GB1025679A - The preparation of organic compounds containing a carbonyl group and compositions for use therein - Google Patents

The preparation of organic compounds containing a carbonyl group and compositions for use therein

Info

Publication number
GB1025679A
GB1025679A GB4909862A GB4909862A GB1025679A GB 1025679 A GB1025679 A GB 1025679A GB 4909862 A GB4909862 A GB 4909862A GB 4909862 A GB4909862 A GB 4909862A GB 1025679 A GB1025679 A GB 1025679A
Authority
GB
United Kingdom
Prior art keywords
acid
component
compounds containing
moo3
oxidized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4909862A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1025679A publication Critical patent/GB1025679A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/36—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in compounds containing six-membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Olefins are converted to carbonyl compounds containing the same number of C atoms by contacting, in the liquid or vapour phase, optionally with oxygen, at 25 DEG to 170 DEG C., 1 to 100 ats. optionally diluted with steam, with a contact agent comprising component (1) which is from (100-1 x 10-5) % to 97% of MoO3 or a heteropoly-acid or a salt thereof and from 1 x 10-5% to 3% of component (2) which is Pt or Pd metal or a compound of Pt or Pd comprising at least 1% of component (1), at least 1 x 10-5% of component (2) and a support up to 100%. Ethylene is oxidized to acetaldehyde, styrene to acetophenone, propylene to acrolein or acetone. Other starting materials specified butene to dodecene, buta and pentadienes, cyclopentene and cyclohexene.ALSO:Olefines are oxidized to carbonyl compounds in the presence of Pt or Pd metal or a compound thereof and MoO3 or a heteropolyacid or salt, if desired supported on a carrier. The heteropolyacid acid may be a phospho-, tungsto- or silico-molybdic acid a mixed hetero acid e.g. silicomolybdo anadic acid, or the co-ordinated atom may be Ti, Ge, Cr, Sn and B. Pumice, Kieselguhr ZrO2, ThO2, clays. Al2O3, TiO2 or SiO2 may be used as carriers. The surface area of such carriers is preferably 8-200 sq. m/gm.
GB4909862A 1961-12-29 1962-12-31 The preparation of organic compounds containing a carbonyl group and compositions for use therein Expired GB1025679A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US16307961A 1961-12-29 1961-12-29

Publications (1)

Publication Number Publication Date
GB1025679A true GB1025679A (en) 1966-04-14

Family

ID=22588396

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4909862A Expired GB1025679A (en) 1961-12-29 1962-12-31 The preparation of organic compounds containing a carbonyl group and compositions for use therein

Country Status (1)

Country Link
GB (1) GB1025679A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4386217A (en) 1981-05-21 1983-05-31 E. I. Du Pont De Nemours And Company Oxidative alkoxycarbonylation of olefins with palladium/heteropoly acid catalyst systems
WO1994022803A1 (en) * 1993-04-06 1994-10-13 Showa Denko K.K. Process for producing acetic acid
EP1157739A1 (en) * 1999-02-26 2001-11-28 Showa Denko Kabushiki Kaisha Catalyst for producing acetic acid, method for preparing the same and method for producing acetic acid using the same
EP1226868A1 (en) * 1999-10-05 2002-07-31 Showa Denko K.K. Process for producing alkyd resin
US6706919B1 (en) 1999-10-05 2004-03-16 Showa Denko K. K. Catalyst for use in producing acetic acid, process for producing the catalyst, and process for producing acetic acid using the catalyst
WO2011033689A1 (en) 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4386217A (en) 1981-05-21 1983-05-31 E. I. Du Pont De Nemours And Company Oxidative alkoxycarbonylation of olefins with palladium/heteropoly acid catalyst systems
WO1994022803A1 (en) * 1993-04-06 1994-10-13 Showa Denko K.K. Process for producing acetic acid
EP0620205A1 (en) * 1993-04-06 1994-10-19 Showa Denko Kabushiki Kaisha Process for producing acetic acid
US5405996A (en) * 1993-04-06 1995-04-11 Showa Denko K.K. Process for producing acetic acid
AU673905B2 (en) * 1993-04-06 1996-11-28 Showa Denko Kabushiki Kaisha Process for producing acetic acid
EP1157739A4 (en) * 1999-02-26 2002-11-06 Showa Denko Kk Catalyst for producing acetic acid, method for preparing the same and method for producing acetic acid using the same
EP1157739A1 (en) * 1999-02-26 2001-11-28 Showa Denko Kabushiki Kaisha Catalyst for producing acetic acid, method for preparing the same and method for producing acetic acid using the same
EP1226868A1 (en) * 1999-10-05 2002-07-31 Showa Denko K.K. Process for producing alkyd resin
EP1226868A4 (en) * 1999-10-05 2003-05-14 Showa Denko Kk Process for producing alkyd resin
US6706919B1 (en) 1999-10-05 2004-03-16 Showa Denko K. K. Catalyst for use in producing acetic acid, process for producing the catalyst, and process for producing acetic acid using the catalyst
WO2011033689A1 (en) 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
EP2695672A3 (en) * 2009-09-18 2014-04-30 Nippon Kayaku Kabushiki Kaisha Process for preparing acrolein by dehydration of glycerin in the presence of a catalyst
US9162954B2 (en) 2009-09-18 2015-10-20 Arkema France Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin

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