JP2013505119A5 - - Google Patents
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- JP2013505119A5 JP2013505119A5 JP2012529412A JP2012529412A JP2013505119A5 JP 2013505119 A5 JP2013505119 A5 JP 2013505119A5 JP 2012529412 A JP2012529412 A JP 2012529412A JP 2012529412 A JP2012529412 A JP 2012529412A JP 2013505119 A5 JP2013505119 A5 JP 2013505119A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst composition
- impregnation
- composition according
- elements
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 18
- 239000003054 catalyst Substances 0.000 claims 18
- 239000000203 mixture Substances 0.000 claims 17
- 238000005470 impregnation Methods 0.000 claims 10
- 238000004519 manufacturing process Methods 0.000 claims 9
- 239000000243 solution Substances 0.000 claims 9
- 239000011964 heteropoly acid Substances 0.000 claims 5
- 230000000737 periodic effect Effects 0.000 claims 5
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 229910052750 molybdenum Inorganic materials 0.000 claims 4
- 239000008247 solid mixture Substances 0.000 claims 4
- 229910052721 tungsten Inorganic materials 0.000 claims 4
- 229910052720 vanadium Inorganic materials 0.000 claims 4
- 238000001354 calcination Methods 0.000 claims 3
- 150000001768 cations Chemical class 0.000 claims 3
- 229910052804 chromium Inorganic materials 0.000 claims 3
- 229910052802 copper Inorganic materials 0.000 claims 3
- 229910052733 gallium Inorganic materials 0.000 claims 3
- 229910052738 indium Inorganic materials 0.000 claims 3
- 229910052742 iron Inorganic materials 0.000 claims 3
- 229910052745 lead Inorganic materials 0.000 claims 3
- 229910052748 manganese Inorganic materials 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 229910052759 nickel Inorganic materials 0.000 claims 3
- 229910052758 niobium Inorganic materials 0.000 claims 3
- 229910052715 tantalum Inorganic materials 0.000 claims 3
- 229910052716 thallium Inorganic materials 0.000 claims 3
- 229910052718 tin Inorganic materials 0.000 claims 3
- 229910052719 titanium Inorganic materials 0.000 claims 3
- 239000010936 titanium Substances 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- 229910052726 zirconium Inorganic materials 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 230000018044 dehydration Effects 0.000 claims 2
- 238000006297 dehydration reaction Methods 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 235000011187 glycerol Nutrition 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 239000011261 inert gas Substances 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- -1 alkali metal cation Chemical class 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 239000002243 precursor Substances 0.000 claims 1
- 239000012266 salt solution Substances 0.000 claims 1
- CGFYHILWFSGVJS-UHFFFAOYSA-N silicic acid;trioxotungsten Chemical compound O[Si](O)(O)O.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 CGFYHILWFSGVJS-UHFFFAOYSA-N 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2009/067115 WO2011033689A1 (en) | 2009-09-18 | 2009-09-18 | Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012202968A Division JP2013040179A (ja) | 2012-09-14 | 2012-09-14 | グリセリンの脱水反応によってアクロレインおよび／またはアクリル酸を製造するための触媒および方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013505119A JP2013505119A (ja) | 2013-02-14 |
| JP2013505119A5 true JP2013505119A5 (enExample) | 2014-04-24 |
| JP5784609B2 JP5784609B2 (ja) | 2015-09-24 |
Family
