化剂及其制备方法和应用
DK181711B1 (en) 2023-03-29 2024-10-28 Topsoe As Process and plant for the conversion of oxygenates to C5+ hydrocarbons boiling in the jet fuel boiling range

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5573990A (en) * 1992-05-03 1996-11-12 Dalian Institute Of Chemical Physics Process for the conversion of methanol to light olefins and catalyst for such process
EP2082802A1 (en) * 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining a catalyst composite
EP2143700A1 (en) * 2008-06-25 2010-01-13 Total Petrochemicals Research Feluy Process to make olefins from oxygenates

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3911041A (en) 1974-09-23 1975-10-07 Mobil Oil Corp Conversion of methanol and dimethyl ether
US3972832A (en) 1974-09-23 1976-08-03 Mobil Oil Corporation Phosphorus-containing zeolite catalyst
US4356338A (en) 1979-07-27 1982-10-26 Mobil Oil Corporation Extending catalyst life by treating with phosphorus and/or steam
US4433189A (en) * 1982-03-18 1984-02-21 Mobil Oil Corporation Catalytic conversion of methanol to light olefins
JPH07106317B2 (ja) * 1987-02-13 1995-11-15 触媒化成工業株式会社 炭化水素油の接触分解用触媒組成物の製造方法
AU652222B2 (en) 1991-03-12 1994-08-18 Mobil Oil Corporation Preparation of cracking catalysts, and cracking process using them
US5231064A (en) 1991-03-12 1993-07-27 Mobil Oil Corp. Cracking catalysts comprising phosphorus and method of preparing and using the same
US5171921A (en) * 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins
US6797851B2 (en) 2001-08-30 2004-09-28 Exxonmobil Chemical Patents Inc. Two catalyst process for making olefin
US6644015B2 (en) * 2001-10-29 2003-11-11 Hmx, Inc. Turbojet with precompressor injected oxidizer
US6872680B2 (en) * 2002-03-20 2005-03-29 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
EP1396481A1 (en) 2002-08-14 2004-03-10 ATOFINA Research Production of olefins
EP1508555A1 (en) 2003-08-19 2005-02-23 Total Petrochemicals Research Feluy Production of olefins
US7408092B2 (en) 2004-11-12 2008-08-05 Uop Llc Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst
US7662737B2 (en) * 2005-12-22 2010-02-16 Saudi Basic Industries Corporation Bound phosphorus-modified zeolite catalyst, method of preparing and method of using thereof
JP4951263B2 (ja) * 2006-04-05 2012-06-13 出光興産株式会社 オレフィン類の製造方法
JP4904076B2 (ja) * 2006-04-24 2012-03-28 出光興産株式会社 含酸素化合物からのオレフィン類の製造方法
EP2025402A1 (en) 2007-07-31 2009-02-18 Total Petrochemicals Research Feluy Phosphorus modified molecular sieves, their use in conversion of organics to olefins
EP1970351A1 (en) 2007-03-13 2008-09-17 Total Petrochemicals Research Feluy Method of preparing metalloaluminophosphate (Meapo) molecular sieve
EP1970350A1 (en) 2007-03-13 2008-09-17 Total Petrochemicals Research Feluy Metalloaluminophosphate molecular sieves with lamellar crystal morphology and their preparation
EP1970361A1 (en) 2007-03-13 2008-09-17 Total Petrochemicals Research Feluy MTO process based on MeAPO molecular sieves combined with an OCP process to make olefins
EP2027918A1 (en) 2007-07-31 2009-02-25 Total Petrochemicals Research Feluy Mixtures of molecular sieves comprising MeAPO, their use in conversion of organics to olefins
MX2010008723A (es) 2008-02-07 2010-11-30 Total Petrochemicals Res Feluy Deshidratacion de alcoholes en silicatos cristalinos.
MX2010008722A (es) 2008-02-07 2010-11-30 Total Petrochemicals Res Feluy Deshidratacion de alcoholes en presencia de un componente inerte.
US20110105815A1 (en) 2008-02-07 2011-05-05 Total Petrochemicals Research Feluy Process to Make Olefins from Ethanol
CN101939276B (zh) 2008-02-07 2013-05-08 道达尔石油化学产品研究弗吕公司 由乙醇制造烯烃的方法
EA020577B1 (ru) * 2008-06-25 2014-12-30 Тотал Ресерч Энд Текнолоджи Фелюи Способ получения олефинов из оксигенатов
US8957272B2 (en) 2008-06-25 2015-02-17 Total Research & Technology Feluy Process to make olefins from oxygenates
WO2010100069A1 (en) * 2009-03-03 2010-09-10 Total Petrochemicals Research Feluy Process to make olefins from organics and paraffins
EP2348004A1 (en) 2010-01-25 2011-07-27 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5573990A (en) * 1992-05-03 1996-11-12 Dalian Institute Of Chemical Physics Process for the conversion of methanol to light olefins and catalyst for such process
EP2082802A1 (en) * 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining a catalyst composite
EP2143700A1 (en) * 2008-06-25 2010-01-13 Total Petrochemicals Research Feluy Process to make olefins from oxygenates