ID=42173600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012529412A Active JP5784609B2 (ja) | 2009-09-18 | 2009-09-18 | グリセリンの脱水反応によってアクロレインおよび／またはアクリル酸を製造するための触媒および方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US20130053595A1 (enExample) |
| EP (2) | EP2695672B1 (enExample) |
| JP (1) | JP5784609B2 (enExample) |
| KR (2) | KR101399376B1 (enExample) |
| CN (1) | CN102655931A (enExample) |
| BR (2) | BR112012006076A2 (enExample) |
| IN (1) | IN2012DN02381A (enExample) |
| SG (1) | SG179188A1 (enExample) |
| WO (1) | WO2011033689A1 (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013008279A1 (en) * | 2011-07-14 | 2013-01-17 | Nippon Kayaku Kabushiki Kaisha | Process for preparing catalyst used in production of acrolein and/or acrylic acid and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin |
| JPWO2013018752A1 (ja) * | 2011-07-29 | 2015-03-05 | 日本化薬株式会社 | グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造法 |
| WO2013017904A1 (en) * | 2011-07-29 | 2013-02-07 | Arkema France | Improved process of dehydration reactions |
| EP2762464B1 (en) | 2011-09-29 | 2017-11-22 | Nippon Shokubai Co., Ltd. | Method for producing acrolein, acrylic acid, and derivative thereof |
| JP2013075842A (ja) * | 2011-09-29 | 2013-04-25 | Nippon Shokubai Co Ltd | アクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法 |
| WO2013056268A2 (en) * | 2011-10-06 | 2013-04-18 | Celanese International Corporation | Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol |
| WO2013084258A1 (en) * | 2011-12-06 | 2013-06-13 | Nippon Kayaku Kabushiki Kaisha | Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst |
| IN2014DN07484A (enExample) * | 2012-03-07 | 2015-04-24 | Myriant Corp | |
| FR2989684B1 (fr) | 2012-04-18 | 2014-10-31 | Arkema France | Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol |
| FR2997398B1 (fr) * | 2012-10-30 | 2014-11-21 | Adisseo France Sas | Procede de preparation de l’acroleine a partir de glycerol |
| KR101616528B1 (ko) | 2013-07-16 | 2016-04-28 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법 |
| KR101606191B1 (ko) | 2013-09-30 | 2016-03-24 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법 |
| WO2015046716A1 (ko) * | 2013-09-30 | 2015-04-02 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법 |
| KR20150055402A (ko) | 2013-11-13 | 2015-05-21 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매의 제조 방법 및 아크롤레인의 제조 방법 |
| KR101629003B1 (ko) | 2013-11-18 | 2016-06-09 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법 |
| FR3017617B1 (fr) | 2014-02-19 | 2016-02-12 | Arkema France | Procede de production d'acide acrylique bio-source |
| US9796648B2 (en) | 2014-05-02 | 2017-10-24 | University Of Tennessee Research Foundation | Glycerol dehydration methods and products thereof |
| WO2016026763A1 (en) | 2014-08-18 | 2016-02-25 | Basf Se | Process for preparing acrylic acid using a heterogeneous alumina catalyst |
| CN104892382B (zh) * | 2015-05-28 | 2017-08-11 | 珠海凯美科技有限公司 | 甘油液相氧化制备丙烯醛的方法 |
| KR102052708B1 (ko) | 2015-12-22 | 2019-12-09 | 주식회사 엘지화학 | 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법 |
| WO2017111392A1 (ko) * | 2015-12-22 | 2017-06-29 | 주식회사 엘지화학 | 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법 |
| WO2017111391A1 (ko) * | 2015-12-23 | 2017-06-29 | 주식회사 엘지화학 | 글리세린으로부터 아크릴산의 제조방법 |
| KR102044428B1 (ko) * | 2015-12-23 | 2019-12-02 | 주식회사 엘지화학 | 글리세린으로부터 아크릴산의 제조방법 |
| KR102164613B1 (ko) * | 2016-03-28 | 2020-10-12 | 주식회사 엘지화학 | 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법 |