Also Published As

Publication number Publication date
MY159864A (en) 2017-02-15
PL2528881T3 (pl) 2018-04-30
EP2528881B1 (en) 2017-11-15
US20130204061A1 (en) 2013-08-08
US9067199B2 (en) 2015-06-30
AR080012A1 (es) 2012-03-07
US9260356B2 (en) 2016-02-16
EA023291B1 (ru) 2016-05-31
EP2528880A1 (en) 2012-12-05
JP2015034164A (ja) 2015-02-19
JP2013517319A (ja) 2013-05-16
IN2012DN06276A (enExample) 2015-09-25
BR112012018501A8 (pt) 2018-04-03
EA201270686A1 (ru) 2012-12-28
DK2528881T3 (en) 2018-02-26
CA2787548A1 (en) 2011-07-28
PE20130568A1 (es) 2013-04-27
EP2528881A1 (en) 2012-12-05
JP2015211970A (ja) 2015-11-26
US20150251970A1 (en) 2015-09-10
KR101549733B1 (ko) 2015-09-02
KR20120106996A (ko) 2012-09-27
BR112012018501A2 (pt) 2017-11-28
US20130197291A1 (en) 2013-08-01
EP2348004A1 (en) 2011-07-27
US8981173B2 (en) 2015-03-17
CO6571890A2 (es) 2012-11-30
EA201270694A1 (ru) 2012-12-28
JP5833569B2 (ja) 2015-12-16
ES2657429T3 (es) 2018-03-05
CA2787548C (en) 2015-12-29
CN102858718B (zh) 2016-04-06
CN102858718A (zh) 2013-01-02
WO2011089262A1 (en) 2011-07-28
UA104077C2 (ru) 2013-12-25
EP2528880B1 (en) 2016-10-19
CN102822124A (zh) 2012-12-12
EA023019B1 (ru) 2016-04-29
US20150148579A1 (en) 2015-05-28
WO2011089263A1 (en) 2011-07-28

Similar Documents

Publication Publication Date Title
CN102822124B (zh) 制造用于mto工艺的包含磷改性沸石的催化剂的方法
CN103842078B (zh) 制造包括磷改性沸石的催化剂的方法以及所述沸石的用途
CN103842080B (zh) 包括磷改性沸石且部分地具有alpo结构的催化剂
CN103561868B (zh) 用于将含氧化合物转化成烯烃的改进的催化剂
CN103561867B (zh) 制造用于将甲醇转化成烯烃的沸石基催化剂的改进方法
CN101939277A (zh) 醇在结晶硅酸盐上的脱水
TW201318702A (zh) 包括磷改質沸石的觸媒在醇類去水製程中的用途
RU2563649C2 (ru) Способ получения катализатора на основе цеолита для превращения метанола в олефины
KR20250075723A (ko) 촉매 제조 방법
US9120078B2 (en) Process for the preparation of an olefinic product, oxygenate conversion catalyst particles, and process for the manufacutre thereof
SG175965A1 (en) Process for the manufacture of a formulated oxygenate conversion catalyst, formulated oxygenate conversion catalyst and process for the preparation of an olefinic product
WO2010100069A1 (en) Process to make olefins from organics and paraffins

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150617

Termination date: 20190125

CF01 Termination of patent right due to non-payment of annual fee