| EP3738670A4 (en) * | 2018-01-12 | 2021-10-06 | Sekisui Chemical Co., Ltd. | CATALYST AND METHOD FOR MANUFACTURING THEREOF AND METHOD FOR MANUFACTURING A SERVICE CONNECTION USING THE SAID CATALYST |
| CN109433266A (zh) * | 2018-11-29 | 2019-03-08 | 东北师范大学 | 赖氨酸修饰的三中心POMs催化氧化甘油制备乳酸的技术 |
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| CN1301152C (zh) * | 2004-06-04 | 2007-02-21 | 南京工业大学 | 一种用于乙酸和正丁醇液相酯化反应的脱铝usy沸石负载杂多酸盐催化剂的制备方法 |
| FR2882053B1 (fr) * | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acrolene |
| FR2882052B1 (fr) | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acroleine |
| FR2884818B1 (fr) | 2005-04-25 | 2007-07-13 | Arkema Sa | Procede de preparation d'acide acrylique a partir de glycerol |
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| CN100528349C (zh) * | 2005-12-21 | 2009-08-19 | 中国科学院山西煤炭化学研究所 | 二甲醚氧化合成甲缩醛的催化剂及制法和应用 |
| JP2008088149A (ja) * | 2006-01-04 | 2008-04-17 | Nippon Shokubai Co Ltd | アクロレイン製造用触媒及びそれを用いたアクロレイン製造方法 |
| FR2897059B1 (fr) | 2006-02-07 | 2008-04-18 | Arkema Sa | Procede de preparation d'acide acrylique |
| FR2897058B1 (fr) | 2006-02-07 | 2008-04-18 | Arkema Sa | Procede de preparation d'acroleine |
| JP5372769B2 (ja) | 2006-11-28 | 2013-12-18 | シーエルエス セラピューティック リミティド | 組織の細胞外間隙においてデオキシリボ核酸の量が増量することに関連するヒトの病気の治療方法及び該方法を実施するための医薬製剤 |
| FR2909999B1 (fr) | 2006-12-19 | 2009-04-03 | Arkema France | Procede de preparation d'acide acrylique a partir de glycerol |
| DE102007004350A1 (de) * | 2007-01-29 | 2008-07-31 | Evonik Degussa Gmbh | Verfahren zur Regenerierung eines Katalysators |
| FR2912742B1 (fr) | 2007-02-16 | 2010-03-05 | Arkema France | Procede de synthese d'acrylonitrile a partir de glycerol |
| US20090054538A1 (en) | 2007-08-24 | 2009-02-26 | Peterson Thomas H | Chemical production processes, systems, and catalyst compositions |
| WO2009127889A1 (en) | 2008-04-16 | 2009-10-22 | Arkema France | Process for manufacturing acrolein from glycerol |
| EP2275204A4 (en) * | 2008-04-16 | 2011-09-28 | Nippon Kayaku Kk | CATALYST FOR THE PREPARATION OF ACROLEINE AND ACRYLIC ACID BY GLYCERINE DEHYDRATION AND METHOD OF PREPARATION THEREOF |
| EP2488298A4 (en) * | 2009-10-15 | 2013-06-19 | Nippon Kayaku Kk | PROCESS FOR PREPARING A CATALYST FOR USE IN THE PREPARATION OF UNSATURATED ALDEHYDE AND / OR UNSATURATED CARBOXYLIC ACID BY DEHYDRATING THE REACTION OF GLYCERIN AND THE CATALYZER OBTAINED THEREON |
-
2009
- 2009-09-18 WO PCT/JP2009/067115 patent/WO2011033689A1/en not_active Ceased
- 2009-09-18 BR BR112012006076-7A patent/BR112012006076A2/pt not_active Application Discontinuation
- 2009-09-18 KR KR1020127008519A patent/KR101399376B1/ko not_active Expired - Fee Related
- 2009-09-18 JP JP2012529412A patent/JP5784609B2/ja active Active
- 2009-09-18 BR BR122013017195-9A patent/BR122013017195A2/pt not_active Application Discontinuation
- 2009-09-18 IN IN2381DEN2012 patent/IN2012DN02381A/en unknown
- 2009-09-18 US US13/496,339 patent/US20130053595A1/en not_active Abandoned
- 2009-09-18 KR KR1020137027958A patent/KR20130128478A/ko not_active Abandoned
- 2009-09-18 CN CN2009801625040A patent/CN102655931A/zh active Pending
- 2009-09-18 SG SG2012018800A patent/SG179188A1/en unknown
- 2009-09-18 EP EP13191431.9A patent/EP2695672B1/en active Active
- 2009-09-18 EP EP09801291A patent/EP2477736A1/en not_active Withdrawn
-
2014
- 2014-09-19 US US14/491,433 patent/US9162954B2/en active Active
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